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    • 1. 发明专利
    • Cellulose acylate film, polarizing plate and liquid crystal display device
    • 纤维素聚酯薄膜,偏光板和液晶显示装置
    • JP2014070159A
    • 2014-04-21
    • JP2012217701
    • 2012-09-28
    • Fujifilm Corp富士フイルム株式会社
    • NAGURA MASATOKUMON YOSHIAKIINOUE RIKIO
    • C08J5/18C08K5/103C08L1/10C08L5/00C08L67/02G02B5/30G02F1/1335
    • PROBLEM TO BE SOLVED: To provide a cellulose acylate film to be used for a polarizing plate protective film having small optical anisotropy and suitable for an IPS type liquid crystal display device, and a polarizing plate and a liquid crystal display device using the cellulose acylate film, and to provide a cellulose acylate film capable of satisfying recent demands for reducing the thickness of a polarizing plate protective film and improving the durability of a polarizing plate comparable to or higher than conventional products, and to provide a polarizing plate and a liquid crystal display device using the cellulose acylate film.SOLUTION: The cellulose acylate film contains at least one in each of the following additives (A) and (B), has an in-plane retardation (Re) of -5 to 5 nm and a retardation (Rth) in a thickness direction of -10 to 5 nm at a wavelength of 590 nm in an environment of 25°C and 60% relative humidity, and has a thickness of 15 to 35 μm. The additives (A) are polyester oligomers having a number average molecular weight of 500 to 3000 and having a repeating unit comprising a dicarboxylic acid and diol, in which when a molar ratio of an aliphatic dicarboxylic acid and a molar ratio of an aromatic dicarboxylic acid in the dicarboxylic acid are denoted by m and n, respectively, m:n ranges from 5:5 to 0:10. The additives (B) are sugar ester compounds having 1 to 12 of at least one of a pyranose structure and a furanose structure, in which hydroxyl groups are wholly or partially alkyl-esterified.
    • 要解决的问题:提供一种用于具有小的光学各向异性并适用于IPS型液晶显示装置的偏振片保护膜的纤维素酰化物膜,以及使用纤维素酰化物膜的偏振片和液晶显示装置 ,并且提供能够满足减少偏振片保护膜的厚度的最近要求并提高与常规产品相当或更高的偏振片的耐久性的纤维素酰化物膜,并且提供偏振片和液晶显示器 使用纤维素酰化物膜的装置。解决方案:纤维素酰化物膜在以下各种添加剂(A)和(B)中含有至少一种,其面内延迟(Re)为-5〜5nm,延迟 Rth)在25℃,60%相对湿度的环境下,波长590nm的厚度方向为-10〜5nm,厚度为15〜35μm。 添加剂(A)是数均分子量为500〜3000的聚酯低聚物,具有包含二羧酸和二醇的重复单元,其中当脂族二羧酸与芳族二羧酸的摩尔比 在二羧酸中分别由m和n表示,m:n的范围为5:5至0:10。 添加剂(B)是具有1至12个至少一个吡喃糖结构和呋喃糖结构的糖酯化合物,其中羟基被全部或部分烷基酯化。
    • 2. 发明专利
    • Polarizing plate, and liquid crystal display device
    • 极化板和液晶显示装置
    • JP2013083912A
    • 2013-05-09
    • JP2012055642
    • 2012-03-13
    • Fujifilm Corp富士フイルム株式会社
    • ONO TAKAHIROINOUE RIKIO
    • G02B5/30G02B5/02G02F1/1335
    • PROBLEM TO BE SOLVED: To improve vertical and horizontal viewing angle CR of a liquid crystal display device.SOLUTION: A polarizing plate includes at least a polarizer and a retardation film. An in-plane retardation Re(550) and a thickness direction retardation Rth(550) in a wavelength of 550nm of the retardation film satisfy the following three formulas (I)-(III), and Re(550) of the retardation film, and a narrow-angle θ between an in-plane slow axis of the retardation film and an absorption axis or transmission axis of the polarizer satisfy the following formula (IV), where (I) 110nm≤Re(550)+Rth(550)≤220nm, (II) 1nm≤Re(550), (III) Rth>0.5×Re and (IV) 0.01≤Re(550)×sinθ≤0.7. There is also provided a liquid crystal display device having the polarizing plate.
    • 要解决的问题:提高液晶显示装置的垂直和水平视角CR。 解决方案:偏振片至少包括偏振片和延迟膜。 延迟膜的550nm的面内延迟Re(550)和厚度方向延迟Rth(550)满足延迟膜的以下三个式(I) - (III)和Re(550) 并且相位差膜的平面内慢轴与偏振片的吸收轴或透射轴之间的窄角度θ满足下式(IV),其中(I)110nm≤Re(550)+ Rth(550) ≤220nm,(II)1nm≤Re(550),(III)Rth> 0.5×Re和(IV)0.01≤Re(550)×sinθ≤0.7。 还提供了一种具有偏光板的液晶显示装置。 版权所有(C)2013,JPO&INPIT
    • 5. 发明专利
    • Antireflection film
    • 抗反射膜
    • JP2008310119A
    • 2008-12-25
    • JP2007158559
    • 2007-06-15
    • Fujifilm Corp富士フイルム株式会社
    • INOUE RIKIO
    • G02B1/11B32B7/02G02B1/10G02F1/1335G09F9/00
    • PROBLEM TO BE SOLVED: To provide an antireflection film with: high manufacturing efficiency; high uniformity; excellent adhesion; and extremely low reflection, wherein the antireflection film is constituted of three-layer thin film and a high refractive index layer and a middle refractive index layer can be formed by one application process. SOLUTION: The middle refractive index layer, the high refractive index layer and a low refractive index layer, each of which has film thickness of ≤150 nm, are laminated in this order on a film base material or on the film base material having a hard coat layer to form the antireflection film. The high refractive index layer contains first metal oxide particulates having surface ornamentation by a specific polymer and mean grain size of ≤50 nm. The middle refractive index layer contains second metal oxide particulates which are different from the first metal oxide particulates and have mean grain size of ≤50 nm. Further, the middle refractive index layer and the high refractive index layer are two layers separated from one application film or the middle refractive index layer and the high refractive index layer are two layers obtained by simultaneous multilayer application. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有高制造效率的抗反射膜; 高均匀性 优良的附着力; 并且极低的反射率,其中抗反射膜由三层薄膜和高折射率层和中折射率层构成可以通过一次涂布工艺形成。 解决方案:将膜厚度≤150nm的中间折射率层,高折射率层和低折射率层依次层叠在膜基材上或膜基材上 具有硬涂层以形成抗反射膜。 高折射率层含有具有由特定聚合物表面装饰的第一金属氧化物微粒,平均粒径≤50nm。 中间折射率层含有与第一金属氧化物微粒不同的第二金属氧化物微粒,平均粒径≤50nm。 此外,中间折射率层和高折射率层是从一个施加膜或中间折射率层分离的两层,并且高折射率层是通过同时多层涂布获得的两层。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Antireflection film
    • 抗反射膜
    • JP2008233656A
    • 2008-10-02
    • JP2007075056
    • 2007-03-22
    • Fujifilm Corp富士フイルム株式会社
    • INOUE RIKIO
    • G02B1/11
    • PROBLEM TO BE SOLVED: To provide an antireflection film with high chemical resistance, in which crosslinking of an interface adjacent to a high refractive index layer (especially, crosslinking of an interface between the adjacent low-refractive index layer and the high refractive index layer) is enhanced, physical strength such as contactness, abrasion resistance is raised and further more, the physical strength is not impaired, even when saponification processing is performed. SOLUTION: The antireflection film is used, in which there is the high refractive index layer, containing metal alkoxide having an ethylenically unsaturated group on a transparent support, the content of Ti and/or Zr per gram for solid content of the high refractive index layer is at least 2.0 millimoles; furthermore, the low refractive index layer containing fluorine-containing compound, having silica fine particles and the ethylenically unsaturated group as major components, is formed on the high refractive index layer and which is cured through heat and UV irradiation. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供具有高耐化学性的抗反射膜,其中与高折射率层相邻的界面的交联(特别是相邻的低折射率层与高折射率层之间的界面的交联) 指数层)增强,接触性,耐磨性等物理强度进一步提高,即使进行皂化处理,物理强度也不受损害。 解决方案:使用在透明载体上含有具有烯属不饱和基团的金属醇盐的高折射率层的抗反射膜,其固体含量高的Ti和/或Zr的含量 折射率层至少为2.0毫摩尔; 此外,在高折射率层上形成含有二氧化硅微粒和烯键式不饱和基团作为主要成分的含氟化合物的低折射率层,并通过热和紫外线照射而固化。 版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Thermosensitive transfer image receiving sheet
    • 感温传输图像接收片
    • JP2011073204A
    • 2011-04-14
    • JP2009225401
    • 2009-09-29
    • Fujifilm Corp富士フイルム株式会社
    • MURO SUKETSUGUINOUE RIKIOARAI TAKUYA
    • B41M5/382B41M5/50B41M5/52
    • PROBLEM TO BE SOLVED: To provide a thermosensitive transfer image receiving sheet which is suitable for high-speed printing, does not generate reduced density even after time passes under a high humidity environment, and hardly generates peeling lines of high-density imaging parts. SOLUTION: The thermosensitive transfer image receiving sheet having a receiving layer and at least one heat insulating layer on a supporting body is characterized in that the receiving layer contains at least (1) vinyl chloride based copolymer latex, (2) polyether modified silicone, and (3) dicarboxylic acid component having a naphthalene skeleton, dicarboxylic acid component having a sulfo group, and divalent alcohol component as constituting components, 60 mol% or more of the divalent alcohol component contains at least one kind of component of polyester which is divalent alcohol component of alkylene oxide adduct of a bisphenol. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供适合于高速印刷的热敏转印图像接收片材,即使在高湿度环境下经过一段时间后也不会产生降低的密度,并且几乎不产生高密度成像的剥离线 部分。 解决方案:具有接收层和支撑体上的至少一个隔热层的热敏转印图像接收片的特征在于接收层至少含有(1)氯乙烯基共聚物胶乳,(2)聚醚改性的 硅氧烷和(3)具有萘骨架的二羧酸成分,具有磺基的二羧酸成分和作为构成成分的二价醇成分,二元醇成分的60摩尔%以上含有至少一种聚酯成分, 是双酚的环氧烷加成物的二价醇成分。 版权所有(C)2011,JPO&INPIT