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1. 发明授权

US5318116A Vacuum method for removing soil contaminants utilizing thermal conduction heating 失效
标题翻译：使用热传导加热去除土壤污染物的真空方法
公开(公告)号：US5318116A
公开(公告)日：1994-06-07
申请号：US9505
申请日：1993-01-26
申请人： Harold J. Vinegar , George L. Stegemeier , Eric P. de Rouffignac , Charles C. Chou
发明人： Harold J. Vinegar , George L. Stegemeier , Eric P. de Rouffignac , Charles C. Chou
IPC分类号： B09C1/00 , B09C1/06 , E02D3/11 , E21B36/04 , E21B43/30 , E21B43/24
CPC分类号： E21B43/30 , B09C1/005 , B09C1/062 , E02D3/11 , E21B36/04 , B09C2101/00
摘要： An in situ method for removal of contaminants from soil imposes a vacuum on the soil through perforated heater wells that are positioned in the soil. The heater wells heat the soil to elevated temperatures by thermal conduction. The heater wells are permeable to vapors which emanate from the soil when heated and which are drawn towards the heater wells by the imposed vacuum. An impermeable flexible sheeting on the soil surface reduces the amount of air that is being pulled into the heater well from the atmosphere. A thermal insulator covers the soil surface and reduces heat losses from the soil surface. The heater wells are connected to a vacuum manifold for collection of vapors. A heat front moves away from the heater wells through the soil by thermal conduction, and the superposition of heat from a plurality of heater wells results in a more uniform temperature rise throughout the well pattern. Soil contaminants are removed by vaporization, in situ thermal decomposition, oxidation, combustion, and by steam distillation. Both the presence of water vapor and the low pressure results in vaporization of the contaminants at temperatures well below their normal boiling points. Moreover, the heater wells and the nearby soil are extremely hot and most contaminants drawn into the wells will decompose with a residence time of the order of seconds. The heater well can also be packed with a catalyst that accelerates high temperature decomposition into simpler molecules. Water vapor and remaining contaminants may be incinerated in line or may be collected in a cold trap upstream from the vacuum pump.
摘要翻译：从土壤中去除污染物的原位方法通过位于土壤中的穿孔加热井在土壤上施加真空。加热井通过热传导将土壤加热到升高的温度。加热井对加热时从土壤发出的蒸气是可渗透的，并通过施加的真空向加热器井拉出。在土壤表面上的不透水柔性薄板减少了从大气中吸入加热器的空气量。绝热体覆盖土壤表面，减少土壤表面的热量损失。加热器井连接到用于收集蒸汽的真空歧管。热源通过热传导离开加热器井通过土壤，并且来自多个加热井的热量的叠加导致整个井模式中更均匀的温度升高。通过蒸发，原位热分解，氧化，燃烧和蒸汽蒸馏除去土壤污染物。水蒸汽的存在和低压都导致污染物在远低于其正常沸点的温度下蒸发。此外，加热器井和附近的土壤是非常热的，并且大部分被吸入井中的污染物将以几秒的停留时间分解。加热器井也可以填充催化剂，将催化剂高温分解加速成更简单的分子。水蒸汽和剩余的污染物可以排成一行，或者可以被收集在真空泵上游的冷阱中。

2. 发明授权

US06951436B2 Thermally enhanced soil decontamination method 有权
标题翻译：热增强土壤去污方法
公开(公告)号：US06951436B2
公开(公告)日：2005-10-04
申请号：US10279771
申请日：2002-10-24
申请人： George L. Stegemeier , Harold J. Vinegar , Eric P. de Rouffignac
发明人： George L. Stegemeier , Harold J. Vinegar , Eric P. de Rouffignac
IPC分类号： B09B3/00 , B09C1/06
CPC分类号： B09C1/06 , B09C2101/00
摘要： A method is provided to remove contaminants from contaminated soil. The method may include withdrawing vapors from a vapor extraction well, estimating the amount of water vapor removed from the contaminated soil in the vapors being withdrawn from the vapor extraction well, and applying heat to the contaminated soil from a plurality of heater wells at a rate not greater than that which would vaporize the estimated amount of water vapor. The permeability of the soil may thereby increase by the application of heat. Six or more heat injection wells may be provided for each vapor extraction well, and the heat injection wells may be placed and energized in a regular pattern around the vapor extraction well, which may include multiple rings of heaters around each vapor extraction well.
摘要翻译：提供了一种从污染土壤中去除污染物的方法。该方法可以包括从蒸气提取井中抽出蒸气，估计从蒸气提取井取出的蒸气中的污染土壤中去除的水蒸气的量，并以多个加热井以一定比例向受污染的土壤施加热量不大于将蒸发估计的水蒸汽量。因此，通过施加热可以增加土壤的渗透性。可以为每个蒸气提取井提供六个或更多个热注入井，并且热注入井可以以围绕蒸气提取井的规则图案放置和通电，该蒸气提取井可以包括围绕每个蒸气提取井的多个加热环。

3. 发明授权

US5229583A Surface heating blanket for soil remediation 失效
标题翻译：用于土壤修复的表面加热毯
公开(公告)号：US5229583A
公开(公告)日：1993-07-20
申请号：US951954
申请日：1992-09-28
申请人： Cornelis F. van Egmond , Frederick G. Carl, Jr. , George L. Stegemeier , Harold J. Vinegar
发明人： Cornelis F. van Egmond , Frederick G. Carl, Jr. , George L. Stegemeier , Harold J. Vinegar
IPC分类号： B09C1/06 , H05B3/34
CPC分类号： H05B3/34 , B09C1/06 , B09C2101/00 , H05B2203/005 , H05B2203/011 , H05B2203/012
摘要： This invention comprises a surface heating blanket assembly useful for soil remediation. The assembly principally comprises a metallic furnace belt with tubular electric heating elements inserted between the rungs thereof and making low resistance contact therewith. The furnace belt heater is capable of being rolled and dragged, and flexibly conforms to the earth's surface for maximum heat transfer to the soil. A layer of permeable insulation and an impermeable sheet may be placed on top of the heater. A vacuum may be pulled under the impermeable layer by means of a hole therethrough connected to a vacuum pump.
摘要翻译：本发明包括用于土壤修复的表面加热毯组件。该组件主要包括金属炉带，其带有插入其梯级之间的管状电加热元件并与其低阻力接触。炉带加热器能够被滚动和拖动，并且灵活地符合地球表面，以最大限度地传递到土壤。可渗透绝缘层和不渗透片材可放置在加热器的顶部。可以通过连接到真空泵的孔穿过不透水层的真空。

4. 发明授权

US06485232B1 Low cost, self regulating heater for use in an in situ thermal desorption soil remediation system 有权
标题翻译：低成本，自调节加热器，用于原位热解吸土壤修复系统
公开(公告)号：US06485232B1
公开(公告)日：2002-11-26
申请号：US09549899
申请日：2000-04-14
申请人： Harold J. Vinegar , George L. Stegemeier
发明人： Harold J. Vinegar , George L. Stegemeier
IPC分类号： A62D300
CPC分类号： H05B3/03 , B09C1/062 , B09C2101/00 , E21B36/04 , H05B3/0004
摘要： An in situ thermal desorption soil remediation system may be used to remove contamination from soil. Heat may be applied to the soil by metallic strip heaters that have large cross sectional areas as compared to conventional heater elements. The strip heaters may be made of stainless steel. Large cross sectional areas of the strip heaters allow for large areas of thermal contact between the strip heaters and the soil being treated. Casings may not be needed between the strip heaters and the soil. The operating temperature of the strip heaters is self-regulating. As the temperature of a strip heater increases, the electrical resistance of the strip heater also increases. The increase in resistance causes a decrease in the power dissipation of the strip heater. The decrease in power dissipation as temperature increases allows a steady state heater strip temperature to be attained during use.
摘要翻译：原位热解吸土壤修复系统可用于去除土壤污染。与常规加热器元件相比，可以通过具有大横截面积的金属条加热器将热施加到土壤上。带状加热器可以由不锈钢制成。带状加热器的大横截面积允许带状加热器和待处理的土壤之间的大面积的热接触。带状加热器和土壤之间可能不需要外壳。带式加热器的工作温度是自调节的。随着带状加热器的温度升高，带状加热器的电阻也增加。电阻的增加导致带状加热器功率的降低。随着温度升高，功耗的降低允许在使用期间获得稳态加热器带温度。

5. 发明授权

US06962466B2 Soil remediation of mercury contamination 有权
标题翻译：汞污染的土壤修复
公开(公告)号：US06962466B2
公开(公告)日：2005-11-08
申请号：US10279758
申请日：2002-10-24
申请人： Harold J. Vinegar , George L. Stegemeier
发明人： Harold J. Vinegar , George L. Stegemeier
IPC分类号： B01D53/64 , B01D53/00 , B09B3/00 , B09C1/02 , B09C1/06 , B09C1/08 , B09C1/00
CPC分类号： B01D53/002 , B01D2257/602 , B09C1/02 , B09C1/06 , B09C1/08 , B09C2101/00
摘要： An in situ soil remediation system may be used to remove or reduce levels of mercury contamination within soil. The soil remediation system may also remove or reduce levels of other contaminants within the soil. Mercury may be vaporized within the soil by a heating system. The vaporized mercury may be removed from the soil by a vacuum system. The vaporized mercury may pass through heated risers that elevate the vaporized mercury. After the vaporized mercury passes from the heated risers, the vaporized mercury may be allowed to cool, condense, and flow downward to a treatment facility. Removing mercury from the soil as a vapor may provide an economical, safe, and efficient way to remediate mercury contaminated soil.
摘要翻译：原位土壤修复系统可用于去除或降低土壤中汞污染的水平。土壤修复系统也可以去除或降低土壤中其他污染物的含量。汞可以通过加热系统在土壤内蒸发。蒸发的汞可以通过真空系统从土壤中去除。蒸发的汞可以通过升高蒸发的汞的加热立管。蒸发的汞从加热的立管中通过后，蒸发的汞可以冷却，冷凝并向下流到处理设备。从蒸汽中去除水中的汞可能会提供一种经济，安全和有效的方式来补救受污染污染的土壤。

6. 发明授权

US06632047B2 Heater element for use in an in situ thermal desorption soil remediation system 有权
标题翻译：用于原位热解吸土壤修复系统的加热元件
公开(公告)号：US06632047B2
公开(公告)日：2003-10-14
申请号：US09836447
申请日：2001-04-16
申请人： Harold J. Vinegar , George L. Stegemeier
发明人： Harold J. Vinegar , George L. Stegemeier
IPC分类号： A62D300
CPC分类号： H05B3/03 , B09C1/062 , B09C2101/00 , E21B36/04 , H05B3/0004
摘要： An in situ thermal desorption (ISTD) soil remediation system may be used to remove or reduce contamination within soil. Heat may be transferred to the soil from resistively heated, bare metal heater elements. The heater elements may be placed directly within the soil. Alternately, the heater elements may be suspended within casings. The heater elements may be conductive heaters, or the heater elements may be radiative heater elements. The ISTD soil remediation system may include temperature-resistant, chemical resistant, flexible conduits that transport off-gas removed from the ground to a treatment facility. A residence time of off-gas within the conduits may be sufficient to allow the off-gas to cool so that the off-gas may pass to a treatment facility through a manifold and piping made of polymeric material.
摘要翻译：原位热解吸（ISTD）土壤修复系统可用于去除或减少土壤内的污染。热可以从电阻加热的裸金属加热器元件转移到土壤中。加热器元件可以直接放置在土壤中。或者，加热器元件可以悬挂在壳体内。加热器元件可以是导电加热器，或者加热器元件可以是辐射加热器元件。 ISTD土壤修复系统可以包括将从地面移除的废气输送到处理设施的耐温，耐化学腐蚀的柔性管道。废气在管道内的停留时间可能足以使尾气冷却，使得废气可以通过歧管和由聚合材料制成的管道传递到处理设施。

7. 发明授权

US06543539B1 Perforated casing method and system 有权
标题翻译：穿孔套管方法和系统
公开(公告)号：US06543539B1
公开(公告)日：2003-04-08
申请号：US09716366
申请日：2000-11-20
申请人： Harold J. Vinegar , George L. Stegemeier
发明人： Harold J. Vinegar , George L. Stegemeier
IPC分类号： E21B4312
CPC分类号： B09C1/00 , E21B43/086
摘要： A perforated casing may be placed within contaminated soil. Perforations within the casing may be covered during insertion of the casing into the ground. Covering the perforations may inhibit plugging of the perforations during installation. Covering the perforations may also inhibit worker exposure to contaminant dust or vapors during insertion of the casing into the ground. The covering for the perforations in a casing may be plugs that are placed or formed in the casing perforations. Alternately, the covering for the perforations may be a sleeve placed adjacent to the perforations. After installation of the casing, heating or chemically treating the perforation coverings may remove the coverings and allow insertion or removal of fluids and vapor through the casing.
摘要翻译：穿孔的外壳可以放置在污染的土壤中。外壳内的穿孔可能在套管插入地面时被覆盖。覆盖穿孔可能会在安装过程中阻止穿孔堵塞。覆盖穿孔也可以防止工人在将套管插入地面期间暴露于污染物的灰尘或蒸汽。用于套管中的穿孔的覆盖物可以是放置或形成在套管穿孔中的塞子。或者，用于穿孔的覆盖物可以是与穿孔相邻放置的套筒。在安装壳体之后，加热或化学处理穿孔覆盖物可以移除覆盖物并允许流体和蒸气穿过套管的插入或移除。

8. 发明授权

US07534926B2 Soil remediation using heated vapors 有权
标题翻译：使用加热蒸气进行土壤修复
公开(公告)号：US07534926B2
公开(公告)日：2009-05-19
申请号：US10438779
申请日：2003-05-15
申请人： George L. Stegemeier , Harold J. Vinegar
发明人： George L. Stegemeier , Harold J. Vinegar
IPC分类号： A62D3/00
CPC分类号： B09C1/10 , B09C1/00 , B09C1/005 , B09C1/02 , B09C1/06 , B09C1/08
摘要： Methods are provided for remediating contaminated soil. The methods may include collecting contaminated soil at a plurality of treatment sites. The contaminated soil at one or more of the plurality of treatment sites may be at least partially contained. Vapors produced from heating soil at one site may be used to heat contaminated soil at another site. A fluid directed to a portion of heated contaminated soil may accelerate heat transfer through the site of contaminated soil or through another site of contaminated soil. A method may include heating contaminated soil from more than one site at substantially the same time. Heating contaminated soil from more than one site at substantially the same time may include in situ and ex situ treatment at a common location.
摘要翻译：提供了补救污染土壤的方法。所述方法可以包括在多个处理部位收集污染的土壤。可以至少部分地包含多个处理部位中的一个或多个的被污染的土壤。在一个地方加热土壤产生的蒸气可用于加热另一地点的污染土壤。导向受热污染土壤的一部分的流体可能加速通过污染土壤的位置或通过另一污染土壤的位置进行热传递。一种方法可以包括在同一时间从多于一个地点加热受污染的土壤。在同一时间从多个地点加热受污染的土壤可能包括在一个共同的位置的原位和非原位处理。

9. 发明授权

US06881009B2 Remediation of soil piles using central equipment 有权
标题翻译：使用中央设备修复土桩
公开(公告)号：US06881009B2
公开(公告)日：2005-04-19
申请号：US10438768
申请日：2003-05-15
申请人： George L. Stegemeier , Harold J. Vinegar , Ralph S. Baker , John M Bierschenk
发明人： George L. Stegemeier , Harold J. Vinegar , Ralph S. Baker , John M Bierschenk
IPC分类号： B09C1/00 , B09C1/02 , B09C1/06 , B09C1/08 , B09C1/10 , E02D3/11
CPC分类号： B09C1/00 , B09C1/005 , B09C1/02 , B09C1/06 , B09C1/08 , B09C1/10 , E02D3/11
摘要： Methods are provided for remediating contaminated soil. The methods may include collecting contaminated soil at a plurality of treatment sites. The contaminated soil at one or more of the plurality of treatment sites may be at least partially contained. Contaminated soil at the plurality of treatment sites may be treated with equipment in a central treatment facility. Treatment of the plurality of sites may be coordinated such that equipment in the central treatment facility operates substantially continuously as soil is delivered to, treated at, and removed from various treatment sites. The plurality of sites may be treated in a sequential manner, in which soil is delivered to one site, treated at a second site, and removed from a third site substantially simultaneously.
摘要翻译：提供了补救污染土壤的方法。所述方法可以包括在多个处理部位收集污染的土壤。可以至少部分地包含多个处理部位中的一个或多个的被污染的土壤。多个处理场所的污染土壤可以用中央处理设备的设备进行处理。可以协调多个部位的处理，使得当土壤被输送到各处理部位处理和从其处理时，中央处理设备中的设备基本连续地运行。可以以顺序的方式处理多个部位，其中将土壤输送到一个部位，在第二部位处理，并且基本上同时从第三部位移除。

10. 发明申请

US20140305640A1 IN SITU THERMAL PROCESSING OF AN OIL SHALE FORMATION USING CONDUCTIVE HEATING 审中-公开
标题翻译：使用导热加热的油层形成的原位热处理
公开(公告)号：US20140305640A1
公开(公告)日：2014-10-16
申请号：US14104605
申请日：2013-12-12
申请人： Scott L. Wellington , Ilya E. Berchenko , Thomas D. Fowler , John M. Karanikas , Eric de Rouffignac , Robert C. Ryan , Gordon T. Shahin, JR. , George L. Stegemeier , Harold J. Vinegar , Etuan Zhang
发明人： Scott L. Wellington , Ilya E. Berchenko , Thomas D. Fowler , John M. Karanikas , Eric de Rouffignac , Robert C. Ryan , Gordon T. Shahin, JR. , George L. Stegemeier , Harold J. Vinegar , Etuan Zhang
IPC分类号： E21B43/24
CPC分类号： E21B43/24 , E21B43/2401 , E21B43/243 , E21B43/247 , E21B43/30
摘要： Methods and systems of treating an oil shale formation using an in situ thermal process are described herein. A method of treating an oil shale formation in situ includes providing heat from one or more heat sources to at least a portion of the formation; allowing the heat to transfer from at least the portion to a selected section of the formation substantially by conduction of heat; pyrolyzing at least some hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
摘要翻译：本文描述了使用原位热处理处理油页岩层的方法和系统。原位处理油页岩形成的方法包括从一个或多个热源向地层的至少一部分提供热量; 允许热量基本上通过热传导从至少部分转移到地层的选定部分; 在地层的选定部分内热解至少一些碳氢化合物; 并从地层产生混合物。

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