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1. 发明申请

US20100022789A1 Catalytic compositions for the metathesis of unsaturated fatty bodies with olefins and metathesis methods using catalytic compositions 审中-公开
标题翻译：用于烯烃不饱和脂肪体复分解的催化组合物和使用催化组合物的复分解方法
公开(公告)号：US20100022789A1
公开(公告)日：2010-01-28
申请号：US12458856
申请日：2009-07-24
申请人： Gérard Mignani , Virginie Pevere , Hélène Olivier-Bourbigou , Christophe Vallee , Mikael Berthod , Cécilia Citadelle
发明人： Gérard Mignani , Virginie Pevere , Hélène Olivier-Bourbigou , Christophe Vallee , Mikael Berthod , Cécilia Citadelle
IPC分类号： C07C67/00 , C07F15/00 , C07C51/00
CPC分类号： B01J31/2273 , B01J31/2208 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C2531/22 , C07C69/533
摘要： Catalytic compositions useful for carrying out the metathesis of unsaturated fatty bodies, in particular unsaturated fatty bodies comprising oleic acid or oleic acid esters, contain a ruthenium-based catalyst which can be isolated and which has the formula (I) below:
摘要翻译：用于进行不饱和脂肪体，特别是包含油酸或油酸酯的不饱和脂肪酸的复分解的催化组合物含有可以被分离并具有下式（I）的钌基催化剂：

2. 发明授权

US07906663B2 Process for co-producing olefins and diesters or diacids starting from unsaturated fats 有权
标题翻译：从不饱和脂肪开始共聚产生烯烃和二酯或二酸的方法
公开(公告)号：US07906663B2
公开(公告)日：2011-03-15
申请号：US11626077
申请日：2007-01-23
申请人： Hélène Olivier-Bourbigou , Christophe Vallee , Gérard Hillion
发明人： Hélène Olivier-Bourbigou , Christophe Vallee , Gérard Hillion
IPC分类号： C07C51/00
CPC分类号： C07C51/347 , C07C1/213 , C07C6/04 , C07C67/333 , C07C67/475 , C07C2531/24 , C07C11/04 , C07C11/02 , C07C57/13 , C07C69/533 , C07C69/593
摘要： In order to produce both an olefinic fraction and a composition of diacids or diesters of fats, a process is carried out which comprises, in succession: a) metathesis of an unsaturated fat with ethylene in the presence of at least one non-aqueous ionic liquid; b) separating and recycling the ionic liquid used in the first step; c) separating, by distillation, the olefinic fraction (fraction A) from the unsaturated fat mono-ester or mono-basic acid fraction (fraction B) formed in step a); d) homometathesis of the mono-unsaturated fat ester or acid cut (fraction B) which allows the co-production of unsaturated fat diesters or diacids (fraction C) and ethylene which is recycled to the first methathesis step of the process; and e) optionally, recycling the ionic liquid containing the catalyst used in step d). Of particular application to an oleic sunflower oil, an oleic rapeseed oil or to a mixture of mono-alcohol esters of said oils, whereupon the process can produce both an olefinic fraction (mainly composed of 1-decene) and a composition of diesters or diacids wherein, in general, over half of the chains is constituted by unsaturated C18 chains (mainly composed of octadecene-9 1,18-iacid or diester) and to recycle the ethylene employed.
摘要翻译：为了产生烯烃级分和脂肪二酸或二酯的组合物，进行了以下过程：a）在至少一种非水离子液体的存在下，不饱和脂肪与乙烯的复分解 ; b）分离和再循环第一步中使用的离子液体; c）通过蒸馏从步骤a）中形成的不饱和脂肪单酯或单碱性酸部分（级分B）分离出烯烃级分（级分A）; d）单不饱和脂肪酯或酸切割（B馏分）的同位素，其允许共生产不饱和脂肪二酯或二酸（馏分C）和乙烯，其被再循环到该方法的第一个复分解步骤; 和e）任选地，循环含步骤d）中使用的催化剂的离子液体。特别适用于油酸向日葵油，油菜菜籽油或所述油的单醇酯的混合物，于是该方法可以产生烯烃级分（主要由1-癸烯组成）和二酯或二酸的组合物其中通常一半以上的链由不饱和C18链（主要由十八碳烯-9,18-酸或二酯组成）构成，并循环使用乙烯。

3. 发明授权

US07754904B2 Process for co-producing olefins and diesters or diacids by homomethathesis of unsaturated fats in non-aqueous ionic liquids 有权
标题翻译：通过非水离子液体中不饱和脂肪的同位素共同生产烯烃和二酯或二酸的方法
公开(公告)号：US07754904B2
公开(公告)日：2010-07-13
申请号：US11626082
申请日：2007-01-23
申请人： Hélène Olivier-Bourbigou , Gérard Hillion , Christophe Vallee
发明人： Hélène Olivier-Bourbigou , Gérard Hillion , Christophe Vallee
IPC分类号： C11C1/00
CPC分类号： C07C1/2078 , C07C51/347 , C07C67/475 , C07C2523/46 , C07C11/02 , C07C57/13 , C07C69/593
摘要： A process is described in which an unsaturated fat is reacted in a homometathesis reaction in the presence of at least one non-aqueous ionic liquid to produce both an olefinic fraction and a composition of monoalcohol diesters or diacids.Particular application to a mixture of esters of an oleic sunflower seed oil or an oleic rapeseed oil, the process producing both an olefinic fraction and a composition of monoalcohol diesters or diacids wherein, in general, more than half of its chains is constituted by unsaturated C18 chains.
摘要翻译：描述了一种方法，其中不饱和脂肪在同位素反应中在至少一种非水离子液体的存在下反应，以产生烯烃级分和单醇二酯或二酸的组合物。特别适用于油酸向日葵籽油或油菜菜籽油的酯的混合物，该方法生产烯烃级分和单醇二酯或二酸的组合物，其中通常一半以上的链由不饱和C18 链条

4. 发明授权

US06706657B2 Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins 有权
标题翻译：用于二烯化，共二聚和低聚烯烃的催化组合物
公开(公告)号：US06706657B2
公开(公告)日：2004-03-16
申请号：US09775556
申请日：2001-02-05
申请人： Dominique Commereuc , Dominique Le Pennec , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Dominique Le Pennec , Hélène Olivier-Bourbigou
IPC分类号： B01J3100
CPC分类号： C07C2/32 , B01J31/0284 , B01J31/0288 , B01J31/14 , B01J31/143 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/2409 , B01J2231/20 , B01J2531/847 , C07C2/26 , C07C2527/128 , C07C2531/22
摘要： A catalytic composition comprising at least one nickel compound mixed or complexed with at least one tertiary phosphine or a phosphite carrying a functional group, at least partly dissolved in a non-aqueous medium with an ionic nature resulting from bringing at least one aluminum halide into contact with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, is useful for dimerizing, co-dimerizing and oligomerizing olefins. Functional groups include, but are not limited to, an amine, a cyclic amine, a nitrogen-containing heterocycle, an ester, an acid, an alcohol, a quaternary ammonium, a quaternary phosphonium, a sulfonium, a sulfonate or a phosphonate group.
摘要翻译：一种催化组合物，其包含与至少一种叔膦或携带官能团的亚磷酸酯混合或络合的至少一种镍化合物，至少部分地溶解在具有离子性质的非水介质中，所述非水介质使至少一种卤化铝接触与至少一种季铵卤化物和/或至少一种季鏻卤化物可用于烯烃的二聚，共二聚和低聚。官能团包括但不限于胺，环胺，含氮杂环，酯，酸，醇，季铵，季鏻，锍，磺酸盐或膦酸酯基团。

5. 发明授权

US07060860B2 Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权
标题翻译：在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法
公开(公告)号：US07060860B2
公开(公告)日：2006-06-13
申请号：US10411389
申请日：2003-04-11
申请人： Lionel Magna , Hélène Olivier-Bourbigou , Lucien Saussine , Virginie Kruger-Tissot
发明人： Lionel Magna , Hélène Olivier-Bourbigou , Lucien Saussine , Virginie Kruger-Tissot
IPC分类号： C07C45/50
CPC分类号： C07B41/06 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.
摘要翻译：通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。

6. 发明授权

US06951831B2 Catalyst composition for dimerizing, co-dimerizing, oligomerizing and polymerizing olefins 有权
标题翻译：用于二聚，共二聚，低聚和聚合烯烃的催化剂组合物
公开(公告)号：US06951831B2
公开(公告)日：2005-10-04
申请号：US10356745
申请日：2003-02-03
申请人： Vincent Lecocq , Hélène Olivier-Bourbigou
发明人： Vincent Lecocq , Hélène Olivier-Bourbigou
IPC分类号： B01J31/22 , B01J31/02 , B01J31/18 , B01J31/28 , C07B61/00 , C07C2/26 , C07C2/34 , C07C11/02 , C07C11/08 , C07C11/107 , C08F4/70 , C08F4/80 , B01J71/00 , C07C2/02 , C07C2/24 , C08F4/44
CPC分类号： B01J31/2282 , B01J31/0284 , B01J31/0288 , B01J31/0289 , B01J31/1805 , B01J31/183 , B01J31/185 , B01J31/28 , B01J2231/12 , B01J2231/20 , B01J2531/847 , C07C2/26 , C07C2531/22 , C07C11/02
摘要： A catalyst composition for use in dimerizing, co-dimerizing or oligomerizing olefins comprises: at least one zero-valent nickel complex; at least one acid with formula H+X− in which X− represents an anion; and at least one ionic liquid with general formula Q+ A− in which A− is an anion identical to or different from X−. The composition can also comprise a nitrogen-containing ligand. It can be used in dimerizing, co-dimerizing, oligomerizing and in polymerizing olefins.
摘要翻译：用于使烯烃二聚，共二聚或低聚的催化剂组合物包括：至少一种零价镍络合物; 至少一种其中X为 - 表示阴离子的式Ⅳ+ X - - ;;;;;;;;;;;;;;;;;;; 和至少一种具有通式Q +，其中A是与X 1或X 2相同或不同的阴离子的至少一种离子液体， - 。组合物还可以包含含氮配体。它可用于二聚，共二聚，低聚和烯烃聚合。

7. 发明授权

US06646173B2 Sequence of processes for olefin oligomerisation 有权
公开(公告)号：US06646173B2
公开(公告)日：2003-11-11
申请号：US09984053
申请日：2001-10-26
申请人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier-Bourbigou
IPC分类号： C07C202
CPC分类号： C07C2/30 , C07C2/32 , C07C2531/14 , C07C2531/16
摘要： A process is described for carrying out olefin oligomerisation in two catalysis steps of different types, using an organic feed containing at least one olefin. The cut to be treated, containing at least one olefin (Cn), is introduced into a first reaction zone where, in a first step, it undergoes catalytic oligomerisation either of the homogeneous liquid phase type, or of the heterogeneous type with a solid support. The effluent produced is generally sent to a heat exchanger traversed by a cold liquid, the effluent thus being cooled before being sent to a second reaction zone where it undergoes catalytic oligomerisation in a liquid—liquid two-phase medium, the invention being characterized in that at least an ethylenic hydrocarbon containing 3 to 5 carbon atoms per molecule is added to the inlet to the second reaction zone.

8. 发明授权

US07223374B2 Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权
标题翻译：在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法
公开(公告)号：US07223374B2
公开(公告)日：2007-05-29
申请号：US11350881
申请日：2006-02-10
申请人： Lionel Magna , Hélène Olivier-Bourbigou , Lucien Saussine , Virginie Kruger-Tissot
发明人： Lionel Magna , Hélène Olivier-Bourbigou , Lucien Saussine , Virginie Kruger-Tissot
IPC分类号： B01J19/00 , B01J8/08
CPC分类号： C07B41/06 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.
摘要翻译：通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。

9. 发明授权

US06235959B1 Aliphatic hydrocarbon alkylation process 失效
标题翻译：脂肪烃烷基化方法
公开(公告)号：US06235959B1
公开(公告)日：2001-05-22
申请号：US09378709
申请日：1999-08-23
申请人： André Hirschauer , Hélène Olivier-Bourbigou
发明人： André Hirschauer , Hélène Olivier-Bourbigou
IPC分类号： C07C260
CPC分类号： B01J31/26 , B01J27/125 , B01J31/0239 , B01J31/0284 , B01J31/38 , B01J2231/323 , C07C2/60 , C07C2527/125 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2531/38 , C10G50/00
摘要： The invention concerns a process for alkylating isoparaffins by olefins using a novel catalyst, the olefin preferably being a low reactivity olefin. The catalyst is a composition resulting from a mixture of at least aluminum halide, at least one quaternary ammonium halide and/or at least one amine hydrohalide and at least one group IVB metal compound, preferably a group IVB metal halide.
摘要翻译：本发明涉及使用新型催化剂使烯烃烷基化的方法，烯烃优选为低活性烯烃。催化剂是由至少卤化铝，至少一种卤化铵和/或至少一种胺氢卤酸盐和至少一种IVB族金属化合物，优选IVB族金属卤化物的混合物产生的组合物。

10. 发明授权

US06911410B2 Catalyst composition containing an aluminoxane for dimerizing, co-dimerizing and oligomerizing olefins 有权
标题翻译：催化剂组合物含有用于使烯烃二聚，共二聚和低聚的铝氧烷
公开(公告)号：US06911410B2
公开(公告)日：2005-06-28
申请号：US10356741
申请日：2003-02-03
申请人： Vincent Lecocq , Hélène Olivier-Bourbigou
发明人： Vincent Lecocq , Hélène Olivier-Bourbigou
IPC分类号： B01J31/02 , B01J31/12 , B01J31/14 , B01J31/18 , B01J31/22 , B01J31/30 , C07B61/00 , C07C2/22 , C07C2/32 , C07C2/34 , C07C2/36 , C07C11/02 , C08F4/80 , B01J31/00
CPC分类号： C07C2/36 , B01J31/0239 , B01J31/0284 , B01J31/0288 , B01J31/143 , B01J31/1805 , B01J31/1845 , B01J31/2234 , B01J31/2291 , B01J31/30 , B01J2231/20 , B01J2531/847 , C07C2/32 , C07C2/34 , C07C2527/125 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： A catalyst composition for use in dimerizing, co-dimerizing or oligomerizing olefins results from dissolving a nickel compound, optionally mixed or complexed with a ligand, in a medium resulting from mixing: at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide; at least one aluminum halide; and at least one aluminoxane.
摘要翻译：用于二烯化，共二聚或低聚烯烃的催化剂组合物是将由任选与配体混合或络合的镍化合物溶解在由混合产生的介质中产生的：至少一种季铵卤化物和/或至少一种季鏻卤化物; 至少一种卤化铝; 和至少一种铝氧烷。

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