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1. 发明授权

US08058466B2 Method for producing 3-pentenenitrile by means of the hydrocyanation of 1,3-butadiene 有权
标题翻译：通过1,3-丁二烯氢氰化生产3-戊烯腈的方法
公开(公告)号：US08058466B2
公开(公告)日：2011-11-15
申请号：US12376731
申请日：2007-08-01
申请人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Hermann Luyken , Peter Pfab , Jens Scheidel , Andrea Haunert , Thomas Genger
发明人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Hermann Luyken , Peter Pfab , Jens Scheidel , Andrea Haunert , Thomas Genger
IPC分类号： C07C253/10
CPC分类号： C07C253/10 , C07C255/07
摘要： An process for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene, in which the process yield with regard to recycled 1,3-butadiene is maximized.
摘要翻译：通过氢化1,3-丁二烯制备3-戊烯腈的方法，其中关于回收的1,3-丁二烯的方法产率最大化。

2. 发明授权

US07705171B2 Process for producing nickel(0)-phosphorus ligand complexes 有权
标题翻译：制备镍（0） - 磷配体络合物的方法
公开(公告)号：US07705171B2
公开(公告)日：2010-04-27
申请号：US12279795
申请日：2007-02-13
申请人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Peter Pfab , Hermann Luyken , Jens Scheidel
发明人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Peter Pfab , Hermann Luyken , Jens Scheidel
IPC分类号： C07F15/04
CPC分类号： B01J31/1845 , B01J31/24 , B01J2231/32 , B01J2531/847
摘要： A process for preparing nickel(0)-phosphorus ligand complexes comprising at least one nickel(0) central atom and at least one phosphorus ligand by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, wherein a) the molar reducing agent:nickel(II) compound ratio in the reaction is from 1:1 to 1000:1, calculated as the molar ratio of the redox equivalents, b) the molar phosphorus ligand:nickel(II) compound ratio in the reaction is not more than 30:1, calculated as the molar P atoms:Ni atoms ratio, c) the nickel(0) content in the resulting reaction mixture is not more than 1.3% by weight and d) the resulting reaction mixture is extracted by adding at least one dinitrile and at least one hydrocarbon to form at least two immiscible phases.
摘要翻译：一种通过在配体存在下使镍（II）化合物与还原剂反应而制备包含至少一个镍（O）中心原子和至少一个磷配体的镍（0） - 磷配体络合物的方法，得到反应混合物，其中a）摩尔还原剂：反应中的镍（II）化合物比例为1:1至1000:1，以氧化还原当量的摩尔比计算，b）磷配体：镍（II）反应中的化合物比例不超过30:1，以P原子摩尔数计算：Ni原子比，c）所得反应混合物中的镍（0）含量不超过1.3重量％，d）所得的通过加入至少一种二腈和至少一种烃以形成至少两个不混溶的相来萃取反应混合物。

3. 发明申请

US20090270645A1 METHOD FOR THE SEPARATION OF NICKEL(0) COMPLEXES AND PHOSPHOROUS-CONTAINING LIGANDS FROM NITRILE MIXTURES 审中-公开
标题翻译：从镍混合物中分离镍（0）复合物和含磷的配体的方法
公开(公告)号：US20090270645A1
公开(公告)日：2009-10-29
申请号：US12296038
申请日：2007-03-28
申请人： Gerd Haderlein , Tobias Aechtner , Michael Bartsch , Hermann Luyken , Peter Pfab , Jens Scheidel , Andreas Leitner
发明人： Gerd Haderlein , Tobias Aechtner , Michael Bartsch , Hermann Luyken , Peter Pfab , Jens Scheidel , Andreas Leitner
IPC分类号： C07F9/28 , C07F9/06
CPC分类号： B01J31/403 , B01D11/0426 , B01D11/0457 , B01J31/1845 , B01J31/185 , B01J31/1865 , B01J31/24 , B01J31/4053 , C07C253/34 , C07D333/48 , Y02P20/584 , C07C255/09
摘要： A process for extractively removing nickel(0) complexes having phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the nitrile-containing solution into two phases being effected, by feeding at least one polar additive to the hydrocyanation effluent (feedstream) and/or to the extraction stage.
摘要翻译：一种从不饱和单腈的氢氰化反应流出物中通过烃萃取将具有磷配体的镍（0）络合物从碳氢化合物萃取到二腈的方法，将烃和含腈溶液相分离成两相，即通过将至少一种极性添加剂进料到氢化氰化流出物（进料流）和/或提取阶段来实现。

4. 发明申请

US20090247779A1 METHOD FOR PRODUCING 3-PENTENENITRILE BY MEANS OF THE HYDROCYANATION OF 1,3-BUTADIENE 有权
公开(公告)号：US20090247779A1
公开(公告)日：2009-10-01
申请号：US12376731
申请日：2007-08-01
申请人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Hermann Luyken , Peter Pfab , Jens Scheidel , Andrea Haunert , Thomas Genger
发明人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Hermann Luyken , Peter Pfab , Jens Scheidel , Andrea Haunert , Thomas Genger
IPC分类号： C07C253/10
CPC分类号： C07C253/10 , C07C255/07
摘要： A method for producing 3-pentenenitrile by means of the hydrocyanation of 1,3-butadiene, which comprises the following process steps: (b′) distillation of 1,3-butadiene comprising water, 1- and 2-butenes and a stabilizer in a distillation apparatus K4 to obtain a stream 15 as the bottom product, which comprises dried 1,3-butadiene, 1- and 2-butenes and the stabilizer, and a stream 16 as the top product, which comprises an azeotropic 1,3-butadiene/water mixture, condensation of the stream 16 in a condenser W, transfer of the resulting condensate (stream 17) into a phase separation apparatus, recycling of the upper liquid phase (stream 18) consisting of 1,3-butadiene as reflux to the column K4, and discharge of the lower liquid aqueous phase (stream 19), (a) reaction of stream 15 in a reactor R1 with hydrogen cyanide over at least one catalyst (stream 6d) to obtain a stream 1 which comprises 3-pentenenitrile, 2-methyl-3-butenenitrile, the at least one catalyst, unconverted 1,3-butadiene, and 1- and 2-butenes, with or without residues of unconverted hydrogen cyanide, (b) distillation of stream 1 in a distillation apparatus K1 to obtain a stream 2 as the top product, which comprises the predominant portion of the 1,3-butadiene from stream 1, and to obtain a stream 3 as the bottom product, which comprises 3-pentenenitrile, the at least one catalyst, 2-methyl-3-butenenitrile, 1- and 2-butenes and the remaining proportion of the 1,3-butadiene from stream 1 which has not been removed in stream 2, (c) distillation of stream 3 in a distillation apparatus K2 to obtain a stream 5 at a side draw of the column, which 3-pentenenitrile and 2-methyl-3-butenenitrile, a stream 6 as the bottom product, which comprises the at least one catalyst, and a stream 4 as the top product, (d) compression of stream 4 in the compressor V1, discharge of a gaseous substream 4b which comprises 1- and 2-butenes, transfer of the compressed stream 4a into the condenser W1, combined cond. With stream 2 from b) in combined condensation of this stream 2 from b) and transfer of the condensate as stream 9, partly as reflux to the column K1 (stream 9b), partly as return stream into the reactor R1 (stream 9a), and (e) distillative separation of stream 5 to obtain 3-pentenenitrile and 2-methyl-3-butenenitrile.

5. 发明申请

US20090054671A1 PROCESS FOR PRODUCING NICKEL(0)-PHOSPHORUS LIGAND COMPLEXES 有权
标题翻译：生产镍（0） - 磷配体复合物的方法
公开(公告)号：US20090054671A1
公开(公告)日：2009-02-26
申请号：US12279795
申请日：2007-02-13
申请人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Peter Pfab , Hermann Luyken , Jens Scheidel
发明人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Peter Pfab , Hermann Luyken , Jens Scheidel
IPC分类号： C07F15/04
CPC分类号： B01J31/1845 , B01J31/24 , B01J2231/32 , B01J2531/847
摘要： A process for preparing nickel(0)-phosphorus ligand complexes comprising at least one nickel(0) central atom and at least one phosphorus ligand by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, wherein a) the molar reducing agent:nickel(II) compound ratio in the reaction is from 1:1 to 1000:1, calculated as the molar ratio of the redox equivalents, b) the molar phosphorus ligand:nickel(II) compound ratio in the reaction is not more than 30:1, calculated as the molar P atoms:Ni atoms ratio, c) the nickel(0) content in the resulting reaction mixture is not more than 1.3% by weight and d) the resulting reaction mixture is extracted by adding at least one dinitrile and at least one hydrocarbon to form at least two immiscible phases.
摘要翻译：一种通过在配体存在下使镍（II）化合物与还原剂反应而制备包含至少一个镍（O）中心原子和至少一个磷配体的镍（0） - 磷配体络合物的方法，得到反应混合物，其中a）摩尔还原剂：反应中的镍（II）化合物比例为1:1至1000:1，以氧化还原当量的摩尔比计算，b）磷配体：镍（II）反应中的化合物比例不超过30:1，以P原子摩尔数计算：Ni原子比，c）所得反应混合物中的镍（0）含量不超过1.3重量％，d）所得的通过加入至少一种二腈和至少一种烃以形成至少两个不混溶的相来萃取反应混合物。

6. 发明授权

US08410299B2 Method for producing linear pentenenitrile 有权
标题翻译：线性戊烯腈的制备方法
公开(公告)号：US08410299B2
公开(公告)日：2013-04-02
申请号：US13361783
申请日：2012-01-30
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Baβler
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Baβler
IPC分类号： C07C253/30
CPC分类号： C07C253/30 , C07C253/10 , Y02P20/582 , C07C255/07
摘要： A method for producing 3-pentenenitrile is provided that includes: (a) isomerizing an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerization catalyst to form a stream (1), which contains the isomerization catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distilling the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerization catalyst(s); (c) distilling the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2); (d) distilling stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product containing 2-methyl-3-butenenitrile.
摘要翻译：提供了一种制备3-戊烯腈的方法，其包括：（a）在至少一种溶解或分散的异构化催化剂上使含有2-甲基-3-丁烯腈的流出物异构化以形成含有异构化催化剂（ s），2-甲基-3-丁烯腈，3-戊烯腈和（Z）-2-甲基-2-丁烯腈; （b）蒸馏物流（1）以获得作为塔顶产物的物流（2），其含有2-甲基-3-丁烯腈，3-戊烯腈和（Z）-2-甲基-2-丁烯腈和流（ 3）作为含有异构化催化剂的底部产物; （c）与料流（2）相比，蒸馏物流（2）以获得作为塔顶产物的物流（4），其与（2）相比富含（Z）-2-甲基-2-丁烯腈，作为与料流（2）相比富含3-戊烯腈和2-甲基-3-丁烯腈的底部产物; （d）蒸馏物流（5），得到作为底物的物流（6），其含有3-戊烯腈和作为含有2-甲基-3-丁烯腈的头部产物的物流（7）。

7. 发明申请

US20080083607A1 Extraction of Nickel (0) Complexes from Nitrile Mixtures with Reduced Rag Formation 有权
标题翻译：从腈混合物中提取镍（0）配合物，减少碎屑形成
公开(公告)号：US20080083607A1
公开(公告)日：2008-04-10
申请号：US11577231
申请日：2005-10-12
申请人： Petra Deckert , Peter Bassler , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Peter Pfab , Tobias Aechtner , Wolfgang Siegel
发明人： Petra Deckert , Peter Bassler , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Peter Pfab , Tobias Aechtner , Wolfgang Siegel
IPC分类号： B01D11/04
CPC分类号： B01J31/4053 , B01D11/0434 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/403 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C253/32 , Y02P20/584 , C07C255/04
摘要： A process for extractively removing homogeneously dissolved catalysts from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction by means of a hydrocarbon H, which comprises a) adding a nonpolar aprotic liquid L to the reaction effluent to obtain a stream I, and b) extracting the stream I at a temperature T with the hydrocarbon H to obtain a stream II comprising the hydrocarbon H enriched with the catalyst and a stream III having a low catalyst content.
摘要翻译：一种通过烃H提取从不饱和单腈的氢化氰化反应流出物向二腈提取均匀溶解的催化剂的方法，该方法包括：a）向反应流出物中加入非极性非质子液体L以获得流I，和b）用烃H提取温度T下的物流I以获得包含富含催化剂的烃H的流II和具有低催化剂含量的流III。

8. 发明申请

US20120178958A1 METHOD FOR PRODUCING LINEAR PENTENENITRILE 有权
标题翻译：生产线性胆固醇的方法
公开(公告)号：US20120178958A1
公开(公告)日：2012-07-12
申请号：US13361783
申请日：2012-01-30
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Baßler
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Baßler
IPC分类号： C07C253/30
CPC分类号： C07C253/30 , C07C253/10 , Y02P20/582 , C07C255/07
摘要： A method for producing 3-pentenenitrile is provided that includes: (a) isomerizing an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerisation catalyst to form a stream (1), which contains the isomerisation catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distilling the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerisation catalyst(s); (c) distilling the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2); (d) distilling stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product containing 2-methyl-3-butenenitrile.
摘要翻译：提供了一种制备3-戊烯腈的方法，其包括：（a）在至少一种溶解或分散的异构化催化剂上异构化含有2-甲基-3-丁烯腈的流出物流以形成含有异构化催化剂（ s），2-甲基-3-丁烯腈，3-戊烯腈和（Z）-2-甲基-2-丁烯腈; （b）蒸馏物流（1）以获得作为塔顶产物的物流（2），其含有2-甲基-3-丁烯腈，3-戊烯腈和（Z）-2-甲基-2-丁烯腈和流（ 3）作为含有异构化催化剂的底部产物; （c）与料流（2）相比，蒸馏物流（2）以获得作为塔顶产物的物流（4），其与（2）相比富含（Z）-2-甲基-2-丁烯腈，作为与料流（2）相比富含3-戊烯腈和2-甲基-3-丁烯腈的底部产物; （d）蒸馏物流（5），得到作为底物的物流（6），其含有3-戊烯腈和作为含有2-甲基-3-丁烯腈的头部产物的物流（7）。

9. 发明申请

US20080281120A1 Method for Producing Linear Pentenenitrile 审中-公开
标题翻译：生产线性戊烯腈的方法
公开(公告)号：US20080281120A1
公开(公告)日：2008-11-13
申请号：US10586470
申请日：2005-01-27
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Bassler
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Bassler
IPC分类号： C07C255/00
CPC分类号： C07C253/30 , C07C253/10 , Y02P20/582 , C07C255/07
摘要： A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) isomerizing a reactant stream which comprises 2-methyl-3-butenenitrile over at least one dissolved or dispersed isomerization catalyst to give a stream 1 which comprises the at least one isomerization catalyst, 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, (b) distilling stream 1 to obtain a stream 2 as the top product which comprises 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, and a stream 3 as the bottom product which comprises the at least one isomerization catalyst, (c) distilling stream 2 to obtain a stream 4 as the top product which, compared to stream 2, is enriched in (Z)-2-methyl-2-butenenitrile, based on the sum of all pentenenitriles in stream 2, and a stream 5 as the bottom product which, compared to stream 2, is enriched in 3-pentenenitrile and 2-methyl-3-butenenitrile, based on the sum of all pentenenitriles in stream 2, (d) distilling stream 5 to obtain a stream 6 as the bottom product which comprises 3-pentenenitrile and a stream 7 as the top product which comprises 2-methyl-3-butenenitrile.
摘要翻译：描述了制备3-戊烯腈的方法，其特征在于以下方法步骤：（a）在至少一种溶解或分散的异构化催化剂上异构化包含2-甲基-3-丁烯腈的反应物流，得到流1，其包含至少一种异构化催化剂，2-甲基-3-丁烯腈，3-戊烯腈和（Z）-2-甲基-2-丁烯腈，（b）蒸馏物流1，得到作为顶部产物的物流2，其包含2-甲基 -3-丁烯腈，3-戊烯腈和（Z）-2-甲基-2-丁烯腈，以及作为底部产物的料流3，其包含至少一种异构化催化剂，（c）蒸馏物流2以获得物流4，与流2相比，基于流2中的所有五烯丙烯的总和和作为底部产物的流5，与流2相比富含（Z）-2-甲基-2-丁烯腈的顶部产物与流2相比较，富含3-戊烯腈和2-甲基-3-丁烯腈，基于所有pentenenit （d）蒸馏流5以获得作为底部产物的料流6，其包含3-戊烯腈和作为顶部产物的料流7，其包含2-甲基-3-丁烯腈。

10. 发明授权

US07935229B2 Extraction of nickel (0) complexes from nitrile mixtures with reduced rag formation 有权
标题翻译：从腈混合物中提取镍（0）配合物，并减少破布形成
公开(公告)号：US07935229B2
公开(公告)日：2011-05-03
申请号：US11577231
申请日：2005-10-12
申请人： Petra Deckert , Peter Bassler , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Peter Pfab , Tobias Aechtner , Wolfgang Siegel
发明人： Petra Deckert , Peter Bassler , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Peter Pfab , Tobias Aechtner , Wolfgang Siegel
IPC分类号： B01D3/34 , B01D11/04 , B01J31/40 , B01J38/56 , C07C253/32
CPC分类号： B01J31/4053 , B01D11/0434 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/403 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C253/32 , Y02P20/584 , C07C255/04
摘要： A process for extractively removing homogeneously dissolved catalysts from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles with a hydrocarbon H, including performing the steps of a) concentrating the reaction effluent before step b) by distillation at pressures of from 0.1 to 5000 mbar and temperatures of from 10 to 150° C., b) adding a hydrocarbon H to the concentrated reaction effluent to obtain a stream I, and c) feeding stream I, without prior separation of the liquid phases, into an extraction apparatus and extracting it at a temperature T with the hydrocarbon H to obtain a stream II comprising the hydrocarbon H enriched with the catalyst and a stream III having a low catalyst content.
摘要翻译：一种从均匀溶解的催化剂中将不饱和单腈的氢化氰化为碳氢化合物的反应流出物的方法，包括以下步骤：a）在步骤b）之前将反应流出物浓缩至0.1至5000毫巴和10至150℃的温度，b）向浓缩的反应流出物中加入烃H以获得流I，和c）将料流I未经预先分离的液相进入萃取装置并萃取在与烃H的温度T下，获得包含富含催化剂的烃H的流II和具有低催化剂含量的流III。

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