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    • 6. 发明授权
    • Photoelectric conversion element and solar cell
    • 光电转换元件和太阳能电池
    • US08242355B2
    • 2012-08-14
    • US12056712
    • 2008-03-27
    • Kazukuni NishimuraAkihiko ItamiFumitaka MochizukiHideya MiwaHidekazu Kawasaki
    • Kazukuni NishimuraAkihiko ItamiFumitaka MochizukiHideya MiwaHidekazu Kawasaki
    • H01L31/00H01L51/00H01L21/00C07C211/00H01M6/30
    • H01L51/0061H01G9/2004H01G9/2013H01G9/2031H01G9/2059H01L51/0053H01L51/0059H01L51/006H01L51/0068H01L51/0071H01L51/0072H01L51/4226H01L2251/306Y02E10/542Y02E10/549
    • A photoelectric conversion element having a pair of electrodes, and a semiconductor layer comprising a semiconductor carrying a dye and an electrolyte layer is disclosed. The dye is represented by Formulas 1 or 2; in Formula 1, Ar1 and Ar2 are each an arylene or heterocyclic group, or a composite group of an arylene group and a heterocyclic group, each of which may have a substituent, Ar3 is an aryl or heterocyclic group or a composite group of an arylene group and a heterocyclic group, each of which may have a substituent, Ar1, Ar2 and Ar3 may form a ring by bonding with each other, X1 and X2 are each a straight chain residue having an acidic group which may have a mono-valent substituent, and one to eight saturated or unsaturated aliphatic hydrocarbon group having 5 to 30 carbon atoms are bonded to Ar1, Ar2 and Ar3; in the formula, Ar11, Ar12, Ar13, Ar14 and Ar15 are each an arylene or heterocyclic group, or a composite group of an arylene group and a heterocyclic group, each of which may have a substituent, Ar11, Ar12, Ar13, Ar14 and Ar15 may form a ring by bonding with together, at least two of X11, X12, X13 and X14 are each an alkyl or alkenyl group having an acidic group which may have a mono-valent substituent and the remainders are each a hydrogen atom, and one to eight saturated or unsaturated aliphatic hydrocarbon group having 5 to 30 carbon atoms are bonded to Ar11, Ar12, Ar13, Ar14 and Ar15.
    • 公开了一种具有一对电极的光电转换元件,以及包含带有染料和电解质层的半导体的半导体层。 染料由式1或2表示; 在式1中,Ar 1和Ar 2各自为亚芳基或杂环基,或者可以具有取代基的亚芳基和杂环基的复合基,Ar 3为芳基或杂环基或亚芳基的复合基 基团和杂环基,其各自可以具有取代基,Ar1,Ar2和Ar3可以通过彼此键合形成环,X1和X2各自是具有可以具有一价取代基的酸性基团的直链残基 并且具有5至30个碳原子的1至8个饱和或不饱和脂族烃基与Ar 1,Ar 2和Ar 3键合; 在式中,Ar 11,Ar 12,Ar 13,Ar 14和Ar 15各自为亚芳基或杂环基,或者可以具有取代基的亚芳基和杂环基的复合基团Ar 11,Ar 12,Ar 13,Ar 14和 Ar15可以通过键合而形成环,X11,X12,X13和X14中的至少两个各自为具有可以具有一价取代基的酸性基团的烷基或烯基,余数各为氢原子, 1〜8个碳原子数为5〜30的饱和或不饱和脂肪族烃基与Ar 11,Ar 12,Ar 13,Ar 14,Ar 15键合。