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    • 7. 发明公开
    • Hydantoin-substituted acylacetanilide compounds and method of manufacturing the same
    • 乙内酰脲替代物Azylacetanilid Verbindungen und Verfahren zu deren Herstellung
    • EP0705822A1
    • 1996-04-10
    • EP95115552.2
    • 1995-10-02
    • Fuji Photo Film Co., Ltd.
    • Yamakawa, KatsuyoshiSato, TadahisaHanaki, Koichi
    • C07D233/78C07D233/80
    • C07D233/66C07D233/78C07D233/86G03C7/30535
    • There is disclosed a hydantoin-substituted acylacetanilide compound of formula (I):
      formula (I)

         wherein R¹ represents a tert-butyl group or a p-alkoxyphenyl group, R² represents a chlorine atom or an alkoxy group, R³ represents a hydrogen atom, an alkyl group, a benzyl group, an alkylsulfonyl group, or an arylsulfonyl group, R⁴ represents a hydrogen atom or an alkyl group, and R⁵ represents an alkyl group or an alkoxy group. There is also disclosed a method of manufacturing the compound of formula (I), which method comprises reacting a hydantoin-substituted acetyl compound of formula (III) with a urethane compound of formula (IV) in the presence of a base: formula (III)

      formula (IV)

      wherein R¹, R², R³, R⁴, and R⁵ each have the same meanings as those of formula (I). The compound of formula (I) is useful as an intermediate of a photographic yellow coupler.
    • 公开了式(I)的乙内酰脲取代的酰基乙酰苯胺化合物:式(I)其中R 1表示叔丁基或对 - 烷氧基苯基,R 2表示氯原子或 烷氧基,R 3表示氢原子,烷基,苄基,烷基磺酰基或芳基磺酰基,R 4表示氢原子或烷基,R 5表示烷基 基团或烷氧基。 还公开了制备式(I)化合物的方法,该方法包括使式(III)的乙内酰脲取代的乙酰基化合物与式(IV)的氨基甲酸酯化合物在碱的存在下反应:式(III )其中R 1,R 2,R 3,R 4和R 5各自具有与式(I)相同的含义。 式(I)化合物可用作照相黄色偶联剂的中间体。
    • 10. 发明公开
    • Process for preparing 1,1-disubstituted-1h-benzo[e]indole derivatives and hydroxyl-substituted 1,1-disubstituted-1H-benzo[e]indole derivatives
    • 一种的制备方法,1,1-二取代的1H苯并[e]吲哚衍生物和羟基取代的1,1-二取代 - 1H苯并[e]吲哚衍生物
    • EP0790238A2
    • 1997-08-20
    • EP97102233.0
    • 1997-02-12
    • FUJI PHOTO FILM CO., LTD.
    • Yamakawa, KatsuyoshiSato, Tadahisa
    • C07D209/60
    • C07D401/04C07D209/60C07D209/96C07D409/04
    • A process for preparing a 1,1-disubstituted-1H-benzo[e]indole compound represented by formula (III) comprising reacting a 2-naphthol compound represented by formula (I), a carbonyl compound represented by formula (II), and a hydrazine compound in the presence of an acid catalyst,
      wherein R 1 represents a group capable of substituting a hydrogen atom on the naphthalene ring; m represents 0 or an integer of 1 to 6; R 2 and R 3 each represents an alkyl group, an aryl group or a heterocyclic group; and R 4 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; and a hydroxyl-substituted 1,1-disubstituted -1H-benzo[e]indole compound represented by formula (IV):
      wherein R 2 and R 3 each represents an alkyl group, an aryl group or a heterocyclic group; and R 4 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group.
    • 一种制备由式表示的1,1-二取代的1H-benzoÄeÜindole化合物的方法(III)包括使由式(I)表示的2-萘酚化合物,由式(II)表示的羰基化合物,以及在肼化合物 酸催化剂的存在下, worin - [R <1> darstellt能取代萘环上的氢原子的基团; 米darstellt 0或1至6的整数; [R <2>和R <3>烷基与芳基团或杂环基团的每个darstellt; 且R <4>表示一个氢原子,在烷基,芳基或杂环基团; 和由式表示的羟基取代的1,1-二取代-1H-benzoÄeÜindole化合物(IV):其中,R <2>和R <3>烷基与芳基团或杂环基团的每个darstellt; 且R <4> darstellt氢原子的烷基基团的芳基或杂环基。