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1. 发明申请

US20060264681A1 Preparation of highly pure methyl tert-butyl ether 有权
标题翻译：制备高纯度甲基叔丁基醚
公开(公告)号：US20060264681A1
公开(公告)日：2006-11-23
申请号：US10519397
申请日：2003-06-14
申请人： Fritz Obenaus , Wilhelm Droste , Bernhard Scholz , Franz Nierlich , Rainer Malzkorn , Udo Peters , Jochen Praefke , Richard Filipiak , Joachim Neumeister
发明人： Fritz Obenaus , Wilhelm Droste , Bernhard Scholz , Franz Nierlich , Rainer Malzkorn , Udo Peters , Jochen Praefke , Richard Filipiak , Joachim Neumeister
IPC分类号： C07C41/58
CPC分类号： C07C41/42 , C07C43/046
摘要： The invention relates to a process for preparing methyl tert-butyl ether (MTBE) in qualities which are suitable for organic syntheses and for use as a specialty solvent from MTBE in fuel quality.
摘要翻译：本发明涉及一种制备甲基叔丁基醚（MTBE）的方法，该方法适用于有机合成，并用作燃料质量中MTBE的特种溶剂。

2. 发明授权

US07304188B2 Preparation of highly pure methyl tert-butyl ether 有权
标题翻译：制备高纯度甲基叔丁基醚
公开(公告)号：US07304188B2
公开(公告)日：2007-12-04
申请号：US10519397
申请日：2003-06-14
申请人： Fritz Obenaus , Wilhelm Droste , Bernhard Scholz , Franz Nierlich , Rainer Malzkorn , Udo Peters , Jochen Praefke , Richard Filipiak , Joachim Neumeister
发明人： Fritz Obenaus , Wilhelm Droste , Bernhard Scholz , Franz Nierlich , Rainer Malzkorn , Udo Peters , Jochen Praefke , Richard Filipiak , Joachim Neumeister
IPC分类号： C07C41/58
CPC分类号： C07C41/42 , C07C43/046
摘要： The invention relates to a process for preparing methyl tert-butyl ether (MTBE) in qualities which are suitable for organic syntheses and for use as a specialty solvent from MTBE in fuel quality.
摘要翻译：本发明涉及一种制备甲基叔丁基醚（MTBE）的方法，该方法适用于有机合成，并用作燃料质量中MTBE的特种溶剂。

3. 发明授权

US5177282A Oligomerization of olefins 失效
标题翻译：油脂的低聚
公开(公告)号：US5177282A
公开(公告)日：1993-01-05
申请号：US503951
申请日：1990-04-04
申请人： Franz Nierlich , Joachim Neumeister , Thomas Wildt , Wilhelm Droste , Fritz Obenaus
发明人： Franz Nierlich , Joachim Neumeister , Thomas Wildt , Wilhelm Droste , Fritz Obenaus
IPC分类号： B01J20/18 , B01J21/16 , B01J23/755 , B01J29/06 , C07B61/00 , C07C2/12 , C07C2/24 , C07C7/13 , C07C7/163 , C07C11/02
CPC分类号： C07C11/02 , C07C2/12 , C07C7/13 , C07C2529/04
摘要： Olefins are oligomerized by passing a hydrocarbon feedstock mixture containing olefins of from 2 to 8 carbon atoms over a molecular sieve having a pore diameter of from greater than 4 angstroms to 15 angstroms, and then oligomerizing said olefins by passing the hydrocarbon feedstock over a nickel-containing catalyst at a temperature of from 0.degree.to 200.degree. C. and at a pressure of from 1 to 70 bar absolute.
摘要翻译：烯烃通过使含有2至8个碳原子的烯烃的烃原料混合物通过孔径大于4埃的分子筛至15埃，然后使烃原料通过镍 - 在0℃至200℃的温度和1至70巴绝对压力下进行。

4. 发明授权

US5146039A Process for low level desulfurization of hydrocarbons 失效
标题翻译：烃类低水平脱硫工艺
公开(公告)号：US5146039A
公开(公告)日：1992-09-08
申请号：US608623
申请日：1990-11-06
申请人： Thomas Wildt , Franz Nierlich , Wilhelm Droste , Joachim Neumeister , Bernhard Scholz
发明人： Thomas Wildt , Franz Nierlich , Wilhelm Droste , Joachim Neumeister , Bernhard Scholz
IPC分类号： C10G25/03 , C07C7/13 , C10G25/05
CPC分类号： C10G25/05 , C07C7/13
摘要： A hydrocarbon containing sulfides, disulfides, trisulfides, tetrasulfides or mixtures can be desulfurized by contacting the hydrocarbon with a zeolite containing copper, silver, zinc or mixtures thereof.
摘要翻译：含硫化物，二硫化物，三硫化物，四硫化物或混合物的烃可以通过使烃与含有铜，银，锌或其混合物的沸石接触来脱硫。

5. 发明授权

US4219678A Process for preparing pure methyl tert.-butyl ether 失效
标题翻译：纯甲基叔丁基醚的制备方法
公开(公告)号：US4219678A
公开(公告)日：1980-08-26
申请号：US974550
申请日：1978-12-29
申请人： Fritz Obenaus , Wilhelm Droste , Wolf Streubel , Michael Zolffel , Wolfgang Muller
发明人： Fritz Obenaus , Wilhelm Droste , Wolf Streubel , Michael Zolffel , Wolfgang Muller
IPC分类号： C07C43/04 , B01J31/00 , C07B61/00 , C07C41/00 , C07C41/01 , C07C41/05 , C07C41/06 , C07C41/34 , C07C67/00 , C07C41/12
CPC分类号： C07C41/06 , C07C41/42
摘要： Process for the preparation of pure methyl tert.-butyl ether. Isobutene or isobutene-containing hydrocarbon mixtures are reacted with methanol in a molar ratio of 1:1 to 1:2 in the liquid phase at temperatures of between 30.degree. and 100.degree. C. on sulfonated, strongly acidic, macroporous organic ion exchange resins. After separation of the unreacted hydrocarbons, the reaction mixture is distilled under pressure; the methanol-containing distillate formed during the distillation is recycled into the zone of the reaction between methanol and isobutene; and pure methyl tert.-butyl ether is withdrawn from the sump of the distillation column.
摘要翻译：纯甲基叔丁基醚的制备方法。在磺化，强酸性，大孔有机离子交换树脂的温度为30-100℃的液相中，使含异丁烯或异丁烯的烃混合物与摩尔比为1:1至1:2的甲醇反应。分离未反应的烃后，将反应混合物在压力下蒸馏; 在蒸馏期间形成的含甲醇的馏出物循环到甲醇和异丁烯之间的反应区域中; 从蒸馏塔的贮槽中取出纯甲基叔丁基醚。

6. 发明授权

US4000199A Process for the production of acetone 失效
标题翻译：生产乙腈的方法
公开(公告)号：US4000199A
公开(公告)日：1976-12-28
申请号：US562360
申请日：1975-03-26
申请人： Fritz Obenaus , Wilhelm Droste
发明人： Fritz Obenaus , Wilhelm Droste
IPC分类号： C07C49/08 , B01J23/00 , C07B61/00 , C07C45/00 , C07C45/33 , C07C67/00
CPC分类号： C07C45/33
摘要： Acetone is produced by the catalytic, oxidative decarbonylation of isobutyraldehyde in the gaseous phase by contacting a gaseous mixture of 1-15% by volume of isobutyraldehyde, at least a stoichiometric amount and up to about 30% by volume of oxygen, and an inert diluent, with a copper oxide catalyst.

7. 发明授权

US4282389A Process for the simultaneous manufacture of pure MTBE and a substantially isobutene-free mixture of C.sub.4 -hydrocarbons 失效
标题翻译：用于同时制造纯MTBE和基本上不含异丁烯的C 4烃混合物的方法
公开(公告)号：US4282389A
公开(公告)日：1981-08-04
申请号：US100058
申请日：1979-12-04
申请人： Wilhelm Droste , Fritz Obenaus
发明人： Wilhelm Droste , Fritz Obenaus
IPC分类号： C07C43/04 , B01J31/00 , C07B61/00 , C07C1/00 , C07C7/148 , C07C11/08 , C07C41/00 , C07C41/06 , C07C67/00 , C07C41/12
CPC分类号： C07C41/06 , C07C7/14891
摘要： A process for the simultaneous manufacture of pure methyl tertiary butyl ether (MTBE) and a substantially isotubene-free mixture of C.sub.4 -hydrocarbons, by reacting the isobutene contained in the mixture of C.sub.4 -hydrocarbons with excess methanol in the liquid phase at elevated temperatures on strongly acid, macroporous, organic ion exchange resins.The process has the following steps:(a) methanol and isobutene are reacted in a molar ratio of 2:1 to 5:1 at temperatures between 30.degree. and 100.degree. C.;(b) the unconverted hydrocarbons are then removed as the top product under a pressure of 2 to 10 bars from a first rectification column;(c) the bottom product from this first column is rectified in a second column under normal pressure or under a slight excess pressure of up to 2 bars at the top of the column, the bottom product of this rectification is recycled to reaction zone (a), if necessary, after separating off a portion of the tertiary butanol formed and the C.sub.8 -olefins; and(d) the distillate from this second column is rectified in a third rectification column under a pressure of 5 to 30 bars, the distillate thus obtained is recycled into the feed to the second column and pure methyl tertiary butyl ether is withdrawn from the bottom of the third column.
摘要翻译：通过使C4-烃混合物中所含的异丁烯与过量的甲醇在液相中在高温下反应，同时制备纯甲基叔丁基醚（MTBE）和基本上不含异丁烯的C 4烃混合物的方法强酸，大孔，有机离子交换树脂。该方法具有以下步骤：（a）甲醇和异丁烯在30℃和100℃之间的温度下以2:1至5:1的摩尔比反应; （b）然后从第一精馏塔在2至10巴的压力下将未转化的烃作为顶部产物除去; （c）来自该第一塔的底部产物在常压或第二塔中在塔的顶部在常压或低至2巴的轻微过量压力下进行精馏，该精馏的底部产物再循环至反应区），如果需要，在分离一部分形成的叔丁醇和C8-烯烃之后; 和（d）来自该第二塔的馏出物在第三精馏塔中在5至30巴的压力下进行精馏，由此获得的馏出物再循环到进料到第二塔中，从底部排出纯甲基叔丁基醚的第三列。

8. 发明授权

US5998685A Process for preparing butene oligomers from field butanes 失效
标题翻译：从场丁烷制备丁烯低聚物的方法
公开(公告)号：US5998685A
公开(公告)日：1999-12-07
申请号：US899897
申请日：1997-07-24
申请人： Franz Nierlich , Paul Olbrich , Wilhelm Droste , Richard Mueller , Walter Toetsch
发明人： Franz Nierlich , Paul Olbrich , Wilhelm Droste , Richard Mueller , Walter Toetsch
IPC分类号： C07C2/08 , C07C11/02 , C07C11/28 , C07C29/16 , C07C1/00 , C07C5/00 , C07C5/373 , C07C27/20
CPC分类号： C07C29/16 , C07C11/02 , C07C2/24 , C07C5/3337 , C07C7/005 , C07C7/04 , C07C7/12 , C07C7/163 , C07C2523/04 , C07C2523/14 , C07C2523/62 , C07C2529/76
摘要： A highly flexible process for preparing butene oligomers from field butanes. The process can be controlled to produce the desired oligomerization products by appropriate selection of the starting materials.
摘要翻译：一种用于从场丁烷制备丁烯低聚物的高度灵活的方法。可以通过适当选择原料来控制该方法以产生所需的低聚产物。

9. 发明授权

US5912191A Process for preparing alkyl tert-butyl ethers and di-n-butene from field butanes 失效
标题翻译：从野外丁烷制备烷基叔丁基醚和二正丁烯的方法
公开(公告)号：US5912191A
公开(公告)日：1999-06-15
申请号：US899797
申请日：1997-07-24
申请人： Franz Nierlich , Paul Olbrich , Wilhelm Droste , Richard Mueller , Walter Toetsch
发明人： Franz Nierlich , Paul Olbrich , Wilhelm Droste , Richard Mueller , Walter Toetsch
IPC分类号： C07C11/02 , C07C41/06 , C10L1/18
CPC分类号： C07C41/06 , C07C11/02
摘要： A process for the coupled production of alkyl tert-butyl ethers and butene oligomers from a mixture containing isobutane and n-butane. The isobutane is converted to the alkyl tert-butyl ether and the n-butane is converted to the oligomers. The ratio of the two reaction products may be controlled by setting the ratio of n-butane to isobutane appropriately by isomerization.
摘要翻译：从含有异丁烷和正丁烷的混合物偶联生产烷基叔丁基醚和丁烯低聚物的方法。将异丁烷转化为烷基叔丁基醚，将正丁烷转化为低聚物。可以通过将正丁烷与异丁烷的比例通过异构化适当地控制来控制两种反应产物的比例。

10. 发明授权

US5864052A Process for preparing alkyl tert-butyl ethers and di-n-butene from field butanes 失效
标题翻译：从野外丁烷制备烷基叔丁基醚和二正丁烯的方法
公开(公告)号：US5864052A
公开(公告)日：1999-01-26
申请号：US899792
申请日：1997-07-24
申请人： Franz Nierlich , Paul Olbrich , Wilhelm Droste , Richard Mueller , Walter Toetsch
发明人： Franz Nierlich , Paul Olbrich , Wilhelm Droste , Richard Mueller , Walter Toetsch
IPC分类号： C07C11/02 , C07C41/06 , C07C43/04
CPC分类号： C07C11/02 , C07C41/06
摘要： The invention relates to a process for preparing di-n-butene and alkyl tertbutyl ethers in a coupled production from field butanes, which indicates (a) separating the field butanes 1 into n-butane and isobutane in the separation stage 4, (b) dehydrogenating the n-butane 5 in a dehydrogenation stage 6 to give an n-butene-containing dehydrogenation mixture 7, oligomerizing the n-butene in the oligomerization stage 10 to give an oligomer mixture 11 and separating di-n-butene 12 off from this, and (c) de-hydrogenating the isobutane 15 in the dehydrogenation stage 16 to give an isobutene-containing dehydrogenation mixture 17 and reacting the isobutene with an alkanol 20 in the etherification stage 19 to give an alkyl tert-butyl ether 21. In an advantageous embodiment, the field butanes 1, prior to entry into the separation stage 4, are subjected to hydrogenation conditions in the hydrogenation stage 2 and an isomerization stage 3 is assigned to the separation stage 4, by means of which isomerization stage the ratio of n-butane to isobutane is set in accordance with the desired ratio of alkyl tertbutyl ether to di-n-butene.
摘要翻译：本发明涉及一种从场丁烷偶联制备二正丁烯和烷基叔丁基醚的方法，其表明（a）在分离段4中将场丁烷1分离成正丁烷和异丁烷;（b）在脱氢阶段6中使正丁烷5脱氢，得到含正丁烯的脱氢混合物7，使低聚反应阶段10中的正丁烯低聚，得到低聚物混合物11，并从其中分离出二 - 正丁烯12 ，和（c）脱氢阶段16中的异丁烷15脱氢，得到含异丁烯的脱氢混合物17，并使异丁烯与醚化阶段19中的链烷醇20反应，得到烷基叔丁基醚21.在有利的实施方案中，进入分离阶段4之前的现场丁烷1在氢化阶段2中经受氢化条件，异构化阶段3分配给分离阶段4 根据所需的烷基叔丁醚与二正丁烯的比例来设定正丁烷与异丁烷的比例。

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