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1. 发明授权

US07189869B2 Method for making polycarbonate 有权
标题翻译：制作聚碳酸酯的方法
公开(公告)号：US07189869B2
公开(公告)日：2007-03-13
申请号：US10979608
申请日：2004-11-01
申请人： Gerardo Hidalgo , Patrick J. McCloskey , Alberto Nisoli , Lina Prada
发明人： Gerardo Hidalgo , Patrick J. McCloskey , Alberto Nisoli , Lina Prada
IPC分类号： C07C69/96
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonates comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate phenol, wherein the separated phenol has a phosphorus concentration of less than or equal to about 3 part per million, based upon the total weight of the phenol separated.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 和纯化副产物流以分离苯酚，其中基于分离的苯酚的总重量，分离的苯酚的磷浓度小于或等于约3ppm。

2. 发明授权

US07183371B2 Method for making polycarbonate 有权
标题翻译：制作聚碳酸酯的方法
公开(公告)号：US07183371B2
公开(公告)日：2007-02-27
申请号：US10979479
申请日：2004-11-01
申请人： Gerardo Hidalgo , Patrick J. McCloskey , Alberto Nisoli , Lina Prada
发明人： Gerardo Hidalgo , Patrick J. McCloskey , Alberto Nisoli , Lina Prada
IPC分类号： C08G64/00
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonate comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate the carbonic acid diester, wherein the separated carbonic acid diester has a phosphorous concentration of less than or equal to about 30 parts per million.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 并纯化副产物流以分离碳酸二酯，其中分离的碳酸二酯的磷浓度小于或等于约30ppm。

3. 发明申请

US20060094854A1 METHOD FOR MAKING POLYCARBONATE 有权
标题翻译：制备聚碳酸酯的方法
公开(公告)号：US20060094854A1
公开(公告)日：2006-05-04
申请号：US10979479
申请日：2004-11-01
申请人： Gerardo Hidalgo , Patrick McCloskey , Alberto Nisoli , Lina Prada
发明人： Gerardo Hidalgo , Patrick McCloskey , Alberto Nisoli , Lina Prada
IPC分类号： C08G64/00 , B01J19/00
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonate comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate the carbonic acid diester, wherein the separated carbonic acid diester has a phosphorous concentration of less than or equal to about 30 parts per million.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 并纯化副产物流以分离碳酸二酯，其中分离的碳酸二酯的磷浓度小于或等于约30ppm。

4. 发明申请

US20060094856A1 Method for making polycarbonate 有权
标题翻译：制作聚碳酸酯的方法
公开(公告)号：US20060094856A1
公开(公告)日：2006-05-04
申请号：US10979608
申请日：2004-11-01
申请人： Gerardo Hidalgo , Patrick McCloskey , Alberto Nisoli , Linda Prada
发明人： Gerardo Hidalgo , Patrick McCloskey , Alberto Nisoli , Linda Prada
IPC分类号： C07C69/96 , C08G64/00
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonates comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate phenol, wherein the separated phenol has a phosphorus concentration of less than or equal to about 3 part per million, based upon the total weight of the phenol separated.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 和纯化副产物流以分离苯酚，其中基于分离的苯酚的总重量，分离的苯酚的磷浓度小于或等于约3ppm。

5. 发明申请

US20060069228A1 Process to make polycarbonate from bismethylsalicylcarbonate (BMSC) 有权
标题翻译：由二甲基水杨酸碳酸酯（BMSC）制备聚碳酸酯的方法
公开(公告)号：US20060069228A1
公开(公告)日：2006-03-30
申请号：US10951574
申请日：2004-09-27
申请人： Patrick McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
发明人： Patrick McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
IPC分类号： B29C47/00 , C08G64/00
CPC分类号： B29C47/76 , B29C47/0009 , C08G64/307
摘要： The present invention relates to a method of preparing polycarbonate comprising the steps of: (i) introducing to an extruder through a feed port a plurality of reaction components comprising a polycarbonate oligomer, an activated carbonate residue, and a transesterification catalyst, wherein the extruder comprises the feed port, a first back vent port, and a polycarbonate exit port, wherein the feed port is located between the first back vent port and the polycarbonate exit port, and wherein the resistance to flow of the reaction components from the feed port to the first back vent port is less than or equal to the resistance to flow of the reaction components from the feed port to the polycarbonate exit port; and (ii) extruding the reaction components at one or more temperatures in a range between 100° C. and 400° C., wherein during the extrusion of the reaction components, activated carbonate residue is removed through the first back vent port, thereby preparing a polycarbonate.
摘要翻译：本发明涉及一种制备聚碳酸酯的方法，包括以下步骤：（i）通过进料口将包含聚碳酸酯低聚物，活性碳酸酯残余物和酯交换催化剂的多个反应组分引入挤出机，其中挤出机包含所述进料口，第一后排气口和聚碳酸酯出口，其中所述进料口位于所述第一后排气口和所述聚碳酸酯出口之间，并且其中所述反应组分从所述进料口流向第一后排气口小于或等于反应组分从进料口到聚碳酸酯出口的流动阻力; 和（ii）在100℃和400℃之间的一个或多个温度下挤出反应组分，其中在反应组分的挤出期间，通过第一后排气口除去活性碳酸盐残余物，由此制备聚碳酸酯。

6. 发明申请

US20050234211A1 Method for preparing a polycarbonate oligomer mixture at low temperature for manufacturing polycarbonate 失效
标题翻译：低温制备聚碳酸酯低聚物混合物制造聚碳酸酯的方法
公开(公告)号：US20050234211A1
公开(公告)日：2005-10-20
申请号：US10830163
申请日：2004-04-21
申请人： Maria Martinez , Alberto Nisoli , Alfredo Carretero , Ganesh Kailasam , David Domingo , Patrick McCloskey
发明人： Maria Martinez , Alberto Nisoli , Alfredo Carretero , Ganesh Kailasam , David Domingo , Patrick McCloskey
IPC分类号： B01J19/18 , B01J19/20 , C08G64/20 , C08G64/30 , C08G64/00
CPC分类号： C08G64/307 , B01J19/18 , B01J19/1806 , B01J19/1887 , B01J19/20 , B01J2219/00031 , B01J2219/0004 , B01J2219/00083 , B01J2219/00094 , B01J2219/00166 , B01J2219/00184 , B01J2219/00186 , C08G64/205
摘要： The present invention provides a method of making polycarbonate oligomers, polycarbonate, molded articles formed from polycarbonate, and an apparatus for making polycarbonate. An oligomer mixture is first prepared by the steps of providing an equilibration system comprising a vessel, a reaction mixture contained within the vessel, and means for mixing the reaction mixture contained within the vessel wherein the reaction mixture comprises a melted activated diaryl carbonate composition, and a catalyst present in sufficient amount to initiate an oligomerization reaction between a dihydroxy composition and the activated diaryl carbonate to form polycarbonate oligomers. The method further includes the steps of introducing a melted dihydroxy composition to the reaction mixture contained within the equilibration system, maintaining the reaction mixture contained within the vessel at an oligomerization temperature, said oligomerization temperature being below the melting point the dihydroxy composition, and sufficiently high to allow formation of a homogeneous melt within the vessel, and continuously drawing off a product stream from the equilibration system, wherein the product stream comprises a polycarbonate oligomer mixture. This polycarbonate oligomer mixture is suitably used as a feed stock for producing polycarbonate in a polycondensation system. The polycarbonate is suitably used for the preparation of molded articles.
摘要翻译：本发明提供一种制备聚碳酸酯低聚物，聚碳酸酯，由聚碳酸酯形成的模制品的方法和用于制备聚碳酸酯的装置。首先通过以下步骤制备低聚物混合物，所述步骤包括提供包含容器，容器内的反应混合物的平衡系统和用于混合包含在容器内的反应混合物的装置，其中反应混合物包含熔融的活化碳酸二芳基酯组合物和存在足够量的催化剂以引发二羟基组合物和活化的碳酸二芳基酯之间的低聚反应以形成聚碳酸酯低聚物。该方法还包括以下步骤：将熔融的二羟基组合物引入平衡系统中包含的反应混合物中，将容器内的反应混合物保持在低聚温度，所述低聚温度低于二羟基组合物的熔点，并且足够高以允许在容器内形成均匀的熔体，并且从平衡系统连续地抽出产物流，其中产物流包含聚碳酸酯低聚物混合物。该聚碳酸酯低聚物混合物适合用作在缩聚体系中制造聚碳酸酯的原料。聚碳酸酯适合用于制备模塑制品。

7. 发明申请

US20050033078A1 Method and apparatus for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates 审中-公开
标题翻译：制备碳酸二烷基酯的方法和装置及其在制备碳酸二芳基酯和聚碳酸酯中的用途
公开(公告)号：US20050033078A1
公开(公告)日：2005-02-10
申请号：US10740578
申请日：2003-12-22
申请人： Daniele Delledonne , Franco Rivetti , Eugene Boden , Ganesh Kailasam , Larry Lewis , Alberto Nisoli , John Ofori , Angel Gonzalez , Ignacio Fernandez
发明人： Daniele Delledonne , Franco Rivetti , Eugene Boden , Ganesh Kailasam , Larry Lewis , Alberto Nisoli , John Ofori , Angel Gonzalez , Ignacio Fernandez
IPC分类号： B01J19/00 , C07B61/00 , C07C68/00 , C07C68/08 , C07C69/96
CPC分类号： B01J19/002 , B01J2219/00006 , B01J2219/00247 , B01J2219/00272 , C07C68/005 , C07C69/96
摘要： Unexpected corrosion of downstream sections of a dialkyl carbonate manufacturing apparatus has been traced to alkyl chloroformate impurities, which slowly decompose to yield hydrochloric acid. An improved process and apparatus for dialkyl carbonate synthesis reduce corrosion by physically removing or chemically decomposing the alkyl chloroformate impurities within the corrosion-resistant upstream sections of the apparatus. The alkyl chloroformate may be decomposed by passing it through a passageway at a temperature of about 30 C to about 130° C. for a time of about 0.5 hour to about 10 hours. The passageway may include one or more holding vessels or a tubular section that promotes plug flow.
摘要翻译：碳酸二烷基酯制造装置的下游部分的意外腐蚀已经被追溯到氯代甲酸烷基酯杂质中，其缓慢分解以产生盐酸。用于碳酸二烷基酯合成的改进方法和装置通过物理去除或化学分解装置的耐腐蚀上游部分中的氯甲酸烷基酯杂质来减少腐蚀。氯甲酸烷基酯可以通过在约30℃至约130℃的温度通过通道约0.5小时至约10小时来分解。通道可以包括一个或多个保持容器或者促进活塞流动的管状部分。

8. 发明授权

US07345187B2 Method and apparatus for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates 有权
标题翻译：制备碳酸二烷基酯的方法和装置及其在制备碳酸二芳基酯和聚碳酸酯中的用途
公开(公告)号：US07345187B2
公开(公告)日：2008-03-18
申请号：US09682286
申请日：2001-08-14
申请人： Eugene Pauling Boden , Ganesh Kailasam , Larry Neil Lewis , Alberto Nisoli , John Yaw Ofori , Angel Sanchez Gonzalez
发明人： Eugene Pauling Boden , Ganesh Kailasam , Larry Neil Lewis , Alberto Nisoli , John Yaw Ofori , Angel Sanchez Gonzalez
IPC分类号： C07C69/96
CPC分类号： B01J19/002 , B01J2219/00006 , B01J2219/00247 , B01J2219/00272 , C07C68/005 , C07C69/96
摘要： Unexpected corrosion of downstream sections of a dialkyl carbonate manufacturing apparatus has been traced to alkyl chloroformate impurities, which slowly decompose to yield hydrochloric acid. An improved process and apparatus for dialkyl carbonate synthesis reduce corrosion by physically removing or chemically decomposing the alkyl chloroformate impurities within the corrosion-resistant upstream sections of the apparatus.
摘要翻译：碳酸二烷基酯制造装置的下游部分的意外腐蚀已经被追溯到氯代甲酸烷基酯杂质中，其缓慢分解以产生盐酸。用于碳酸二烷基酯合成的改进方法和装置通过物理去除或化学分解装置的耐腐蚀上游部分中的氯甲酸烷基酯杂质来减少腐蚀。

9. 发明授权

US07132498B2 Process to make polycarbonate from bismethylsalicylcarbonate (BMSC) 有权
公开(公告)号：US07132498B2
公开(公告)日：2006-11-07
申请号：US10951574
申请日：2004-09-27
申请人： Patrick Joseph McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
发明人： Patrick Joseph McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
IPC分类号： C08G63/00
CPC分类号： B29C47/76 , B29C47/0009 , C08G64/307
摘要： The present invention relates to a method of preparing polycarbonate comprising the steps of: (i) introducing to an extruder through a feed port a plurality of reaction components comprising a polycarbonate oligomer, an activated carbonate residue, and a transesterification catalyst, wherein the extruder comprises the feed port, a first back vent port, and a polycarbonate exit port, wherein the feed port is located between the first back vent port and the polycarbonate exit port, and wherein the resistance to flow of the reaction components from the feed port to the first back vent port is less than or equal to the resistance to flow of the reaction components from the feed port to the polycarbonate exit port; and (ii) extruding the reaction components at one or more temperatures in a range between 100° C. and 400° C., wherein during the extrusion of the reaction components, activated carbonate residue is removed through the first back vent port, thereby preparing a polycarbonate.

10. 发明授权

US07041775B2 Method for preparing a polycarbonate oligomer mixture at low temperature for manufacturing polycarbonate 失效
标题翻译：低温制备聚碳酸酯低聚物混合物制造聚碳酸酯的方法
公开(公告)号：US07041775B2
公开(公告)日：2006-05-09
申请号：US10830163
申请日：2004-04-21
申请人： Maria Tomas Martinez , Alberto Nisoli , Alfredo Lopez Carretero , Ganesh Kailasam , David Domingo , Patrick Joseph McCloskey
发明人： Maria Tomas Martinez , Alberto Nisoli , Alfredo Lopez Carretero , Ganesh Kailasam , David Domingo , Patrick Joseph McCloskey
IPC分类号： C08G64/00
CPC分类号： C08G64/307 , B01J19/18 , B01J19/1806 , B01J19/1887 , B01J19/20 , B01J2219/00031 , B01J2219/0004 , B01J2219/00083 , B01J2219/00094 , B01J2219/00166 , B01J2219/00184 , B01J2219/00186 , C08G64/205
摘要： The present invention provides a method of making polycarbonate oligomers, polycarbonate, molded articles formed from polycarbonate, and an apparatus for making polycarbonate. An oligomer mixture is first prepared by the steps of providing an equilibration system comprising a vessel, a reaction mixture contained within the vessel, and means for mixing the reaction mixture contained within the vessel wherein the reaction mixture comprises a melted activated diaryl carbonate composition, and a catalyst present in sufficient amount to initiate an oligomerization reaction between a dihydroxy composition and the activated diaryl carbonate to form polycarbonate oligomers. The method further includes the steps of introducing a melted dihydroxy composition to the reaction mixture contained within the equilibration system, maintaining the reaction mixture contained within the vessel at an oligomerization temperature, said oligomerization temperature being below the melting point the dihydroxy composition, and sufficiently high to allow formation of a homogeneous melt within the vessel, and continuously drawing off a product stream from the equilibration system, wherein the product stream comprises a polycarbonate oligomer mixture. This polycarbonate oligomer mixture is suitably used as a feed stock for producing polycarbonate in a polycondensation system. The polycarbonate is suitably used for the preparation of molded articles.
摘要翻译：本发明提供一种制备聚碳酸酯低聚物，聚碳酸酯，由聚碳酸酯形成的模制品的方法和用于制备聚碳酸酯的装置。首先通过以下步骤制备低聚物混合物，所述步骤包括提供包含容器，容器内的反应混合物的平衡系统和用于混合包含在容器内的反应混合物的装置，其中反应混合物包含熔融的活化碳酸二芳基酯组合物和存在足够量的催化剂以引发二羟基组合物和活化的碳酸二芳基酯之间的低聚反应以形成聚碳酸酯低聚物。该方法还包括以下步骤：将熔融的二羟基组合物引入平衡系统中包含的反应混合物中，将容器内的反应混合物保持在低聚温度，所述低聚温度低于二羟基组合物的熔点，并且足够高以允许在容器内形成均匀的熔体，并且从平衡系统连续地抽出产物流，其中产物流包含聚碳酸酯低聚物混合物。该聚碳酸酯低聚物混合物适合用作在缩聚体系中制造聚碳酸酯的原料。聚碳酸酯适合用于制备模塑制品。

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