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1. 发明授权

US4746681A Molded polyurea articles and a process for the production thereof 失效
标题翻译：模制聚脲制品及其生产方法
公开(公告)号：US4746681A
公开(公告)日：1988-05-24
申请号：US36834
申请日：1987-04-10
申请人： Friedhelm Pilger , Reinhold Franzen , Wolfgang Reichmann
发明人： Friedhelm Pilger , Reinhold Franzen , Wolfgang Reichmann
IPC分类号： C08J5/00 , C08G18/10 , C08G18/50 , C08G18/66 , C08J9/02 , C08J9/04 , C08G18/14
CPC分类号： C08G18/6685 , C08G18/10 , C08G18/5027 , C08G18/5048 , C08G2101/0008 , C08G2101/0033 , C08G2101/0066 , C08G2120/00 , Y10S264/14
摘要： Molded polyurea foam parts having densities of from 200 to 600 kg/m.sup.3 and a compact skin are made by reacting a polyisocyanate component with a polyamine component in a closed mold at an isocyanate index of from 70 to 130. The polyamine component generally includes (1) an aminopolyether having a molecular weight of from 1800 to 12,000 and 2 to 3 isocyanate reactive groups of which at least 90% are aromatically bound primary and/or secondary amino groups, (2) an aromatic diamine, (3) a foaming agent and optionally (4) known auxiliaries and additives. The polyisocyanate component includes any aromatic di- and/or poly-isocyanate. Parts produced by this process have excellent mechanical properties and a well-defined solid skin.
摘要翻译：通过使多异氰酸酯组分与多胺组分在封闭模具中以70至130的异氰酸酯指数反应制备密度为200至600kg / m 3的模制聚脲泡沫部件和紧密表皮。多胺组分通常包括（1 ）分子量为1800〜12,000的氨基聚醚和2〜3个异氰酸酯反应性基团，其中至少90％是芳族结合的伯和/或仲氨基，（2）芳族二胺，（3）发泡剂和（4）已知的助剂和添加剂。多异氰酸酯组分包括任何芳族二 - 和/或多异氰酸酯。通过该方法生产的部件具有优异的机械性能和明确的固体皮肤。

2. 发明授权

US4919878A Process for the production of polyurethane-and/or polyurea-based moldings 失效
标题翻译：用于生产聚氨酯和/或聚脲基模制品的方法
公开(公告)号：US4919878A
公开(公告)日：1990-04-24
申请号：US81043
申请日：1987-08-03
申请人： Friedhelm Pilger , Richard Kopp , Otto Ganster
发明人： Friedhelm Pilger , Richard Kopp , Otto Ganster
IPC分类号： B29C33/56 , B29C33/60 , C08K5/098 , C08K5/16 , C08L75/00 , C08L75/04
CPC分类号： C08K5/098 , B29C33/60 , C08K5/16 , B29K2075/00 , B29K2105/04 , Y10S264/83
摘要： A process for the production of optionally foamed moldings having a compact surface by the reaction in closed molds of a mixture of(a) organic polyisocyanates,(b) compounds containing isocyanate-reactive groups and having a molecular weight of 62 to about 10,000 and(c) mold release agents based on salts of (i) saturated or unsaturated aliphatic or cycloaliphatic carboxylic acids or carboxylic acid mixtures containing (on a statistical average) at least 8 carbon atoms per molecule and (ii) tertiary amines,characterized in that the release agents (c) used are salts in which the amine component (ii) is based on tertiary monoamines or mixtures of tertiary monoamines corresponding to the following formula ##STR1## in which R.sub.1 represents a saturated or unsaturated aliphatic hydrocarbon radical containing at least 12 carbon atoms and R.sub.2 and R.sub.3 may be the same or different and represent saturated or unsaturated, preferably saturated, aliphatic hydrocarbon radicals containing from 1 to 18, preferably from 1 to 4 carbon atoms, more preferably, methyl groups and/or C.sub.2 -C.sub.40 hydroxyalkyl radicals optionally containing ether bridges.
摘要翻译：通过在（a）有机多异氰酸酯，（b）含有异氰酸酯反应性基团并且具有62至约10,000的分子量的化合物的混合物的闭合模具中的反应中产生具有紧密表面的任选发泡模制品的方法， c）基于（i）饱和或不饱和脂族或脂环族羧酸或含有每分子至少8个碳原子的统计平均值的羧酸混合物和（ii）叔胺的盐的脱模剂，其特征在于，使用的试剂（c）是其中胺组分（ii）基于叔单胺或对应于下式的IMA单体的混合物的盐，其中R 1表示含有至少12个碳原子的饱和或不饱和脂族烃基并且R 2和R 3可以相同或不同，表示含有1至18个p的饱和或不饱和的，优选饱和的脂族烃基可以具有1至4个碳原子，更优选甲基和/或任选含有醚桥的C 2 -C 40羟基烷基。

3. 发明授权

US4772639A Process for the production of molded polyurethane parts 失效
标题翻译：生产模制聚氨酯零件的工艺
公开(公告)号：US4772639A
公开(公告)日：1988-09-20
申请号：US142759
申请日：1988-01-11
申请人： Friedhelm Pilger , Ulrich Knipp , Reinhard Halpaap
发明人： Friedhelm Pilger , Ulrich Knipp , Reinhard Halpaap
IPC分类号： C08G18/22 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/73 , C08G18/75 , C08G18/79 , C08G18/70
CPC分类号： C08G18/755 , C08G18/6688 , C08G18/725 , C08G18/792 , C08G2120/00
摘要： The present invention is directed to a process for the production of light-resistant, optionally foamed elastomeric molded polyurethanes by reacting(a) organic polyisocyanates which are either mixtures of isophorone diisocyanate with polyisocyanates containing isocyanurate groups and based on 1,6-diisocyanatohexane or mixtures of IPDI with polyisocyanates containing isocyanurate groups and based on 1,6-diisocyanato-hexane and IPDI with organic compounds containing isocyanate-reactive groups in the presence of catalysts, wherein the components are reacted together inside closed molds in an isocyanate index of about 70 to 130.The present invention is additionally directed to the elastomeric polyurethanes prepared by this process.
摘要翻译：本发明涉及通过使（a）有机多异氰酸酯与异佛尔酮二异氰酸酯的混合物与含有异氰脲酸酯基的多异氰酸酯和基于1,6-二异氰酸根合己烷或其混合物的混合物反应生产耐光，任选发泡的弹性体模制聚氨酯的方法的IPDI与含有异氰脲酸酯基团的多异氰酸酯，并且在催化剂存在下，基于1,6-二异氰酸根合 - 己烷和含有异氰酸酯反应性基团的有机化合物的IPDI，其中组分在封闭模具内以约70至异氰酸酯指数反应本发明另外涉及通过该方法制备的弹性体聚氨酯。

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