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1. 发明授权

US08980961B2 Conversion of carbon dioxide to methanol using bi-reforming of methane or natural gas 有权
标题翻译：使用甲烷或天然气的双重重整将二氧化碳转化为甲醇
公开(公告)号：US08980961B2
公开(公告)日：2015-03-17
申请号：US12941773
申请日：2010-11-08
申请人： George A. Olah , G. K. Surya Prakash
发明人： George A. Olah , G. K. Surya Prakash
IPC分类号： C07C27/06 , C07C29/151 , C01B3/38 , C07C29/154 , C07C41/09
CPC分类号： C07C29/1518 , C01B3/38 , C01B3/382 , C01B2203/0233 , C01B2203/0238 , C01B2203/061 , C01B2203/062 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1076 , C01B2203/1082 , C01B2203/1211 , C01B2203/1235 , C01B2203/1241 , C01B2203/141 , C01B2203/148 , C07C29/154 , C07C41/01 , C07C41/09 , Y02P20/52 , C07C43/043 , C07C31/04
摘要： The invention provides for \ a method of forming methanol by combining a mixture of methane, water and carbon dioxide under reaction conditions sufficient to form a mixture of hydrogen and carbon monoxide. Hydrogen and carbon monoxide are reacted under conditions sufficient to form methanol. The molar ratio of hydrogen to carbon monoxide is at least two moles of hydrogen to one mole of carbon monoxide and the overall molar ratio between methane, water and carbon dioxide is about 3:2:1. Methane, carbon dioxide and water are bi-reformed over a catalyst. The catalyst includes a single metal, a metal oxide, a mixed catalyst of a metal and a metal oxide or a mixed catalyst of at least two metal oxides.
摘要翻译：本发明提供了在足以形成氢气和一氧化碳的混合物的反应条件下，通过组合甲烷，水和二氧化碳的混合物来形成甲醇的方法。氢气和一氧化碳在足以形成甲醇的条件下反应。氢与一氧化碳的摩尔比为1摩尔一氧化碳至少2摩尔的氢，而甲烷，水和二氧化碳之间的总摩尔比约为3：2：1。甲烷，二氧化碳和水在催化剂上进行双重改性。催化剂包括单一金属，金属氧化物，金属和金属氧化物的混合催化剂或至少两种金属氧化物的混合催化剂。

2. 发明授权

US08212088B2 Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products 有权
标题翻译：二氧化碳对甲醇，二甲醚和衍生产物的高效选择性化学回收
公开(公告)号：US08212088B2
公开(公告)日：2012-07-03
申请号：US12537647
申请日：2009-08-07
申请人： George A. Olah , G. K. Surya Prakash
发明人： George A. Olah , G. K. Surya Prakash
IPC分类号： C07C29/51 , C07C29/15 , C07C29/132
CPC分类号： C07C29/136 , C07C1/20 , C07C29/04 , C07C29/14 , C07C29/141 , C07C29/149 , C07C41/09 , C07C51/15 , C07C67/08 , C07C67/38 , C07C68/005 , C07C68/02 , C25B3/04 , C07C31/08 , C07C31/04 , C07C31/10 , C07C11/02 , C07C53/02 , C07C69/06 , C07C69/96 , C07C43/043
摘要： An efficient and environmentally beneficial method of recycling and producing methanol from varied sources of carbon dioxide including flue gases of fossil fuel burning powerplants, industrial exhaust gases or the atmosphere itself. Converting carbon dioxide by chemical or electrochemical reduction seconardy treatment to produce essentially methanol, dimethyl ether and derived products.
摘要翻译：一种从不同来源的二氧化碳回收和生产甲醇的有效和环保的方法，包括化石燃料燃烧发电厂，工业废气或大气本身的烟道气。通过化学或电化学还原仲胺处理来转化二氧化碳，主要生产甲醇，二甲醚和衍生产物。

3. 发明授权

US07906559B2 Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas 有权
标题翻译：使用甲烷或天然气的双重重整将二氧化碳转化为甲醇和/或二甲醚
公开(公告)号：US07906559B2
公开(公告)日：2011-03-15
申请号：US11850501
申请日：2007-09-05
申请人： George A. Olah , G. K. Surya Prakash
发明人： George A. Olah , G. K. Surya Prakash
IPC分类号： C07C27/00
CPC分类号： C07C29/1518 , C01B3/38 , C01B3/382 , C01B2203/0233 , C01B2203/0238 , C01B2203/061 , C01B2203/062 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1076 , C01B2203/1082 , C01B2203/1211 , C01B2203/1235 , C01B2203/1241 , C01B2203/141 , C01B2203/148 , C07C29/154 , C07C41/01 , C07C41/09 , Y02P20/52 , C07C43/043 , C07C31/04
摘要： The invention discloses a method of converting carbon dioxide to methanol and/or dimethyl ether using any methane source or natural gas consisting of a combination of steam and dry reforming, in a specific ratio to produce a 2:1 molar ratio of hydrogen and carbon monoxide with subsequent conversion of the CO and H2 mixture exclusively to methanol and/or dimethyl ether. This method is termed the BI-REFORMING™ process. Dehydrating formed methanol allows producing dimethyl ether (DME) using any suitable catalytic method, including use of solid acid catalysts. When recycling formed water into the bi-reforming step the conversion of carbon dioxide with methane produces exclusively dimethyl ether without any by-product formation and complete utilization of hydrogen.
摘要翻译：本发明公开了一种将二氧化碳转化为甲醇和/或二甲醚的方法，使用任何甲烷源或由蒸汽和干重整组合组成的天然气，以特定比例将氢气和一氧化碳摩尔比为2:1 随后将CO和H 2混合物随后转化成甲醇和/或二甲醚。这种方法被称为双重重整过程。脱水形成的甲醇允许使用任何合适的催化方法生产二甲醚（DME），包括使用固体酸催化剂。当将形成的水再循环到双重重整步骤中时，二氧化碳与甲烷的转化仅产生二甲醚，没有任何副产物形成和氢的完全利用。

4. 发明申请

US20100261937A1 RENDERING PETROLEUM OIL AS AN ENVIRONMENTALLY CARBON DIOXIDE NEUTRAL SOURCE MATERIAL FOR FUELS, DERIVED PRODUCTS AND AS A REGENERATIVE CARBON SOURCE 有权
标题翻译：将油石油作为环境二氧化碳中和源燃料，衍生产品和作为再生碳源的材料
公开(公告)号：US20100261937A1
公开(公告)日：2010-10-14
申请号：US12755975
申请日：2010-04-07
申请人： George A. Olah , G.K. Surya Prakash
发明人： George A. Olah , G.K. Surya Prakash
IPC分类号： C07C41/01 , C07C31/04
CPC分类号： C10L1/02 , C07C29/1518 , C07C41/09 , C07C31/04 , C07C43/043
摘要： The invention provides a method for rendering petroleum oil as an essentially environmentally carbon dioxide-neutral fuel and source material. Carbon dioxide produced from petroleum oil combustion is captured, purified, combined with steam and light hydrocarbon fractions, or with hydrogen, and reacted under reaction conditions sufficient to form methanol and/or dimethyl ether, which can be used as fuel or feedstock for derived synthetic hydrocarbons and products.
摘要翻译：本发明提供一种使石油作为基本环境的二氧化碳中性燃料和源材料的方法。从石油燃烧产生的二氧化碳被捕获，纯化，与蒸汽和轻烃馏分或氢气结合，并在足以形成甲醇和/或二甲醚的反应条件下反应，其可用作衍生合成的燃料或原料碳氢化合物和产品。

5. 发明授权

US07705059B2 Selective oxidative conversion of methane to methanol, dimethyl ether and derived products 有权
公开(公告)号：US07705059B2
公开(公告)日：2010-04-27
申请号：US11402051
申请日：2006-04-12
申请人： George A. Olah , G. K. Surya Prakash
发明人： George A. Olah , G. K. Surya Prakash
IPC分类号： C07C27/00
CPC分类号： C07C41/09 , C07C29/14 , C07C29/149 , C07C29/48 , C07C29/50 , C07C45/28 , C07C45/33 , C07C51/215 , C07C67/44 , C10G2300/1025 , C10G2300/1029 , C10G2400/20 , C10G2400/22 , C10G2400/30 , C10L1/023 , C10L1/026 , C25B3/04 , Y02P30/40 , Y02P30/42 , C07C47/04 , C07C53/02 , C07C69/06 , C07C31/04 , C07C43/043 , C07C31/08 , C07C31/10
摘要： The present invention relates to a method of producing methanol from a methane source by oxidizing methane under conditions sufficient to a mixture of methanol and formaldehyde while minimizing the formation of formic acid and carbon dioxide. The oxidation step is followed by treatment step in which formaldehyde is converted into methanol and formic acid which itself can further be converted into methanol via catalytic hydrogenation of intermediately formed methyl formate.

6. 发明申请

US20080039538A1 METHOD FOR PRODUCING METHANOL, DIMETHYL ETHER, DERIVED SYNTHETIC HYDROCARBONS AND THEIR PRODUCTS FROM CARBON DIOXIDE AND WATER (MOISTURE) OF THE AIR AS SOLE SOURCE MATERIAL 失效
标题翻译：用于生产甲醇，二甲醚，衍生的合成烃及其二氧化碳和空气作为纯源材料的水（水分）的产品的方法
公开(公告)号：US20080039538A1
公开(公告)日：2008-02-14
申请号：US11780171
申请日：2007-07-19
申请人： George A. Olah , Robert Aniszfeld
发明人： George A. Olah , Robert Aniszfeld
IPC分类号： C07C27/06
CPC分类号： C07C41/09 , C07C1/20 , C07C29/149 , C07C67/36 , Y02P30/42 , C07C11/02 , C07C69/06 , C07C43/043 , C07C31/04
摘要： A method for producing methanol and dimethyl ether using the air as the sole source of materials is disclosed. The invention relates to a method for separating the water (i.e., the moisture in the air) and carbon dioxide content of atmospheric air for their use in the subsequent production of methanol, dimethyl ether and derived synthetic hydrocarbons as products. The method includes the conversion of carbon dioxide and water under conditions sufficient to produce methanol and/or dimethyl ether. Methanol and/or dimethyl ether can be used as fuel or fuel additives or further converted to synthetic hydrocarbons and their products. Carbon dioxide is captured on a suitable absorbent, preferentially polyethyleneimine supported on nano-structured fumed silica. The process can also involve hydrogenation with hydrogen produced by electrolysis of water obtained from the air or from any other water source. Methanol can be dehydrated to produce dimethyl ether or further processed to produce synthetic hydrocarbons, polymers, and products derived from them by other known methods.
摘要翻译：公开了使用空气作为唯一材料来源生产甲醇和二甲醚的方法。本发明涉及一种分离水（即空气中的水分）和大气中二氧化碳含量的方法，用于随后生产甲醇，二甲醚和衍生的合成烃作为产物。该方法包括在足以产生甲醇和/或二甲醚的条件下转化二氧化碳和水。甲醇和/或二甲醚可用作燃料或燃料添加剂或进一步转化为合成烃及其产品。将二氧化碳捕获在合适的吸收剂上，优选负载在纳米结构的热解法二氧化硅上的聚乙烯亚胺。该方法还可以涉及通过电解从空气或从任何其他水源获得的水产生的氢氢化。可以将甲醇脱水生产二甲醚或进一步加工，以通过其他已知方法生产合成烃，聚合物和衍生自其的产物。

7. 发明授权

US07087789B2 Methods for nucleophilic fluoromethylation 有权
标题翻译：亲核氟甲基化方法
公开(公告)号：US07087789B2
公开(公告)日：2006-08-08
申请号：US10755902
申请日：2004-01-12
申请人： G. K. Surya Prakash , Jinbo Hu , George A. Olah
发明人： G. K. Surya Prakash , Jinbo Hu , George A. Olah
IPC分类号： C07C319/00
CPC分类号： C07D307/42 , C07C29/38 , C07C319/14 , C07C2603/74 , C07C323/03 , C07C33/46 , C07C31/38 , C07C35/52
摘要： A novel, convenient and efficient method for trifluoromethylation of substrate compounds is disclosed. Particularly, alkoxide and hydroxide induced nucleophilic trifluoromethylation of carbonyl compounds, disulfides and other electrophiles, using phenyl trifluoromethyl sulfone PhSO2CF3 (or sulfoxide PhSOCF3) is disclosed. A method of both symmetrical and unsymmetrical anti-2,2-difluoropropan-1,3-diols with high diastereoselectivity (up to 94% de) is disclosed using difluoromethyl phenyl sulfone. This unusual type of high diastereoselectivity was obtained via an intramolecular charge-charge repulsion effect rather than the traditional steric control (based on the Cram's rule). Thus, difluoromethyl phenyl sulfone can be used as a novel difluoromethylene dianion species (“−CF2−”), which can couple two electrophiles (such as diphenyl disulfide or non-enolizable aldehydes) to give new difluoromethylenated products.
摘要翻译：公开了一种用于底物化合物三氟甲基化的新颖，方便和有效的方法。特别地，使用苯基三氟甲基砜PhSO 2 CF 3 N 3（或亚砜PhSOCF 3 N 3），烷氧基和氢氧化物诱导羰基化合物，二硫化物和其它亲电子试剂的亲核三氟甲基化 >）被公开。使用二氟甲基苯基砜公开了具有高非对映选择性（高达94％de）的对称和不对称的2,2-二氟丙-1,3-二醇的方法。这种不寻常类型的高非对映选择性通过分子内电荷 - 排斥效应而不是传统的空间控制获得（基于Cram的规则）。因此，二氟甲基苯基砜可以用作新的二氟亚甲基二氧化物（“ CF2”），其可以偶合两种亲电子（如二苯基二硫化物或不可烯化的醛），得到新的二氟亚甲基化产物。

8. 发明授权

US06803477B2 Magnesium mediated preparation of fluorinated alkyl silanes 失效
标题翻译：镁介导氟化烷基硅烷的制备
公开(公告)号：US06803477B2
公开(公告)日：2004-10-12
申请号：US10305025
申请日：2002-11-27
申请人： G. K. Surya Prakash , Jinbo Hu , George A. Olah
发明人： G. K. Surya Prakash , Jinbo Hu , George A. Olah
IPC分类号： C07F704
CPC分类号： C07F7/0827
摘要： An efficient method is disclosed for the preparation of trifluoromethyl- and difluoromethylsilanes using magnesium metal mediated reductive tri- and difluoromethylation of chlorosilanes with tri- and difluoromethyl sulfides, sulfoxides, and sulfones. One byproduct of the process is diphenyl disulfide. Since phenyl trifluoromethyl sulfone, sulfoxide and sulfide are readily prepared from readily available trifluoromethane and diphenyl disulfide, the method can be considered “pseudo-catalytic” for the preparation of (trifluoromethyl)trimethylsilane from environmentally benign trifluoromethane.
摘要翻译：公开了一种使用镁金属介导的氯硅烷与三 - 和二氟甲基硫化物，亚砜和砜的还原性三氟甲基化和二氟甲基化制备三氟甲基 - 和二氟甲基硅烷的有效方法。该方法的一个副产物是二苯基二硫化物。由于苯基三氟甲基砜，亚砜和硫化物容易由容易得到的三氟甲烷和二苯基二硫化物制备，所以该方法可以被认为是用于从环境友好的三氟甲烷制备（三氟甲基）三甲基硅烷的“假催化”。

9. 发明授权

US4861923A Hydration of propylene to isopropyl alcohol over solid superacidic perfluorinated sulfonic acid catalysts 失效
标题翻译：在固体超强酸全氟磺酸催化剂上丙烯与异丙醇的水合
公开(公告)号：US4861923A
公开(公告)日：1989-08-29
申请号：US648861
申请日：1984-09-07
申请人： George A. Olah
发明人： George A. Olah
IPC分类号： C07C29/04
CPC分类号： C07C29/04
摘要： A process for the hydration of lower olefins to a corresponding alcohol by reacting the olefins with water in the presence of a solid perfluorinated sulfonic superacid catalyst.
摘要翻译：一种通过使烯烃与水在固体全氟磺酸超强酸催化剂存在下反应使低级烯烃水合成相应的醇的方法。

10. 发明授权

US4523040A Methyl halides and methyl alcohol from methane 失效
标题翻译：来自甲烷的甲基卤化物和甲醇
公开(公告)号：US4523040A
公开(公告)日：1985-06-11
申请号：US494915
申请日：1983-05-16
申请人： George A. Olah
发明人： George A. Olah
IPC分类号： C07C17/10 , C07C29/00 , C07C29/124 , C07C41/01 , C07C27/00
CPC分类号： C07C29/124 , C07C17/10 , C07C29/00 , C07C41/01 , Y02P20/52
摘要： This invention relates to solid acidic or metal catalyst-promoted halogenation of methane to produce methyl monohalides in high selectivity. Concurrent or simultaneous hydrolysis provides methyl alcohol and/or dimethyl ether in good yields.
摘要翻译：本发明涉及固体酸性或金属催化剂促进甲烷卤化以高选择性生产甲基一卤化物。同时或同时水解以良好的产率提供甲醇和/或二甲醚。

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