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    • 6. 发明申请
    • PHOSPHORESCENT FLUORENE, ANTHRACENE AND/OR THIOPHENE SUBSTITUTED METALLO- PORPHYRINS AND RELATED COMPOUNDS
    • 磷酸荧光素,蒽醌和/或噻吩取代的金属茂和相关化合物
    • WO2006076247A3
    • 2006-08-31
    • PCT/US2006000572
    • 2006-01-09
    • GEN ELECTRICLITZ KYLE ERIKCELLA JAMES ANTHONYYE QING
    • LITZ KYLE ERIKCELLA JAMES ANTHONYYE QING
    • C07D487/22C09K11/07
    • C07D487/22
    • The invention discloses compounds of structure I wherein M is a divalent, bivalent or tetravalent metal ion; "a" is 0, 1, 2, or a non-zero fraction having a value between 0 and 1; Y is independently at each occurrence a charge balancing counterion; R 1 and R 2 are independently at each occurrence a halogen, a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycioaliphatic radical, a C 2 -C 20 aromatic radical, or R 1 and R 2 may together form a divalent aliphatic radical, a divalent cycioaliphatic radical, or a divalent aromatic radical; R 3 is independently at each occurrence an organic radical having structure II wherein Ar 1 is a C 2 -C 50 aromatic radical; L 1 is a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycioaliphatic radical, or a C 2 -C 20 aromatic radical; F is independently at each occurrence a structural unit derived from an olefin monomer selected from the group consisting of polycyclic olefin monomers and heterocyclic olefin monomers; "n" is independently at each occurrence an integer from 1 to about 200; Q is independently at each occurrence a hydrogen, a halogen, a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycioaliphatic radical, or a C 2 -C 20 aromatic radical; and "m" is independently at each occurrence an integer from 1 to about 10.
    • 本发明公开了结构I的化合物,其中M是二价,二价或四价金属离子; “a”为0,1,2或具有介于0和1之间的值的非零分数; Y在每次出现时都是独立的电荷平衡抗衡离子; R 1和R 2在每次出现时独立地为卤素,C 1 -C 20 - 脂族基团, C 3 -C 20脂环族基团,C 2 -C 20芳族基团或R SUP > 1和R 2可以一起形成二价脂族基团,二价环脂族基团或二价芳族基团; R 3在每次出现时独立地为具有结构II的有机基团,其中Ar 1为C 2 -C 50 芳香族; L 1是C 1 -C 20脂族基团,C 3 -C 20脂族基团,C 1 -C 20脂族基团, / SUB>环脂族基团或C 2 -C 20芳族基团; F在每次出现时独立地是衍生自选自多环烯烃单体和杂环烯烃单体的烯烃单体的结构单元; “n”在每次出现时独立地为1至约200的整数; Q在每次出现时独立地为氢,卤素,C 1 -C 20脂肪族基,C 3 -C 3 - 20个环脂族基团或C 2 -C 20芳族基团; 和“m”在每次出现时独立地为1至约10的整数。