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1. 发明授权

US5364414A Tinctorial composition for keratinous fibres containing oxidation dye precursors and aminoindole couplers, methods for dyeing using these compositions and new compounds 失效
标题翻译：含有氧化染料前体和氨基吲哚成色剂的角质纤维的着色组合物，使用这些组合物染色的方法和新化合物
公开(公告)号：US5364414A
公开(公告)日：1994-11-15
申请号：US916706
申请日：1992-07-22
申请人： Gerard Lang , Alex Junino , Jean Cotteret , Jean J. Vandenbossche
发明人： Gerard Lang , Alex Junino , Jean Cotteret , Jean J. Vandenbossche
IPC分类号： C07D209/08 , A61K8/00 , A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , C07D209/42 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/492
摘要： Oxidation tinctorial composition intended to be used for dyeing keratinous fibres, in particular human keratinous fibres and especially hair, characterized in that it contains, in a solvent medium appropriate for dyeing these fibres, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor and at least one heterocyclic coupler corresponding to the formula (I): ##STR1## in which: R.sub.1 and R.sub.3, which may be identical or different, denote a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl group, a carboxyl group or an alkoxycarbonyl group; at least one of the radicals R.sub.2 or R.sub.3 denotes hydrogen;R.sub.4 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl or C.sub.2 -C.sub.4 polyhydroxyalkyl group;the group NHR.sub.4 occupying the positions 4, 6 or 7 of the benzene ring, as well as their salts.
摘要翻译：用于染色角质纤维，特别是人角质纤维，特别是毛发的氧化着色组合物，其特征在于，其在适于染色这些纤维的溶剂介质中含有至少一种对氧化染料前体或至少一种邻位氧化染料前体和对应于式（I）的至少一种杂环成色剂：其中：R 1和R 3可以相同或不同，表示氢原子或C 1 -C 4烷基; R2表示氢原子，C1-C4烷基，羧基或烷氧基羰基; 基团R2或R3中的至少一个表示氢; R4表示氢原子或C1-C4烷基或C1-C4羟烷基或C2-C4多羟基烷基; 占据苯环位置4,6或7的NHR4基团以及它们的盐。

2. 发明授权

US5609649A Tinctorial composition for keratinous fibers containing oxidation dye precursors and couplers derived from 4-hydroxyindole, and dyeing method using them 失效
标题翻译：含有氧化染料前体和衍生自4-羟基吲哚的成色剂的角质纤维的着色组合物和使用它们的染色方法
公开(公告)号：US5609649A
公开(公告)日：1997-03-11
申请号：US262444
申请日：1994-06-20
申请人： Alex Junino , Jean J. Vandenbossche , Herve Richard , Jean Cotteret
发明人： Alex Junino , Jean J. Vandenbossche , Herve Richard , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/33 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/492
摘要： Tinctorial composition for keratinous fibers, in particular for human hair, characterized in that it contains, in a medium appropriate for dyeing these fibers, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor in combination with at least one heterocyclic coupler, corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical; R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical or an alkoxycarbonyl radical; R.sub.3 denotes a hydrogen or halogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical, an alkoxycarbonyl radical or a formyl radical; X denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a halogen atom, a C.sub.1 -C.sub.4 alkoxy radical, an acetylamino group or a dialkyl(C.sub.1 -C.sub.4)aminomethyl group; at least one of the groups X, R.sub.1, R.sub.2 and R.sub.3 differing from hydrogen; as well as their salts.
摘要翻译：用于角质纤维，特别是人类头发的着色组合物，其特征在于，在适于对这些纤维进行染色的介质中含有至少一种对氧化染料前体或至少一种邻位氧化染料前体与至少一种杂环成色剂对应于下式：其中R 1表示氢原子或C 1 -C 4烷基; R2表示氢原子，C1-C4低级烷基，羧基或烷氧基羰基; R3表示氢或卤素原子，C1-C4低级烷基，羧基，烷氧基羰基或甲酰基; X表示氢原子，C1-C4烷基，卤素原子，C1-C4烷氧基，乙酰氨基或二烷基（C1-C4）氨基甲基; X，R1，R2和R3中的至少一个不同于氢; 以及它们的盐。

3. 发明授权

US5938792A Process for dyeing keratinous fibers with aminoindoles and oxidation dye precursors at basic Ph's and dyeing agents 失效
标题翻译：在碱性Ph和染色剂上用氨基吲哚和氧化染料前体染色角质纤维的方法
公开(公告)号：US5938792A
公开(公告)日：1999-08-17
申请号：US889896
申请日：1997-07-08
申请人： Gerard Lang , Alex Junino , Jean Cotteret , Alain Lagrange
发明人： Gerard Lang , Alex Junino , Jean Cotteret , Alain Lagrange
IPC分类号： A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/492
摘要： The invention relates to a process for dyeing keratinous fibres, which consists in applying to these fibres a composition containing, in a suitable medium for dyeing, at least one coupler of formula: ##STR1## where R.sub.1 denotes hydrogen or alkyl,R.sub.2 and R.sub.3 denote hydrogen, alkyl, COOR' where R' is alkyl or hydrogen,at least one of the groups R.sub.2 and R.sub.3 denoting hydrogen,R.sub.4 denotes hydrogen, alkyl, hydroxyalkyl, polyhydroxyalkyl or aminoalkyl,Z.sub.1 and Z.sub.2 denote hydrogen, alkyl, hydroxyl, halogen, alkoxy,at least one of the groups Z.sub.1 and Z.sub.2 is other than hydrogenat least one oxidation dye precursor,at least one oxidizing agent, the pH of the composition applied to the fibres being higher than 7.
摘要翻译：本发明涉及一种用于染色角质纤维的方法，其包括在适用于这些纤维的组合物中，该组合物在合适的染色介质中含有至少一种下式的成色剂：其中R1表示氢或烷基，R2和R3表示氢，烷基，COOR'，其中R'是烷基或氢，R 2和R 3中的至少一个表示氢，R 4表示氢，烷基，羟基烷基，多羟基烷基或氨基烷基，Z 1和Z 2表示氢，烷基，羟基，卤素，烷氧基，组Z1和Z2中的至少一个不是氢，至少一种氧化染料前体，至少一种氧化剂，施加到纤维上的组合物的pH高于7。

4. 发明授权

US5752982A Methods for dyeing keratinous fibers with compositions which contain aminoindole couplers, oxidation dye precursors, and oxidizing agents at acid pHs 失效
标题翻译：在酸性pH下用含有氨基吲哚成色剂，氧化染料前体和氧化剂的组合物染色角质纤维的方法
公开(公告)号：US5752982A
公开(公告)日：1998-05-19
申请号：US470274
申请日：1995-06-06
申请人： Gerard Lang , Alex Junino , Jean Cotteret , Alain Lagrange
发明人： Gerard Lang , Alex Junino , Jean Cotteret , Alain Lagrange
IPC分类号： A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/492 , A61Q5/10
摘要： A method for dyeing keratin fibers, wherein a composition is applied to said fibers which contains, in a suitable dyeing medium, at least one coupler having formula (I) ##STR1## wherein R.sub.1 is hydrogen or alkyl; R.sub.2 and R.sub.3 are hydrogen, alkyl, COOR', where R' is alkyl or hydrogen; R.sub.4 is hydrogen, hydroxyalkyl, alkyl, polyhydroxyalkyl or acetyl or aminoalkyl wherein the amine may be mono- or disubstituted by alkyl; Z.sub.1 and Z.sub.2 are hydrogen, alkyl, hydroxy, halogen, alkoxy or a salt thereof; at least one precursor of an oxidation hair dye; and at least one oxidizing agent, the pH of the composition applied to the fibers being less than 7.
摘要翻译：一种用于染色角蛋白纤维的方法，其中将组合物施加到所述纤维中，所述纤维在合适的染色介质中包含至少一种具有式（I）的偶联剂：其中R 1是氢或烷基; R2和R3是氢，烷基，COOR'，其中R'是烷基或氢; R4是氢，羟烷基，烷基，多羟基烷基或乙酰基或氨基烷基，其中胺可以被烷基单或二取代; Z 1和Z 2是氢，烷基，羟基，卤素，烷氧基或其盐; 氧化染发剂的至少一种前体; 和至少一种氧化剂，施加到纤维上的组合物的pH小于7。

5. 发明授权

US5254135A Methods for dyeing keratinous fibres with aminoindoles, compositions and devices for use 失效
标题翻译：用氨基吲哚染色角质纤维的方法，组合物和使用的装置
公开(公告)号：US5254135A
公开(公告)日：1993-10-19
申请号：US915649
申请日：1992-07-21
申请人： Gerard Lang , Alex Junino , Jean Cotteret
发明人： Gerard Lang , Alex Junino , Jean Cotteret
IPC分类号： A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/492
摘要： Method for dyeing keratinous fibres, in particular human keratinous fibres, such as hair, characterized in that a composition (A) containing, in a medium appropriate for dyeing, at least one aminoindole corresponding to the formula: ##STR1## in which: R.sub.1 and R.sub.3, independently of one another, represent a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.2 denotes hydrogen or a C.sub.1 -C.sub.4 alkyl group or COOR', R' being a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.4 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 hydroxyalkyl or C.sub.2 -C.sub.4 polyhydroxyalkyl group;Z.sub.1 represents a hydrogen or halogen atom or a C.sub.1 -C.sub.4 alkyl group or OR;R being a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group; andZ.sub.2 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;and its saltsis applied to said fibres, the colour being developed with the aid of an oxidizing system.
摘要翻译：用于染色角质纤维，特别是人角质纤维如毛发的方法，其特征在于，在适于染色的培养基中含有至少一个对应于下式的氨基吲哚的组合物（A）：其中 R 1和R 3彼此独立地表示氢原子或C 1 -C 4烷基; R2表示氢或C1-C4烷基或COOR'，R'为氢原子或C1-C4烷基; R4表示氢原子或C1-C4烷基，C1-C4羟烷基或C2-C4多羟基烷基; Z1表示氢或卤原子或C1-C4烷基或OR; R为氢原子或C 1 -C 4烷基; Z2表示氢原子或C1-C4烷基; 并且其盐被施加到所述纤维上，颜色借助氧化体系显影。

6. 发明授权

US4725283A Dyeing compositions for keratinic fibres, based on halogenated meta-phenylenediamines 失效
标题翻译：基于卤代间苯二胺的角质纤维染色组合物
公开(公告)号：US4725283A
公开(公告)日：1988-02-16
申请号：US872387
申请日：1986-06-10
申请人： Jean Cotteret , Alex Junino , Gerard Lang
发明人： Jean Cotteret , Alex Junino , Gerard Lang
IPC分类号： A61K8/00 , A61K20060101 , A61K8/34 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/49 , A61K8/73 , A61Q5/06 , A61Q5/10 , C09B20060101 , C09B51/00 , D06P3/04 , A61K7/13
CPC分类号： A61K8/418 , A61Q5/065
摘要： The invention relates to dyeing compositions for direct dyeing of keratinic fibres, containing, in a cosmetically acceptable medium:(a) at least one yellow or green-yellow dye corresponding to the formula (I): ##STR1## in which X=Cl, Br, F, and R.sub.1 and R.sub.2 denote, independently of each other, hydrogen, alkyl, hydroxyalkyl, or alkylaminoalkyl in which the aminoalkyl group may be mono- or disubstituted provided that R.sub.1 and R.sub.2 do not simultaneously denote a hydrogen atom, and(b) at least one blue or violet dye corresponding to the formula: ##STR2## in which R.sub.3 denotes a hydrogen atom or an alkyl, monohydroxyalkyl, polyhydroxyalkyl or alkoxyalkyl radical and R.sub.4 and R.sub.5 have separately the same meanings as R.sub.3 but cannot denote a hydrogen atom.
摘要翻译：本发明涉及用于直接染色角蛋白纤维的染色组合物，其包含在化妆品可接受的介质中：（a）至少一种对应于式（I）的黄色或绿黄色染料：其中X = Cl，Br，F和R 1和R 2彼此独立地表示氢，烷基，羟基烷基或烷基氨基烷基，其中氨基烷基可以被单或二取代，条件是R 1和R 2不同时表示氢原子，和（b）对应于下式的至少一种蓝色或紫色染料：其中R 3表示氢原子或烷基，单羟基烷基，多羟基烷基或烷氧基烷基，R 4和R 5分别具有与R 3 但不能表示氢原子。

7. 发明授权

US4692166A Use of halogenated 4,5-methylenedioxyphenol in the dyeing of keratinous fibres 失效
标题翻译：卤代4,5-亚甲二氧基苯酚在角质纤维染色中的应用
公开(公告)号：US4692166A
公开(公告)日：1987-09-08
申请号：US841813
申请日：1986-03-20
申请人： Alex Junino , Gerard Lang , Herve Andrean , Jean Cotteret
发明人： Alex Junino , Gerard Lang , Herve Andrean , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/33 , A61K8/34 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/73 , A61Q5/10 , C07D317/48 , C07D317/52 , C07D317/54 , D06P1/32 , D06P1/64 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/4973
摘要： Use for dyeing keratinous fibres, and especially human hair, on a compound corresponding to the formula: ##STR1## in which X denotes a bromine or chlorine atom.
摘要翻译：用于将角质纤维特别是人发染色在对应于下式的化合物：其中X表示溴或氯原子。

8. 发明授权

US4736067A New dimethyl derivatives of 3-nitro-4-aminoaniline, process for their preparation and their use for dyeing keratinic fibers 失效
标题翻译： 3-硝基-4-氨基苯胺的新二甲基衍生物，其制备方法及其用于染色角蛋白纤维的用途
公开(公告)号：US4736067A
公开(公告)日：1988-04-05
申请号：US647755
申请日：1984-09-06
申请人： Andree Bugaut , Alain Genet , Jean Cotteret , Alex Junino
发明人： Andree Bugaut , Alain Genet , Jean Cotteret , Alex Junino
IPC分类号： A61K8/00 , A61K20060101 , A61K8/34 , A61K8/35 , A61K8/40 , A61K8/41 , A61Q5/06 , A61Q5/10 , C07C20060101 , C07C67/00 , C07C209/00 , C07C209/08 , C07C209/18 , C07C209/36 , C07C209/60 , C07C209/62 , C07C211/52 , C07C215/16 , C09B51/00 , C09B53/00 , C09B67/42 , D06P1/32 , D06P1/42 , D06P3/08 , C07C87/58 , A61K7/13 , C07C87/28
CPC分类号： A61K8/418 , A61Q5/065 , A61Q5/10
摘要： New dimethyl derivatives of 3-nitro-4-aminoaniline, process for their preparation, and their use for dyeing keratinic fibres.The invention relates to dimethyl derivatives of 3-nitro-4-aminoaniline of formula: ##STR1## in which CH.sub.3 is in position 2 or 5 of the benzene ring and R.sub.1 and R.sub.2 denote independently of each other a hydrogen atom, a lower alkyl group, a lower mono- or polyhydroxyalkyl or a lower aminoalkyl group in which the amino group is optionally mono- or disubstituted by a lower alkyl radical or by a lower mono- or polyhydroxyalkyl radical, it being understood that the two symbols R.sub.1 and R.sub.2 can be simultaneously other than hydrogen only when the mobile CH.sub.3 radical is in position 5, or cosmetically acceptable salts of these compounds, as well as the process for preparing them and their use in dye compositions, in particular for hair, equally for direct coloring and for coloring by an oxidation route.
摘要翻译： 3-硝基-4-氨基苯胺的新二甲基衍生物，其制备方法及其用于染色角蛋白纤维的用途。本发明涉及下列结构式的3-硝基-4-氨基苯胺的二甲基衍生物：其中CH 3位于苯环的2或5位，R 1和R 2彼此独立地表示氢原子，低级烷基，低级单羟基烷基或多羟基烷基或低级氨基烷基，其中氨基任选被低级烷基或低级单羟基或多羟基烷基单取代或二取代，应理解，两个符号R1和R2可以是同时除了氢，只有当可移动的CH3基团在5位时，或这些化合物的美容上可接受的盐，以及它们的制备方法以及它们在染料组合物中的用途，特别是用于毛发，同样用于直接着色和着色通过氧化路线。

9. 发明授权

US5516942A Hydroxyethylated 2-nitro-p-phenylenediamines and use thereof for dyeing keratin fibers 失效
标题翻译：羟乙基化2-硝基对苯二胺及其用于染色角蛋白纤维的用途
公开(公告)号：US5516942A
公开(公告)日：1996-05-14
申请号：US351242
申请日：1994-12-07
申请人： Alain Lagrange , Alex Junino , Alain Genet , Jean Cotteret
发明人： Alain Lagrange , Alex Junino , Alain Genet , Jean Cotteret
IPC分类号： A61K8/00 , A61K8/31 , A61K8/34 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61Q5/06 , A61Q5/10 , C07C215/16 , C09B51/00 , C09B53/00 , D06P3/04 , D06P3/08 , A61K7/13
CPC分类号： A61K8/418 , A61Q5/065 , C07C215/16
摘要： A N1,N4-dihydroxyethylated 2-nitro-p-phenylenediamine of formula (I), wherein R is C3-4 aklyl, and cosmetically acceptable salts thereof, for use in direct dyeing to give blue through purple shades which are wash-fast, light-fast, weatherproof and sweat resistant, and optionally combined with yellow and optionally read or orange-coloured dyes to give natural hues.
摘要翻译： PCT No.PCT / FR93 / 00571 Sec。 371日期1994年12月7日第 102（e）日期1994年12月7日PCT提交1993年6月15日PCT公布。第WO94 / 00415号公报日本1994年1月6日。一种式（I）的N1，N4-二羟基乙基化2-硝基 - 对苯二胺，其中R为C3-4亚烷基，及其美容上可接受的盐，用于直接染色以使紫色经紫色洗涤快速，耐光，耐候和耐汗的色调，并且可选地与黄色和任选的读取或橙色染料组合以提供天然色调。

10. 发明授权

US5792221A Hydroxypropylated 2-nitro-p-phenylenediamines, and compositions for dyeing keratinous fibers which contain hydroxypropylated 2-nitro-p-phenylenediamines 失效
标题翻译：羟丙基化2-硝基对苯二胺和用于染色含有羟丙基化2-硝基对苯二胺的角质纤维的组合物
公开(公告)号：US5792221A
公开(公告)日：1998-08-11
申请号：US755628
申请日：1996-11-25
申请人： Alain Lagrange , Alex Junino , Alain Genet , Jean Cotteret
发明人： Alain Lagrange , Alex Junino , Alain Genet , Jean Cotteret
IPC分类号： C07C215/16 , A61K7/13 , C07C211/29
CPC分类号： C07C215/16
摘要： A hydroxypropylated 2-nitro-p-phenylenediamine of formula (I), wherein R1 is a C1-4 alkyl, .beta.-hydroxyethyl, .beta.-hydroxypropyl or .gamma.-hydroxypropyl radical; R2 and R3 independently represent a .beta.-hydroxyethyl, .beta.-hydroxypropyl, .gamma.-hydroxypropyl or .beta.,.gamma.-dihydroxypropyl radical, with the proviso that at least one of R1, R2 and R3 is a .gamma.-hydroxypropyl radical, while the other two are not both a .beta.-hydroxyethyl radical; and cosmetically acceptable salts thereof. This compound may be used for directly dyeing hair to give blue through purplish blue shades which are wash-fast, light-fast, waterproof and sweat resistant.
摘要翻译：式（I）的羟丙基化2-硝基 - 对苯二胺，其中R 1是C 1-4烷基，β-羟乙基，β-羟丙基或γ-羟丙基; R2和R3独立地表示β-羟乙基，β-羟丙基，γ-羟丙基或β，γ-二羟丙基，条件是R 1，R 2和R 3中的至少一个是γ-羟丙基，而另外两个是不是β羟基乙基; 及其化妆品可接受的盐。该化合物可用于直接染发，通过紫色蓝色色调赋予蓝色，其具有洗涤性，耐光性，防水性和耐汗性。

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