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    • 1. 发明申请
    • FLUOROALKYL GROUP-CONTAINING N-SUBSTITUTED (METH)ACRYLAMIDE COMPOUND, POLYMER THEREOF , AND USE THEREOF
    • 含有氟取代基的N-取代(甲基)丙烯酰胺化合物,其聚合物及其用途
    • US20120149860A1
    • 2012-06-14
    • US13391120
    • 2010-08-17
    • Fusae IshiwataRyo HirabayashiHirotaka Shimizu
    • Fusae IshiwataRyo HirabayashiHirotaka Shimizu
    • C07C229/30C08F20/58C08F26/06C07D207/16C07D205/04C07D211/62C08F22/38
    • C07C233/49C08F20/58C08F220/22
    • A compound represented by the following formula (a): CH2═CR1—CONJ-CKR2—(CH2)n—COO-Q1-Rf1  (a) is provided. This compound is capable of forming a polymer having an oil repellency equivalent to polymers containing a polyfluoroalkyl group containing at least 8 carbon atoms, although the polyfluoroalkyl group contains up to 6 carbon atoms. In the formula, R1 is hydrogen atom or methyl group, R2 is hydrogen atom or a group represented by —(CH2)m—COO-Q2-Rf2 (r), n and m are independently an integer of 0 to 4, Rf1 and Rf2 are independently a polyfluoroalkyl group or a polyfluoroether group containing 1 to 6 carbon atoms, Q1 and Q2 are independently single bond or a divalent linkage group, J is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, K is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, and j and k are independently single bond or an alkylene group containing 1 to 3 carbon atoms with the proviso that j and k are not simultaneously single bond.
    • 提供由下式(a)表示的化合物:CH2 = CR1-CONJ-CKR2-(CH2)n-COO-Q1-Rf1(a)。 尽管多氟烷基含有最多6个碳原子,但是该化合物能够形成斥油性等同于含有至少8个碳原子的多氟烷基的聚合物的聚合物。 式中,R 1为氢原子或甲基,R 2为氢原子或 - (CH 2)m -COO-Q 2 -R f 2(r)表示的基团,n和m分别为0〜4的整数,Rf 1及 Rf2独立地为含有1〜6个碳原子的多氟烷基或多氟醚基,Q1和Q2独立地为单键或二价连接基团,J为氢原子或含有1〜3个碳原子的烷基,K为氢原子或 含有1〜3个碳原子的烷基,j和k独立地为单键或含有1〜3个碳原子的亚烷基,条件是j和k不同时为单键。
    • 2. 发明授权
    • Fluoroalkyl group-containing n-substituted (meth)acrylamide compound, polymer thereof, and use thereof
    • 含氟烷基的正取代(甲基)丙烯酰胺化合物,其聚合物及其用途
    • US09000110B2
    • 2015-04-07
    • US13391120
    • 2010-08-17
    • Fusae IshiwataRyo HirabayashiHirotaka Shimizu
    • Fusae IshiwataRyo HirabayashiHirotaka Shimizu
    • C08F22/38C08F20/58C07C233/49C08F220/22
    • C07C233/49C08F20/58C08F220/22
    • A compound represented by the following formula (a): CH2═CR1—CONJ-CGR2—(CH2)n—COO-Q1-Rf1  (a) is provided. This compound is capable of forming a polymer having an oil repellency equivalent to polymers containing a polyfluoroalkyl group containing at least 8 carbon atoms, although the polyfluoroalkyl group contains up to 6 carbon atoms. In the formula, R1 is hydrogen atom or methyl group, R2 is hydrogen atom or a group represented by —(CH2)m—COO-Q2-Rf2 (r), n and m are independently an integer of 0 to 4, Rf1 and Rf2 are independently a polyfluoroalkyl group or a polyfluoroether group containing 1 to 6 carbon atoms, Q1 and Q2 are independently single bond or a divalent linkage group, J is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, and G is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms.
    • 提供由下式(a)表示的化合物:CH2 = CR1-CONJ-CGR2-(CH2)n-COO-Q1-Rf1(a)。 尽管多氟烷基含有最多6个碳原子,但是该化合物能够形成斥油性等同于含有至少8个碳原子的多氟烷基的聚合物的聚合物。 式中,R 1为氢原子或甲基,R 2为氢原子或 - (CH 2)m -COO-Q 2 -R f 2(r)表示的基团,n和m分别为0〜4的整数,Rf 1及 Rf2独立地为含有1〜6个碳原子的多氟烷基或多氟醚基,Q1和Q2独立地为单键或二价连接基团,J为氢原子或含有1〜3个碳原子的烷基,G为氢原子 或含有1至3个碳原子的烷基。