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    • 1. 发明申请
    • IMPACT-MODIFIED COMPOSITIONS
    • 影响改性的组合物
    • WO2004000936A8
    • 2005-05-19
    • PCT/US0320956
    • 2003-06-20
    • GEN ELECTRIC
    • BERZINIS ALBIN PETERPICKETT JAMES EDWARD
    • C08L25/12C08F265/04C08L51/00C08L51/04C08F291/02
    • C08F265/04C08F212/10
    • In one of its aspects the invention is directed to rubber modified thermoplastic resin compositions comprising a discontinuous elastomeric phase dispersed in a rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is grafted to the elastomeric phase, and wherein said thermoplastic phase comprises structural units derived from at least one vinyl aromatic monomer, at least one monoethylenically unsaturated nitrile monomer and at least one (C1-C12)alkyl- or aryl­(meth)acrylate monomer. In another aspect the rigid thermoplastic phase of said compositions comprises a first thermoplastic phase at least a portion of which is grafted to the elastomeric phase; and a second thermoplastic phase prepared separately in the absence of elastomeric phase and added to the composition, wherein said first thermoplastic phase comprises structural units derived from at least one vinyl aromatic monomer, at least one monoethylenically unsaturated nitrile monomer and at least one (C1-C12)alkyl- or aryl-(meth)acrylate monomer; and wherein said second thermoplastic phase comprises structural units derived from at least one vinyl aromatic monomer and at least one monoethylenically unsaturated nitrile monomer.
    • 在其一个方面,本发明涉及橡胶改性的热塑性树脂组合物,其包含分散在刚性热塑性相中的不连续弹性体相,其中刚性热塑性相的至少一部分接枝到弹性体相上,并且其中所述热塑性相包含 衍生自至少一种乙烯基芳族单体,至少一种单烯属不饱和腈单体和至少一种(C1-C12)烷基 - 或(甲基)丙烯酸芳基酯单体的结构单元。 在另一方面,所述组合物的刚性热塑性相包含第一热塑性相,其至少一部分接枝到弹性体相; 和在不存在弹性体相的情况下分别制备并加入组合物中的第二热塑性相,其中所述第一热塑性相包含衍生自至少一种乙烯基芳族单体,至少一种单烯属不饱和腈单体和至少一种(C1- C12)烷基 - 或芳基 - (甲基)丙烯酸酯单体; 并且其中所述第二热塑性相包含衍生自至少一种乙烯基芳族单体和至少一种单烯属不饱和腈单体的结构单元。