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    • 7. 发明授权
    • Process for flocculating an aqueous suspension of particles with
quaternary ammonium graft copolymers
    • 用季铵接枝共聚物絮凝颗粒水悬浮液的方法
    • US4305829A
    • 1981-12-15
    • US156732
    • 1980-06-05
    • Donald R. KelseyRussell L. Kreeger
    • Donald R. KelseyRussell L. Kreeger
    • A01N33/12C02F1/54C08G73/02C02F1/56B01D21/01
    • A01N33/12C02F1/54C08G73/0226
    • Described herein is a process for flocculating an aqueous suspension of finely divided particles which comprises treating the suspension with an effective amount of a water-soluble graft copolymer to achieve the desired degree of flocculation of said particles, said water soluble graft copolymer being comprised of polymeric units characterized by the general formula: ##STR1## wherein n, y and z represent the relative molar equivalent fractions of each of the respective polymeric units in the graft copolymer, the sum of n, y and z being 1.0, the value of n varying from 0.00 to 0.99, the value of y varying from 0.00 to 0.99 and the value of z varying from 0.01 to 0.99; q is an integer greater than 1; A is the unit derived from at least one difunctional amine selected from the group consisting of primary amines and di(secondary)amines; t is an integer varying from 1 to 2; E is the unit obtained from a compound selected from the group consisting of epihalohydrins and diepoxides after its reaction with said difunctional amine; R is an organic radical derived from a quaternizing agent having the general formula RX, where X is the residual counter ion formed after quaternization; B is the unit derived from an organic dihalide having the general formula BY.sub.2, where Y is Cl.sup.-, Br.sup.- or l.sup.- with the proviso that such halogens are not attached to the same carbon atom; and C is the unit derived from an organic di(tertiary)amine after its reaction with said organic dihalide.
    • 本文描述了一种使细碎颗粒的水悬浮液絮凝的方法,其包括用有效量的水溶性接枝共聚物处理悬浮液以达到所需颗粒的所需程度的絮凝,所述水溶性接枝共聚物由聚合物 其特征在于以下通式:其中n,y和z表示接枝共聚物中各相应聚合物单元的相对摩尔当量级数,n,y和z之和为1.0,n值变化 从0.00到0.99,y的值从0.00变化到0.99,z的值从0.01到0.99变化; q是大于1的整数; A是衍生自选自伯胺和二(仲)胺的至少一种二官能胺的单元; t是1至2的整数; E是在与所述双官能胺反应后由选自表卤代醇和二环氧化物的化合物获得的单元; R是衍生自具有通式RX的季铵化剂的有机基团,其中X是季铵化后形成的残余抗衡离子; B是衍生自具有通式BY 2的有机二卤化物的单元,其中Y是Cl-,Br-或1-,条件是这样的卤素不连接到相同的碳原子上; C是在与所述有机二卤化物反应后衍生自有机二(叔)胺的单元。