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1. 发明授权

US5929018A Detergent composition comprising a polymeric polycarboxylic compound, a chelant, and an amylase enzyme 失效
标题翻译：包含聚合多元羧酸化合物，螯合剂和淀粉酶的洗涤剂组合物
公开(公告)号：US5929018A
公开(公告)日：1999-07-27
申请号：US913211
申请日：1997-09-10
申请人： Gerard Marcel Baillely , Richard Timothy Hartshorn , Christian Leo Marie Vermote
发明人： Gerard Marcel Baillely , Richard Timothy Hartshorn , Christian Leo Marie Vermote
IPC分类号： C11D3/33 , C11D3/36 , C11D3/37 , C11D3/386 , C11D3/39 , C11D3/10 , C11D3/395
CPC分类号： C11D3/3907 , C11D3/33 , C11D3/361 , C11D3/3761 , C11D3/38609 , C11D3/3942 , C11D3/3917
摘要： There is provided a non-phosphate builder-containing detergent composition formulated with a surfactant, a water-soluble organic polymeric polycarboxylic compound, a chelant, an amylase and a source of alkalinity, wherein (a) said water-soluble organic polymeric polycarboxylic compound is in amount less than 3% by weight, (b) said chelant is in amount from 0.1% to 10% by weight, (c) said amylase is in amount from 0.001% to 5% by weight, and (d) said alkalinity source has the capacity to deliver alkalinity to a wash solution as measured by the alkalinity release test described herein, such that the % weight NaOH equivalent of the composition is greater than 8.0% by weight of the composition. Also provided herein is a method for reducing fabric encrustation which comprises contacting the fabric with an effective amount of an aqueous solution of said detergent composition.
摘要翻译： PCT No.PCT / US96 / 02118 Sec。 371日期：1997年9月10日 102（e）1997年9月10日PCT PCT 1996年2月20日PCT公布。公开号WO96 / 28531 日本1996年9月19日提供了一种用表面活性剂，水溶性有机聚合物多元羧酸化合物，螯合剂，淀粉酶和碱源配制的含磷酸盐助洗剂的洗涤剂组合物，其中（a）所述水溶性有机聚合物多元羧酸化合物的量小于3重量％，（b）所述螯合剂的量为0.1重量％至10重量％，（c）所述淀粉酶的量为0.001重量％至5重量％，和 d）所述碱度源具有通过本文所述的碱度释放试验测量的将碱度输送到洗涤溶液的能力，使得组合物的重量％NaOH当量大于组合物的8.0重量％。本文还提供了一种减少织物结垢的方法，其包括使织物与有效量的所述洗涤剂组合物的水溶液接触。

2. 发明授权

US5925609A Detergent composition comprising source of hydrogen peroxide and protease enzyme 失效
标题翻译：包含过氧化氢源和蛋白酶的洗涤剂组合物
公开(公告)号：US5925609A
公开(公告)日：1999-07-20
申请号：US913212
申请日：1997-09-10
申请人： Gerard Marcel Baillely , Richard Timothy Hartshorn , Christian Leo Marie Vermote
发明人： Gerard Marcel Baillely , Richard Timothy Hartshorn , Christian Leo Marie Vermote
IPC分类号： C11D3/36 , C11D3/39 , C11D3/386 , C11D3/37 , C11D3/395
CPC分类号： C11D3/364 , C11D3/361 , C11D3/391 , C11D3/3917
摘要： A non-phosphate builder-containing detergent composition comprising a surfactant, and a) at least 0.5% by weight of a source of hydrogen peroxide; b) from 0.01% to 10% by weight of an organic peroxyacid bleach precursor; c) from 0.001% to 5% by weight of a proteolytic enzyme; d) an alkalinity source having the capacity to deliver alkalinity to a wash solution as measured by the alkalinity release test described herein, such that the % weight of NaOH equivalent of the composition is greater than 10.6% by weight of the composition, and wherein the detergent composition has a Hydrogen peroxide Precursor Proteolytic enzyme (HPP) Index of at least 0.35 as defined by the formula: ##EQU1## wherein the % weight of proteolytic enzyme in the formulation is based on an enzyme activity of 13 knpu/g of the enzyme particle, and wherein the % AvO.sub.2 is the total amount of available oxygen present in the composition is provided. The detergent composition optionally comprises a water-soluble organic polymeric polycarboxylic compound, which when present, is present in the detergent composition in an amount wherein the weight ratio of water-soluble organic polymeric polycarboxylic compound to the alkalinity source is 0.0732:1 or less.
摘要翻译： PCT No.PCT / US96 / 02337 Sec。 371日期：1997年9月10日 102（e）1997年9月10日PCT PCT 1996年2月20日PCT公布。公开号WO96 / 28534 日期1996年9月19日含有表面活性剂的非磷酸助洗剂洗涤剂组合物，和a）至少0.5重量％的过氧化氢源; b）0.01重量％至10重量％的有机过氧酸漂白剂前体; c）0.001％至5％重量的蛋白水解酶; d）碱度源，其具有通过本文所述的碱度释放测试测量的将碱度输送到洗涤溶液的能力，使得组合物的NaOH当量的重量％大于组合物的10.6重量％，并且其中洗涤剂组合物具有如下式所定义的至少0.35的过氧化氢前体蛋白水解酶（HPP）指数：其中制剂中蛋白水解酶的重量百分比是基于酶活性为13knp / g的酶颗粒，以及其中％AvO2是提供组合物中存在的可用氧的总量。洗涤剂组合物任选地包含水溶性有机聚合多元羧酸化合物，其当存在时，以水溶性有机聚合物多元羧酸化合物与碱度源的重量比为0.0732:1或更低的量存在于洗涤剂组合物中。

3. 发明授权

US5686014A Bleach compositions comprising manganese-containing bleach catalysts 失效
标题翻译：漂白组合物包含含锰漂白催化剂
公开(公告)号：US5686014A
公开(公告)日：1997-11-11
申请号：US410622
申请日：1995-03-24
申请人： Gerard Marcel Abel Baillely , Richard Timothy Hartshorn , Thomas Edward Cook , Alistair John Pretty , Christian Leo Marie Vermote
发明人： Gerard Marcel Abel Baillely , Richard Timothy Hartshorn , Thomas Edward Cook , Alistair John Pretty , Christian Leo Marie Vermote
IPC分类号： C11D3/39 , C11D11/00 , D06L3/02 , C01B13/00
CPC分类号： C11D3/3932 , C11D11/0017 , D06L3/023
摘要： Bleaching compositions useful for laundering fabrics comprising a manganese bleach catalyst at a level below about 40 ppm manganese sourced by the catalyst. Also, acid wash methods useful for reducing the bleach catalyst carry-over from laundry bleach compositions containing metal-containing bleach catalysts, said methods comprising contacting fabrics impregnated with metal-containing bleach catalysts with an aqueous acidic solution having a pH below about 4.0.
摘要翻译：用于洗涤织物的漂白组合物，其包含低于约40ppm锰的催化剂的锰漂白催化剂。另外，酸洗方法可用于减少含有含金属漂白催化剂的洗衣漂白剂组合物中的漂白催化剂残留物，所述方法包括将浸渍有含金属漂白催化剂的织物与pH低于约4.0的酸性水溶液接触。

4. 发明授权

US5773400A Nil-phosphate granular detergent compositions which contain percarbonate and sulfate particles 失效
标题翻译：含有过碳酸盐和硫酸盐颗粒的无磷酸盐颗粒洗涤剂组合物
公开(公告)号：US5773400A
公开(公告)日：1998-06-30
申请号：US648112
申请日：1996-05-21
申请人： Gerard Marcel Baillely , Richard Timothy Hartshorn
发明人： Gerard Marcel Baillely , Richard Timothy Hartshorn
IPC分类号： C11D3/02 , C11D3/08 , C11D3/10 , C11D3/12 , C11D3/39 , C11D3/04 , C11D3/395
CPC分类号： C11D3/046 , C11D3/08 , C11D3/10 , C11D3/128 , C11D3/3942
摘要： Stable granular detergent compositions with good flow and dispensing properties are prepared using percarbonate bleach and selected sulfate salts. Thus, particles comprising builders and surfactants are prepared separately from percarbonate bleach particles of defined particle size. Water-soluble sulfate particles having a defined size range and no more than 40 ppm iron and no more than 5 ppm copper are used in the compositions. The specified moisture content of the ingredients and overall compositions improves stability and flow/dispensing properties.
摘要翻译： PCT No.PCT / US94 / 13700 Sec。 371日期：1996年5月21日 102（e）日期1996年5月21日PCT 1994年12月1日PCT PCT。 WO95 / 16018 PCT公开号日期1996年6月15日使用过碳酸盐漂白剂和选择的硫酸盐制备具有良好流动性和分散性的稳定的颗粒状洗涤剂组合物。因此，包含助洗剂和表面活性剂的颗粒与规定粒径的过碳酸盐漂白剂颗粒分开制备。在组合物中使用具有规定尺寸范围且不超过40ppm铁和不超过5ppm铜的水溶性硫酸盐颗粒。成分和整体组合物的指定含水量提高了稳定性和流动/分配性能。

5. 发明授权

US06673766B1 Solid detergent compositions containing mixtures of surfactant/builder particles 有权
标题翻译：含有表面活性剂/助洗剂颗粒混合物的固体洗涤剂组合物
公开(公告)号：US06673766B1
公开(公告)日：2004-01-06
申请号：US09787448
申请日：2001-07-11
申请人： Richard Timothy Hartshorn , Zayeed Alam , Sylvestre Canceil , Alan Thomas Brooker , Gerard Marcel Baillely , Kevin Norwood , David Scott Bohlen
发明人： Richard Timothy Hartshorn , Zayeed Alam , Sylvestre Canceil , Alan Thomas Brooker , Gerard Marcel Baillely , Kevin Norwood , David Scott Bohlen
IPC分类号： C11D122
CPC分类号： C11D3/126 , C11D1/22 , C11D3/08 , C11D17/0073 , C11D17/06
摘要： The invention relates to detergent compositions comprising from 10-60 wt % of a surfactant system and having a maximum Residues Index of 25 and a maximum Secondary Residues Index of 15. The detergents claim provide good performance in the wash based on the quantities of detergent components in the compositions.
摘要翻译：本发明涉及洗涤剂组合物，其包含10-60重量％的表面活性剂体系，其最大残留指数为25，最大二级残留指数为15.洗涤剂要求在洗涤中提供了基于洗涤剂组分的量的良好性能在组合物中。

6. 发明授权

US5773399A Stabilization of oxidation-sensitive ingredients in percarbonate detergent compositions 失效
标题翻译：氧化敏感成分在过碳酸盐洗涤剂组合物中的稳定化
公开(公告)号：US5773399A
公开(公告)日：1998-06-30
申请号：US648111
申请日：1996-05-21
申请人： Gerard Marcel Baillely , Richard Timothy Hartshorn
发明人： Gerard Marcel Baillely , Richard Timothy Hartshorn
IPC分类号： C11D3/02 , C11D3/08 , C11D3/12 , C11D3/386 , C11D3/39 , C11D3/42 , C11D3/50 , C11D17/06 , C11D3/395
CPC分类号： C11D3/128 , C11D17/06 , C11D3/046 , C11D3/08 , C11D3/10 , C11D3/1233 , C11D3/386 , C11D3/3917 , C11D3/42 , C11D3/50
摘要： Granular laundry detergents are formulated with percarbonate bleach and oxidation-sensitive ingredients such as brighteners, enzymes, perfumes and the like. The storage stability of such compositions is improved by the presence of silicate. For example, the tendency of stilbene-type brighteners to form undesirable yellow shades in the presence of percarbonate is diminished by the corporation of silicate materials into the granules.
摘要翻译： PCT No.PCT / US94 / 13653 Sec。 371日期：1996年5月21日 102（e）日期1996年5月21日PCT 1994年12月1日PCT PCT。出版物WO95 / 16019 日期1995年6月15日颗粒洗衣洗涤剂配制有过碳酸盐漂白剂和氧化敏感成分，如增白剂，酶，香料等。这种组合物的储存稳定性通过硅酸盐的存在得到改善。例如，在过碳酸盐存在下，茋型增白剂形成不期望的黄色阴影的倾向由于硅酸盐材料进入颗粒而减少。

7. 发明授权

US6066611A Bleaching compositions comprising protease enzymes 失效
标题翻译：包含蛋白酶的漂白组合物
公开(公告)号：US6066611A
公开(公告)日：2000-05-23
申请号：US848793
申请日：1997-05-01
申请人： Chanchal Kumar Ghosh , Michael Eugene Burns , David Neil DiGiulio , Edward Eugene Getty , Richard Timothy Hartshorn , Alan David Willey , Philip F. Brode , Bobby L. Barnett , Donn N. Rubingh
发明人： Chanchal Kumar Ghosh , Michael Eugene Burns , David Neil DiGiulio , Edward Eugene Getty , Richard Timothy Hartshorn , Alan David Willey , Philip F. Brode , Bobby L. Barnett , Donn N. Rubingh
IPC分类号： A61K8/41 , A61K8/49 , A61Q11/00 , C11D3/386 , C11D3/39 , G06Q40/04 , C11D3/28 , C11D3/395
CPC分类号： G06Q40/04 , A61K8/416 , A61K8/49 , A61K8/4906 , A61Q11/00 , C11D3/38609 , C11D3/3917 , C11D3/3945
摘要： The invention herein provides bleaching compositions comprising a protease enzyme which is a carbonyl hydrolase variant having an amino acid sequence not found in nature, which is derived by replacement of a plurality of amino acid residues of a precursor carbonyl hydrolase with different amino acids, wherein said plurality of amino acid residues replaced in the precursor enzyme correspond to position +76 in combination with one or more of the following residues: +99, +101, +103, +104, +107, +123, +27, +105, +109, +126, +128, +135, +156, +166, +195, +197, +204, +206, +210, +216, +217, +218, +222, +260, +265, and/or +274, where the numbered positions corresponds to naturally-occurring subtilisin from Bacillus amyloliquefaciens or to equivalent amino acid residues in other carbonyl hydrolases or subtilisins (such as Bacillus lentus subtilisin) and a bleaching agent.
摘要翻译：本发明提供了包含蛋白酶的漂白组合物，其是具有自然界中没有发现的氨基酸序列的羰基水解酶变体，其是通过用不同氨基酸替代前体羰基水解酶的多个氨基酸残基得到的，其中所述在前体酶中替换的多个氨基酸残基对应于与一个或多个以下残基组合的位置+76：+99，+ 101，+ 103，+ 104，+ 107，+ 123，+ 27，+ 105， +109，+126，+128，+135，+ 156，+166，+ 195，+ 197，+ 204，+ 206，+210，+216，+217，+218，+222，+260，+265 ，和/或+274，其中编号的位置对应于从解淀粉芽孢杆菌芽孢杆菌中天然存在的枯草杆菌蛋白酶或其它羰基水解酶或枯草杆菌蛋白酶（如枯草杆菌枯草杆菌蛋白酶）和漂白剂中的等同氨基酸残基。

8. 发明授权

US06964945B1 Solid detergent compositions 有权
标题翻译：固体洗涤剂组合物
公开(公告)号：US06964945B1
公开(公告)日：2005-11-15
申请号：US09787454
申请日：1998-09-25
申请人： Richard Timothy Hartshorn , Zayeed Alam , Kevin Norwood
发明人： Richard Timothy Hartshorn , Zayeed Alam , Kevin Norwood
IPC分类号： C11D1/02 , C11D3/00 , C11D3/08 , C11D3/12 , C11D3/39 , C11D17/00
CPC分类号： C11D3/0052 , C11D3/128 , C11D3/3907 , C11D17/0073
摘要： The invention relates to solid detergent compositions comprising an aluminosilicate builder and an anionic surfactant and comprising (n) components (i), n being at least 2, whereby the level of aluminosilicate builder in said components together is at least 5% by weight of the composition and the level of the anionic surfactant in said components together is at least 5% by weight of the composition, and whereby the degree of mixture (M) of the anionic surfactant and the aluminosilicate builder is from 0 to 0.7, as defined in the description.
摘要翻译：本发明涉及包含硅铝酸盐助洗剂和阴离子表面活性剂的固体洗涤剂组合物，其包含（n）组分（i），n至少为2，由此所述组分中的铝硅酸盐助洗剂的含量为至少5重量％所述组分中的组合物和阴离子表面活性剂的含量为组合物的至少5重量％，并且其中阴离子表面活性剂和铝硅酸盐助洗剂的混合度（M）为0至0.7，如描述。

9. 发明授权

US07563857B2 Linear polyamino and/or polyammonium polysiloxane copolymers I 有权
标题翻译：线性聚氨基和/或聚铵聚硅氧烷共聚物I
公开(公告)号：US07563857B2
公开(公告)日：2009-07-21
申请号：US10533769
申请日：2003-10-31
申请人： Horst Lange , Anita Witossek , Roland Wagner , Karl-Heinz Stachulla , Andrew Russell Graydon , Richard Timothy Hartshorn , Jean-Pol Boutique , Patrick Firmin August Delplanque , James Pyott Johnston , Karl-Heinz Sockel
发明人： Horst Lange , Anita Witossek , Roland Wagner , Karl-Heinz Stachulla , Andrew Russell Graydon , Richard Timothy Hartshorn , Jean-Pol Boutique , Patrick Firmin August Delplanque , James Pyott Johnston , Karl-Heinz Sockel
IPC分类号： C08G77/54
CPC分类号： A61Q19/00 , A61K8/898 , A61Q5/02 , A61Q19/10 , C08G73/02 , C08G73/0226 , C08G73/0273 , C08G73/0616 , C08G73/0633 , C08G77/54 , C11D3/3723 , C11D3/3742 , D06M15/6436 , D06M2200/20
摘要： The invention relates to linear polyamino- and/or polyammonium-polysiloxane copolymers, particularly hydrophilic polyquaternary polysiloxane copolymers, and to their use in cosmetic formulations, in laundry detergents or for surface-treating substrates.
摘要翻译：本发明涉及线性聚氨基和/或聚铵 - 聚硅氧烷共聚物，特别是亲水性聚季铵聚硅氧烷共聚物，以及它们在化妆品配方，衣物洗涤剂或表面处理基材中的用途。

10. 发明申请

US20080242570A1 LIQUID COMPOSITION SYSTEM HAVING A VISUAL INDICATION CHANGE 审中-公开
标题翻译：具有视觉指示变化的液体组合物系统
公开(公告)号：US20080242570A1
公开(公告)日：2008-10-02
申请号：US12054485
申请日：2008-03-25
申请人： John David Carter , Richard Timothy Hartshorn , Corinne Daumer , Sharon McIntyre
发明人： John David Carter , Richard Timothy Hartshorn , Corinne Daumer , Sharon McIntyre
IPC分类号： C11D3/40
CPC分类号： C11D3/40
摘要： A detergent composition having a pH dye and an amphoteric surfactant that changes color when added to a volume of water.
摘要翻译：一种具有pH染料和两性表面活性剂的洗涤剂组合物，当加入到一定体积的水中时，其变色。

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