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    • 9. 发明申请
    • ENHANCED POLYMERIZATION PROCESS
    • 增强聚合工艺
    • WO2003010214A1
    • 2003-02-06
    • PCT/US2002/023674
    • 2002-07-24
    • GENERAL ELECTRIC COMPANY
    • VILASAGAR, ShripathyLOWRY, VernFERRARIS, Dane, M.COLBORN, Robert, E.FENG, KeLITTLEJOHN, Matthew, HalTOWNSEND, David, Francis
    • C08F36/04
    • C08F279/04C08F2/38C08F36/04
    • An emulsion polymerization process for the preparation of polybutadiene grafted with styrene and acrylonitrile monomers in a reaction system is provided. The resultant product has a low end content of unreacted residual monomers, low yellowness index, and improved impact strength. The diene rubber is prepared via a process wherein a chain transfer agent is added on a continuous basis to give a rubber substrate having a low crosslink density. In one embodiment of the invention, the process includes charging the reaction system with a pre-selected diene emulsion with a low crosslink density, adding a first portion of at least one of a styrene monomer and acrylonitrile monomer to the diene emulsion, adding to the reaction system, over a predetermined time, an initiator and a second portion of acrylonitrile and styrene monomer, and polymerizing the catalyzed reaction mixture of diene substrate, styrene and acrylonitrile to form ABS graft polymers. In another embodiment, a third monomer is added after the conversion rate of the monomers is greater than 98%.
    • 提供了一种用于制备在反应体系中用苯乙烯和丙烯腈单体接枝的聚丁二烯的乳液聚合方法。 所得产物具有未反应残余单体的低端含量,低黄度指数和改善的冲击强度。 二烯橡胶通过其中连续加入链转移剂以得到交联密度低的橡胶底物的方法制备。 在本发明的一个实施方案中,该方法包括用具有低交联密度的预选择的二烯乳液装入反应体系,向苯二酚乳液中加入至少一种苯乙烯单体和丙烯腈单体的第一部分, 反应体系,预定时间,引发剂和丙烯腈和苯乙烯单体的第二部分,并且聚合二烯基体,苯乙烯和丙烯腈的催化反应混合物以形成ABS接枝聚合物。 在另一个实施方案中,在单体的转化率大于98%之后加入第三单体。