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1. 发明授权

US5851300A Cationic modification of starch and use of the cationically modified starch 失效
标题翻译：淀粉的阳离子改性和阳离子改性淀粉的使用
公开(公告)号：US5851300A
公开(公告)日：1998-12-22
申请号：US817644
申请日：1997-04-29
申请人： Friedrich Linhart , Andreas Stange , Rudolf Schuhmacher , Heinrich Hartmann , Walter Denzinger , Manfred Niessner , Claudia Nilz , Wolfgang Reuther , Hubert Meixner
发明人： Friedrich Linhart , Andreas Stange , Rudolf Schuhmacher , Heinrich Hartmann , Walter Denzinger , Manfred Niessner , Claudia Nilz , Wolfgang Reuther , Hubert Meixner
IPC分类号： C08B31/12 , C08B31/00 , C08G73/02 , C08G81/00 , D21H17/29 , D21H21/18 , C08B30/12 , C08B30/00 , D21H11/00
CPC分类号： C08G73/0213 , C08B31/00 , C08G81/00 , D21H17/29 , D21H21/18
摘要： In a cationic modification process for starch, starch is reacted with polymers that contain amino and/or ammonium groups in an aqueous medium at temperatures from 115.degree. C. to 180.degree. C. under an increased pressure and in the absence of oxidizers, polymerization initiators and alkali. The reaction is conducted so that maximum 10% by weight starch has its molar weight reduced. Also disclosed is the use of the thus obtained reaction products as dry strength agents for paper.
摘要翻译： PCT No.PCT / EP95 / 04075第 371日期1997年04月29日 102（e）1997年4月29日PCT PCT 1995年10月17日PCT公布。第WO96 / 13525号公报日期1996年5月9日在淀粉的阳离子改性方法中，淀粉与含水氨基和/或铵基团的聚合物在115℃至180℃的温度下在升高的压力下和在不存在氧化剂，聚合引发剂和碱。进行反应使得最大10重量％的淀粉具有降低的摩尔重量。还公开了由此获得的反应产物作为纸的干强度剂的用途。

2. 发明授权

US5630907A Use of hydrolyzed copolymers of N-vinylcarboxamides and monoethylenically unsaturated carboxylic acids in papermaking 失效
标题翻译：在造纸中使用N-乙烯基甲酰胺和单烯属不饱和羧酸的水解共聚物
公开(公告)号：US5630907A
公开(公告)日：1997-05-20
申请号：US651655
申请日：1996-05-21
申请人： Claudia Nilz , Walter Denzinger , Heinrich Hartmann , Michael Kroener , Friedrich Linhart , Rudolf Schuhmacher , Dietmar Moench , Andreas Stange
发明人： Claudia Nilz , Walter Denzinger , Heinrich Hartmann , Michael Kroener , Friedrich Linhart , Rudolf Schuhmacher , Dietmar Moench , Andreas Stange
IPC分类号： C08F8/12 , D21H21/10
CPC分类号： C08F8/12 , C08J5/18 , C08F2810/50
摘要： Copolymers which are obtained by copolymerization ofa) from 5 to 99 mol % of N-vinylcarboxamides,b) from 95 to 1 mol % of monoethylenically unsaturated carboxylic acids and/or the alkali metal, alkaline earth metal, ammonium or amine salts thereof, and if required,c) up to 30 mol % of other monoethylenically unsaturated compounds, and if required,d) up to 2 mol % of crosslinking agents,and subsequent partial or complete elimination of the acyl groups from the N-vinylcarboxamides polymerized in the copolymer, with formation of amino or ammonium groups, are used as additives to paper stock for increasing the drainage rate and the retention in papermaking, and the dry and wet strength of the paper.
摘要翻译：通过a）5〜99摩尔％的N-乙烯基酰胺共聚得到的共聚物，b）95〜1摩尔％的单烯属不饱和羧酸和/或其碱金属，碱土金属，铵或胺盐，并且如果需要，c）至多30mol％的其它单烯键式不饱和化合物，如果需要，d）最多达2mol％的交联剂，随后部分或完全消除由乙烯基酰胺聚合的N-乙烯基酰胺共聚物，形成氨基或铵基，被用作纸浆的添加剂，以增加造纸中的排水速率和保留性，以及纸的干和湿强度。

3. 发明授权

US6060566A Graft polymers of polymers containing vinyl ester and/or vinyl alcohol units and ethylenically unsaturated compounds, their preparation and their use 失效
标题翻译：含有乙烯基酯和/或乙烯醇单元和烯键式不饱和化合物的聚合物的接枝聚合物，其制备及其应用
公开(公告)号：US6060566A
公开(公告)日：2000-05-09
申请号：US983141
申请日：1998-01-21
申请人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
发明人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
IPC分类号： C08B37/00 , C08F8/12 , C08F261/04 , C08F263/02 , C08F283/06 , C08F291/00 , C09D7/45 , D21H17/34 , D21H17/37 , D21H21/10 , D21H21/14 , D21H21/16 , D21H21/18 , C08F263/04 , C08L51/04
CPC分类号： D21H17/37 , C08F261/04 , C08F263/02 , C08F8/12 , C08F8/44 , D21H21/10 , D21H21/146 , D21H21/16 , D21H21/18
摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures comprising(a) from 1 to 100% by weight of N-vinylcarboxamides of the formula ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0 to 99% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule,in the presence of(B) polymers which contain units of vinyl esters of saturated C.sub.1 -C.sub.4 -carboxylic acids and/or vinyl alcohol units, or of mixtures which contain these polymers and polymers having at least 3 alkylene oxide units or polytetrahydrofuran,in a weight ratio (A):(B) of from 95:5 to 10:90 and, if required, subsequent elimination of the group ##STR2## from the polymerized monomers (I) of the graft polymer with formation of units of the formula ##STR3## and the graft polymers described above are used in the production of paper, board and cardboard as dry and wet strength agents, as retention and drainage aids and as promoters in diketene sizing and as starch cationization agents, as dispersants for pigments and as creping assistants in the production of tissue papers.
摘要翻译： PCT No.PCT / EP96 / 02991 Sec。 371日期1998年1月21日 102（e）1998年1月21日PCT PCT 1996年7月9日PCT公布。第WO97 / 04014号公报日期1997年2月6日通过（A）单体或单体混合物的自由基聚合获得接枝聚合物，所述单体或单体混合物包含（a）1至100重量％的下式的N-乙烯基甲酰胺其中R 1和R 2各自为H或C 1 -C 6 - 烷基，（b）0至99重量％的可与单体（a）和（c）共聚的其它单烯属不饱和单体，0至5重量％的具有至少两个烯属不饱和的非共轭双键的单体分子，在（B）包含饱和C 1 -C 4羧酸和/或乙烯醇单元的乙烯基酯单元的聚合物存在下，或包含这些聚合物和具有至少3个烯化氧单元或聚四氢呋喃的聚合物的混合物的存在下，在95:5至10:90的重量比（A）：（B））中，如果需要，随后从形成下式的单元的接枝聚合物的聚合单体（I）中除去该基团，上述接枝聚合物用于制备纸，纸板和纸板作为干和湿强度剂，作为保留和引流助剂以及作为二烯酮上浆和淀粉阳离子化剂的促进剂，作为颜料的分散剂和用于生产薄纸的起皱助剂。

4. 发明授权

US6048945A Graft polymers comprising polymers, containing alkylene oxide units, and ethylenically unsaturated compounds, their preparation and their use 失效
标题翻译：包含含有烯化氧单元的聚合物和烯键式不饱和化合物的接枝聚合物，其制备及其用途
公开(公告)号：US6048945A
公开(公告)日：2000-04-11
申请号：US945546
申请日：1997-11-03
申请人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
发明人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
IPC分类号： C08B31/12 , C08F8/12 , C08F283/00 , C08F283/06 , C09B67/46 , C09D17/00 , D21H17/53 , D21H19/20 , D21H21/10 , D21H21/16 , D21H21/18 , D21H17/00 , D21H17/33 , D21H17/46
CPC分类号： D21H21/18 , C08F283/00 , C08F8/44 , C09B67/0085 , C09D17/00 , D21H21/10 , D21H21/16
摘要： A graft polymer obtained by free radically polymerizing:(A) a monomer or monomer mixture comprising:(a) from 10-100% by weight of a N-vinylcarboxamide of the formula: ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0-90% by weight of at least one other monoethylenically unsaturated monomer which is copolymerizable with (a), and(c) from 0-5% by weight of at least one monomer having at least two ethylenically unsaturated nonconjugated double bonds in the molecule, in the presence of(B) a polytetrahydrofuran or a polymer which contains at least 3 units of a C.sub.2 -C.sub.4 alkylene oxide and is a hornopolymer of C.sub.2-4 -alkylene oxide having two free terminal OH groups or random or block copolymers of C.sub.2-4 -alkylene oxides having two free terminal OH groups or the reaction products of C.sub.2-4 -alkylene oxides with phenols, amines or fatty carboxylic acids, in a weight ratio (A):(B) ranging from 95:5 to 10:80, some or all of the amide groups having been eliminated by hydrolysis.
摘要翻译： PCT No.PCT / EP96 / 01663 Sec。 371日期：1997年11月3日 102（e）日期1997年11月3日PCT 1996年4月20日PCT PCT。 WO96 / 34903 PCT出版物日期：1996年11月7日通过自由基聚合获得的接枝聚合物：（A）单体或单体混合物，其包含：（a）10-100重量％的下式的N-乙烯基甲酰胺：其中R1和R2各自为H 或（c）0-90重量％的至少一种其它单烯属不饱和单体，其可以与（a）和（c）0-5重量％的至少一种单体共聚，在（B）聚四氢呋喃或含有至少3个单元的C 2 -C 4环氧烷烃的聚合物存在下，分子中至少有两个烯属不饱和非共轭双键，并且是具有两个碳原子的C2-4-氧化烯的角质聚合物游离末端OH基团或具有两个自由末端OH基团的C 2-4亚烷基氧化物或C 2-4 - 烯化氧与酚，胺或脂肪羧酸的反应产物的重量比（A）：（B）的范围为95:5至10:80，部分或全部酰胺基已被水解除去。

5. 发明授权

US6159340A Hydrolyzed polymers of N-vinylcarboxamides as paper, paperboard and cardboard dry strength enhancers 有权
标题翻译： N-乙烯基甲酰胺的水解聚合物作为纸，纸板和纸板干强度增强剂
公开(公告)号：US6159340A
公开(公告)日：2000-12-12
申请号：US125795
申请日：1998-08-31
申请人： Manfred Niessner , Claudia Nilz , Jens Utecht , Martin Rubenacker , Rudolf Schuhmacher
发明人： Manfred Niessner , Claudia Nilz , Jens Utecht , Martin Rubenacker , Rudolf Schuhmacher
IPC分类号： C08F8/12 , C08F26/02 , D21H17/34 , D21H17/37 , D21H21/18 , D21H17/00
CPC分类号： D21H21/18 , C08F8/44 , D21H17/37
摘要： Partially hydrolyzed polymers of N-vinylcarboxamides obtainable by sole polymerization of N-vinylcarboxamides of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 - to C.sub.6 -alkyl, and elimination from the polymers of from 0.5 to 95 mol % of the groups of the formula ##STR2## where R.sup.1 is hydrogen or C.sub.1 - to C.sub.6 -alkyl, can be used as paper, paperboard and cardboard dry strength enhancers.
摘要翻译： PCT No.PCT / EP97 / 00801 Sec。 371日期1998年8月31日 102（e）日期1998年8月31日PCT提交1997年2月20日PCT公布。出版物WO97 / 31518 PCT 日期1997年9月4日，N-乙烯基甲酰胺的部分水解聚合物可通过下式的N-乙烯基甲酰胺单独聚合得到：其中R 1和R 2各自为氢或C 1至C 6烷基，并且从聚合物中消除0.5至95摩尔％其中R 1为氢或C 1至C 6烷基的下式基团可用作纸，纸板和纸板干强度增强剂。

6. 发明授权

US6114435A Preparation of aqueous solutions of polymers containing vinylamine units, which solutions have a long shelf life, and their use 失效
标题翻译：含有乙烯胺单元的聚合物的水溶液的制备，该溶液具有长的保质期及其用途
公开(公告)号：US6114435A
公开(公告)日：2000-09-05
申请号：US716280
申请日：1996-09-30
申请人： Claudia Nilz , Manfred Winter , Michael Kroner , Andreas Stange , Rudolf Schuhmacher
发明人： Claudia Nilz , Manfred Winter , Michael Kroner , Andreas Stange , Rudolf Schuhmacher
IPC分类号： C08F8/12 , D21H17/34 , D21H21/18 , D21H21/20 , C08L39/02
CPC分类号： D21H21/20 , C08F8/12 , D21H17/34 , D21H21/18 , C08F2800/20
摘要： Solutions of polymers containing vinylamine units, which solutions have a long shelf life, are prepared by hydrolyzing polymers containing N-vinylcarboxamide units with acids in an aqueous medium and removing the carboxylic acids eliminated from the polymers as esters from the aqueous polymer solution after the hydrolysis by adding at least stoichiometric amounts of at least one C.sub.1 -C.sub.6 -alcohol and distilling off the esters from the reaction mixture, and said aqueous solutions are used as dry and wet strength agents in papermaking.
摘要翻译： PCT No.PCT / EP95 / 01030 Sec。 371日期1996年9月30日 102（e）1996年9月30日PCT PCT 1995年3月20日PCT公布。公开号WO95 / 26989 日期1995年10月12日含有乙烯基胺单元的聚合物的溶液具有长的保存期限，其通过在水性介质中水解含有N-乙烯基甲酰胺单元的聚合物和酸从聚合物中除去作为酯的羧酸从水溶液通过加入至少一种化学计量的至少一种C 1 -C 6醇并从反应混合物中蒸馏出酯，水解后的聚合物溶液，并将所述水溶液用作造纸中的干和湿强度剂。

7. 发明授权

US08188197B2 Method for producing a polymer 有权
标题翻译：聚合物的制造方法
公开(公告)号：US08188197B2
公开(公告)日：2012-05-29
申请号：US12742552
申请日：2008-09-08
申请人： Ilshat Gubaydullin , Karl-Heinz Wassmer , Robert Rupaner , Jochen Kessler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Huemmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
发明人： Ilshat Gubaydullin , Karl-Heinz Wassmer , Robert Rupaner , Jochen Kessler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Huemmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
IPC分类号： C08F2/00 , C08F4/00 , C08F4/28 , B01J10/00
CPC分类号： B01J19/0006 , B01J19/18 , B01J2219/00166 , B01J2219/00184 , C08F2/00 , C08F2/24 , C08F2400/02
摘要： The present invention relates to a method for performing a polymerization process in a stirred reactor, wherein a critical time window is determined by means of a monitor of at least one polymerization process parameter and an associated process window, and when a critical time window is present, an adaptation of process conditions is made in order to configure the polymerization process to conform to the process window.
摘要翻译：本发明涉及一种在搅拌反应器中进行聚合过程的方法，其中通过至少一个聚合过程参数和相关工艺窗口的监测来确定临界时间窗，并且当存在临界时间窗时为了配置聚合过程以符合工艺窗口，进行工艺条件的适应。

8. 发明申请

US20120237403A1 METHOD FOR PRODUCING A POLYMER 有权
标题翻译：生产聚合物的方法
公开(公告)号：US20120237403A1
公开(公告)日：2012-09-20
申请号：US13442221
申请日：2012-04-09
申请人： Ilshat Gubaydullin , Karl-Heinz Waßmer , Robert Rupaner , Jochen Keßler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Hümmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
发明人： Ilshat Gubaydullin , Karl-Heinz Waßmer , Robert Rupaner , Jochen Keßler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Hümmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
IPC分类号： B01J19/18
CPC分类号： B01J19/0006 , B01J19/18 , B01J2219/00166 , B01J2219/00184 , C08F2/00 , C08F2/24 , C08F2400/02
摘要： Provided is a method for performing a polymerization process in a stirred reactor, wherein a critical time window is determined by means of a monitor of at least one polymerization process parameter and an associated process window, and when a critical time window is present, an adaptation of process conditions is made in order to configure the polymerization process to conform to the process window.
摘要翻译：提供了一种在搅拌反应器中进行聚合过程的方法，其中通过至少一个聚合过程参数和相关工艺窗口的监测来确定临界时间窗，并且当存在临界时间窗时，适应的工艺条件是为了配置聚合过程以符合工艺窗口。

9. 发明授权

US5700351A Antifoams based on oil-in-water emulsions for the paper industry 失效
标题翻译：基于造纸工业的水包油乳液的消泡剂
公开(公告)号：US5700351A
公开(公告)日：1997-12-23
申请号：US379442
申请日：1995-02-06
申请人： Rudolf Schuhmacher , Gabriele Dralle-Voss , Knut Oppenlaender , Brigitte Wegner , Andreas Hohmann
发明人： Rudolf Schuhmacher , Gabriele Dralle-Voss , Knut Oppenlaender , Brigitte Wegner , Andreas Hohmann
IPC分类号： D21H17/14 , D21H19/44 , D21H21/12 , B01D19/04
CPC分类号： B01D19/0404 , D21H17/14 , D21H21/12
摘要： Antifoams based on oil-in-water emulsions, in which the oil phase accounts for from 5 to 50% by weight of the emulsions and consists essentially of a mixture of (a) fatty esters of C.sub.12 -C.sub.22 -carboxylic acids with monohydric to trihydric C.sub.1 -C.sub.22 -alcohols, (b) polyglyceryl esters which are obtainable by at least 20% esterification of polyglycerols which contain at least 2 glyceryl units with at least one C.sub.12 -C.sub.36 -fatty acid and (c) fatty esters of C.sub.12 -C.sub.22 -carboxylic acids and polyalkylene glycols, the molecular weight of the polyalkylene glycols being up to 5,000 g/mol, and, if required, (d) long-chain alcohols, fatty esters of alcohols of at least 22 carbon atoms and C.sub.1 -C.sub.36 -carboxylic acids, distillation residues which are obtainable in the preparation of alcohols having a relatively large number of carbon atoms by oxo synthesis or by the Ziegler process and which may be alkoxylated, and/or (e) hydrocarbons having a boiling point above 200.degree. C. or fatty acids of 12 to 22 carbon atoms, are used for controlling foam in pulp digestion, in the beating of paper stock, in papermaking and in the dispersing of pigments for papermaking.
摘要翻译： PCT No.PCT / EP93 / 02531 Sec。 371日期：1995年2月6日 102（e）日期1995年2月6日PCT 1993年9月18日PCT公布。出版物WO94 / 08091 日期1994年04月14日基于水包油乳液的消泡剂，其中油相占乳液的5至50重量％，基本上由（a）C12-C22-羧酸的脂肪酯具有一元至三元C 1 -C 22醇的酸，（b）聚甘油酯，其可通过至少20％含有至少2个甘油基单元与至少一种C 12 -C 36脂肪酸酯化的聚甘油酯化，和（c）脂肪酸酯的C 12 -C 22羧酸和聚亚烷基二醇，聚亚烷基二醇的分子量高达5,000g / mol，如果需要，（d）长链醇，至少22个碳原子的醇的脂肪酸酯和 C1-C36-羧酸，可通过氧代合成或通过齐格勒方法制备具有相对大量碳原子的醇并可被烷氧基化得到的蒸馏残余物，和/或（e）具有沸点的烃高于200℃或12至22的脂肪酸碳原子，用于控制纸浆消化中的泡沫，纸浆的打浆，造纸和分散造纸用颜料。

10. 发明授权

US5270376A Aqueous polymer dispersion having divalent metal salt(s) incorporated therein 失效
标题翻译：含有二价金属盐的水性聚合物分散体
公开(公告)号：US5270376A
公开(公告)日：1993-12-14
申请号：US928768
申请日：1992-08-17
申请人： Franz Matejcek , Maximilian Angel , Rudolf Schuhmacher
发明人： Franz Matejcek , Maximilian Angel , Rudolf Schuhmacher
IPC分类号： C08F8/44 , C08J3/03 , C08K3/22 , D06N5/00 , C08J3/02 , C08K3/20 , C08L33/08
CPC分类号： D06N5/00 , C08F8/44 , C08J3/03 , C08K3/22 , Y10T428/31815 , Y10T442/2631
摘要： A process is provided for the preparation of an aqueous polymer dispersion which entails incorporating one or more divalent metals of magnesium, calcium or zinc in the form of an oxide, hydroxide, carbonate or bicarbonate, or in the form of a mixture of these basic salts into an aqueous starting dispersion containing a polymer A as the dispersed phase, an effective amount of an emulsifier and water as the remainder, at a temperature below the boiling point of pure water and above the glass transition point of the polymer A, wherein polymer A consists essentially of monomers, a) which are one or more .alpha., .beta.-monoethylenically unstaturated mono- or di-carboxylic acids containing from 3 to 5 carbon atoms, an anhydride o these acids or a mixture thereof; and monomers b) being one or more other copolymerizable monomers.
摘要翻译：提供了一种制备含水聚合物分散体的方法，其需要引入一种或多种氧化物，氢氧化物，碳酸盐或碳酸氢盐形式的镁，钙或锌的二价金属，或以这些碱式盐的混合物的形式在低于纯水沸点并高于聚合物A的玻璃化转变温度的温度下，将含有聚合物A作为分散相的有效量的乳化剂和水作为剩余部分，其中聚合物A 基本上由单体组成，a）它们是含有3至5个碳原子的一个或多个α，β-单烯属不饱和单羧酸或二羧酸，这些酸或它们的混合物的酸酐; 和单体b）是一种或多种其它可共聚单体。

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