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1. 发明授权

US09266995B2 Binding agent mixture, coating agents containing said binding agent mixture, and coatings produced from said coating agents, said coatings having a high scratch resistance, high weathering stability, and good optical properties 有权
标题翻译：结合剂混合物，包含所述粘合剂混合物的涂层剂和由所述涂覆剂制备的涂层，所述涂层具有高耐刮擦性，高风化稳定性和良好的光学性能
公开(公告)号：US09266995B2
公开(公告)日：2016-02-23
申请号：US13395576
申请日：2010-08-03
申请人： Günter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
发明人： Günter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
IPC分类号： C08L75/06 , C08G18/42 , C08G18/16 , C08G18/28 , C08G18/71 , C08G18/77 , C08G18/80 , C09D175/04 , C08G18/18
CPC分类号： C08G18/4288 , C08G18/168 , C08G18/18 , C08G18/1883 , C08G18/289 , C08G18/42 , C08G18/718 , C08G18/778 , C08G18/809 , C09D175/04 , Y10T428/31663
摘要： Binder mixture comprising a hydroxyl-containing compound (A), and at least 1.0% by weight, based on the nonvolatile constituents of the binder mixture, of a phosphorus- and nitrogen-containing catalyst (D) for the crosslinking of silane groups, wherein the hydroxyl-containing compound (A) comprises a hydroxyl-functional polyester having on average at least one hydroxyl function of the polyester esterified with a C8 to C9 monocarboxylic acid, and the catalyst (D) is blocked with at least one tertiary amine of the formula (I) where R1 is an acyclic aliphatic or araliphatic hydrocarbon radical having at least 3 C atoms, R2 is an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R3, and R3 is hydrogen or an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R2.
摘要翻译：包含含羟基化合物（A）的粘合剂混合物和至少1.0重量％，基于粘合剂混合物的不挥发成分，用于交联硅烷基团的含磷和氮的催化剂（D），其中含羟基化合物（A）包含平均具有C8-C9单羧酸酯化的聚酯的至少一个羟基官能团的羟基官能聚酯，催化剂（D）被至少一种叔胺式（I）其中R 1是具有至少3个C原子的无环脂族或芳脂族烃基，R 2是与R 1和/或R 3相同或不同的无环脂族或芳脂族烃基，R 3是氢或无环与R 1和/或R 2相同或不同的脂族或芳脂族烃基。

2. 发明申请

US20130052469A1 BINDING AGENT MIXTURE, COATING AGENTS CONTAINING SAID BINDING AGENT MIXTURE, AND COATINGS PRODUCED FROM SAID COATING AGENTS, SAID COATINGS HAVING A HIGH SCRATCH RESISTANCE, HIGH WEATHERING STABILITY, AND GOOD OPTICAL PROPERTIES 有权
标题翻译：粘合剂混合物，含有粘合剂混合物的涂料代理，以及由上述涂料代理生产的涂料，具有高耐刮擦性，高耐候性和良好光学性能的涂料
公开(公告)号：US20130052469A1
公开(公告)日：2013-02-28
申请号：US13395576
申请日：2010-08-03
申请人： Gunter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
发明人： Gunter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
IPC分类号： C08L67/08 , B05D1/36 , B32B9/00 , C09D183/08
CPC分类号： C08G18/4288 , C08G18/168 , C08G18/18 , C08G18/1883 , C08G18/289 , C08G18/42 , C08G18/718 , C08G18/778 , C08G18/809 , C09D175/04 , Y10T428/31663
摘要： Binder mixture comprising a hydroxyl-containing compound (A), and at least 1.0% by weight, based on the nonvolatile constituents of the binder mixture, of a phosphorus- and nitrogen-containing catalyst (D) for the crosslinking of silane groups, wherein the hydroxyl-containing compound (A) comprises a hydroxyl-functional polyester having on average at least one hydroxyl function of the polyester esterified with a C8 to C9 monocarboxylic acid, and the catalyst (D) is blocked with at least one tertiary amine of the formula (I) where R1 is an acyclic aliphatic or araliphatic hydrocarbon radical having at least 3 C atoms, R2 is an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R3, and R3 is hydrogen or an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R2.
摘要翻译：包含含羟基化合物（A）的粘合剂混合物和至少1.0重量％，基于粘合剂混合物的不挥发成分，用于交联硅烷基团的含磷和氮的催化剂（D），其中含羟基化合物（A）包含平均具有C8-C9单羧酸酯化的聚酯的至少一个羟基官能团的羟基官能聚酯，催化剂（D）被至少一种叔胺式（I）其中R 1是具有至少3个C原子的无环脂族或芳脂族烃基，R 2是与R 1和/或R 3相同或不同的无环脂族或芳脂族烃基，R 3是氢或无环与R 1和/或R 2相同或不同的脂族或芳脂族烃基。

3. 发明申请

US20110152440A1 PAINT COMPOSITIONS, A METHOD OF FINISH-PAINTING AND PAINTED OBJECTS 有权
标题翻译：涂料组合物，涂漆和涂漆物品的方法
公开(公告)号：US20110152440A1
公开(公告)日：2011-06-23
申请号：US12674534
申请日：2008-08-22
申请人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
发明人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
IPC分类号： C09D133/08
CPC分类号： C09D133/066 , C08K5/29 , C08L33/066 , C08L101/02 , C08L2666/04
摘要： [Problem] To provide a paint composition which forms paint films which are excellent in terms of car-wash scratching resistance, acid resistance and weather resistance, a method of finish painting and painted objects.[Means of Resolution] A paint composition which has as essential components hydroxyl group containing resin (A) which has a hydroxyl group value of from 80 to 220 mgKOH/g, a glass transition temperature of −50° C. or above but below 0° C. and which contains from 25 to 55 mass % of units of 4-hydroxybutyl (meth)acrylate origin, hydroxyl group containing resin (B) which has a hydroxyl group value of from 80 to 220 mgKOH/g and a glass transition temperature of from 0 to 50° C. and crosslinking agent (C) comprising polyisocyanate compound, characterized in that the proportions of hydroxyl group containing resin (A) and hydroxyl group containing resin (B) included are, as a ratio of the solid fraction masses, from 95/5 to 50/50, and the proportion of isocyanate groups which are the functional groups of the crosslinking agent (C) included with respect to the hydroxyl groups in total of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), as the NCO/OH mol ratio, is from 0.5 to 1.5.
摘要翻译： [问题]提供一种油漆组合物，其形成在洗车耐刮擦性，耐酸性和耐候性方面优异的漆膜，涂漆和涂漆物品的方法。 [解决方法]将羟基含量为80〜220mgKOH / g，玻璃化转变温度为-50℃以上但低于0的含羟基树脂（A）作为必要成分的涂料组合物 ℃，含有25〜55质量％的（甲基）丙烯酸4-羟基丁酯单元，羟值为80〜220mgKOH / g的羟基树脂（B），玻璃化转变温度为0〜50℃，含有多异氰酸酯化合物的交联剂（C）的特征在于，含有羟基的树脂（A）和含有羟基的树脂（B）的比例为固体成分质量比，95/5〜50/50，作为交联剂（C）的官能团的异氰酸酯基的含量相对于含羟基的树脂（A）和羟基的羟基的比例含有树脂（B），作为NCO / OH摩尔比例为0.5〜1.5。

4. 发明授权

US08236895B2 Paint compositions, a method of finish-painting and painted objects 有权
标题翻译：油漆成分，涂漆方法和涂漆物品
公开(公告)号：US08236895B2
公开(公告)日：2012-08-07
申请号：US12674534
申请日：2008-08-22
申请人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
发明人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
IPC分类号： C08L75/02
CPC分类号： C09D133/066 , C08K5/29 , C08L33/066 , C08L101/02 , C08L2666/04
摘要： Disclosed is a finish paint composition having a hydroxyl group containing resin (A) comprising a hydroxyl group value of 80 to 220 mgKOH/g, a glass transition temperature of −50° or above but below 0° C., and 25 to 55 mass% of units of 4-hydroxybutyl (meth)acrylate origin, a hydroxyl group containing resin (B) with a hydroxyl group value of 80 to 220 mgKOH/g, and a glass transition temperature of 0 to 50° C., and a crosslinking agent (C) comprising polyisocyanate compound having isocyanate groups, wherein the proportions of hydroxyl group containing resin (A) and hydroxyl group containing resin (B) are, as a ratio of solid fraction masses, from 95/5 to 50/50, and the proportion of isocyanate groups of the crosslinking agent (C) with respect to the hydroxyl groups in total of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), as the NCO/OH mol ratio, is 0.5 to 1.5.
摘要翻译：公开了具有羟基值为80〜220mgKOH / g，玻璃化转变温度为-50℃以上且低于0℃的含羟基的树脂（A）和25〜55质量％的表面漆组合物（甲基）丙烯酸4-羟基丁酯单元的％，羟基值为80〜220mgKOH / g，玻璃化转变温度为0〜50℃的含羟基的树脂（B），交联包含具有异氰酸酯基的多异氰酸酯化合物的试剂（C），其中含羟基的树脂（A）和含羟基的树脂（B）的比例为固体成分质量比为95/5至50/50，和作为NCO / OH摩尔比，交联剂（C）的异氰酸酯基相对于含羟基树脂（A）和含羟基树脂（B）的总数相对于羟基的比例为0.5〜 1.5。

5. 发明授权

US09090732B2 Coating composition having a high scratch resistance and weathering stability 有权
标题翻译：具有高耐擦伤性和耐候性稳定性的涂料组合物
公开(公告)号：US09090732B2
公开(公告)日：2015-07-28
申请号：US12808987
申请日：2008-12-18
申请人： Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Oliver Hilge , Günter Klein
发明人： Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Oliver Hilge , Günter Klein
IPC分类号： C08G18/28 , C08L83/04 , B05D3/02 , B05D7/00 , C08G18/20 , C08G18/62 , C08G18/77 , C08G18/79 , C08G18/80 , C09D175/04
CPC分类号： C08G18/2063 , C08G18/6254 , C08G18/778 , C08G18/792 , C08G18/809 , C09D175/04
摘要： The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one phosphate-containing catalyst (C) for the crosslinking of silane groups, (d) at least one further catalyst (D), one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the catalyst (D) is a bicyclic amine.
摘要翻译：本发明涉及包含（a）至少一种含羟基的化合物（A），（b）至少一种具有游离和/或封闭的异氰酸酯基团的化合物（B）的涂料组合物，和（c）至少一种磷酸盐（D），含有可水解硅烷基的涂料组合物的一种或多种成分，其中催化剂（D）是双环胺。

6. 发明申请

US20110263789A1 CLEAR PAINT COMPOSITIONS COMPRISING HYPERBRANCHED, DENDRITIC, HYDROXYL- FUNCTIONAL POLYESTERS 有权
标题翻译：含有高分子量，羟基，羟基官能聚酯的清漆组合物
公开(公告)号：US20110263789A1
公开(公告)日：2011-10-27
申请号：US12663356
申请日：2008-06-05
申请人： Hitoshi Taniguchi , Eishi Tsukamoto , Hiroyuki Takagi , Andreas Poppe , Günter Klein , Veronika Lackstadter , Bianca Giesen , Petra Wagner , Björn Feldmann , Sabine Holtschulte , Julia Melzer , Tanja Bricke , Oliver Hilge , Benedikt Schnier , Silke Hottenbacher , Ulrike Clausen-Meiring
发明人： Hitoshi Taniguchi , Eishi Tsukamoto , Hiroyuki Takagi , Andreas Poppe , Günter Klein , Veronika Lackstadter , Bianca Giesen , Petra Wagner , Björn Feldmann , Sabine Holtschulte , Julia Melzer , Tanja Bricke , Oliver Hilge , Benedikt Schnier , Silke Hottenbacher , Ulrike Clausen-Meiring
IPC分类号： C09D167/00 , C08G63/91
CPC分类号： C08G18/42 , C08G63/912 , C08L61/28 , C09D167/00 , C08L2666/16
摘要： Disclosed is a hyperbranched, dendritic, hydroxyl-functional polyester comprising an OH number greater than or equal to 180 mg KOH/g as measured via DIN 53240 and to clearcoat compositions comprising said polyesters. Also disclosed are processes for preparing the disclosed polyester, methods of making coated automotive substrates by applying the disclosed clearcoat compositions to automotive substrates, and to coated substrates made therefrom.
摘要翻译：公开了一种超支化树枝状羟基官能聚酯，其包含通过DIN 53240测量的大于或等于180mg KOH / g的OH数，以及包含所述聚酯的透明涂料组合物。还公开了制备所公开的聚酯的方法，通过将所公开的透明涂料组合物应用于汽车基材来制备涂覆的汽车基材的方法以及由其制备的涂布的基材。

7. 发明授权

US09334355B2 Clear paint compositions comprising hyperbranched, dendritic, hydroxyl-functional polyesters 有权
标题翻译：包含超支化，树枝状，羟基官能的聚酯的清漆组合物
公开(公告)号：US09334355B2
公开(公告)日：2016-05-10
申请号：US12663356
申请日：2008-06-05
申请人： Hitoshi Taniguchi , Eishi Tsukamoto , Hiroyuki Takagi , Andreas Poppe , Günter Klein , Veronika Lackstadter , Bianca Giesen , Petra Wagner , Björn Feldmann , Sabine Holtschulte , Julia Melzer , Tanja Bricke , Oliver Hilge , Benedikt Schnier , Silke Hottenbacher , Ulrike Clausen-Meiring
发明人： Hitoshi Taniguchi , Eishi Tsukamoto , Hiroyuki Takagi , Andreas Poppe , Günter Klein , Veronika Lackstadter , Bianca Giesen , Petra Wagner , Björn Feldmann , Sabine Holtschulte , Julia Melzer , Tanja Bricke , Oliver Hilge , Benedikt Schnier , Silke Hottenbacher , Ulrike Clausen-Meiring
IPC分类号： C08G63/00 , C08L67/00 , C08L73/00 , C08L77/00 , C08F283/00 , C08G63/91 , C08G67/00 , C08G69/00 , C08G63/02 , C08G63/16 , C08G18/42 , C09D167/00 , C08L61/28
CPC分类号： C08G18/42 , C08G63/912 , C08L61/28 , C09D167/00 , C08L2666/16
摘要： Disclosed is a hyperbranched, dendritic, hydroxyl-functional polyester comprising an OH number greater than or equal to 180 mg KOH/g as measured via DIN 53240 and to clearcoat compositions comprising said polyesters. Also disclosed are processes for preparing the disclosed polyester, methods of making coated automotive substrates by applying the disclosed clearcoat compositions to automotive substrates, and to coated substrates made therefrom.
摘要翻译：公开了一种超支化树枝状羟基官能聚酯，其包含通过DIN 53240测量的大于或等于180mg KOH / g的OH数，以及包含所述聚酯的透明涂料组合物。还公开了制备所公开的聚酯的方法，通过将所公开的透明涂料组合物应用于汽车基材来制备涂覆的汽车基材的方法以及由其制备的涂布的基材。

8. 发明申请

US20110245406A1 COATING COMPOSITIONS AND COATINGS PRODUCED FROM THEM WITH HIGH SCRATCH RESISTANCE, WEATHERING STABILITY, AND GOOD OPTICAL PROPERTIES 有权
标题翻译：涂层组合物和涂层，具有高耐蚀性，耐候稳定性和良好的光学性能
公开(公告)号：US20110245406A1
公开(公告)日：2011-10-06
申请号：US13132847
申请日：2009-08-22
申请人： Günter Klein , Björn Feldmann , Sabine Holtschulte , Silke Hottenbacher , Andreas Poppe , Ulrike Clausen-Meiring
发明人： Günter Klein , Björn Feldmann , Sabine Holtschulte , Silke Hottenbacher , Andreas Poppe , Ulrike Clausen-Meiring
IPC分类号： C08L67/00 , B05D1/36 , B05D3/02
CPC分类号： C09D175/04 , B05D5/005 , B05D7/14 , B05D7/53 , C08G18/4288 , C08G18/809 , C09D167/00 , C09D201/005 , Y10T428/31786
摘要： The invention relates to coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one saturated compound (B) having free and/or blocked isocyanate groups and containing at least in part hydrolyzable silane groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, wherein the coating composition comprises as hydroxyl-containing compound (A) at least one hyperbranched, dendritic hydroxy-functional polyester in which on average at least one hydroxyl function of the polyester is esterified with at least one acid selected from the group of the isomeric C8 to C9 monocarboxylic acids. The present invention also provides a multistage coating method using these coating compositions, and also the use of the coating compositions as clearcoat material for producing multicoat effect and/or color paint systems, and use of the coating method for automotive OEM finishing and automotive refinish.
摘要翻译：本发明涉及涂料组合物，其包含（a）至少一种含羟基的化合物（A），（b）至少一种具有游离和/或封闭的异氰酸酯基团并且至少部分可水解的硅烷基团的饱和化合物（B）和（c）至少一种用于硅烷基交联的催化剂（D），其中所述涂料组合物包含作为含羟基的化合物（A）至少一种超支化的树枝状羟基官能聚酯，其中平均具有至少一个羟基官能团的聚酯与至少一种选自异构C8-C9单羧酸的酸酯化。本发明还提供了使用这些涂料组合物的多级涂布方法，以及使用涂料组合物作为制备多色效果和/或彩色涂料体系的透明涂层材料，以及使用涂覆方法用于汽车OEM整理和汽车修补漆。

9. 发明授权

US08679589B2 Coating agent having high scratch resistance and high weathering resistance 有权
标题翻译：涂层剂具有高耐刮擦性和高耐候性
公开(公告)号：US08679589B2
公开(公告)日：2014-03-25
申请号：US12808973
申请日：2008-12-18
申请人： Matthijs Groenewolt , Günter Klein , Andreas Poppe , Simone Hesener , Wilfried Stübbe , Manuela Niemeier , Sabine Holtschulte , Oliver Hilge , Björn Feldmann
发明人： Matthijs Groenewolt , Günter Klein , Andreas Poppe , Simone Hesener , Wilfried Stübbe , Manuela Niemeier , Sabine Holtschulte , Oliver Hilge , Björn Feldmann
IPC分类号： B05D3/02
CPC分类号： C08G18/289 , C08G18/778 , C08G18/792 , C08G18/809 , C08K5/06 , C08K5/29 , C08K5/521
摘要： The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (C) for the crosslinking of silane groups, one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the coating composition contains a water scavenger as further constituent (D).
摘要翻译：本发明涉及包含（a）至少一种含羟基的化合物（A），（b）至少一种具有游离和/或封闭的异氰酸酯基的化合物（B）的涂料组合物，和（c）至少一种催化剂（C）用于硅烷基团的交联，所述涂料组合物的一种或多种组分含有可水解的硅烷基团，其中所述涂料组合物含有除水剂作为另外的组分（D）。

10. 发明授权

US08486539B2 Coating compositions and coatings produced from them with high scratch resistance, weathering stability, and good optical properties 有权
标题翻译：涂料组合物和涂料由它们制备，具有高耐刮擦性，耐候性稳定性和良好的光学性能
公开(公告)号：US08486539B2
公开(公告)日：2013-07-16
申请号：US13132847
申请日：2009-08-22
申请人： Günter Klein , Björn Feldmann , Sabine Holtschulte , Silke Hottenbacher , Andreas Poppe , Ulrike Clausen-Meiring
发明人： Günter Klein , Björn Feldmann , Sabine Holtschulte , Silke Hottenbacher , Andreas Poppe , Ulrike Clausen-Meiring
IPC分类号： C08L67/04 , B32B27/36
CPC分类号： C09D175/04 , B05D5/005 , B05D7/14 , B05D7/53 , C08G18/4288 , C08G18/809 , C09D167/00 , C09D201/005 , Y10T428/31786
摘要： The invention relates to coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one saturated compound (B) having free and/or blocked isocyanate groups and containing at least in part hydrolyzable silane groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, wherein the coating composition comprises as hydroxyl-containing compound (A) at least one hyperbranched, dendritic hydroxy-functional polyester in which on average at least one hydroxyl function of the polyester is esterified with at least one acid selected from the group of the isomeric C8 to C9 monocarboxylic acids. The present invention also provides a multistage coating method using these coating compositions, and also the use of the coating compositions as clearcoat material for producing multicoat effect and/or color paint systems, and use of the coating method for automotive OEM finishing and automotive refinish.
摘要翻译：本发明涉及涂料组合物，其包含（a）至少一种含羟基的化合物（A），（b）至少一种具有游离和/或封闭的异氰酸酯基团并且至少部分可水解的硅烷基团的饱和化合物（B）和（c）至少一种用于硅烷基交联的催化剂（D），其中所述涂料组合物包含作为含羟基的化合物（A）至少一种超支化的树枝状羟基官能聚酯，其中平均具有至少一个羟基官能团的聚酯与至少一种选自异构C8-C9单羧酸的酸酯化。本发明还提供了使用这些涂料组合物的多级涂布方法，以及使用涂料组合物作为制备多色效果和/或彩色涂料体系的透明涂层材料，以及使用涂覆方法用于汽车OEM整理和汽车修补漆。

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