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1. 发明申请

WO2008058462A1 AN ALUMINATE PHOSPHOR CONTAINING BIVALENCE METAL ELEMENTS, ITS PREPARATION AND THE LIGHT EMITTING DEVICES INCORPORATING THE SAME 审中-公开
标题翻译：含有金属元素的铝酸盐荧光体及其制备方法和引入其的发光装置
公开(公告)号：WO2008058462A1
公开(公告)日：2008-05-22
申请号：PCT/CN2007003205
申请日：2007-11-13
申请人： GEN RES INST FOR NONFERROUS ME , GRIREM ADVANCED MATERIALS CO , ZHUANG WEIDONG , HU YUNSHENG , LONG ZHEN , ZHANG SHUSHENG , HUANG XIAOWEI , LI HONGWEI
发明人： ZHUANG WEIDONG , HU YUNSHENG , LONG ZHEN , ZHANG SHUSHENG , HUANG XIAOWEI , LI HONGWEI
IPC分类号： C09K11/78
CPC分类号： C09K11/7774 , C09K11/778
摘要： The present invention relates to a phosphor that can be excited by UV3 purple or blue light LED, its production and the light emitting devices. General formula of the phosphor is Ln a M b (O,F) 12 :(R 3+ , M '2+ ) x, wherein, Ln is at least one metal element selected from a group consisting of Sc, Y, La, Pr, Nd, Gd, Ho, Yb and Sm, 2.6= a=3.4; M is at least one element selected from a group consisting of B, Al and Ga, 4.5=b=5.5; R is at least one metal element selected from a group consisting of Ce and Tb; M' is at least one metal element selected from a group consisting of Ca, Sr, Ba, Mn and Zn, 0.001=x=0.4. Production method of the phosphor is: raw materials are weighed according to general formula. Further, flux is added. The raw materials are mixed, grinded sequentially and then baked at high temperature in reducing atmosphere. After post-treatment, the phosphor of the present invention is obtained. The phosphor possess broad emitting range, high efficiency, better uniformity and stability. The production method is simple, no pollution and lower cost. A light emitting device can be obtained by incorporating this phosphor into a UV, purple or blue light emitting device.
摘要翻译：本发明涉及一种能够被紫外线紫光或蓝光LED激发的荧光体，其制造方法和发光装置。荧光体的通式为Ln（O，F）12：（R 3 +），其中，Ln是选自Sc，Y，La，Pr，Nd，Gd，Ho中的至少一种金属元素， Yb和Sm，2.6 = a = 3.4; M是选自B，Al和Ga中的至少一种元素，4.5 = b = 5.5; R是选自Ce和Tb中的至少一种金属元素; M'是选自Ca，Sr，Ba，Mn和Zn中的至少一种金属元素，0.001 = x = 0.4。荧光体的制造方法是：按照通式称量原料。此外，加入助熔剂。将原料混合，依次研磨，然后在还原气氛中在高温下烘烤。后处理后，得到本发明的荧光体。荧光粉具有广泛的发光范围，高效率，更好的均匀性和稳定性。生产方法简单，无污染，成本低廉。通过将该荧光体掺入UV，紫色或蓝色发光器件中，可以获得发光器件。

2. 发明专利

DE112007002622T5 未知
公开(公告)号：DE112007002622T5
公开(公告)日：2009-10-29
申请号：DE112007002622
申请日：2007-11-13
申请人： GEN RES INST FOR NONFERROUS ME , GRIREM ADVANCED MATERIALS CO
发明人： ZHUANG WEIDONG , HU YUNSHENG , LONG ZHEN , ZHANG SHUSHENG , HUANG XIAOWEI , LI HONGWEI
IPC分类号： C09K11/78
摘要： A phosphor can be excited by UV, purple or blue light LED, its production and the light emitting devices. The general formula of the phosphor is LnaMb(O,F)12:(R3+,M′2+)x, wherein, Ln is at least one metal element selected from a group consisting of Sc, Y, La, Pr, Nd, Gd, Ho, Yb and Sm, 2.6≦̸a≦̸3.4; M is at least one element selected from a group consisting of B, Al and Ga, 4.5≦̸b≦̸5.5; R is at least one metal element selected from a group consisting of Ce and Tb; M′ is at least one metal element selected from a group consisting of Ca, Sr, Ba, Mn and Zn, 0.001≦̸x≦̸0.4. The phosphor possesses broad emitting range, high efficiency, better uniformity and stability. A light emitting device can be obtained by incorporating this phosphor into a UV, purple or blue light emitting device.

3. 发明专利

DE112007000656T5 未知
公开(公告)号：DE112007000656T5
公开(公告)日：2009-02-12
申请号：DE112007000656
申请日：2007-03-16
申请人： GEN RES INST FOR NONFERROUS ME , GRIREM ADVANCED MATERIALS CO
发明人： ZHUANG WEIDONG , HU YUNSHENG , LONG ZHEN , HUANG XIAOWEI , LI HONGWEI , ZHANG SHUSHENG , HE HUAQIANG
IPC分类号： C09K11/86 , H01L33/50
摘要： A phosphor can be excited by UV, purple or blue light LED, its preparation method, and light emitting devices incorporating the same. The phosphor contains rare earth, silicon, alkaline-earth metal, halogen, and oxygen, as well as aluminum or gallium. Its General formula of is aLn2O3.MO.bM′2O3.fSiO2.cAXe:dR, wherein Ln is at least one metal element selected from a group consisting of Sc, Y, La, Pr, Nd, Gd, Ho, Yb and Sm; M is at least one metal element selected from a group consisting of Ca, Sr and Ba; M′ is at least one metal element selected from Al and Ga; A is at least one metal element selected from a group consisting of Li, Na, K, Mg, Ca, Sr and Ba; X is at least one element selected from F and Cl; R is at least one metal element selected from a group consisting of Ce, Eu, Tb and Mn; 0.01≦̸a≦̸2, 0.35≦̸b≦̸4, 0.01≦̸c≦̸1, 0.01≦̸d≦̸0.3, 0.01≦̸f≦̸3, 0.6≦̸e≦̸2.4. The phosphor has broad emitting range, high efficiency, better uniformity and stability. A light emitting device is obtained by incorporating the phosphor into a UV, purple or blue light emitting device.

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