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1. 发明授权

US5320938A High chloride tabular grain emulsions and processes for their preparation 失效
标题翻译：高氯化物片状颗粒乳剂及其制备方法
公开(公告)号：US5320938A
公开(公告)日：1994-06-14
申请号：US112489
申请日：1993-08-25
申请人： Gary L. House , Thomas B. Brust , Debra L. Hartsell , Donald L. Black , Michael G. Antoniades , Jerzy A. Budz , Yun C. Chang , Roger Lok , Sherrill A. Puckett , Allen K. Tsaur
发明人： Gary L. House , Thomas B. Brust , Debra L. Hartsell , Donald L. Black , Michael G. Antoniades , Jerzy A. Budz , Yun C. Chang , Roger Lok , Sherrill A. Puckett , Allen K. Tsaur
IPC分类号： G03C1/005 , G03C1/047 , G03C1/07 , G03C1/16 , G03C1/18 , G03C1/015 , G03C1/09 , G03C1/34
CPC分类号： G03C1/0053 , G03C1/047 , G03C1/07 , G03C1/16 , G03C1/18 , G03C1/34 , G03C2001/0055 , G03C2001/0156 , G03C2001/03511 , G03C2001/03558 , G03C2001/03594 , G03C2001/094 , G03C2200/01 , G03C2200/33 , G03C2200/40 , G03C2200/59
摘要： Silver halide emulsions are disclosed in which at least 50 percent of total grain projected area is accounted for by tabular grains (1) bounded by {100} major faces having adjacent edge ratios of less than 10, (2) each having an aspect ratio of at least 2, and (3) internally at their nucleation site containing iodide and at least 50 mole percent chloride. The emulsions are prepared by a process comprised of the steps of (a) introducing silver and halide salts into a dispersing medium so that nucleation of the tabular grains occurs in the presence of iodide with chloride accounting for at least 50 mole percent of the halide present in the dispersing medium and the pCl of the dispersing medium being maintained in the range of from 0.5 to 3.5 and (b) following nucleation completing grain growth under conditions that maintain the {100} major faces of the tabular grains.
摘要翻译：公开了卤化银乳剂，其中总颗粒投影面积的至少50％由具有相邻边缘比率小于10的{100}主面界定的片状颗粒（1）占据，（2）各自具有纵横比为至少2和（3）内部在其含有碘化物和至少50摩尔％氯化物的成核位置。通过以下步骤制备乳剂：（a）将银和卤化物盐引入分散介质中，使得在存在氯化物的碘化物存在下，片状颗粒的成核占至少50％的卤化物存在在分散介质中，分散介质的pCl保持在0.5〜3.5的范围内，（b）在维持片状颗粒的{100}主面的条件下，成核后完成晶粒生长。

2. 发明授权

US5494788A Chemical and spectral sensitization of high-chloride tabular grains using high-temperature heat treatment 失效
标题翻译：使用高温热处理的高氯化物片状颗粒的化学和光谱增感
公开(公告)号：US5494788A
公开(公告)日：1996-02-27
申请号：US315031
申请日：1994-09-29
申请人： Yun C. Chang , Jerzy A. Budz
发明人： Yun C. Chang , Jerzy A. Budz
IPC分类号： G03C1/005 , G03C1/07 , G03C1/09 , G03C1/14 , G03C1/16 , G03C1/18 , G03C1/035 , G03C1/34
CPC分类号： G03C1/09 , G03C1/0053 , G03C1/07 , G03C1/14 , G03C1/16 , G03C1/18 , G03C2001/091 , G03C2001/095 , G03C2200/03
摘要： The invention relates to a method of sensitizing (111) high chloride tabular grains having {111} major faces comprising providing the high chloride tabular grains, and sensitizing using temperatures greater than 70.degree. C.
摘要翻译：本发明涉及一种致敏（111）高氯化物片状颗粒的方法，其具有{111}主面，包括提供高氯化物片状颗粒，并使用大于70℃的温度进行敏化。

3. 发明授权

US06265145B1 Process for the preparation of high chloride emulsions containing iodide 失效
标题翻译：制备含有碘化物的高氯化物乳液的方法
公开(公告)号：US06265145B1
公开(公告)日：2001-07-24
申请号：US09475405
申请日：1999-12-30
申请人： Rajesh V. Mehta , Jerzy A. Budz , Jess B. Hendricks, III , Heinz E. Stapelfeldt , Seshadri Jagannathan , Ramesh Jagannathan
发明人： Rajesh V. Mehta , Jerzy A. Budz , Jess B. Hendricks, III , Heinz E. Stapelfeldt , Seshadri Jagannathan , Ramesh Jagannathan
IPC分类号： G03C1005
CPC分类号： G03C1/015 , G03C1/035 , G03C1/07 , G03C2001/03517 , G03C2200/01
摘要： A process for the preparation of a radiation-sensitive silver halide emulsion comprised of high chloride cubical silver halide grains containing from 0.05 to 3 mole percent iodide, based on total silver, where the iodide is incorporated in the grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration is disclosed, the process comprising: (a) providing in a stirred reaction vessel a dispersing medium and host high chloride silver halide cubical grains comprising a speed enhancing amount of iodide, and (b) precipitating silver halide onto the host grains by introducing at least a silver salt solution into the dispersing medium at a rate such that the normalized molar addition rate, Rn, is above 3.0×10−2 min−1, Rn satisfying the formula: Rn=[Qf×Cf]/M where Qf is the volumetric rate of addition, in L/min, of silver salt solution into the reaction vessel; Cf is the concentration, in moles/L, of the silver salt solution; and M is total moles of silver halide in the host grains in the reaction vessel at the precise moment of addition of the silver salt solution. In a further aspect, this invention is directed towards a photographic recording element comprising a support and at least one light sensitive silver halide emulsion layer comprising silver halide grains prepared as described above. The advantages of the invention are generally accomplished in accordance with the discovery that when the exterior portion of profiled silver iodochloride grains are grown under specific conditions of high molar addition rates, iodochloride emulsions of enhanced sensitivity and photographic curve shape are produced, as speed can be increased while keeping fog to a low level.
摘要翻译：一种用于制备辐射敏感的卤化银乳剂的方法，其包含基于总银含有0.05至3摩尔％碘化物的高氯化物立方体卤化银颗粒，其中碘化物以受控的，不均匀的方式掺入颗粒中分布形成包含总银的至少50％，厚度大于Å的无碘化物表面壳和含有最大碘化物浓度的亚表面壳的芯，该方法包括：（a）提供在搅拌的反应容器中，分散介质和包含加速量的碘化物的高氯化物卤化银立方晶粒和（b）通过将至少一种银盐溶液以一定速率引入到分散介质中而将卤化银沉淀到主体颗粒上使得归一化的摩尔加成速率Rn高于3.0×10 -2分钟-1，Rn满足下式：其中Qf是硅的体积加入速率（L / min）将盐溶液加入到反应容器中; Cf是银盐溶液的浓度，以摩尔/ L表示; 并且M是在银盐溶液的添加的精确时刻反应容器中的主体颗粒中卤化银的总摩尔数。在另一方面，本发明涉及一种照相记录元件，其包括载体和包含如上所述制备的卤化银颗粒的至少一种感光卤化银乳剂层。本发明的优点通常根据以下发现来实现：当异氰酸银碘化银颗粒的外部部分在高摩尔添加速率的特定条件下生长时，产生增强灵敏度的碘氯化物乳剂和照相曲线形状，因为速度可以在将雾保持在低水平的同时增加。

4. 发明授权

US5866314A Preparation and use of A dimethylamine silver chloro-iodide complex as a single source precursor for iodide incorporation of silver chloride crystals 失效
标题翻译：制备和使用二甲胺碘化银碘络合物作为氯化银晶体碘化物的单一来源前体
公开(公告)号：US5866314A
公开(公告)日：1999-02-02
申请号：US866853
申请日：1997-05-30
申请人： Tommie L. Royster, Jr. , Seshadri Jagannathan , Jerzy A. Budz , Jerzy Z. Mydlarz
发明人： Tommie L. Royster, Jr. , Seshadri Jagannathan , Jerzy A. Budz , Jerzy Z. Mydlarz
IPC分类号： C01G5/02 , C07C211/63 , C07F1/00 , C07F1/10 , G03C1/015 , G03C1/035 , G03C1/005 , C01G5/00
CPC分类号： C07F1/005 , G03C1/015
摘要： A dimethylamine silver chloro-iodide complex is used as a single source precursor for iodide incorporation in silver chloride crystals.
摘要翻译：氯化二甲基胺络合物被用作氯化银晶体中碘化物的单一来源前体。

5. 发明授权

US5783373A Digital imaging with high chloride emulsions 失效
标题翻译：数字成像与高氯化物乳剂
公开(公告)号：US5783373A
公开(公告)日：1998-07-21
申请号：US740535
申请日：1996-10-30
申请人： Jerzy Z. Mydlarz , Jerzy A. Budz , Eric L. Bell
发明人： Jerzy Z. Mydlarz , Jerzy A. Budz , Eric L. Bell
IPC分类号： G03C1/005 , G03C1/035 , G03C1/047 , G03C1/08 , G03C1/09 , G03C7/30
CPC分类号： G03C1/035 , G03C1/0053 , G03C1/08 , G03C1/09 , G03C7/3022 , G03C1/047 , G03C2001/03517 , G03C2001/03535 , G03C2001/03541 , G03C2001/0845 , G03C2001/0854 , G03C2001/093 , G03C2001/094 , G03C2200/01 , G03C2200/39 , G03C2200/42 , G03C5/164
摘要： An electronic printing method is disclosed which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100.mu. seconds duration in a pixel-by-pixel mode. The silver halide emulsion layer is comprised of grains predominantly bounded by {100} crystal faces and internally containing three dopants each selected to satisfy a different one of the following class requirements: (i) a metal coordination complex containing a nitrosyl or thionitrosyl ligand in combination with a transition metal chosen from groups 5 to 10 inclusive of the periodic table of elements, (ii) a shallow electron trapping dopant, and (iii) a iridium coordination complex having ligands each of which are more electropositive than a cyano ligand. A gelatino-peptizer for the grains is employed that contains less than 30 micromoles of methionine per gram. The dopants and peptizer in combination increase contrast and provide a highly unexpected increase in high density contrast.
摘要翻译：公开了一种电子印刷方法，其包括以逐像素模式对记录元件的辐射敏感卤化银乳剂层进行至少10-4erg / cm2的光化辐射长达100μs的持续时间。卤化银乳剂层由主要由{100}晶面限定的晶粒组成，内部含有三种掺杂剂，每种掺杂剂选择满足以下类别要求中的不同之一：（i）含有亚硝酰基或亚硫酰基配位体的金属配位络合物具有选自元素周期表第5至10族的过渡金属，（ii）浅电子俘获掺杂剂，和（iii）具有比氰基配体更具有正电性的配体的铱配位络合物。使用含有每克少于30微摩尔甲硫氨酸的晶粒的明胶胶溶剂。掺杂剂和胶溶剂组合增加了对比度，并提供了高度意想不到的高密度对比度的增加。

6. 发明授权

US06326134B1 Process for manufacture of photographic emulsion 失效
标题翻译：摄影乳液的制造方法
公开(公告)号：US06326134B1
公开(公告)日：2001-12-04
申请号：US09645625
申请日：2000-08-24
申请人： Lloyd A. Lobo , Sridhar Sadasivan , John W. Boettcher , Seshadri Jagannathan , Jerzy A. Budz , David C. Gliottone
发明人： Lloyd A. Lobo , Sridhar Sadasivan , John W. Boettcher , Seshadri Jagannathan , Jerzy A. Budz , David C. Gliottone
IPC分类号： G03C1005
CPC分类号： G03C1/043 , G03C1/005 , G03C1/047 , G03C2001/7448
摘要： A process for forming a silver halide photographic emulsion is disclosed comprising precipitating silver halide grains in an aqueous dispersing medium to which has been added silver and halide salt solutions while agitating the dispersing medium, wherein the precipitation is done in the presence of an antifoamant compound of the formula RO(CH2CH2O)nH wherein R represents an alkyl or alkenyl group containing 10 to 25 carbon atoms, or mixtures thereof, and n represents a mean value of from 2 to 4. The antifoamant material may be delivered to the aqueous dispersing medium as a small particle dispersion, made with the same peptizer used for manufacturing the emulsion or another stabilizer. A further embodiment of the invention is directed towards a silver halide photographic material comprising a support upon which is coated at least one light sensitive silver halide emulsion layer, comprising a silver halide emulsion precipitated in accordance with the described process.
摘要翻译：公开了一种形成卤化银照相乳剂的方法，其包括在水分散介质中沉淀卤化银颗粒，在其中加入银和卤化物盐溶液同时搅拌分散介质，其中沉淀是在消泡化合物式RO（CH 2 CH 2 O）n H其中R表示含10至25个碳原子的烷基或链烯基，或其混合物，n表示平均值为2至4.消泡剂可以作为由用于制造乳液或另一种稳定剂的相同胶溶剂制成的小颗粒分散体。本发明的另一个实施方案涉及一种包含载体的卤化银照相材料，其上涂覆有至少一种感光卤化银乳剂层，其包含根据所述方法沉淀的卤化银乳剂。

7. 发明授权

US06248507B1 Composite silver halide grains with improved reciprocity and process for their preparation 失效
标题翻译：具有改进的互易性的复合卤化银颗粒及其制备方法
公开(公告)号：US06248507B1
公开(公告)日：2001-06-19
申请号：US09475839
申请日：1999-12-30
申请人： Jerzy A. Budz , Seshadri Jagannathan , Alan R. Sadler
发明人： Jerzy A. Budz , Seshadri Jagannathan , Alan R. Sadler
IPC分类号： G03C1005
CPC分类号： G03C1/015 , G03C1/035 , G03C1/09 , G03C5/04 , G03C2001/03535 , G03C2001/03541 , G03C2001/03552 , G03C2001/093 , G03C2200/39
摘要： A process for the preparation of a radiation-sensitive silver halide emulsion comprised of high chloride cubical host grains containing from 0.05 to 3 mole percent iodide, based on total silver, and epitaxially deposited silver bromide, where the iodide is incorporated in the host grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration is disclosed, the process comprising: (a) providing in a stirred reaction vessel a dispersing medium and high chloride silver halide cubical grains which form the high chloride host grain cores, (b) adding fine silver iodide grains to the reaction vessel and ripening out the fine silver iodide grains to form the sub-surface shells that contain a maximum iodide concentration, (c) precipitating silver chloride onto the sub-surface shells to form an iodide free surface shell, and (d) depositing silver bromide in an amount of from 0.05 to 5 mole percent, based on total silver, on the host grain surfaces in the presence of an iridium dopant. Also disclosed are photographic recording elements comprising a support and at least one light sensitive silver halide emulsion layer comprising silver halide grains prepared as described above, and an electronic printing method which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10−4 ergs/cm2 for up to 100&mgr; seconds duration in a pixel-by-pixel mode, wherein the silver halide emulsion layer is comprised of silver halide grains prepared as described above.
摘要翻译：一种用于制备辐射敏感的卤化银乳剂的方法，其由高氯化物立方体主体颗粒组成，其含有基于总银的0.05至3摩尔％的碘化物和外延沉积的溴化银，其中将碘化物掺入主体颗粒中公开了一种控制的，不均匀的分布，形成包含总银的至少50％，厚度大于的无碘化物表面壳和含有最大碘化物浓度的亚表面壳的核心，该方法包括：（a）在搅拌的反应容器中提供形成高氯化物主体颗粒芯的分散介质和高氯化物卤化银立方晶粒，（b）向反应容器中加入细小的碘化银颗粒并熟化出碘化银细颗粒以形成含有最大碘化物浓度的亚表面壳，（c）将氯化银沉淀到次表面壳上以形成无碘化物并且（d）在铱掺杂剂的存在下，在主体颗粒表面上以基于总银的0.05至5摩尔％的量沉积溴化银。还公开了包含载体和包含如上所述制备的卤化银颗粒的至少一种感光卤化银乳剂层的照相记录元件和电子印刷方法，其包括使记录元件的辐射敏感卤化银乳剂层进行光化辐射至少10-4ergerg / cm2，以逐像素模式持续长达100mu秒，其中卤化银乳剂层由如上所述制备的卤化银颗粒组成。

8. 发明授权

US06242172B1 High chloride emulsions doped with iridium complexes 失效
标题翻译：掺有铱络合物的高氯化物乳液
公开(公告)号：US06242172B1
公开(公告)日：2001-06-05
申请号：US09475841
申请日：1999-12-30
申请人： Jerzy A. Budz , Eric L. Bell , Rajesh V. Mehta
发明人： Jerzy A. Budz , Eric L. Bell , Rajesh V. Mehta
IPC分类号： G03C108
CPC分类号： G03C5/04 , G03C1/035 , G03C1/09 , G03C2001/03535 , G03C2001/03541 , G03C2001/093 , G03C2200/39
摘要： A radiation-sensitive emulsion is disclosed comprised of cubical silver halide grains containing from 0.05 to 3 mole percent iodide, based on total silver, and an iridium coordination complex dopant, wherein (i) the iodide is incorporated in the grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration, and (ii) the iridium coordination complex dopant is incorporated into the sub-surface shell or into a region of the core extending up to 60% of the total silver into the grain from the sub-surface shell. Speed and reciprocity of iodochloride emulsions can be improved by localized addition of known in the art reciprocity-controlling iridium dopants in relation to high iodide region of the grain. By carefully incorporating reciprocity-controlling dopant within a well defined band within a grain the difficulties of the prior art can be overcome.
摘要翻译：公开了一种辐射敏感性乳剂，其包含基于总银含有0.05至3摩尔％碘化物的立方体卤化银颗粒和铱配位络合物掺杂剂，其中（i）碘化物以受控的非 - - 均匀分布，形成含有至少50％的总银，不含碘离子的表面壳，厚度大于的核心，以及含有最大碘化物浓度的亚表面壳，和（ⅱ）铱配位络合物掺杂剂结合到子表面壳体中或引入芯部的区域中，该区域从底表面壳体延伸到总银的60％到晶粒内。通过本领域已知的互易控制铱掺杂剂相对于颗粒的高碘化物区域的局部添加可以提高碘氯化物乳剂的速度和互惠。通过将互易控制掺杂剂小心地结合在晶粒内的良好限定的带内，可以克服现有技术的困难。

9. 发明授权

US5451490A Digital imaging with tabular grain emulsions 失效
标题翻译：数字成像与片状颗粒乳剂
公开(公告)号：US5451490A
公开(公告)日：1995-09-19
申请号：US179056
申请日：1994-01-07
申请人： Jerzy A. Budz , Julie K. Ligtenberg , Michael R. Roberts , Susan K. Mroczek
发明人： Jerzy A. Budz , Julie K. Ligtenberg , Michael R. Roberts , Susan K. Mroczek
IPC分类号： G03C1/00 , G03C1/005 , G03C1/035 , G03C5/08 , G03C5/16 , G03C7/30 , G03C7/00
CPC分类号： G03C5/164 , G03C1/0053 , G03C7/3041 , G03C2200/01 , Y10S430/145 , Y10S430/146
摘要： An electronic printing method which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100 microseconds duration in a pixel-by-pixel mode is disclosed. The radiation sensitive silver halide emulsion layer contains a silver halide grain population comprising at least 50 mole percent chloride, based on silver, forming the grain population projected area. At least 50 percent of the grain population projected area is accounted for by tabular grains that are bounded by {100} major faces having adjacent edge ratios of less than 10, each having an aspect ratio of at least 2.
摘要翻译：公开了一种电子印刷方法，其包括使记录元件的辐射敏感卤化银乳剂层以逐像素模式经受至少10-4erg / cm 2的光化辐射长达100微秒的持续时间。辐射敏感的卤化银乳剂层包含卤化银颗粒群，其包含基于银的至少50摩尔百分比的氯化物，形成颗粒群投影面积。至少百分之五十的粮食种群投入面积是由具有相邻边缘比率小于10的{100}主面限制的片状颗粒占据，每个面都具有至少2的长宽比。

10. 发明授权

US5434038A Photographic image display material 失效
标题翻译：摄影图像显示材料
公开(公告)号：US5434038A
公开(公告)日：1995-07-18
申请号：US220989
申请日：1994-03-31
申请人： Anne E. Bohan , Jerzy A. Budz , Pamela M. Ferguson , Alberto M. Martinez , James P. Merrill , Scott F. O'Dell , Richard P. Szajewski
发明人： Anne E. Bohan , Jerzy A. Budz , Pamela M. Ferguson , Alberto M. Martinez , James P. Merrill , Scott F. O'Dell , Richard P. Szajewski
IPC分类号： G03C7/00 , G03C1/005 , G03C1/035 , G03C1/10 , G03C1/12 , G03C1/16 , G03C1/22 , G03C7/20 , G03C7/30 , G03C1/46
CPC分类号： G03C1/12 , G03C1/0053 , G03C1/16 , G03C1/22 , G03C2001/03594 , G03C2200/01 , G03C2200/11 , G03C7/3022
摘要： An improved image display material comprising a light sensitive tabular grain silver chloride emulsion spectrally sensitized to a peak wavelength of less than about 475 nm, and a method of use comprising the step of optically printing a color image onto the improved color photographic display material is provided. The material and method enable reduced printing times, improved color reproduction and lowered image granularity.
摘要翻译：提供一种改进的图像显示材料，其包括光谱敏化至小于约475nm的峰值波长的光敏性片状银氯化银乳剂，以及包括将彩色图像光学打印到改进的彩色照相显示材料上的步骤的使用方法。该材料和方法能够缩短打印时间，改善色彩再现和降低图像粒度。

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