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1. 发明授权

US06624238B1 Intrinsically viscous clear powder coating slurry which is free of organic solvents and external emulsifiers, method for producing said slurry and use of the same 有权
标题翻译：不含有机溶剂和外用乳化剂的本质粘稠透明粉末涂料浆料，所述浆料的制备方法及其用途
公开(公告)号：US06624238B1
公开(公告)日：2003-09-23
申请号：US09786956
申请日：2001-03-12
申请人： Günther Ott , Ulrike Röckrath , Maximilian Bendix , Joachim Woltering , Fatmir Raka , Ute Schuhmacher , Ulrich Poth
发明人： Günther Ott , Ulrike Röckrath , Maximilian Bendix , Joachim Woltering , Fatmir Raka , Ute Schuhmacher , Ulrich Poth
IPC分类号： C08K300
CPC分类号： C08G18/0866 , C08G18/6254 , C08G18/807 , C08G2150/20 , C08J3/07 , C09D5/02
摘要： A pseudoplastic powder clearcoat slurry which is free from organic solvents and external emulsifiers and comprises solid spherical particles with an average size of from 0.8 to 20 &mgr;m and a maximum size of 30 &mgr;m, at least one ionic thickener and at least one nonionic associative thickener, the powder clearcoat slurry having an ion-forming group content of from 0.05 to 1 meq/g, a neutralizing agent content of from 0.05 to 1 meq/g, and a viscosity of (i) from 50 to 1 500 mPas at a shear rate of 1 000 s−1, (ii) from 150 to 8 000 mPas at a shear rate of 10 s−1, and (iii) from 180 to 12 000 mPas at a shear rate of 1 s−1.
摘要翻译：一种不含有机溶剂和外部乳化剂的假塑性粉末清漆浆料，其包含平均尺寸为0.8至20μm，最大尺寸为30μm，至少一种离子增稠剂和至少一种非离子缔合增稠剂的固体球形颗粒，离子形成基团含量为0.05〜1meq / g，中和剂含量为0.05〜1meq / g，粘度为（i）为50〜1500mPa·s的粉末透明涂料浆料为剪切速率 1 000 s -1，（ii）剪切速率为10 s -1的150至8 000 mPas，（iii）180 s至1 000 mPas，剪切速率为1 s -1 >。

2. 发明授权

US07132472B2 Intrinsically-viscous clear-lacquer slurry, method for production and use thereof 有权
标题翻译：本质粘稠的清漆浆料，其生产方法和用途
公开(公告)号：US07132472B2
公开(公告)日：2006-11-07
申请号：US10479918
申请日：2002-07-23
申请人： Joachim Woltering , Fatmir Raka , Ulrike Röckrath , Ute Schumacher
发明人： Joachim Woltering , Fatmir Raka , Ulrike Röckrath , Ute Schumacher
IPC分类号： C08L31/02 , C08L33/02
CPC分类号： C09D133/10 , C08G18/6254 , C08G18/807 , C08G2190/00 , C09D175/04 , C09J133/10
摘要： A pseudoplastic clearcoat slurry comprising solid and/or highly viscous particles which are dimensionally stable under storage and application conditions and which comprise as binders methacrylate copolymers containing in copolymerized form, based on a given methacrylate copolymer, at least 90% by weight of methacrylate comonomers, including (meth)acrylate comonomers having potentially ionic groups; process for preparing it, and its use.
摘要翻译：包含在储存和使用条件下尺寸稳定的固体和/或高粘度颗粒的假塑性透明浆料浆料，其包含作为粘合剂的甲基丙烯酸酯共聚物，所述甲基丙烯酸酯共聚物以共聚形式，基于给定的甲基丙烯酸酯共聚物，至少90重量％的甲基丙烯酸酯共聚单体，包括具有潜在离子基团的（甲基）丙烯酸酯共聚单体; 其准备过程及其使用。

3. 发明授权

US07041729B2 Structurally viscous powder clearcoat slurry free from organic solvents and external emulsifiers, method for producing the same the use thereof 失效
标题翻译：不含有机溶剂和外用乳化剂的结构粘性粉末透明涂料浆料的制备方法与其相同
公开(公告)号：US07041729B2
公开(公告)日：2006-05-09
申请号：US10363176
申请日：2001-11-08
申请人： Joachim Woltering , Günther Ott , Fatmir Raka , Heike Florack
发明人： Joachim Woltering , Günther Ott , Fatmir Raka , Heike Florack
IPC分类号： C08F8/30 , C08K3/00
CPC分类号： C08G18/6254 , C08G18/8025 , C08G18/807 , C08G2150/20 , C09D175/04
摘要： A pseudoplastic powder clearcoat slurry free from organic solvents and external emulsifiers and comprising particles which are solid and/or of high viscosity and are dimensionally stable under storage and application conditions, where the particles have an average size of from 1.0 to 20 μm, at least 99% of the particles having a size ≦30 μm, and comprise as binder at least one polyol with an OH number >110 mg KOH/g, containing potentially ionic groups, and where the powder clearcoat slurry has a potentially ionic group content of from 0.05 to 1 meq/g of solids, at a degree of neutralization of not more than 50% contains from 0.005 to 0.1 meq/g of solids of ionic groups produced by neutralization of the potentially ionic groups, and has a viscosity of (i) from 50 to 1 000 mPas at a shear rate of 1 000 s−1, (ii) from 150 to 8 000 mPas at a shear rate of 10 s−1, and (iii) from 180 to 12 000 mPas at a shear rate of 1 s−1.
摘要翻译：不含有机溶剂和外部乳化剂的假塑性粉末清漆浆料，其包含固体和/或高粘度和在储存和使用条件下尺寸稳定的颗粒，其中颗粒的平均尺寸至少为1.0至20μm，至少 99％的粒子尺寸<=30μm，并且包含作为粘合剂的至少一种具有OH值> 110mg KOH / g的多元醇，其含有潜在的离子基团，并且其中粉末透明涂料浆料具有潜在的离子基团含量 0.05至1meq / g的固体，中和度不超过50％时含有0.005至0.1meq / g的通过中和潜在离子基团产生的离子基团的固体，并具有（i ）在1000psi的剪切速率下从50至1000mPas，（ii）150至8000mPas，剪切速率为10s -1 ，和（iii）在1秒-1的剪切速率下180至12000mPas。

4. 发明授权

US07482399B2 Structurally viscose clear lacquer slurry, method for the production and use thereof 有权
标题翻译：结构上粘胶透明漆浆，其生产和使用方法
公开(公告)号：US07482399B2
公开(公告)日：2009-01-27
申请号：US10479903
申请日：2002-07-23
申请人： Fatmir Raka , Joachim Woltering , Heike Florack
发明人： Fatmir Raka , Joachim Woltering , Heike Florack
IPC分类号： C08K5/06
CPC分类号： C09D5/027 , C08L71/02 , C09D5/02 , C09D133/10 , C08L2666/22
摘要： A pseudoplastic clearcoat slurry comprising solid and/or highly viscous particles which are dimensionally stable under storage and application conditions and at least one wetting agent selected from the group consisting of alkoxylated fatty alcohols having from 16 to 18 carbon atoms in the alkyl radical and containing on average per molecule at least 20 oxaalkanediyl groups; process for preparing it, and its use.
摘要翻译：包含固体和/或高粘度颗粒的假塑性透明浆料浆料，其在储存和使用条件下尺寸稳定，以及至少一种润湿剂，其选自烷基中具有16至18个碳原子的烷氧基化脂肪醇，并含有每分子平均至少20个氧杂烷二基; 其准备过程及其使用。

5. 发明申请

US20110262649A1 TWO-LAYER COATING SYSTEM HAVING IMPROVED INTERCOAT ADHESION 有权
标题翻译：具有改进的INTERCOAT粘合剂的两层涂料体系
公开(公告)号：US20110262649A1
公开(公告)日：2011-10-27
申请号：US13057675
申请日：2009-08-05
申请人： Michael Dornbusch , Ulf Schlotterbeck , Frank Strickmann , Fatmir Raka
发明人： Michael Dornbusch , Ulf Schlotterbeck , Frank Strickmann , Fatmir Raka
IPC分类号： B05D5/06 , B05D1/36 , C09D175/04
CPC分类号： C08G18/706 , B05D1/36 , B05D3/02 , B05D3/06 , B05D5/00 , B05D5/005 , B05D7/53 , B05D7/532 , B05D7/542 , B32B27/00 , B32B27/40 , C08F2/46 , C08F283/04 , C08G18/67 , C08G18/80 , C08G18/807 , C08G18/83 , C09D175/16
摘要： A two-coat coating system for producing a two-coat coating, comprising (A) a composition of a transparent radiation-curable or radiation-curable and thermally curable clearcoat material, comprising at least one hydroxy-functional binder, and (B) a pigmented coating composition, the pigmented coating composition comprising at least one blocked, water-soluble or water-dispersible isocyanate.
摘要翻译：一种用于生产双涂层涂层的双层涂层系统，包括（A）包含至少一种羟基官能粘合剂的透明可辐射固化或可辐射固化和可热固化的和可热固化的清漆涂料的组合物，和（B）着色涂料组合物，着色涂料组合物包含至少一种封端的水溶性或水分散性异氰酸酯。

6. 发明申请

US20080003372A1 Method for Curing Radically Curable Compounds in a Protective Atmosphere and Device for Carrying Out Said Method 审中-公开
标题翻译：用于固化保护性气氛中的可自由基固化的化合物的方法和用于进行所述方法的装置
公开(公告)号：US20080003372A1
公开(公告)日：2008-01-03
申请号：US11569213
申请日：2005-05-24
申请人： Martin Kamps , Fatmir Raka , Hubert Baumgart , Berthold Austrup
发明人： Martin Kamps , Fatmir Raka , Hubert Baumgart , Berthold Austrup
IPC分类号： B05D1/18 , B05C3/02
CPC分类号： F26B21/14 , B05D3/0466 , B05D3/0486 , B05D3/067 , F26B3/28
摘要： A method of curing free-radically curable compositions under an inert gas atmosphere, where the curing, which proceeds in accordance with a free-radical mechanism, is initiated, or initiated and maintained, in the free-radically curable compositions by radiation and the lateral escape of the inert gas atmosphere is prevented, which involves (1) immersing the free-radically curable compositions in an inert gas atmosphere below a depth from which the inert gas atmosphere constantly exhibits its lowest oxygen concentration, and (2) irradiating the free-radically curable compositions below this depth in the inert gas atmosphere, at least one of the radiation sources being arranged beneath the inert gas/air interface, and then (3) emersing the resultant cured compositions again from the inert gas atmosphere, and apparatus (1) according to FIG. 1 for its implementation.
摘要翻译：一种在惰性气体气氛下固化可自由基固化的组合物的方法，其中根据自由基机理进行的固化通过辐射和侧向起始或启动并保持在可自由基固化的组合物中防止惰性气体气体的逸出，其包括（1）将自由基可固化组合物浸入惰性气体气氛中低于惰性气体气氛持续显示其最低氧浓度的深度，以及（2）在惰性气体气氛中低于该深度的可自由基固化的组合物，至少一个辐射源设置在惰性气体/空气界面的下方，然后（3）再次从惰性气体气氛中排出所得的固化组合物，以及装置（1 ）。 1执行。

7. 发明授权

US07985478B2 Method for producing moulded parts, in particular for use in the car industry, and a film comprising a coating which is suitable therefor 有权
标题翻译：用于制造模制零件的方法，特别是用于汽车工业的模制件，以及包括适合于其的涂层的薄膜
公开(公告)号：US07985478B2
公开(公告)日：2011-07-26
申请号：US11718457
申请日：2005-10-17
申请人： Hubert Baumgart , Horst Hintze-Brüning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
发明人： Hubert Baumgart , Horst Hintze-Brüning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
IPC分类号： B32B27/08 , B29C51/08
CPC分类号： C09D175/16 , B29C37/0032 , C08G18/672 , Y10T428/31547
摘要： A process for producing moldings, in which a solventborne or aqueous, pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet, a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free- radically crosslinkable component (KK) which comprises carbamate and/or biuret and/or allophanate and/or urea and/or amide groups.
摘要翻译：一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的溶剂型或水性着色涂料组合物（P）和可自由基交联的涂料组合物（K）施加到载体片材上，从涂料组合物（K）制备干燥但尚未完全交联的涂层（KT），涂覆的支撑片被成形并用液体聚合材料注射回模制或泡沫背衬，并且涂层（KT）这还没有发生 - 固化或后固化; 包含可自由基交联的组分（KK）的可交联涂料组合物（K），其包含氨基甲酸酯和/或缩二脲和/或脲基甲酸酯和/或脲和/或酰胺基团。

8. 发明授权

US07935291B2 Method for producing molded plastic parts having functional surfaces 失效
标题翻译：用于制造具有功能表面的模制塑料部件的方法
公开(公告)号：US07935291B2
公开(公告)日：2011-05-03
申请号：US10595060
申请日：2004-07-13
申请人： Horst Hintze-Bruening , Markus Saedler , Fatmir Raka
发明人： Horst Hintze-Bruening , Markus Saedler , Fatmir Raka
IPC分类号： B29C45/14
CPC分类号： B32B27/06 , B29C45/14754 , B29C45/14811 , B29C2045/1477 , B29L2031/3005 , B32B27/08 , B32B37/00 , B32B2255/10 , B32B2255/26 , B32B2255/28 , B32B2307/202 , B32B2307/212 , B32B2307/422 , B32B2307/714 , B32B2307/746
摘要： A process for producing polymer moldings with functional surfaces, in which a coating is produced on a support sheet, the coated support sheet is shaped and backed by injection molding or foaming with a liquid polymeric material, and the coating, if this has not already taken place, is cured or aftercured, the coating is covered at least temporarily with a protective sheet.
摘要翻译：用于生产具有功能表面的聚合物模制品的方法，其中在支撑片材上产生涂层，涂覆的支撑片材通过注射成型或用液体聚合物材料发泡而成形和支撑，并且如果尚未采用该涂层固化或固化后，涂层至少用保护片暂时覆盖。

9. 发明申请

US20090061215A1 METHOD FOR PRODUCING MOLDED PARTS, ESPECIALLY FOR USE IN AUTOMOBILE MANUFACTURE, AND CORRESPONDING APPROPRIATE FILMS COMPRISING A COATING 有权
标题翻译：生产模具的方法，特别适用于汽车制造，以及对应包装涂料的适当膜
公开(公告)号：US20090061215A1
公开(公告)日：2009-03-05
申请号：US11718566
申请日：2005-10-17
申请人： Hubert Baumgart , Horst Hintze-Bruning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
发明人： Hubert Baumgart , Horst Hintze-Bruning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
IPC分类号： B32B27/40
CPC分类号： B29C37/0032 , B29C2037/0042 , C08G18/3212 , C08G18/672 , C08G18/722 , C09D175/16 , Y10T428/265
摘要： A process for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements in an amount such that 1. a coating (MT) produced from the mixture (M) of component (KK) with additives, but as yet not crosslinked to completion, has a ratio of storage modulus G(MT)′ to loss modulus G(MT)″ of from 5 to 200, G(MT)′ and G(MT)″ having been determined at 20° C. by means of rheological oscillation measurements, and 2. a coating (ME) produced from the mixture (M) of component (KK) with additives and crosslinked to completion has a storage modulus E(ME)″ of from 1.0*107.0 to 8.0*107.0 Pa, E(ME)′ having been measured in the rubber-elastic range by dynamic mechanical thermal analysis.
摘要翻译：一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的着色涂料组合物（P）和可自由交联的涂料组合物（K）被施加到干燥但仍然由涂料组合物（K）制备未完全交联的涂料（KT），涂覆的支撑片材成型并用液体聚合物材料注射回模塑或泡沫背衬，并且涂层（KT） - 如果尚未采用地方治愈或后固化; 所述可交联涂料组合物（K）包含可自由基交联的组分（KK），其含有形成氢键的结构元素，其量使得1.由组分（KK）的混合物（M）与添加剂，但尚未交联完成，具有5至200，G（MT）'和G（MT）“的储能模量G（MT）'与损耗模量G（MT）”的比率已被确定在20℃下，通过流变振动测量，和2.由组分（KK）与添加剂的混合物（M）产生并交联至完成的涂层（ME）具有的储能模量E（ME）通过动态机械热分析在橡胶弹性范围内测量的1.0 * 107.0至8.0 * 107.0 Pa，E（ME）'。

10. 发明授权

US09403297B2 Method for producing molded parts, especially for use in automobile manufacture, and corresponding appropriate films comprising a coating 有权
标题翻译：用于制造特别用于汽车制造的模制件的方法以及包括涂层的相应的适当的膜
公开(公告)号：US09403297B2
公开(公告)日：2016-08-02
申请号：US11718566
申请日：2005-10-17
申请人： Hubert Baumgart , Horst Hintze-Bruning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
发明人： Hubert Baumgart , Horst Hintze-Bruning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
IPC分类号： B29C41/20 , C08G18/67 , C09D175/16 , C08G18/73 , C08G18/74 , B29C37/00 , C08G18/72 , C08G18/32
CPC分类号： B29C37/0032 , B29C2037/0042 , C08G18/3212 , C08G18/672 , C08G18/722 , C09D175/16 , Y10T428/265
摘要： A process is disclosed for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet, wherein a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed, and the coating (KT) is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements.
摘要翻译：公开了一种用于生产模制品的方法，其中将着色的涂料组合物（P）和可自由交联的涂料组合物（K）在交联完成后产生透明涂料（KE）施加到支撑片材上，其中干燥，但由涂料组合物（K）制成尚未完全交联的涂料（KT），将涂布的支撑片成形并注射回模塑或泡沫背衬，涂层（KT）固化或后固化; 可交联涂料组合物（K）包含含有形成氢键的结构元素的自由基交联组分（KK）。

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