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    • 1. 发明申请
    • HIGH SPEED DVDS
    • 高速DVD
    • US20130029081A1
    • 2013-01-31
    • US13575780
    • 2011-01-26
    • Friedrich-Karl BruderWilfried HaeseRafael OserWolfgang FischerMichael LudewigRaymond WongIce Zhang
    • Friedrich-Karl BruderWilfried HaeseRafael OserWolfgang FischerMichael LudewigRaymond WongIce Zhang
    • G11B7/256B32B37/12C08L75/14
    • G11B7/2533G11B7/24047G11B7/246G11B7/253Y10T428/21
    • This invention relates to DVDs made from polycarbonate and a special UV curable bonder material consisting of A) an urethane acrylate oligomer as binder, which is the reaction product of i) one or more polyisocyanates and ii) one or more hydroxyfunctional lactone ester (meth)acrylates having a number average molecular weight of from 200 g/mol to 2000 g/mol and having the formula: CH2═C(R1)—C(O)—O—R2—[O—C(O)—R3]n—OH wherein, n is an integer from 1 to 5, R1 is hydrogen or methyl, R2 represents an alkylene group or substituted alkylene group having from 2 to 10 carbon atoms and R3 represents a straight or branched chain alkylene group of from 3 to 8 carbon atoms, and which may be substituted with one or more alkyl groups having from 1 to 12 carbon atoms, B) a reactive thinner, comprising of mono functional acrylates and/or (meth)acrylates C) a photo initiator and D) optional additives which offers improved performance at high data transfer rates.
    • 本发明涉及由聚碳酸酯制成的DVD和由A)氨基甲酸酯丙烯酸酯低聚物作为粘合剂组成的特殊UV固化粘合剂材料,其为i)一种或多种多异氰酸酯和ii)一种或多种羟基官能内酯酯(甲基) 丙烯酸酯,其数均分子量为200g / mol至2000g / mol,具有下式:CH 2 = C(R 1)-C(O)-O-R 2 - [O-C(O)-R 3] n -OH,其中n为1至5的整数,R 1为氢或甲基,R 2表示亚烷基或具有2至10个碳原子的取代的亚烷基,R 3表示3至8的直链或支链亚烷基 碳原子,并且其可以被一个或多个具有1至12个碳原子的烷基取代; B)包含单官能丙烯酸酯和/或(甲基)丙烯酸酯的活性稀释剂C)光引发剂和D)任选的添加剂 这在高数据传输速率下提供了更好的性能。
    • 2. 发明授权
    • High speed DVDs
    • 高速DVD
    • US08778476B2
    • 2014-07-15
    • US13575780
    • 2011-01-26
    • Friedrich-Karl BruderWilfried HaeseRafael OserWolfgang FischerMichael LudewigRaymond WongIce Zhang
    • Friedrich-Karl BruderWilfried HaeseRafael OserWolfgang FischerMichael LudewigRaymond WongIce Zhang
    • G11B7/24G11B7/2533G11B7/253G11B7/24047
    • G11B7/2533G11B7/24047G11B7/246G11B7/253Y10T428/21
    • This invention relates to DVDs made from polycarbonate and a special UV curable bonder material consisting of A) an urethane acrylate oligomer as binder, which is the reaction product of i) one or more polyisocyanates and ii) one or more hydroxyfunctional lactone ester (meth)acrylates having a number average molecular weight of from 200 g/mol to 2000 g/mol and having the formula: CH2═C(R1)—C(O)—O—R2—[O—C(O)—R3]n—OH wherein, n is an integer from 1 to 5, R1 is hydrogen or methyl, R2 represents an alkylene group or substituted alkylene group having from 2 to 10 carbon atoms and R3 represents a straight or branched chain alkylene group of from 3 to 8 carbon atoms, and which may be substituted with one or more alkyl groups having from 1 to 12 carbon atoms, B) a reactive thinner, comprising of mono functional acrylates and/or (meth)acrylates C) a photo initiator and D) optional additives which offers improved performance at high data transfer rates.
    • 本发明涉及由聚碳酸酯制成的DVD和由A)氨基甲酸酯丙烯酸酯低聚物作为粘合剂组成的特殊UV固化粘合剂材料,其为i)一种或多种多异氰酸酯和ii)一种或多种羟基官能内酯酯(甲基) 丙烯酸酯,其数均分子量为200g / mol至2000g / mol,具有下式:CH 2 = C(R 1)-C(O)-O-R 2 - [O-C(O)-R 3] n -OH,其中n为1至5的整数,R 1为氢或甲基,R 2表示亚烷基或具有2至10个碳原子的取代的亚烷基,R 3表示3至8的直链或支链亚烷基 碳原子,并且其可以被一个或多个具有1至12个碳原子的烷基取代; B)包含单官能丙烯酸酯和/或(甲基)丙烯酸酯的活性稀释剂C)光引发剂和D)任选的添加剂 这在高数据传输速率下提供了更好的性能。
    • 9. 发明授权
    • Process for preparing allophanate-containing actinically curable polyurethane prepolymers with increased resistance
    • 制备具有增加电阻的含有脲基甲酸酯的光固化型聚氨酯预聚物的方法
    • US07700662B2
    • 2010-04-20
    • US11731592
    • 2007-03-30
    • Michael LudewigJan WeikardNicolas StoeckelWolfgang Fischer
    • Michael LudewigJan WeikardNicolas StoeckelWolfgang Fischer
    • C07C275/60C07C269/00C07C271/62C07C273/00C08L75/14C08L75/16C08G18/42C08G18/44C08G18/48C08G18/67
    • C08G18/672C08G18/6633C08G18/7837C08G18/8175C09D175/16
    • The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.9 and a number-average molecular weight (Mn) of at least 1000 g/mol, D) optionally in the presence of a catalyst, are reacted to form NCO-group-containing prepolymers having radiation-curing groups, which are subsequently reacted E) optionally after addition of monofunctional isocyanates in the presence F) of an allophanatization catalyst to give allophanate-containing prepolymers, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and C) being 1.45:1.0 to 1.1:1.0 and the ratio of the OH groups from B) to the OH groups from C) being 8.0:1 to 1.5:1.
    • 本发明涉及一种制备可通过光化辐射固化的低粘度,含有脲基甲酸酯和不含NCO的聚氨酯预聚物和通过该方法获得的产品的方法。 预聚物的残留单体含量小于0.5重量%,NCO含量小于1重量%,并且通过以下方法制备:A)二异氰酸酯,B)含有与烯属不饱和基团反应的基团的羟基官能化合物 化合物暴露于光化辐射,以及C)官能度为至少1.9,数均分子量(Mn)至少为1000g / mol的聚酯,聚醚或聚碳酸酯多元醇,D)任选地在催化剂存在下 反应形成具有放射线固化基团的含有NCO基团的预聚物,其随后反应E)任选地在加入单官能异氰酸酯的情况下,在脲基化催化剂存在下,得到含脲基甲酸酯的预聚物,NCO基团 的来自A)的化合物与来自B)和C)的化合物的OH基团的摩尔比为C:1.45:1.0至1.1:1.0,并且B)中的OH基与C)中的OH基团的比例为8.0:1至1.5 :1。