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1. 发明申请

WO2009110957A1 PHOTOVOLTAIC DEVICE HAVING LOW IRON HIGH TRANSMISSION GLASS WITH LITHIUM OXIDE FOR REDUCING SEED FREE TIME AND CORRESPONDING METHOD 审中-公开
标题翻译：具有氧化铁的低铁高透光性的光伏器件，用于减少种子空闲时间和相关方法
公开(公告)号：WO2009110957A1
公开(公告)日：2009-09-11
申请号：PCT/US2009/000787
申请日：2009-02-06
申请人： GUARDIAN INDUSTRIES CORP. , FULTON, Kevin, R. , HULME, Richard , THOMSEN, Scott, V.
发明人： FULTON, Kevin, R. , HULME, Richard , THOMSEN, Scott, V.
IPC分类号： H01L31/048
CPC分类号： C03B1/00 , C03B13/08 , C03C1/00 , C03C3/087 , C03C4/0092 , H01L31/022466 , H01L31/0236 , H01L31/03762 , H01L31/03921 , H01L31/04 , H01L31/202 , Y02E10/50 , Y02P70/521
摘要： A high transmission and low iron glass is provided for use in a photovoltaic device such as a solar cell. The glass substrate may be patterned on at least one surface thereof. In certain example embodiments, a combination of lithium oxide, antimony oxide, and salt cake is used in the glass to improve the refining conditions by lowering the melting temperature of the batch, thereby resulting in a quicker seed free time in the manufacturing process.
摘要翻译：提供了用于太阳能电池等光电器件的高透光率和低铁玻璃。玻璃基板可以在其至少一个表面上被图案化。在某些示例性实施方案中，在玻璃中使用氧化锂，氧化锑和盐饼的组合，以通过降低批料的熔融温度来改善精制条件，由此导致制造过程中更快的无籽时间。

2. 发明申请

WO2010114588A1 LOW IRON HIGH TRANSMISSION GLASS WITH BORON OXIDE FOR IMPROVED OPTICS, DURABILITY AND REFINING, AND CORRESPONDING METHOD 审中-公开
标题翻译：具有氧化硼的低铁高透射玻璃，用于改进光学，耐久性和精炼以及相应的方法
公开(公告)号：WO2010114588A1
公开(公告)日：2010-10-07
申请号：PCT/US2010/000804
申请日：2010-03-18
申请人： GUARDIAN INDUSTRIES CORP. , PHOENICIA AMERICA-ISRAEL (FLAT GLASS) LTD. , FULTON, Kevin, R. , MICHAELIS, Abraham, W. , RESCH, Mario , BIRD, David , HULME, Richard , THOMSEN, Scott, V.
发明人： FULTON, Kevin, R. , MICHAELIS, Abraham, W. , RESCH, Mario , BIRD, David , HULME, Richard , THOMSEN, Scott, V.
IPC分类号： C03C3/089 , C03C3/091
CPC分类号： C03C3/091 , C03C1/00 , C03C3/087 , C03C4/0092
摘要： This invention relates to a high transmission low iron glass that includes boron oxide. The boron oxide, added to this low iron glass, has the effect of improving glass refining, homogeneity and quality (lower seed count) through its flux action and improves glass optical parameters of green and clear glass through the change in refractive index and surface tension. Boron oxide lends to broader and weaker absorption band of such transition element(s) as iron which additionally improves the transmittance of low iron clear glass in certain example embodiments of this invention. In certain example embodiments, the addition of boron oxide in certain quantities in advantageous in that it improves the chemical durability of the glass by decreasing the USPX (or USPXIII) value of the glass via suppression of the silica, sodium ions in the glass structure.
摘要翻译：本发明涉及一种包含氧化硼的高透光低铁玻璃。添加到该低铁玻璃中的氧化硼通过其助焊剂作用具有改善玻璃精炼，均匀性和质量（较低种子计数）的效果，并且通过折射率和表面张力的变化提高了绿色和透明玻璃的玻璃光学参数。氧化硼对于铁的这种过渡元素的更宽和更弱的吸收带，这在本发明的某些示例性实施方案中另外提高了低铁透明玻璃的透射率。在某些示例性实施方案中，以一定量添加氧化硼是有利的，因为通过玻璃结构中的二氧化硅钠离子的降低来降低玻璃的USPX（或USPXIII）值，从而提高玻璃的化学耐久性。

3. 发明申请

WO2010056432A3 PHOTOVOLTAIC DEVICE USING LOW IRON HIGH TRANSMISSION CLASS WITH ANTIMONY AND REDUCED ALKALI CONTENT AND CORRESPONDING METHOD 审中-公开
公开(公告)号：WO2010056432A3
公开(公告)日：2010-05-20
申请号：PCT/US2009/059484
申请日：2009-10-05
申请人： GUARDIAN INDUSTRIES CORP. , FULTON, Kevin R. , HULME, Richard , THOMSEN, Scott, V.
发明人： FULTON, Kevin R. , HULME, Richard , THOMSEN, Scott, V.
IPC分类号： C03C3/087 , C03B13/08 , H01L31/0392 , H01L31/048
摘要： A high transmission low iron glass includes antimony, has reduced total alkali content, and increased silica content, and is suitable for use in photovoltaic devices (e.g., solar cells) or the like. A method of making the glass is also provided. In certain example embodiments, the glass composition may be made on a pattern line with a highly positive batch redox. The glass comprises (in wt.%): SiO 2 73-76% Na 2 O 10 - 20 % CaO 5 - 15 % MgO 0 - 3% K 2 O 0 - 2% total iron. Fe 2 O 3 ) 0.01 to 0.03 % FeO 0 to 0.0015%, cerium oxide 0 to 0.07 % antimony oxide 0.I to 0.4 % SO 3 0.1 to 0.6 % the total alkali content J (Na 2 O + CaO + MgO + K 2 O) being no greater than 24.35 %.

4. 发明申请

WO2007106223A1 LOW IRON HIGH TRANSMISSION FLOAT GLASS FOR SOLAR CELL APPLICATIONS AND METHOD OF MAKING SAME 审中-公开
标题翻译：用于太阳能电池应用的低铁高透射率玻璃及其制造方法
公开(公告)号：WO2007106223A1
公开(公告)日：2007-09-20
申请号：PCT/US2007/001565
申请日：2007-01-22
申请人： GUARDIAN INDUSTRIES CORP. , THOMSEN, Scott, V. , HULME, Richard , LANDA, Leonid, M.
发明人： THOMSEN, Scott, V. , HULME, Richard , LANDA, Leonid, M.
IPC分类号： C03C3/087 , C03C4/10 , H01L25/04
CPC分类号： C03C3/087 , C03C4/0092 , C03C4/10 , C03C17/36 , C03C17/3678 , C03C2217/944 , H01L31/02366 , H01L31/03921 , Y02E10/50
摘要： Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce %FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or T vis ), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.
摘要翻译：本发明的某些示例性实施例涉及高透度低铁玻璃，其被高度氧化并使用浮法工艺制造，用于光伏器件如太阳能电池等。在某些示例性实施方案中，用于玻璃的玻璃组合物通过使用非常高和正批式氧化还原的浮法进行制备，以便将FeO％降低至低水平并允许玻璃始终实现高可见透射（高分辨率红外（IR）传输和高总太阳能（TS）传输。可以在本发明的不同示例性实施例中对玻璃基板进行图案化或未图案化。

5. 发明申请

WO2009014578A1 UV TREATED GREY GLASS AND METHOD OF MAKING SAME 审中-公开
标题翻译：紫外线处理灰色玻璃及其制造方法
公开(公告)号：WO2009014578A1
公开(公告)日：2009-01-29
申请号：PCT/US2008/006755
申请日：2008-05-29
申请人： GUARDIAN INDUSTRIES CORP. , LANDA, Kesenia , THOMSEN, Scott, V. , HULME, Richard
发明人： THOMSEN, Scott, V. , HULME, Richard
IPC分类号： C03C3/095 , C03C23/00
CPC分类号： C03C3/095 , C03C4/02 , C03C4/082 , C03C4/085 , C03C23/002
摘要： This invention relates to grey glass that is capable of achieving high light transmittance in the visible range in combination with good solar properties (e.g., reduced IR, UV and/or TS transmission), and/or a method of making the same. In certain example embodiments, the glass is treated with UV (ultraviolet) radiation in order to increase %FeO and/or CeO2 content, thereby increasing the glass redox and improving solar performance of the glass. Such glass compositions are useful, for example and without limitation, in automotive windows (e.g., windshields, sidelites, backlites and sunroofs) and/or in architectural/residential window applications.
摘要翻译：本发明涉及能够在良好的太阳能（例如降低的IR，UV和/或TS透射）的情况下在可见光范围内实现高透光率的灰玻璃和/或其制备方法。在某些示例性实施例中，用UV（紫外）辐射处理玻璃以增加FeO和/或CeO 2的含量，从而增加玻璃氧化还原并提高玻璃的太阳能性能。这样的玻璃组合物可用于例如但不限于汽车窗户（例如挡风玻璃，边框，背衬和天窗）和/或建筑/住宅窗户应用中。

6. 发明申请

WO2005033030A1 CLEAR GLASS COMPOSITION WITH HIGH VISIBLE TRANSMITTANCE 审中-公开
标题翻译：具有高可见透射率的透明玻璃组合物
公开(公告)号：WO2005033030A1
公开(公告)日：2005-04-14
申请号：PCT/US2004/029432
申请日：2004-09-09
申请人： GUARDIAN INDUSTRIES CORP. , LANDA, Ksenia, A. , LANDA, Leonid , HULME, Richard , THOMSEN, Scott, V.
发明人： LANDA, Ksenia, A. , LANDA, Leonid , HULME, Richard , THOMSEN, Scott, V.
IPC分类号： C03C3/087
CPC分类号： C03C3/095 , C03C3/087 , C03C4/02 , C03C4/085
摘要： A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably
摘要翻译：提供高透光率相当清晰/中性的有色玻璃组合物。为了实现非常氧化的条件（即显着降低所得玻璃的氧化还原），向玻璃批料中加入氧化铈（例如CeO 2）等氧化剂。作为批料中使用的氧化剂的结果，铁被氧化成非常低的FeO（亚铁态）含量。例如，这可能导致玻璃氧化还原值不大于0.12（更优选<= 0.10;甚至更优选<= 0.08，最优选<= 0.05）和％FeO（即含铁含量）的玻璃，为0.0001〜0.05％。在某些示例性实施例中，为了补偿黄色或黄绿色，可以在玻璃中提供少量的钴（Co），以使其能够实现更中立的颜色。

7. 发明申请

WO2009032006A1 GREY GLASS COMPOSITION 审中-公开
标题翻译：灰色玻璃组合物
公开(公告)号：WO2009032006A1
公开(公告)日：2009-03-12
申请号：PCT/US2007/025731
申请日：2007-12-17
申请人： GUARDIAN INDUSTRIES CORP. , HULME, Richard , THOMSEN, Scott, V.
发明人： HULME, Richard , THOMSEN, Scott, V.
IPC分类号： C03C3/076 , C03C3/078 , C03C3/087 , C03C4/02 , C03C4/08
CPC分类号： C03C4/02 , C03C3/087 , C03C4/082 , C03C4/085
摘要： A grey glass composition employing in its colorant portion at least iron (Fe 2 O 3 /FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe 2 O 3 ) 0.20 to 0.40 %, selenium 2-20 ppm, cobalt oxide 0.0025 to 0.0060%, titanium oxide 0 to 1.0%, glass redox:
摘要翻译：提供在其着色剂部分中至少使用铁（Fe 2 O 3 / FeO），钴和硒的灰色玻璃组合物。该玻璃允许高可见透射率和良好的红外吸收，同时实现所需的灰色。在某些示例性实施方案中，着色剂部分包括或可以基本上由以下组成：总铁（表示为Fe 2 O 3）0.20至0.40％，2-20ppm硒，0.0025至0.0060％的氧化钴，0至1.0％的氧化钛，玻璃氧化还原：<= 0.30。

8. 发明申请

WO2005082799A2 CLEAR GLASS COMPOSITION 审中-公开
标题翻译：清洁玻璃组合物
公开(公告)号：WO2005082799A2
公开(公告)日：2005-09-09
申请号：PCT/US2005/002692
申请日：2005-01-28
申请人： GUARDIAN INDUSTRIES CORP. , LANDA, Leonid , LANDA, Ksenia, A. , THOMSEN, Scott, V. , HULME, Richard
发明人： LANDA, Leonid , LANDA, Ksenia, A. , THOMSEN, Scott, V. , HULME, Richard
IPC分类号： C03C3/00
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe 2 0 3 ): 0.01 to 0.30 %, erbium oxide (e.g., Er 2 0 3 ): 0.01 to 0.30 %.
摘要翻译：提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。在某些示例性实施方案中，玻璃可以包括基础玻璃（例如钠钙二氧化硅基底玻璃），另外还包括重量百分比：总铁（以Fe 2 O 3表示）：0.01至0.30％，氧化铒（例如Er 2 O 3）：0.01〜0.30％。

9. 发明申请

WO2008051357A1 UV TRANSMISSIVE SODA-LIME-SILICA GLASS 审中-公开
标题翻译：紫外线透明石墨 - 二氧化硅玻璃
公开(公告)号：WO2008051357A1
公开(公告)日：2008-05-02
申请号：PCT/US2007/021285
申请日：2007-10-04
申请人： GUARDIAN INDUSTRIES CORP. , THOMSEN, Scott, V. , LANDA, Leonid, M. , HULME, Richard
发明人： THOMSEN, Scott, V. , LANDA, Leonid, M. , HULME, Richard
IPC分类号： C03C3/087 , C03C4/00
CPC分类号： C03C3/087 , C03C4/0085
摘要： In certain example embodiments of this invention, an ultraviolet (UV) transmissive soda-lime-silica glass is provided. In certain example embodiments of this invention, the UV transmissive soda-lime-silica glass may be made via the float process.
摘要翻译：在本发明的某些示例性实施例中，提供紫外（UV）透射的钠钙石英玻璃。在本发明的某些示例性实施例中，UV透射钠钙石英玻璃可以通过浮法工艺制成。

10. 发明申请

WO2008045271A1 CLEAR GLASS COMPOSTITION 审中-公开
标题翻译：清洁玻璃组合
公开(公告)号：WO2008045271A1
公开(公告)日：2008-04-17
申请号：PCT/US2007/021284
申请日：2007-10-04
申请人： GUARDIAN INDUSTRIES CORP. , THOMSEN, Scott, V. , HULME, Richard , LANDA, Leonid, M.
发明人： THOMSEN, Scott, V. , HULME, Richard , LANDA, Leonid, M.
IPC分类号： C03C1/00 , C03C3/095
CPC分类号： C03C3/095 , C03C1/004 , C03C4/02
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the clear glass includes a low amount of iron coupled with zinc oxide and/or erbium oxide in amounts designed to provide a neutral color. While the erbium oxide is used to provide for neutral color, the zinc oxide binds sulfur into whitish-colored zinc sulfide thereby reducing the amount of sulfur that binds/bonds with iron in the glass to form sulfides of iron which is/are brownish in color. Thus, the use of the zinc oxide helps make the glass more neutral in color. In certain example embodiments, the use of the erbium oxide brings the a* color value of the resulting glass closer to zero, whereas the use of the zinc oxide brings the b* value of the resulting glass closer to zero.
摘要翻译：提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。在某些示例性实施例中，透明玻璃包括以设计成提供中性色的量的少量与氧化锌和/或氧化铒相结合的铁。虽然氧化铒用于提供中性色素，但是氧化锌将硫结合成发白色的硫化锌，从而减少与玻璃中的铁结合/结合的硫的量，以形成棕色的铁的硫化物。因此，使用氧化锌有助于使玻璃的颜色更中性。在某些示例性实施方案中，使用铒氧化物使所得玻璃的a *颜色值更接近于零，而使用氧化锌使所得玻璃的b *值更接近零。

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