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1. 发明授权

US4740607A Removal of olefins from organohalosilanes 失效
标题翻译：从有机硅烷中除去烯烃
公开(公告)号：US4740607A
公开(公告)日：1988-04-26
申请号：US103474
申请日：1987-10-01
申请人： Gary N. Bokerman , Ollie W. Marko , Robert D. Steinmeyer
发明人： Gary N. Bokerman , Ollie W. Marko , Robert D. Steinmeyer
IPC分类号： C07B61/00 , B01J31/22 , C07F7/12 , C07F7/08
CPC分类号： C07F7/121
摘要： A process for purifying alkylhalosilanes to reduce the content of olefinic impurities is described. The process comprises (A) contacting crude alkylhalosilanes, containing as a minor portion the olefinic impurities, with a hydrogen-containing halosilane and a soluble compound of a Group VIII metal; (B) facilitating reaction of the olefins with the hydrogen-containing silicon compound in contact with the Group VIII metal compound to form linear or branched silalkanes, said silalkanes having the formula,R.sup.ii.sub.m A.sub.n SiX.sub.p ; and(C) separating the alkylhalosilanes from the silalkanes formed in the reaction in (B).

2. 发明授权

US5183914A Alkoxysilanes and oligomeric alkoxysiloxanes by a silicate-acid route 失效
标题翻译：烷氧基硅烷和低聚烷氧基硅氧烷
公开(公告)号：US5183914A
公开(公告)日：1993-02-02
申请号：US692413
申请日：1991-04-29
申请人： Li-Tain Yeh , Malcolm E. Kenney , Gary N. Bokerman , John P. Cannady , Ollie W. Marko
发明人： Li-Tain Yeh , Malcolm E. Kenney , Gary N. Bokerman , John P. Cannady , Ollie W. Marko
IPC分类号： C07F7/04
CPC分类号： C07F7/04 , C07F7/045
摘要： The present invention relates to a novel method of preparing alkoxysilanes and oligomeric alkoxysiloxanes. The method comprises reacting a metal silicate with an acid selected from the group consisting of sulfurous acid and acids with a pKa greater than about 2.5 in the presence of an alcohol. The resultant product is then reacted with an alcohol to form the alkoxysilane or oligomeric alkoxysiloxane, depending on the starting silicate. This method is particularly valuable since the reaction conditions are mild and the reactants are readily available.
摘要翻译：本发明涉及一种制备烷氧基硅烷和低聚烷氧基硅氧烷的新方法。该方法包括在醇的存在下使金属硅酸盐与选自亚硫酸和酸的酸反应，其中pKa大于约2.5。然后，所得产物与醇反应以形成烷氧基硅烷或低聚烷氧基硅氧烷，这取决于起始硅酸盐。该方法特别有价值，因为反应条件温和，反应物容易获得。

3. 发明授权

US5233070A Process for converting chlorine end-terminated polyorganosiloxanes to polyorganocyclosiloxanes 失效
标题翻译：将氯端基聚有机硅氧烷转化为聚有机硅氧烷的方法
公开(公告)号：US5233070A
公开(公告)日：1993-08-03
申请号：US996417
申请日：1992-12-23
申请人： Gary N. Bokerman , Larry H. Wood
发明人： Gary N. Bokerman , Larry H. Wood
IPC分类号： C07F7/21 , C08G77/04 , C08G77/06 , C08G77/10
CPC分类号： C08G77/045 , C07F7/21 , C08G77/10
摘要： The present invention is a process for converting chlorine end-terminated polyorganosiloxanes to polyorganocyclosiloxanes. The process comprises forming a mixture comprising chlorine end-terminated polyorganosiloxanes, aqueous hydrogen chloride, and a heterogeneous reequilibrium catalyst. The mixture is heated at a temperature within a range of about 70.degree. C. to 150.degree. C. to effect reequilibrium of the chlorine end-terminated polyorganosiloxanes to form polyorganocyclosiloxanes which are removed from the process as they are formed.
摘要翻译：本发明是将氯端基聚有机硅氧烷转化为聚有机硅氧烷的方法。该方法包括形成包含氯末端聚有机硅氧烷，氯化氢水溶液和异相重均衡催化剂的混合物。将混合物在约70℃至150℃的温度范围内加热，以实现氯端基聚有机硅氧烷的再平衡，形成聚自由基硅氧烷，当它们形成时从该方法中除去。

4. 发明授权

US4133939A Method for applying a silicone release coating and coated article therefrom 失效
标题翻译：从其中涂覆硅氧烷防粘涂层和涂布制品的方法
公开(公告)号：US4133939A
公开(公告)日：1979-01-09
申请号：US861134
申请日：1977-12-16
申请人： Gary N. Bokerman , David J. Gordon
发明人： Gary N. Bokerman , David J. Gordon
IPC分类号： C09J7/02 , B05D5/08 , C08G77/00 , C08G77/28 , C09D5/00 , C09D5/20 , C09D183/04 , C09D183/08 , C09J7/04 , D21H19/32 , D21H27/00 , B32B21/04 , B05D3/06
CPC分类号： D21H27/001 , C09D183/08 , C09J7/0228 , D21H19/32 , C09J2400/283 , C09J2483/005 , Y10T428/31663 , Y10T428/31993
摘要： Solid substrates are provided with a cured silicone release coating by applying certain mercaptoalkyl-containing triorganosiloxane-endblocked polydiorganosiloxane fluids to the surface of the substrate and exposing the applied fluid to energetic radiation to rapidly cure and bond the fluid. For example, a mixture of benzophenone and a trimethylsiloxane-endblocked copolymer of dimethylsiloxane units and methylmercaptopropylsiloxane units, when applied to kraft paper and cured with ultraviolet light, provides premium release of aggressive acrylic adhesive from the surface of the coated paper.
摘要翻译：通过将某些含巯基烷基的三有机硅氧烷封端的聚二有机硅氧烷流体施加到基材的表面并将所施加的流体暴露于高能辐射以快速固化和粘合流体，从而为固体基材提供固化的硅氧烷剥离涂层。例如，二甲基硅氧烷单元和甲基巯基丙基硅氧烷单元的二苯甲酮和三甲基硅氧烷封端的共聚物的混合物当用于牛皮纸并用紫外线固化时，提供了从涂布纸的表面优良释放的侵蚀性丙烯酸粘合剂。

5. 发明授权

US5175329A Production of organosilanes from polysilanes 失效
标题翻译：从聚硅烷生产有机硅烷
公开(公告)号：US5175329A
公开(公告)日：1992-12-29
申请号：US862856
申请日：1992-04-03
申请人： Gary N. Bokerman , John P. Cannady , Ann E. Ogilvy
发明人： Gary N. Bokerman , John P. Cannady , Ann E. Ogilvy
IPC分类号： B01J21/12 , B01J23/42 , B01J23/44 , B01J23/755 , C07B61/00 , C07F7/12
CPC分类号： C07F7/12 , C07F7/125 , C07F7/126 , C07F7/128
摘要： The present invention is a process for the production of organosilanes from the high-boiling residue resulting from the reaction of organohalides with silicon metalloid in a process typically referred to as the "direct process." The present process comprises forming a mixture comprising a organotrihalosilane and the high-boiling residue in the presence of hydrogen gas, a hydrogenolysis catalyst, and a redistribution catalyst. The organotrihalosilane and high-boiling residue are converted into commercially useful di- and triorganosilanes and organohydrosilanes. The present process results in consumption of the organotrihalosilane rather than the net increase which typically occurs in the absence of the redistribution catalyst.

6. 发明授权

US5239101A Anhydrous process for preparation of polyorganosiloxanes 失效
标题翻译：无机硅氧烷制备方法
公开(公告)号：US5239101A
公开(公告)日：1993-08-24
申请号：US994582
申请日：1992-12-21
申请人： Gary N. Bokerman , David E. Puckett , Larry H. Wood
发明人： Gary N. Bokerman , David E. Puckett , Larry H. Wood
IPC分类号： C08G77/06 , C07F7/08 , C08G77/10 , C08G77/12 , C08G77/38
CPC分类号： C08G77/12 , C07F7/0874 , C07F7/0896 , C08G77/10
摘要： The present invention is an anhydrous process for preparing organosiloxy end-blocked polyorganosiloxanes from chlorine end-terminated polyorganosiloxanes. The process comprises contacting an anhydrous mixture comprising a chlorine end-terminated polyorganosiloxane and an organodisiloxane with a rearrangement catalyst, where the rearrangement catalyst facilitates a chlorine and organosiloxy exchange between the chlorine end-terminated polyorganosiloxane and the organodisiloxane forming a organochlorosilane as a by-product. The organochlorosilane is continuously removed from the process providing a means by which the chlorine displaced from the chlorine end-terminated polyorganosiloxane can be effectively removed from the organosiloxy end-blocked polyorganosiloxanes in a useable form. The present process is especially useful for the rearrangement of chlorine end-terminated polyorganosiloxanes having one or more hydrogen atoms bonded to silicon to organosiloxy end-blocked polyorganohydrosiloxanes.
摘要翻译：本发明是从氯端基聚有机硅氧烷制备有机甲硅烷氧基封端的聚有机硅氧烷的无水方法。该方法包括将包含氯端基聚有机硅氧烷和有机二硅氧烷的无水混合物与重排催化剂接触，其中重排催化剂促进氯端基聚有机硅氧烷和有机二硅氧烷之间的氯和有机甲硅烷氧交换作为副产物形成有机氯硅烷。从该方法中连续除去有机氯代硅烷，提供了从氯端基聚有机硅氧烷中排出的氯可以有效地从有机甲硅烷氧基封端的聚有机硅氧烷中以可用形式除去的方法。本方法对于将具有一个或多个与硅键合的氢原子的氯端基聚有机硅氧烷重排为有机甲硅烷氧基封端的聚有机氢硅氧烷特别有用。

7. 发明授权

US5120520A Silane products from reaction of solid silicon monoxide with aromatic halides 失效
标题翻译：由固体一氧化硅与芳族卤化物反应的硅烷产物
公开(公告)号：US5120520A
公开(公告)日：1992-06-09
申请号：US700277
申请日：1991-05-15
申请人： Gary N. Bokerman , John P. Cannady , Charles S. Kuivila
发明人： Gary N. Bokerman , John P. Cannady , Charles S. Kuivila
IPC分类号： B01J21/02 , B01J23/14 , B01J23/80 , B01J27/122 , B01J27/138 , C01B33/04 , C01B33/08 , C01B33/107 , C07B61/00 , C07F7/12
CPC分类号： C07F7/122 , C01B33/1071
摘要： The described invention is a process for preparing silanes from the reaction of solid silicon monoxide with aromatic halides. The solid silicon monoxide is reacted with the aromatic halide in the presence of a catalyst which can increase the conversion of silicon monoxide to silanes, and partially select for arylsilane products. The process may employ an activation step in which the solid silicon monoxide is activated by heating in an inert atmosphere. Activation of the solid silicon monoxide can increase silicon conversion and increase selectivity for arylsilane products.

8. 发明授权

US4981668A Silicon carbide as a raw material for silicon production 失效
标题翻译：碳化硅作为硅生产的原料
公开(公告)号：US4981668A
公开(公告)日：1991-01-01
申请号：US206633
申请日：1988-06-14
申请人： Vishu D. Dosaj , Alvin W. Rauchholz , Martin D. Young , Gary N. Bokerman
发明人： Vishu D. Dosaj , Alvin W. Rauchholz , Martin D. Young , Gary N. Bokerman
IPC分类号： C01B33/025
CPC分类号： C01B33/025
摘要： What is described is a process for the production of silicon via the carbothermic reduction of silicon dioxide in which silicon carbide is fed as the total reductant source or as a portion of the reductant input. The process also includes recovery and recycle to the furnace silicon monoxide and other silicon-containing materials from the by-produced gases from the furnace to maximize raw material efficiency. Finally, the process includes the recovery of value from the by-produced gases via the use of the gases as a chemical intermediate or the use of the gases as a fuel for a combustion process.
摘要翻译：描述的是通过二氧化碳的碳热还原制备硅的方法，其中碳化硅作为总还原剂源或作为还原剂输入的一部分进料。该方法还包括从来自炉的副产物气体回收和回收炉中的一氧化硅和其它含硅材料，以使原料效率最大化。最后，该方法包括通过使用作为化学中间体的气体或使用气体作为燃烧过程的燃料从副产气体中回收价值。

9. 发明授权

US4052529A Radiation-curable mercaptoalkyl vinyl polydiorganosiloxanes, method of coating there with and coated article 失效
标题翻译：辐射可固化的三烯丙基乙烯基聚氧乙烯硅氧烷，其涂层与涂层的方法
公开(公告)号：US4052529A
公开(公告)日：1977-10-04
申请号：US663324
申请日：1976-03-03
申请人： Gary N. Bokerman , Joseph A. Colquhoun , David J. Gordon
发明人： Gary N. Bokerman , Joseph A. Colquhoun , David J. Gordon
IPC分类号： C09K3/00 , B05D5/08 , C08L83/00 , C08L83/04 , C08L83/08 , C09J7/02 , C09J7/04 , C10M111/04 , C10N20/02 , C10N40/36 , D21H17/59 , B05D3/06
CPC分类号： D21H17/59 , C08L83/08 , C09J7/0228 , C09J2205/31 , C09J2400/226 , C09J2400/283 , C09J2483/005 , Y10T428/31663 , Y10T428/31993
摘要： Certain polydiorganosiloxane compositions bearing mercaptoalkyl radicals and vinyl radicals are disclosed which cure in the presence of radiation such as ultraviolet light. The compositions consist essentially of a mixture of a triorganosiloxane-endblocked polydiorganosiloxane fluid in which from 1 to 5 percent of the organic radicals are mercaptoalkyl radicals and a methylvinylpolysiloxane. The compositions may be applied to a substrate such as paper and exposed to radiation to prepare a coated substrate that provides premium release of aggressive acrylic adhesives.

10. 再颁专利

USRE35298E Production of organosilanes from polysilanes 失效
标题翻译：从聚硅烷生产有机硅烷
公开(公告)号：USRE35298E
公开(公告)日：1996-07-16
申请号：US151654
申请日：1993-11-15
申请人： Gary N. Bokerman , John P. Cannady , Ann O. Skaugset
发明人： Gary N. Bokerman , John P. Cannady , Ann O. Skaugset
IPC分类号： B01J21/12 , B01J23/42 , B01J23/44 , B01J23/755 , C07B61/00 , C07F7/12 , C07F7/08
CPC分类号： C07F7/12 , C07F7/125 , C07F7/126 , C07F7/128
摘要： The present invention is a process for the production of organosilanes from the high-boiling residue resulting from the reaction of organohalides with silicon metalloid in a process typically referred to as the "direct process." The present process comprises forming a mixture comprising a organotrihalosilane and the high-boiling residue in the presence of hydrogen gas, a hydrogenolysis catalyst, and a redistribution catalyst. The organotrihalosilane and high-boiling residue are converted into commercially useful di- and triorganosilanes and organohydrosilanes. The present process results in consumption of the organotrihalosilane rather than the net increase which typically occurs in the absence of the redistribution catalyst.
摘要翻译：本发明是从通常称为“直接方法”的方法由有机卤化物与硅准金属反应产生的高沸点残余物生产有机硅烷的方法。本方法包括在氢气，氢解催化剂和再分布催化剂的存在下形成包含有机三卤代硅烷和高沸点残余物的混合物。有机三卤硅烷和高沸点残余物转化为商业上有用的二 - 和三有机硅烷和有机氢硅烷。本方法导致有机三卤代硅烷的消耗，而不是在不存在再分布催化剂的情况下通常发生的净增加。

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