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1. 发明申请

WO2010149961A2 APPARATUS AND PROCESS FOR THREE-PHASE REACTION 审中-公开
标题翻译：三相反应的装置和方法
公开(公告)号：WO2010149961A2
公开(公告)日：2010-12-29
申请号：PCT/GB2010/001223
申请日：2010-06-22
申请人： GTL.F1 AG , MYRSTAD, Trond , SCHANKE, Dag , SØRAKER, Pål , WAGNER, Matthias , RUPPEL, Manfred , REES, David Christopher
发明人： MYRSTAD, Trond , SCHANKE, Dag , SØRAKER, Pål , WAGNER, Matthias , RUPPEL, Manfred
IPC分类号： B01J8/22
CPC分类号： B01J8/22 , B01D45/08 , B01J8/0055 , B01J8/006 , B01J8/0065 , C10G2/342 , C10G45/58 , C10G47/00 , Y02P20/582
摘要： A system for removing catalyst fines from a Fischer-Tropsch slurry bubble column reactor (11). The unreacted gases are passed through a demister (14) which removes larger droplets and catalyst particles. Smaller droplets and catalyst fines are conveyed to a cyclone (15) which removes substantially all remaining particles.
摘要翻译：用于从费 - 托浆泡沫塔反应器（11）中除去催化剂细粉的系统。未反应的气体通过去除更大的液滴和催化剂颗粒的除雾器（14）。较小的液滴和催化剂细粉被输送到旋风分离器（15），其旋转基本上所有剩余的颗粒。

2. 发明申请

WO2010072992A3 APPARATUS AND METHOD FOR CONDUCTING A FISCHER-TROPSCH SYNTHESIS REACTION 审中-公开
公开(公告)号：WO2010072992A3
公开(公告)日：2010-07-01
申请号：PCT/GB2009/002836
申请日：2009-12-08
申请人： GTL.F1 AG , SORAKER, Pal , RUPPEL, Manfred , SCHANKE, Dag , WAGNER, Matthias , REES, David, Christopher
发明人： SORAKER, Pal , RUPPEL, Manfred , SCHANKE, Dag , WAGNER, Matthias , REES, David, Christopher
IPC分类号： C10G2/00 , B01J8/00 , B01J8/22
摘要： A system for a Fischer-Tropsch synthesis using a three-phase reactor (11) in which a primary filter (12) removes coarse catalyst particles from the product and in which catalyst fines are removed in a secondary filter (14). Some or all portion of the product wax from the secondary filter is recycled back to the reactor, either as a back flush medium for the primary filter (28) or directly to the slurry in the reactor (32), whereby removal of catalyst fines is rendered independent of the rate of wax production.

3. 发明申请

WO2010058164A8 SLURRY BUBBLE COLUMN REACTOR 审中-公开
公开(公告)号：WO2010058164A8
公开(公告)日：2010-05-27
申请号：PCT/GB2009/002698
申请日：2009-11-18
申请人： GTL.F1 AG, , RUPPEL, Manfred, , GUTERMUTH, Thomas, , SCHANKE, Dag , SORAKER, Pal , REES, David Christopher
发明人： RUPPEL, Manfred, , GUTERMUTH, Thomas, , SCHANKE, Dag , SORAKER, Pal
IPC分类号： B01J8/18 , B01J8/22 , C10G2/00
摘要： A slurry bubble column reactor (11) with a gas distribution arrangement comprising an upper sparger (12), a lower sparger (13) and an open-ended tube (14). Gas from the lower sparger (13) enters the tube (14) and lowers the density of slurry in the tube (14) and enters to density of the slurry in the tube (14). The difference in slurry density causes the slurry in the tube (14) to rise, causing slurry outside the tube (14) to move down, maintaining circulation and flushing catalyst from the vessel wall.

4. 发明申请

WO2005082513A1 DOWNCOMERS FOR SLURRY BUBBLE COLUMN REACTORS 审中-公开
标题翻译：浆料泡沫柱反应器的代表
公开(公告)号：WO2005082513A1
公开(公告)日：2005-09-09
申请号：PCT/GB2005/000582
申请日：2005-02-17
申请人： STATOIL ASA , PETRO SA , REES, David, Christopher , SCHANKE, Dag , MYRSTAD, Trond , SORAKER, Pal , JULIUSSEN, Olav , WIIG, Per, Oscar
发明人： SCHANKE, Dag , MYRSTAD, Trond , SORAKER, Pal , JULIUSSEN, Olav , WIIG, Per, Oscar
IPC分类号： B01J8/22
CPC分类号： C10G2/342 , B01J8/226
摘要： A downcomer (61) for use in a slurry bubble column reactor (60) comprises: an upper part (62) including a slurry inlet (66) through which slurry can enter the downcomer (61), gas separation means (65) arranged to separate gas bubbles from the slurry, and a gas outlet through which the separated gas can escape; an elongate, tabular-shaped intermediate section (63) which extends vertically in use and through which slurry can pass downwards; and a lower portion (64) which has a slurry outlet (71). The slurry outlet (71) is defined by a wall (69) which is inclined relative to the longitudinal axis of the intermediate section (63).
摘要翻译：用于浆液鼓泡塔反应器（60）的降液管（61）包括：上部（62），其包括浆料入口（66），浆料可以通过该入口进入降液管（61）;气体分离装置（65）从浆液中分离出气泡，以及气体出口，分离出的气体可通过该出口逸出; 细长的平板状中间部分（63），其在使用中垂直延伸并且浆料可以通过该中间部分向下通过; 和具有浆料出口（71）的下部（64）。浆料出口（71）由相对于中间部分（63）的纵向轴线倾斜的壁（69）限定。

5. 发明申请

WO2004043596A2 FISCHER-TROPSCH CATALYSTS 审中-公开
标题翻译： FISCHER-TROPSCH催化剂
公开(公告)号：WO2004043596A2
公开(公告)日：2004-05-27
申请号：PCT/GB2003/004873
申请日：2003-11-10
申请人： STATOIL ASA , PETROSA , REES, David, Christopher , RYTTER, Erling , ERI, Sigrid , SCHANKE, Dag
发明人： RYTTER, Erling , ERI, Sigrid , SCHANKE, Dag
IPC分类号： B01J35/10
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8896 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , C10G2300/703
摘要： A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 µm; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m 2 /g; the average pore size of the impregnated and calcined catalyst is at least 90Å (9nm); and the pore volume of the impregnated and calcined catalyst is greater than 0.35 cm 3 /g.
摘要翻译：用于费 - 托合成反应的催化剂，其包含负载在氧化铝上的钴，其中：催化剂平均粒度为20-100微米; 浸渍和煅烧的催化剂颗粒的比表面积大于80m 2 / g; 浸渍并煅烧的催化剂的平均孔径至少为90埃; （9纳米）; 并且浸渍并煅烧的催化剂的孔体积大于0.35cm 3 / g。

6. 发明公开

EP2376600A2 APPARATUS AND METHOD FOR CONDUCTING A FISCHER-TROPSCH SYNTHESIS REACTION 审中-公开
标题翻译：装置和方法用于进行费 - 托合成过程中的反应
公开(公告)号：EP2376600A2
公开(公告)日：2011-10-19
申请号：EP09768542.4
申请日：2009-12-08
申请人： GTL.F1 AG
发明人： SORAKER, Pal , RUPPEL, Manfred , SCHANKE, Dag , WAGNER, Matthias
IPC分类号： C10G2/00 , B01J8/00 , B01J8/22
CPC分类号： C07C1/041 , B01J8/006 , B01J8/22 , B01J8/228 , C10G2/32 , C10G2/342 , C10G2/344
摘要： A system for a Fischer-Tropsch synthesis using a three-phase reactor (11) in which a primary filter (12) removes coarse catalyst particles from the product and in which catalyst fines are removed in a secondary filter (14). Some or all portion of the product wax from the secondary filter is recycled back to the reactor, either as a back flush medium for the primary filter (28) or directly to the slurry in the reactor (32), whereby removal of catalyst fines is rendered independent of the rate of wax production.

7. 发明公开

EP2445629A2 APPARATUS AND PROCESS FOR THREE-PHASE REACTION 有权转让
标题翻译：用于三相反应的装置和方法
公开(公告)号：EP2445629A2
公开(公告)日：2012-05-02
申请号：EP10728275.8
申请日：2010-06-22
申请人： GTL.F1 AG
发明人： MYRSTAD, Trond , SCHANKE, Dag , SØRAKER, Pål , WAGNER, Matthias , RUPPEL, Manfred
IPC分类号： B01J8/22
摘要： A system and process for removing catalyst fines from a gas stream overhead the slurry in a Fischer-Tropsch slurry bubble column reactor. The gas phase at the top of the slurry bubble column reactor containing small amounts of entrained liquid and catalyst particles. The unreacted gases are passed through a demister, which removes larger droplets and catalyst particles. Smaller droplets and catalyst fines are conveyed to a secondary gas cleaner, such as a cyclone, whereby substantially all remaining particles are removed from the gas phase. A particle-containing liquid produced in the secondary gas cleaner can be further subjected to a filtrate cleaning unit to filter out fine catalyst particles and produce a substantially particle-free liquid product stream and a slurry stream of liquid product containing catalyst particles.
摘要翻译：一种用于从费 - 托料浆鼓泡塔反应器（11）中除去催化剂细粉的系统。未反应的气体通过除雾器（14），除去较大的液滴和催化剂颗粒。较小的液滴和催化剂细粒被传送到旋风分离器（15），该旋风分离器基本上除去所有剩余的颗粒。

8. 发明授权

EP2367616B1 SLURRY BUBBLE COLUMN REACTOR 有权
标题翻译：鼓泡塔反应器
公开(公告)号：EP2367616B1
公开(公告)日：2013-05-15
申请号：EP09756343.1
申请日：2009-11-18
申请人： GTL.F1 Ag
发明人： RUPPEL, Manfred, , GUTERMUTH, Thomas, , SCHANKE, Dag , SORAKER, Pal
IPC分类号： B01J8/18 , B01J8/22 , C10G2/00
CPC分类号： B01J8/22 , B01J8/1818 , B01J8/224 , B01J8/226 , B01J2208/00911 , C07C1/0415 , C10G2/344

9. 发明公开

EP2367616A1 SLURRY BUBBLE COLUMN REACTOR 有权
标题翻译：鼓泡塔反应器
公开(公告)号：EP2367616A1
公开(公告)日：2011-09-28
申请号：EP09756343.1
申请日：2009-11-18
申请人： GTL.F1 Ag
发明人： RUPPEL, Manfred, , GUTERMUTH, Thomas, , SCHANKE, Dag , SORAKER, Pal
IPC分类号： B01J8/18 , B01J8/22 , C10G2/00
CPC分类号： B01J8/22 , B01J8/1818 , B01J8/224 , B01J8/226 , B01J2208/00911 , C07C1/0415 , C10G2/344
摘要： A slurry bubble column reactor (11) with a gas distribution arrangement comprising an upper sparger (12), a lower sparger (13) and an open-ended tube (14). Gas from the lower sparger (13) enters the tube (14) and lowers the density of slurry in the tube (14) and enters to density of the slurry in the tube (14). The difference in slurry density causes the slurry in the tube (14) to rise, causing slurry outside the tube (14) to move down, maintaining circulation and flushing catalyst from the vessel wall.

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