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    • 1. 发明授权
    • Microporous films
    • 微孔膜
    • US5198162A
    • 1993-03-30
    • US367740
    • 1989-06-13
    • George B. ParkJohn A. CookMike G. L. DorlingDavid J. BarkerRobert H. McLoughlin
    • George B. ParkJohn A. CookMike G. L. DorlingDavid J. BarkerRobert H. McLoughlin
    • C08J9/26C25B13/08H01M2/16
    • C08J9/26C25B13/08H01M2/1653C08J2201/0444C08J2201/0464C08J2323/04C08J2327/12H01M2300/0017H01M2300/002H01M2300/0025
    • A microporous polymeric film of high porosity comprises a halopolymer in which the repeating units are --(C.sub.n H.sub.2n)-- and --(C.sub.m X.sub.2m)-- in which each X independently represents fluorine or chlorine and the values of n and m are greater than one and less than six. The film is the result of firstly melt processing a mixture of the halopolymer, more than 150 parts by weight of an extractable salt and not more than 80 parts by weight of an extractable polymer per 100 parts by weight of the halopolymer, the extractable polymer not being completely and homogeneously mixed with the halopolymer and being less viscous than the halopolymer when both are molten so that the surfaces of the film resulting from melt processing are rich in the extractible polymer, and secondly extracting at least some of the extractable salt to render the film porous and extracting at least some of said polymer to impart surface porosity to the film. The film has a porosity of more than 50% by volume and more usually 60-70%. The film may be used as the separator of an electrochemical cell e.g. a battery having a lithium anode and a thionyl chloride electrolyte.
    • 高孔隙率的微孔聚合物膜包括其中重复单元为 - (C n H 2n) - 和 - (C m X 2 m) - 的卤代聚合物,其中每个X独立地表示氟或氯,并且n和m的值大于1和小于 六。 该膜是首先将卤代聚合物的混合物熔融加工的结果,每100重量份的卤代聚合物,超过150重量份的可萃取盐和不超过80重量份的可萃取聚合物,所述可萃取聚合物不是 与卤代聚合物完全和均匀地混合,并且当两者都熔融时比卤代聚合物粘度小,使得由熔融加工产生的膜的表面富含可萃取的聚合物,其次提取至少一些可提取盐,使得 薄膜多孔并提取至少一些所述聚合物以赋予膜表面多孔性。 该膜的孔隙率大于50体积%,更通常为60-70%。 该膜可以用作电化学电池的隔板,例如, 具有锂阳极和亚硫酰氯电解质的电池。