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    • 7. 发明申请
    • PROCESS FOR THE PRODUCTION OF BRANCHED MELT POLYCARBONATE BY LATE ADDITION OF FRIES-INDUCING CATALYST
    • 通过添加丙烯酸诱导催化剂生产分支的熔融聚碳酸酯的方法
    • WO2003057758A1
    • 2003-07-17
    • PCT/US2002/036370
    • 2002-11-12
    • GENERAL ELECTRIC COMPANY
    • KARLIK, DennisBRACK, Hans, PeterVERHOOGT, HendrikLEMMON, John, PatrickKAMPS, Jan, HenkSEDEREL, Willem, LodewijkGOOSSENS, Johannes, Martinus, Dina
    • C08G64/30
    • C08G64/307
    • The invention relates to a method for the production of a branched polycarbonate composition, having increased melt strength, by late addition of branch-inducing catalysts to the polycarbonate oligomer in a melt polycondensation process. Surprisingly, it has been found that by adding branch-inducing catalysts, such as alkali metal compounds and/ or alkaline earth metal compounds, to the melt polycarbonate oligomer at a later stage of the melt polycondensation process, preferably after the oligomer has reached an average molecular weight of between about 3,000 and 30,000 g/mole, a unique branched polycarbonate composition is formed that has improved properties. It is believed that the addition of the branch-inducing catalysts at the later stages of the process produces a branched polycarbonate composition having longer chains between the branching points, and thus a new composition is produced. The invention also relates to various applications of the branched polycarbonate composition.
    • 本发明涉及一种生产支化聚碳酸酯组合物的方法,其通过在熔融缩聚方法中向聚碳酸酯低聚物中晚期添加分支诱导催化剂而具有增加的熔体强度。 令人惊奇的是,已经发现,在熔融缩聚过程的较后阶段,优选在低聚物达到平均值之后,通过在熔融聚碳酸酯低聚物中加入诸如碱金属化合物和/或碱土金属化合物的分支诱导催化剂 分子量为约3,000至30,000g / mol,形成了具有改进性能的独特的支链聚碳酸酯组合物。 据信,在该方法的后续阶段添加分支诱导催化剂产生在分支点之间具有较长链的支化聚碳酸酯组合物,因此产生新的组合物。 本发明还涉及支化聚碳酸酯组合物的各种应用。
    • 8. 发明申请
    • PROCESS FOR PREPARING BRANCHED AROMATIC POLYCARBONATES
    • 制备分支芳香族聚碳酸酯的方法
    • WO2003050161A1
    • 2003-06-19
    • PCT/US2002/035115
    • 2002-10-30
    • GENERAL ELECTRIC COMPANY
    • BRACK, Hans, PeterKARLIK, DennisVERHOOGT, HendrikGOOSSENS, Johannes, Martinus, Dina
    • C08G64/14
    • C08G64/307C08G64/14
    • A process for the production of a branched aromatic polycarbonate that includes adding a branching agent to a polycarbonate oligomer, and producing a branched aromatic polycarbonate having a melt index ratio greater than an aromatic polycarbonate produced from the polycarbonate oligomer without the addition of the branching agent. The branching agent has the formula (I): AG y wherein A is a C 1-20 polymethylene, C 2-20 alkylene or alkylidene, C 5-36 cycloalkylene or cycloalkylidene, C 6-36 arylene or alkylarylene, or C 6-36 arylalkylene, wherein G is a monovalent C 6 -C 30 hydrocarbon having at least one hydroxyl group bonded directly to an aromatic or cycloaliphatic ring and y is an integer greater than 2, and wherein each G may be the same or different.
    • 一种制备支化芳族聚碳酸酯的方法,其包括向聚碳酸酯低聚物中加入支化剂,以及制备熔融指数比大于由聚碳酸酯低聚物制备的芳族聚碳酸酯而不添加支化剂的支化芳族聚碳酸酯。 支化剂具有式(I):其中A是C 1-20多亚甲基,C 2-20亚烷基或亚烷基,C 5-36亚环烷基或亚环烷基,C 6-36亚芳基或烷基亚芳基或C 6-36芳基亚烷基,其中G是 具有至少一个羟基的一价C 6 -C 30烃直接与芳族或脂环族环结合,y是大于2的整数,并且其中每个G可以相同或不同。