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1. 发明专利

JP2009244608A Polymerizable composition, light-shielding color-filter and solid-state imaging element 有权
标题翻译：可聚合组合物，光屏蔽彩色滤光片和固态成像元件
公开(公告)号：JP2009244608A
公开(公告)日：2009-10-22
申请号：JP2008091229
申请日：2008-03-31
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： TSUCHIMURA TOMOTAKA , MARUYAMA YOICHI , ENAGA HIROYUKI , FUJIMORI TORU , SHIMADA KAZUTO , KANEKO YUJI
IPC分类号： G03F7/004 , G02B5/20 , G03F7/031
摘要： PROBLEM TO BE SOLVED: To provide a polymerizable composition for a solid-state imaging element capable of forming a high-definition light-shielding film pattern in which the deterioration of light-shielding ability on the peripheral part is suppressed, curing sensitivity is high and a residue on an unexposure part is suppressed. SOLUTION: The polymerizable composition comprises a polymerization inhibitor (A), a polymerizable compound (B), a photopolymerization initiator (C) and titanium-black dispersed material (D). COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：提供一种能够形成其中抑制周边部分的遮光能力劣化的高清晰度遮光膜图案的固体摄像元件的可聚合组合物，固化灵敏度高且残留在未曝光部分被抑制。聚合性组合物包含聚合抑制剂（A），聚合性化合物（B），光聚合引发剂（C）和钛黑分散材料（D）。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2010230841A Photosensitive resin composition, method for manufacturing color filter, and color filter 审中-公开
标题翻译：感光树脂组合物，制造彩色滤光片的方法和彩色滤光片
公开(公告)号：JP2010230841A
公开(公告)日：2010-10-14
申请号：JP2009076640
申请日：2009-03-26
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： ENAGA HIROYUKI
IPC分类号： G03F7/004 , G02B5/20 , G02F1/1335 , G03F7/027 , G03F7/033
摘要： PROBLEM TO BE SOLVED: To provide a photosensitive resin composition for forming a rectangular pixel having a small radius at an edge or a corner of a filter face or the cross section, and for forming a pixel pattern with suppressed variations of pattern features and less development residue. SOLUTION: The photosensitive resin composition contains an alkali-soluble resin, a polymerizable monomer, a photopolymerization initiator, a UV-ray absorbent, a polymerization inhibitor by 0.1 to 5.0 mass% with respect to the whole solid content, and an organic solvent. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决的问题：提供一种用于形成具有小的半径的矩形像素的感光性树脂组合物，所述矩形像素在滤光器面的边缘或角部或截面上形成具有抑制的图案特征变化的像素图案少发育残留。解决方案：感光性树脂组合物含有碱溶性树脂，聚合性单体，光聚合引发剂，紫外线吸收剂，聚合抑制剂相对于固体成分全部为0.1〜5.0质量％，有机物溶剂。版权所有（C）2011，JPO＆INPIT

3. 发明专利

JP2009265642A Photosensitive transparent resin composition, process for manufacture of color filter, and color filter 有权
标题翻译：感光透明树脂组合物，彩色滤光片制造工艺和彩色滤光片
公开(公告)号：JP2009265642A
公开(公告)日：2009-11-12
申请号：JP2009079933
申请日：2009-03-27
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： ENAGA HIROYUKI
IPC分类号： G03F7/004 , C07C225/14 , C07C233/36 , C07C255/30 , C07C317/44 , G02B5/20 , G03F7/031
CPC分类号： G02B5/201 , G03F7/0007 , G03F7/031
摘要： PROBLEM TO BE SOLVED: To provide a photosensitive transparent resin composition which is reduced in the dependence on exposure illuminance and which can stably form patterns superior in resolution with high retention of film thickness and nearly without scum; color filters which are reduced in the transmittance drop in the visible light region and enable fine and high-quality display images; and a process for manufacture thereof.
SOLUTION: The photosensitive transparent resin composition includes a polymerizable monomer, an alkali-soluble resin, a photopolymerization initiator, and a compound represented by formula (I): (I) wherein R
1 and R
2 are each independently hydrogen, 1-20C alkyl or 6-20C aryl; R
1 and R
2 may be the same or different from each other, but both must not simultaneously be hydrogen; or R
1 and R
2 together with the nitrogen atom may form a cycloamino group; and R
3 and R
4 are each independently an electron-attracting group, or R
3 and R
4 may be bonded to each other to form a cyclic electron-attracting group. The color filters using the composition and the process for production thereof are also provided.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种根据曝光照度而降低的光敏透明树脂组合物，并且可以稳定地形成分辨率优异的图案，同时具有高的保持膜厚度且几乎不含浮渣; 滤色片，其在可见光区域的透射率降低，并且能够进行精细和高质量的显示图像; 及其制造方法。光敏性透明树脂组合物包括可聚合单体，碱溶性树脂，光聚合引发剂和由式（I）表示的化合物：（I）其中R 1 和R 2各自独立地为氢，1-20C烷基或6-20C芳基; R 1 和R 2可以彼此相同或不同，但两者不能同时为氢; 或R 1 和R 2 与氮原子一起可以形成环氨基; 和R 3 和R 4 各自独立地是吸电子基团，或者R 3 和R 4 彼此键合以形成环状吸电子基团。还提供了使用组合物的滤色器及其生产方法。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2009265527A Polymerizable composition, light-shielding color filter for solid-state image sensor using the same, and solid-state image sensor 有权
标题翻译：聚合物组合物，使用其的固态图像传感器的光屏蔽彩色滤光片和固态图像传感器
公开(公告)号：JP2009265527A
公开(公告)日：2009-11-12
申请号：JP2008117690
申请日：2008-04-28
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： TSUCHIMURA TOMOTAKA , MARUYAMA YOICHI , SHIMADA KAZUTO , FUJIMORI TORU , KANEKO YUJI , ENAGA HIROYUKI
IPC分类号： G03F7/004 , G02B5/20 , G03F7/027 , G03F7/031
摘要： PROBLEM TO BE SOLVED: To provide a polymerizable composition having high curing sensitivity, with which a high-precision light-shielding film pattern can be formed while preventing the decrease in the light-shielding performance in a peripheral portion and the generation of residual matter in an unexposed portion, and moreover, the polymerizable composition being useful for forming a light-shielding film for a solid-state image sensor. SOLUTION: The polymerizable composition contains (A) a polyfunctional monomer having an acid group in the molecule and/or a polymerizable compound having a different structure from that of the polyfunctional monomer having an acid group in the molecule, (B) a photopolymerization initiator, and (C) a titanium black dispersion. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：为了提供具有高固化灵敏度的可聚合组合物，可以在防止周边部分的遮光性能降低的同时形成高精度遮光膜图案，并产生未曝光部的残留物，此外，聚合性组合物可用于形成固体摄像元件的遮光膜。解决方案：聚合性组合物含有（A）分子中具有酸基的多官能单体和/或与分子中具有酸基的多官能单体的结构不同的聚合性化合物，（B）a 光聚合引发剂，（C）钛黑分散体。版权所有（C）2010，JPO＆INPIT

5. 发明专利

JP2009244747A Polymerizable composition, light-blocking color filter for solid-state imaging device, and solid-state imaging device 有权
标题翻译：可聚合组合物，用于固态成像装置的遮光颜色过滤器和固体状态成像装置
公开(公告)号：JP2009244747A
公开(公告)日：2009-10-22
申请号：JP2008093394
申请日：2008-03-31
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： SHIMADA KAZUTO , TSUCHIMURA TOMOTAKA , MARUYAMA YOICHI , FUJIMORI TORU , KANEKO YUJI , ENAGA HIROYUKI
IPC分类号： G02B5/20
CPC分类号： G02F1/133512 , G03F7/0007 , G03F7/032 , G03F7/035 , G03F7/0388 , G03F7/105
摘要： PROBLEM TO BE SOLVED: To provide a polymerizable composition which has high sensitivity and produces less residuals when being hardened even in the case that light-blocking properties for a wavelength region from ultraviolet light to infrared light are required, and a light-blocking color filter for solid-state imaging devices using the same. SOLUTION: The polymerizable composition contains at least (A) a polymerizable compound, (B) a binder polymer, (C) a photopolymerization initiator, and (D) a titanium black dispersion wherein a mass ratio of a content of the (A) polymerizable compound to a content of the (B) binder polymer is larger than one. The light-blocking color filter for solid-state imaging devices has a color region comprising the polymerizable composition on a support member. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种聚合性组合物，即使在需要从紫外线到红外线的波长区域的遮光性的情况下，也能够在硬化的同时具有高灵敏度，残留少的聚合性组合物，用于使用其的固态成像装置的阻挡滤色器。解决方案：聚合性组合物至少含有（A）可聚合化合物，（B）粘合剂聚合物，（C）光聚合引发剂和（D）钛黑分散体，其中（ A）可聚合化合物与（B）粘合剂聚合物的含量相比大于1。用于固态成像装置的遮光滤色器具有在支撑构件上包含可聚合组合物的颜色区域。版权所有（C）2010，JPO＆INPIT

6. 发明专利

JP2009244401A Black photosensitive resin composition for solid state image sensor and method of forming image 审中-公开
标题翻译：用于固态图像传感器的黑色光敏树脂组合物和形成图像的方法
公开(公告)号：JP2009244401A
公开(公告)日：2009-10-22
申请号：JP2008088546
申请日：2008-03-28
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： ENAGA HIROYUKI , MARUYAMA YOICHI , SHIMADA KAZUTO , TSUCHIMURA TOMOTAKA , MAKINO MASAOMI
IPC分类号： G02B5/20 , C08F2/50 , G03F7/004 , G03F7/027 , G03F7/031 , G03F7/32
摘要： PROBLEM TO BE SOLVED: To provide a black photosensitive resin composition for a solid state image sensor in which a small amount of a residue is generated, adhesion to a substrate after being exposed is excellent and a black pattern having an excellent rectangular cross section profile is obtained. SOLUTION: The black photosensitive resin composition for the solid state image sensor contains at least: a color material for black; a photopolymerization compound; and a photopolymerization initiator wherein the solution rate of a non-exposed region when being developed at 23 °C by using a developer having pH (23 °C) of 8 to 12 containing 0.1 mass% of a tetramethylammonium hydroxide, and a nonionic surfactant is ≥0.005 μm/sec and ≤0.060 μm/sec. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：为了提供一种固体摄像传感器的黑色感光性树脂组合物，其中产生少量残留物，曝光后对基材的粘附性优异，并且具有优异矩形交叉的黑色图案截面轮廓得到。解决方案：用于固态图像传感器的黑色感光性树脂组合物至少包含：黑色的着色材料; 光聚合化合物; 和光聚合引发剂，其中通过使用含有0.1质量％的四甲基氢氧化铵的pH（23℃）为8〜12的显影剂和非离子表面活性剂在23℃下显影时的非曝光区域的溶解速度为 ≥0.005μm/ sec，≤0.060μm/ sec。版权所有（C）2010，JPO＆INPIT

7. 发明专利

JP2013122602A Black curable composition, light-shielding color filter for solid-state imaging element and method for manufacturing the same, and solid-state imaging element 有权
标题翻译：黑色可固化组合物，用于固态成像元件的光屏蔽彩色滤光片及其制造方法和固态成像元件
公开(公告)号：JP2013122602A
公开(公告)日：2013-06-20
申请号：JP2013003571
申请日：2013-01-11
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： KANEKO YUJI , MARUYAMA YOICHI , FUJIMORI TORU , ENAGA HIROYUKI , SHIMADA KAZUTO , TSUCHIMURA TOMOTAKA
IPC分类号： G03F7/033 , G02B5/20 , G03F7/004 , G03F7/031 , H04N9/07
摘要： PROBLEM TO BE SOLVED: To provide a black curable composition capable of being cured with high sensitivity even by small amount of exposure and forming a light-shielding color filter for a solid-state imaging element which reduces the residue in a developing part and improves a pattern shape, and further to provide a light-shielding color filter for a solid-state imaging element having excellent light-shielding properties in a wide wavelength region and a method for manufacturing the same and a solid-state imaging element.SOLUTION: There is provided a black curable composition which contains (A) titanium black, (B) an alkali-soluble resin having a weight average molecular weight of 7,000 or more and 18,000 or less, a distribution of molecular weight (weight-average molecular weight/average numerical molecular weight) of 1.8 or more and 2.2 or less and an acid value of 70 mgKOH/g to 130 mgKOH/g, (C) a solvent, (D) a photopolymerization initiator and (E) a compound having an ethylenically unsaturated double bond. The black curable composition is suitable for the manufacture of a light-shielding color filter for a solid-state imaging element and a solid-state imaging element.
摘要翻译：要解决的问题：提供一种即使通过少量曝光也能够以高灵敏度固化的黑色可固化组合物，并且形成用于固态成像元件的遮光滤色器，其减少显影部分中的残留物并提高了图案形状，并且还提供了在宽波长区域中具有优异的遮光性的固态成像元件的遮光滤色器及其制造方法和固态成像元件。解决方案：提供一种黑色可固化组合物，其含有（A）钛黑，（B）重均分子量为7,000以上且18,000以下的碱溶性树脂，分子量（重量）平均分子量/平均数均分子量）为1.8以上且2.2以下，酸值为70mgKOH / g〜130mgKOH / g，（C）溶剂，（D）光聚合引发剂和（E）具有烯属不饱和双键的化合物。黑色固化性组合物适用于固体摄像元件和固体摄像元件的遮光性滤色片的制造。版权所有（C）2013，JPO＆INPIT

8. 发明专利

JP2010077273A Composition for use in formation of transparent film, transparent film, transparent film substrate for use in color filter, and solid-state image pick-up element 有权
标题翻译：用于形成透明膜，透明膜，透明膜用于彩色滤光片的组合物和固体状态图像拾取元件
公开(公告)号：JP2010077273A
公开(公告)日：2010-04-08
申请号：JP2008246970
申请日：2008-09-25
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： ENAGA HIROYUKI
IPC分类号： C08L101/00 , C08F2/44 , C08F265/06 , C08K5/16 , C09K3/00 , G02B5/20
摘要： PROBLEM TO BE SOLVED: To provide: a composition for use in the formation of a transparent film which contains a compound expressed by general formula (I) and as is free from foreign matters after the film formation and is capable of forming a thin film having a pattern with a rectangular cross section; a transparent film; a transparent film substrate for use in color filters; and a solid-state image pick-up element comprising a pattern with a highly precise cross section. SOLUTION: This composition for use in the formation of a transparent film includes a compound expressed by general formula (I) (wherein, R 1 and R 2 are each independently a hydrogen atom, a 1-20C alkyl or 6-20C aryl group, R 1 and R 2 are the same or different, but are not simultaneously hydrogen atoms, and R 1 and R 2 may form a cyclic amino group with a nitrogen atom; R 3 and R 4 are each independently an electron-withdrawing group; and at least one of R 1 , R 2 , R 3 and R 4 , via a linking group, may link to a polymer main chain). COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供：用于形成透明膜的组合物，其含有由通式（I）表示的化合物，并且在成膜后不含异物，并且能够形成具有矩形截面图案的薄膜; 透明胶片用于滤色器的透明膜基板; 以及包括具有高精度横截面的图案的固态图像拾取元件。解决方案：用于形成透明膜的该组合物包括由通式（I）表示的化合物（其中，R 1和R 2各自独立地表示）独立地为氢原子，1-20C烷基或6-20C芳基，R 1 SP 2和R 2 SP 2相同或不同，但不同时为氢原子，并且 R＆lt; SP＆gt; 1＆lt; SP＆gt;和R＆lt; SP＆gt; 2＆lt; SP＆gt;可以与氮原子形成环状氨基; R 3和R 4都是各自独立地是吸电子基团;并且R 1，R 2，R 3，R 3和R 4中的至少一个，通过连接基团可以连接到聚合物主链上）。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2010006932A Dispersion liquid, black curable composition, manufacturing method, manufacturing method of light shielding film or reflection-preventing film for solid imaging element, and solid imaging element 有权
标题翻译：分散液，黑色可固化组合物，制造方法，固体成像元件和固体成像元件的遮光膜或反射防止膜的制造方法
公开(公告)号：JP2010006932A
公开(公告)日：2010-01-14
申请号：JP2008167064
申请日：2008-06-26
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： KANEKO YUJI , MARUYAMA YOICHI , FUJIMORI TORU , ENAGA HIROYUKI , SHIMADA KAZUTO , TSUCHIMURA TOMOTAKA
IPC分类号： C08L101/02 , C08F2/44 , C08F8/00 , C08F271/00 , C08F283/00 , C08G73/02 , C08G81/00 , C08K3/22 , G02B5/20 , G03F7/004 , G03F7/031
摘要： PROBLEM TO BE SOLVED: To provide a dispersion liquid containing a black coloring material having satisfactory dispersion properties and dispersion stability, to provide a black curable composition which has satisfactory stability with passage of time and capable of forming a light shielding film wherein reduction of light shielding ability is suppressed and generation of a residue is eliminated at a peripheral part thereof, to provide the light shielding film for a solid imaging element and method for manufacturing the same and to provide the solid imaging element. SOLUTION: The dispersion liquid includes (A) a resin having (i) a main chain part having a nitrogen atom, (ii) a group [X] having a functional group having pKa of 14 or less and bonded to the nitrogen atom of the main chain part, and (iii) an oligomer chain or a polymer chain [Y] having a number average molecular weight of 500 to 1,000,000 as a side chain, (B) the black coloring material and (C) a solvent. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决问题：为了提供含有具有良好的分散性和分散稳定性的黑色着色材料的分散液，以提供一种黑色可固化组合物，其具有令人满意的稳定性随时间流逝并且能够形成减光膜的光屏蔽能力被抑制，并且在其周边部分消除残留物的产生，以提供用于固体成像元件的遮光膜及其制造方法和提供固体成像元件。解决方案：分散液包括（A）具有（i）具有氮原子的主链部分的树脂，（ii）具有pKa为14或更小的官能团的基团[X]并键合到氮主链部分的原子，（iii）数均分子量为500〜1,000,000的低聚物链或聚合物链[Y]作为侧链，（B）黑色着色材料和（C）溶剂。版权所有（C）2010，JPO＆INPIT

10. 发明专利

JP2009244736A Photosensitive resin composition, light-shielding color filter and method of producing the same, and solid-state imaging device 有权
标题翻译：光敏性树脂组合物，遮光颜料过滤器及其制造方法以及固体成像装置
公开(公告)号：JP2009244736A
公开(公告)日：2009-10-22
申请号：JP2008093231
申请日：2008-03-31
申请人： Fujifilm Corp , 富士フイルム株式会社
发明人： MARUYAMA YOICHI , ENAGA HIROYUKI , FUJIMORI TORU , SHIMADA KAZUTO , TSUCHIMURA TOMOTAKA , KANEKO YUJI
IPC分类号： G03F7/004 , G02B5/20 , G03F7/031
摘要： PROBLEM TO BE SOLVED: To provide a photosensitive resin composition that provides a light-shielding color filter having excellent uniformity of the coating film thickness on a wafer, to provide a light-shielding color filter formed from the above photosensitive resin composition and a method of producing the same, and to provide a solid-state imaging device. SOLUTION: The resin composition contains at least (A) titanium black, (B) a polymerizable compound, (C) a resin, (D) a photopolymerization initiator, (E) a silicone-based surfactant and/or a fluorine-based surfactant and (F) an organic solvent. The light-shielding color filter has a pattern formed by using the above photosensitive resin composition. The solid-state imaging device includes the above light-shielding color filter. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决问题的方案：提供一种提供在晶片上具有优异的涂膜均匀性的遮光滤色器的光敏树脂组合物，以提供由上述感光性树脂组合物形成的遮光滤色器，以及其制造方法，提供固体摄像装置。解决方案：树脂组合物至少包含（A）钛黑，（B）可聚合化合物，（C）树脂，（D）光聚合引发剂，（E）硅氧烷基表面活性剂和/或氟（F）有机溶剂。遮光滤色器具有使用上述感光性树脂组合物形成的图案。固态成像装置包括上述遮光滤色器。版权所有（C）2010，JPO＆INPIT

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