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1. 发明授权

US6077899A Process for production of rubber composition 失效
标题翻译：橡胶组合物生产工艺
公开(公告)号：US6077899A
公开(公告)日：2000-06-20
申请号：US952486
申请日：1997-11-19
申请人： Fumito Yatsuyanagi , Hiroyuki Kaido , Tetsuji Kawazura
发明人： Fumito Yatsuyanagi , Hiroyuki Kaido , Tetsuji Kawazura
IPC分类号： C08L15/00 , C08L9/06 , C08L9/00
CPC分类号： C08L15/00 , C08K3/04 , C08L9/00
摘要： (i) A starting rubber (A) comprising a terminal-modified and/or coupled diene rubber and having an average glass transition temperature TgA (.degree. C.) is mixed with a specific amount of the reinforcing agent are mixed at a temperature of at least 135.degree. C., followed by adding a starting rubber (B) comprising a terminal unmodified diene rubber and having a specific average glass transition temperature TgB (.degree. C.), and the remaining reinforcing agent and a softening agent; (ii) a starting diene rubber (A') having a specific weight average molecular weight Mw(A') and average glass transition temperature TgA' (.degree. C.) is contacted with a reinforcing agent, followed by adding a starting diene rubber (B') having a specific weight average molecular weight Mw(B) and average glass transition temperature TgB' (.degree. C.), and a softening agent to produce a rubber composition; or (iii) 100 parts by weight of a starting rubber comprising a starting rubber (A") comprising 20 to 100% by weight of a terminal-modified and/or coupled diene rubber and a starting rubber (B") comprising a terminal-unmodified and/or uncoupled rubber are mixed with a specific carbon black (X) in specific amounts at a temperature of at least 135.degree. C., followed by adding the starting rubber (B") and the remaining carbon black and a softening agent.
摘要翻译： PCT No.PCT / JP96 / 03635 Sec。 371日期：1997年11月19日 102（e）日期1997年11月19日PCT Filted 1996年12月12日PCT公布。第WO97 / 48766号公报日期1997年12月24日（i）将具有平均玻璃化转变温度TgA（℃）的末端改性和/或偶合二烯橡胶的起始橡胶（A）与特定量的增强剂混合在至少135℃的温度下混合，然后加入包含末端未改性二烯橡胶并具有比平均玻璃化转变温度TgB（℃）的起始橡胶（B），剩余的增强剂和软化代理人（ii）具有比重重均分子量Mw（A'）和平均玻璃化转变温度TgA'（℃）的起始二烯橡胶（A'）与增强剂接触，然后加入起始二烯橡胶（具有比重重均分子量Mw（B）和平均玻璃化转变温度TgB'（℃）的软化剂B'）和软化剂以产生橡胶组合物; 或（iii）100重量份的起始橡胶，其包含起始橡胶（A“），其包含20至100重量％的末端改性和/或偶合的二烯橡胶和起始橡胶（B”），其包含末端未改性和/或未偶联的橡胶与特定碳黑（X）在至少135℃的温度下以特定量混合，随后加入起始橡胶（B“）和剩余的炭黑和软化剂。

2. 发明授权

US06525110B1 Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US06525110B1
公开(公告)日：2003-02-25
申请号：US09713298
申请日：2000-11-16
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K906
CPC分类号： C08K9/06 , C08K9/08 , C08L7/00 , C08L9/06 , C08L21/00 , Y10T428/2982 , Y10T428/2998 , C08L2666/14 , C08L83/06 , C08L9/00
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和具有以下烷氧基甲硅烷基（I）和/或酰氧基甲硅烷基（II）的聚硅氧烷，其平均聚合度为3〜10,000。是具有1至18个碳原子的取代或未取代的一价烃基或含有醚键的有机基团，R 2是氢或具有1至21个碳原子的烃基。

3. 发明授权

US6033597A Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US6033597A
公开(公告)日：2000-03-07
申请号：US188694
申请日：1998-11-10
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K9/06 , C08K9/08 , C08L21/00 , C09K3/00
CPC分类号： C08K9/06 , C08K9/08 , C08L21/00 , C08L7/00 , C08L9/06 , Y10T428/2982 , Y10T428/2998
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a compounding agent comprising a mixture of a polysiloxane having the following alkoxysilyl group (I) and having an average degree of polymerization of 3 to 10,000:.tbd.Si--OR.sup.1 (I).tbd.Si--OCOR.sup.2 (II)wherein, R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R.sup.2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms, and a sulfur containing silane.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和包含具有以下烷氧基甲硅烷基（I）的聚硅氧烷和平均聚合度为3至10,000:3THSi-OR1的混合物的配混剂（I）3 SiSiOOR 2（II）其中，R 1为取代或未取代的碳原子数为1〜18的一价烃基或含有醚键的有机基团，R 2为氢或碳原子数1〜21的烃基，和含硫硅烷。

4. 发明授权

US06337361B1 Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US06337361B1
公开(公告)日：2002-01-08
申请号：US09526733
申请日：2000-03-16
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K906
CPC分类号： C08K9/06 , C08K9/08 , C08L7/00 , C08L9/06 , C08L21/00 , Y10T428/2982 , Y10T428/2998 , C08L2666/14 , C08L83/06 , C08L9/00
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms. The polysiloxane is impregnated in an inert powder.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和具有以下烷氧基甲硅烷基（I）和/或酰氧基甲硅烷基（II）的聚硅氧烷，其平均聚合度为3〜10,000。是具有1至18个碳原子的取代或未取代的一价烃基或含有醚键的有机基团，R 2是氢或具有1至21个碳原子的烃基。聚硅氧烷浸渍在惰性粉末中。

5. 发明授权

US6121347A Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US6121347A
公开(公告)日：2000-09-19
申请号：US188695
申请日：1998-11-10
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K9/06 , C08K9/08 , C08L21/00
CPC分类号： C08K9/06 , C08K9/08 , C08L21/00 , C08L7/00 , C08L9/06 , Y10T428/2982 , Y10T428/2998
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a compounding agent consisting of a silane coupling agent and a carbon black, calcium carbonate or stearic acid powder impregnated with a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000:.tbd.Si--OR.sup.1 (I).tbd.Si--OCOR.sup.2 (II)wherein, R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R.sup.2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和由硅烷偶联剂和炭黑，碳酸钙或硬脂酸粉末组成的配混剂，所述炭黑，碳酸钙或硬脂酸粉末浸渍有具有以下烷氧基甲硅烷基（I）的聚硅氧烷和（II），平均聚合度为3〜10,000：3 Si-OR 1（I）3 SiSiO OCOR 2（II）其中，R 1为取代或未取代的碳原子数为1〜18的一价烃基或含有醚键的有机基团，R 2为氢或碳原子数1〜21的烃基。

6. 发明授权

US06177505B1 Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US06177505B1
公开(公告)日：2001-01-23
申请号：US08708060
申请日：1996-08-30
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K300
CPC分类号： C08K9/06 , C08K9/08 , C08L7/00 , C08L9/06 , C08L21/00 , Y10T428/2982 , Y10T428/2998 , C08L2666/14 , C08L83/06 , C08L9/00
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和具有以下烷氧基甲硅烷基（I）和/或酰氧基甲硅烷基（II）的聚硅氧烷，其平均聚合度为3〜10,000。是具有1至18个碳原子的取代或未取代的一价烃基或含有醚键的有机基团，R 2是氢或具有1至21个碳原子的烃基。

7. 发明授权

US5962575A Rubber composition containing carbon black 失效
标题翻译：含有炭黑的橡胶组合物
公开(公告)号：US5962575A
公开(公告)日：1999-10-05
申请号：US973240
申请日：1997-12-03
申请人： Fumito Yatsuyanagi , Hiroyuki Kaido , Tetsuji Kawazura
发明人： Fumito Yatsuyanagi , Hiroyuki Kaido , Tetsuji Kawazura
IPC分类号： B60C1/00 , C08K3/04 , C08K3/00
CPC分类号： C08K3/04 , B60C1/00 , B60C1/0016
摘要： A carbon-containing rubber composition containing a rubber composition containing carbon black, obtained by coagulating, dehydrating, and drying a rubber latex mixture containing a latex of at least one starting rubber A having an average glass transition temperature TgA of -120.degree. C. to -15.degree. C., carbon black, and part of a softening agent, mixed in an internal mixer with a starting rubber B and part of the softening agent, with a ratio F.sub.A /F.sub.B of the concentration F.sub.A of carbon black in the copolymer in the rubber latex mixture with the concentration F.sub.B of carbon black in the copolymer after kneading by the hermetic mixture being 1.2 to 3.0 and a rubber composition containing carbon black comprising a starting rubber A' comprising a polymer having functional groups represented by formula (I)--C.dbd.N'-- (I)bonded with a polymer chain directly or through another atomic group or a terminal modified diene-based polymer first brought into contact with carbon black, then blended with a starting rubber B' comprising a diene based stock rubber.
摘要翻译： PCT No.PCT / JP97 / 01051 Sec。 371日期1997年12月3日第 102（e）日期1997年12月3日PCT 1997年3月27日PCT公布。第WO97 / 38047号公报日期1997年10月16日含有含有炭黑的橡胶组合物的含碳橡胶组合物，其通过凝固，脱水和干燥含有平均玻璃化转变温度TgA为至少一种起始橡胶A的胶乳的橡胶胶乳混合物而获得， 120℃〜-15℃，炭黑和部分软化剂，在内部混合器中与起始橡胶B和部分软化剂混合，比例FA / FB为碳浓度FA 通过密封混合物捏合后共聚物中的炭黑的浓度FB在橡胶胶乳混合物中的黑色黑色，并且含有炭黑的橡胶组合物包含含有由式（I）-C = N' - （I）直接或通过另一原子团或末端改性二烯基聚合物与聚合物链键合，首先与炭黑接触，然后混合用包含二烯基原料橡胶的起始橡胶B'。

8. 发明授权

US5679728A Surface-treated carbon black and rubber composition containing same 失效
标题翻译：含有它们的表面处理炭黑和橡胶组合物
公开(公告)号：US5679728A
公开(公告)日：1997-10-21
申请号：US552060
申请日：1995-11-02
申请人： Tetsuji Kawazura , Hiroyuki Kaido , Kouichi Ikai , Fumito Yatsuyanagi , Masayuki Kawazoe
发明人： Tetsuji Kawazura , Hiroyuki Kaido , Kouichi Ikai , Fumito Yatsuyanagi , Masayuki Kawazoe
IPC分类号： B60C1/00 , C08K3/00 , C08K3/04 , C08K3/36 , C08K5/00 , C08K5/54 , C08K9/00 , C08K9/02 , C08K9/06 , C08L21/00 , C08L101/00 , C09C1/48 , C09C1/56
CPC分类号： C09C1/56 , C08K3/04 , C08K9/02 , C01P2006/12 , C01P2006/19 , Y02T10/862
摘要： A rubber composition containing a cross-linkable rubber component and a carbon black having silica adhered to the surface thereof and a silica surface-treated carbon black suitable for use in tire tread where the surface-treated carbon black has a nitrogen specific surface area (N.sub.2 SA) of 20 to 300 m.sup.2 /g, a ratio IA.sub.o /IA.sub.f of the adsorption amount of iodine (IA.sub.o) and the adsorption amount of iodine after treatment by hydrogen fluoride (IA.sub.f) of at least 0.30 but less than 1.0, and a ratio IA.sub.e /IA.sub.ef of the adsorption amount of iodine after extraction from a rubber compound (IA.sub.e) and the value of the same after treatment by hydrogen fluoride (IA.sub.ef) of at least 0.30 but less than 1.0.
摘要翻译：一种橡胶组合物，其含有可交联的橡胶组分和具有附着在其表面上的二氧化硅的炭黑和适用于表面处理炭黑具有氮比表面积的轮胎胎面的二氧化硅表面处理炭黑（N2SA ）为20〜300m 2 / g，碘吸附量（IAo）的IAo / IAf与氟化氢处理后的碘吸附量（IAf）为IA以上且1.0以下，IAe / IAef，从橡胶化合物（IAe）提取后的碘吸附量和氟化氢处理后的值（IAef）至少为0.30，但小于1.0。

9. 发明授权

US06329460B1 Polysiloxane composition and rubber composition and resin composition 失效
标题翻译：聚硅氧烷组合物和橡胶组合物及树脂组成
公开(公告)号：US06329460B1
公开(公告)日：2001-12-11
申请号：US09547230
申请日：2000-04-11
申请人： Kazunori Ishikawa , Fumito Yatsuyanagi , Hiroyuki Kaido , Naoya Adachi
发明人： Kazunori Ishikawa , Fumito Yatsuyanagi , Hiroyuki Kaido , Naoya Adachi
IPC分类号： C08K55419
CPC分类号： C09D183/12 , C08G77/12 , C08G77/14 , C08G77/18 , C08G77/70 , C08K9/06 , C08K9/08 , C08L83/04 , C08L83/06 , C08L83/12 , C09D183/04 , C09D183/06 , C08L21/00
摘要： A polysiloxane composition comprising (i) an alkoxysilyl group-containing polysiloxane containing at least six siloxane structures having the following formula (I) in a molecule wherein R1 represents a methyl group, ethyl group or phenyl group, and R2 represents a group selected from the group consisting of hydrocarbon group and ether bond-containing hydrocarbon groups having 1 to 6 carbon atoms; and (ii) an alcohol having the formula R4(OR5)p—OH wherein R4 represents a C1-C18 alkyl group, a phenyl group or a benzyl group, R5 represents C1-C6 alkylene group and p is an integer of 0-20.
摘要翻译：一种聚硅氧烷组合物，其包含（i）在分子中含有至少六个具有下式（I）的硅氧烷结构的含烷氧基甲硅烷基的聚硅氧烷，其中R1表示甲基，乙基或苯基，R2表示选自由具有1至6个碳原子的烃基和含醚键的烃基组成; 和（ii）具有式R a的醇代表C 1 -C 18烷基，苯基或苄基，R 5表示C 1 -C 6亚烷基，p是0〜20的整数。

10. 发明授权

US6084015A Rubber composition 失效
标题翻译：橡胶组成
公开(公告)号：US6084015A
公开(公告)日：2000-07-04
申请号：US91739
申请日：1998-06-24
申请人： Keisuke Chino , Fumito Yatsuyanagi , Hiroyuki Kaido , Masahiro Ikawa , Masayoshi Ito
发明人： Keisuke Chino , Fumito Yatsuyanagi , Hiroyuki Kaido , Masahiro Ikawa , Masayoshi Ito
IPC分类号： B60C1/00 , B60H1/00 , C08K5/01 , C08K5/04 , C08K5/32 , C08K5/3415 , C08K5/3435 , C08K5/3442 , C08K5/41 , C08K5/49 , C08K5/33
CPC分类号： C08K5/41 , B60C1/00 , B60C1/0016 , B60H1/00 , C08K5/01 , C08K5/04 , C08K5/32 , C08K5/3415 , C08K5/3435 , C08K5/3442 , C08K5/49
摘要： A rubber composition comprising a diene rubber, a reinforcing agent and a compound containing radicals capable of being stably present at room temperature in the presence of oxygen in the molecule thereof, selected from the group consisting of nitroxide radicals, hydrazyl radicals, allyloxyl radicals, and trityl radicals and the analogues thereof or a compound having at least one substituent group selected from amino groups, isocyanate groups, hydroxyl groups, carboxyl groups, oxirane groups, and thiirane groups.
摘要翻译： PCT No.PCT / JP97 / 03853 Sec。 371日期：1998年6月24日 102（e）1998年6月24日PCT 1997年10月23日PCT公布。第WO98 / 18859号公报日期1998年5月7日一种橡胶组合物，其包含二烯橡胶，增强剂和含有能够在其分子中的氧气存在下在室温下稳定存在的自由基的化合物，其选自氮氧自由基，腙基，烯丙氧基和三苯甲基及其类似物，或具有至少一个选自氨基，异氰酸酯基，羟基，羧基，环氧乙烷基和硫杂环丁烷基的取代基的化合物。

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