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1. 发明授权

US4876181A Photographic elements containing infrared filter dyes 失效
标题翻译：含红外线滤光片的摄影元素
公开(公告)号：US4876181A
公开(公告)日：1989-10-24
申请号：US166135
申请日：1988-03-10
申请人： Gary S. Proehl , Anthony D. Gingello , David J. Collett , Richard L. Parton , David A. Stegman , Anthony Adin
发明人： Gary S. Proehl , Anthony D. Gingello , David J. Collett , Richard L. Parton , David A. Stegman , Anthony Adin
IPC分类号： C09B23/08 , G03C1/83
CPC分类号： C09B23/086 , G03C1/832
摘要： A dye useful for absorbing infrared radiation in photographic elements, having the structure: ##STR1## is disclosed. In this formula R.sub.1 and R.sub.2 each independently represents sulfoalkyl, carboxyalkyl, or sulfatoalkyl of from 3 to 6 carbon atoms, having at least 3 carbon atoms in the alkyl chain between the nitrogen atom of each Z ring and the sulfo or sulfato group, and at least 2 carbon atoms in the alkyl chain between the nitrogen atom of each Z ring and the carboxy group.R.sub.3 and R.sub.5 are each hydrogen or together represent the atoms necessary to complete 5- or 6-membered carbocyclic ring, and R.sub.4 represents hydrogen, alkyl of 1 to 4 carbon atoms, aryl, cyano, halogen, or ##STR2## where R.sub.6 and R.sub.7 each independently represents alkyl of from 1 to 6 carbon atoms or aryl, or together represent the non-metallic atoms necessary to form a 5- or 6-membered ring.X.sym. represents a cation.Z.sub.1 and Z.sub.2 each independently represent the atoms needed to complete an indole, naphthindole or benzindole nucleus.
摘要翻译：公开了一种用于吸收照相元件中的红外辐射的染料，具有以下结构：。在该式中，R 1和R 2各自独立地表示在每个Z环的氮原子和磺基或硫酸根之间的烷基链中具有至少3个碳原子的3至6个碳原子的磺基烷基，羧烷基或硫酸根烷基，每个Z环的氮原子和羧基之间的烷基链中的至少2个碳原子。 R 3和R 5各自为氢或一起代表完成5-或6-元碳环所必需的原子，并且R 4表示氢，1-4个碳原子的烷基，芳基，氰基，卤素或者其中R 6和R 7 各自独立地表示1至6个碳原子的烷基或芳基，或一起表示形成5-或6-元环所必需的非金属原子。 X（+）表示阳离子。 Z1和Z2各自独立地表示完成吲哚，萘啶或萘吲哚核所需的原子。

2. 发明授权

US4914014A Nucleation of tabular grain emulsions at high pBr 失效
标题翻译：高pBr片状颗粒乳液的成核
公开(公告)号：US4914014A
公开(公告)日：1990-04-03
申请号：US214267
申请日：1988-06-30
申请人： Richard L. Daubendiek , Timothy R. Gersey , Gary S. Proehl
发明人： Richard L. Daubendiek , Timothy R. Gersey , Gary S. Proehl
IPC分类号： G03C1/005 , G03C1/047
CPC分类号： G03C1/0051 , G03C1/047 , G03C2001/0156 , G03C2200/43 , G03C2200/44
摘要： The present invention is directed to a process of precipitating for use in photography a thin tabular grain silver bromide or bromoiodide emulsion within a novel range of low bromide ion concentrations (high pBr levels) at the nucleation stage. A variety of advantages can be realized, including thinner and/or larger diameter tabular grains and novel tabular grain forms.
摘要翻译：本发明涉及一种用于在成核阶段的低溴离子浓度（高pBr水平）的新范围内拍摄薄片状溴化银或溴碘化物乳液的沉淀方法。可以实现各种优点，包括更薄和/或更大直径的片状颗粒和新颖的片状颗粒形式。

3. 发明授权

US5242783A Photographic material and process 失效
标题翻译：摄影材料与工艺
公开(公告)号：US5242783A
公开(公告)日：1993-09-07
申请号：US919421
申请日：1992-07-23
申请人： John M. Buchanan , Gary S. Proehl
发明人： John M. Buchanan , Gary S. Proehl
IPC分类号： C07D211/74 , C07D211/96 , C07D309/30 , C07D335/02 , C07D345/00 , C07D401/12 , C07D403/06 , C07D403/12 , C07D405/12 , C07D409/12 , C07D417/12 , C09K3/00 , G03C7/305 , G03C7/32
CPC分类号： G03C7/30511 , Y10S430/156 , Y10S430/158 , Y10S430/159 , Y10S430/16
摘要： A novel blocked photographically useful compound element and process are based on a new blocking group that comprises a beta-ketocarbonyl group that is part of a 5- to 7-member heterocyclic ring containing a hetero-atom not adjacent to the beta-ketocarbonyl group. Such a blocked photographically useful compound provides a photographic material and process enabling more rapid release of the photographically useful group upon processing.
摘要翻译：一种新型封闭的有用的化合物元素和方法是基于新的封闭基团，其包含β-酮羰基，其是含有不与β-酮羰基相邻的杂原子的5-至7-元杂环的一部分。这种封闭的照相有用化合物提供了一种照相材料和方法，使得在加工时能够更快速地释放相片有用的组。

4. 发明授权

US5019492A Photographic element and process comprising a blocked photographically useful compound 失效
标题翻译：摄影元件和包含封闭的照相用化合物的方法
公开(公告)号：US5019492A
公开(公告)日：1991-05-28
申请号：US343981
申请日：1989-04-26
申请人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
发明人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
IPC分类号： G03C1/06 , G03C1/43 , G03C7/305 , G03C7/392
CPC分类号： G03C7/30511 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16 , Y10S430/161
摘要： A novel blocked photographically useful compound comprises a new blocking group that (a) comprises two electrophilic groups, the least electrophilic of which is bonded directly or through a timing group to the photographically useful group (PUG) of the compound, (b) is capable of reacting with a dinucleophile reagent, and (c) has the two electrophilic groups separated from each other by a bond or unsubstituted or substituted atom that enables nucleophilic displacement to occur with release of PUG when the compound is reacted with a dinucleophile reagent. Such a blocked photographically useful compound is useful in a photographic material and process to provide increased stability and enable more rapid release of the photographically useful group upon reaction with a dinucleophile reagent.

5. 发明授权

US5612173A One equivalent couplers and low PKA release dyes 失效
标题翻译：一种等效的成色剂和低PKA释放染料
公开(公告)号：US5612173A
公开(公告)日：1997-03-18
申请号：US449891
申请日：1995-05-23
申请人： Gary S. Proehl , Stephen P. Singer , J. Michael Buchanan
发明人： Gary S. Proehl , Stephen P. Singer , J. Michael Buchanan
IPC分类号： C07C311/03 , C07C311/36 , C07C311/39 , C07D231/52 , C07D487/04 , C09B53/00 , C09B55/00 , G03C1/10 , G03C1/83 , G03C7/305 , G03C7/32 , G03C7/333 , G03C1/46
CPC分类号： C07D487/04 , C07C311/03 , C07C311/36 , C07C311/39 , C07D231/52 , C09B53/00 , C09B55/009 , G03C1/102 , G03C1/83 , G03C7/30547 , Y10S430/156 , Y10S430/159
摘要： A photographic element containing a dye which when released from a coupler has a sufficiently low pKa, generally less than about 5, such that the dye remains substantially or fully ionized during coating of the film and in the produced film, results in an element containing a dye which has the desired hue without the use of additional additives, such as mordants, to keep the dye ionized. The dye is also useful in photographic elements without release from a coupler, for example, as a filter dye.
摘要翻译：含有染料的照相元件当从耦合剂释放时具有足够低的pKa（通常小于约5），使得染料在膜的涂覆期间保持基本上或完全电离，并且在所制备的膜中导致含有染料具有所需的色调而不使用额外的添加剂，如媒染剂，以保持染料电离。该染料也可用于照相元件而不从成色剂释放，例如作为过滤染料。

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