专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5317036A Gas phase polymerization reactions utilizing soluble unsupported catalysts 失效
标题翻译：使用可溶性无载体催化剂的气相聚合反应
公开(公告)号：US5317036A
公开(公告)日：1994-05-31
申请号：US962119
申请日：1992-10-16
申请人： Robert C. Brady, III , Frederick J. Karol , Timothy R. Lynn , Robert J. Jorgensen , Sun-Chueh Kao , Eric P. Wasserman
发明人： Robert C. Brady, III , Frederick J. Karol , Timothy R. Lynn , Robert J. Jorgensen , Sun-Chueh Kao , Eric P. Wasserman
IPC分类号： C08F4/642 , B01J8/24 , B01J8/38 , C08F2/00 , C08F2/34 , C08F4/60 , C08F4/62 , C08F4/6592 , C08F10/00 , C08F210/18
CPC分类号： C08F2/34 , B01J8/24 , B01J8/382 , C08F210/18 , Y10S526/901 , Y10S526/943
摘要： Gas phase polymerization processes are disclosed which utilize unsupported soluble transition metal coordination catalysts. The catalysts are introduced into the reactor as a solution.
摘要翻译：公开了使用无载体可溶性过渡金属配位催化剂的气相聚合方法。将催化剂作为溶液引入反应器。

2. 发明授权

US5162466A Use of methylene-bridged derivatives of cyclopentadienyl dicarbollide complexes of titanium, zirconium and hafnium as polymerization catalysts 失效
标题翻译：使用钛，锆和铪的环戊二烯基二碳化物复合物的亚甲基桥接衍生物作为聚合催化剂
公开(公告)号：US5162466A
公开(公告)日：1992-11-10
申请号：US814810
申请日：1991-12-31
申请人： Frederick J. Karol , Sun-Chueh Kao , Robert C. Brady, III
发明人： Frederick J. Karol , Sun-Chueh Kao , Robert C. Brady, III
IPC分类号： C08F4/642 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F10/02 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Methylene bridged derivatives of novel cyclopentadienyl dicarbollide complexes of titanium, zirconium and hafnium display high activity as ethylene polymerization catalysts in the absence of a cocatalyst.

3. 发明授权

US06605563B1 Catalyst system and its use in olefin polymerization 有权
标题翻译：催化剂体系及其在烯烃聚合中的应用
公开(公告)号：US06605563B1
公开(公告)日：2003-08-12
申请号：US10359933
申请日：2003-02-06
申请人： Sun-Chueh Kao , Jaimes Sher , Frederick J. Karol
发明人： Sun-Chueh Kao , Jaimes Sher , Frederick J. Karol
IPC分类号： C08F464
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/6592 , Y10S526/943 , C08F4/65912 , C08F210/14 , C08F2500/03
摘要： A polymerization catalyst system and a method for preparing the catalyst system is disclosed. The catalyst system includes a bulky ligand metallocene catalyst compound, preferably containing a single cyclopentadienyl or substituted cyclopentadienyl-type ring system, a Group 13 element containing first modifier, and a cycloalkadiene second modifier. The present invention also provides a process for polymerizing olefin(s) utilizing the catalyst systems described herein.
摘要翻译：公开了聚合催化剂体系和制备催化剂体系的方法。催化剂体系包括体积庞大的配位金属茂催化剂化合物，优选含有单个环戊二烯基或取代的环戊二烯基型环系，含有第13族元素的第一改性剂和环二烯二烯改性剂。本发明还提供了利用本文所述的催化剂体系聚合烯烃的方法。

4. 发明授权

US06552137B1 Catalyst system and its use in olefin polymerization 失效
公开(公告)号：US06552137B1
公开(公告)日：2003-04-22
申请号：US09714371
申请日：2000-11-16
申请人： Sun-Chueh Kao , Jaimes Sher , Frederick J. Karol
发明人： Sun-Chueh Kao , Jaimes Sher , Frederick J. Karol
IPC分类号： C08F464
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/6592 , Y10S526/943 , C08F4/65912 , C08F210/14 , C08F2500/03
摘要： A polymerization catalyst system and a method for preparing the catalyst system is disclosed. The catalyst system includes a bulky ligand metallocene catalyst compound, preferably containing a single cyclopentadienyl or substituted cyclopentadienyl-type ring system, a Group 13 element containing first modifier, and a cycloalkadiene second modifier. The present invention also provides a process for polymerizing olefin(s) utilizing the catalyst systems described herein.

5. 发明授权

US5200502A Deactivator reagent for olefin polymerization catalysts 失效
标题翻译：用于烯烃聚合催化剂的去活剂试剂
公开(公告)号：US5200502A
公开(公告)日：1993-04-06
申请号：US935197
申请日：1992-08-26
申请人： Sun-Chueh Kao , Frederick J. Karol
发明人： Sun-Chueh Kao , Frederick J. Karol
IPC分类号： C08F2/42 , C08F2/38 , C08F6/00 , C08F6/02 , C08F6/06 , C08F10/00
CPC分类号： C08F6/02 , C08F10/00 , Y10S526/901
摘要： A method is disclosed for controlling the activity of or deactivating a transition element olefin polymerization catalyst by contacting the catalyst with a 1,2-diether organic compound.

6. 发明授权

US4923938A Catalyst for regulating the molecular weight distribution of ethylene polymers 失效
标题翻译：用于调节乙烯聚合物分子量分布的催化剂
公开(公告)号：US4923938A
公开(公告)日：1990-05-08
申请号：US339590
申请日：1989-04-14
申请人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
发明人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
IPC分类号： C08F10/00
CPC分类号： C08F10/00
摘要： A vanadium-based catalyst is treated with certain oxygen-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.
摘要翻译：用某些含氧化合物处理钒基催化剂作为缩小并有效调节用催化剂生产的聚合物的分子量分布的手段。

7. 发明授权

US4886771A Catalyst for regulating the molecular weight distribution of ethylene polymers 失效
标题翻译：用于调节乙烯聚合物分子量分布的催化剂
公开(公告)号：US4886771A
公开(公告)日：1989-12-12
申请号：US214581
申请日：1988-07-01
申请人： Sun-Chueh Kao , Frederick J. Karol
发明人： Sun-Chueh Kao , Frederick J. Karol
IPC分类号： C08F4/60 , C08F4/68 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00
摘要： A vanadium-based catalyst is treated with certain phosphorus-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.

8. 发明授权

US5288933A Process for the production of polyethylene 失效
标题翻译：聚乙烯生产工艺
公开(公告)号：US5288933A
公开(公告)日：1994-02-22
申请号：US868860
申请日：1992-04-16
申请人： Sun-Chueh Kao , Frederick J. Karol
发明人： Sun-Chueh Kao , Frederick J. Karol
IPC分类号： C08F4/655 , C08F10/02 , C07C2/36
CPC分类号： C08F10/02
摘要： A process for the polymerization of ethylene or a mixture comprising ethylene and one or more alpha-olefins and, optionally, a diene, comprising passing, under polymerization conditions, the aforementioned monomer(s) into contact with a catalyst system comprising:(a) the reaction product of(i) a titanium based catalyst precursor having the formula Mg.sub.a Ti(OR).sub.b X.sub.c (ED).sub.d whereinED is an inside electron donor comprising a mixture of (A) about 1 to about 80 mole percent of an alkyl, alkoxy, aryl, or aryloxy phosphine oxide, or mixtures thereof, and (B) about 20 to about 99 mole percent of an organic ester, ether, or ketone, or mixtures thereof, said phosphine oxide also being present in a molar ratio of phosphine oxide to titanium of 0.1:1 to 8:1;R is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms of COR' wherein R' is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms;each OR group is the same or different;each X is independently chlorine, bromine, or iodine;wherein component (a) is impregnated into an inorganic support; and(b) a hydrocarbyl aluminum cocatalyst.
摘要翻译：一种乙烯聚合方法或包含乙烯和一种或多种α-烯烃和任选的二烯的混合物的方法，包括在聚合条件下使上述单体与催化剂体系接触，所述催化剂体系包含：（a）（i）具有式MgaTi（OR）bXc（ED）d的钛基催化剂前体的反应产物，其中ED是内电子供体，其包含（A）约1至约80摩尔％的烷基，烷氧基，芳基或芳氧基氧化膦或其混合物，和（B）约20至约99摩尔％的有机酯，醚或酮或其混合物，所述氧化膦也以氧化膦的摩尔比存在至0.1：1至8：1的钛; R是具有1至14个碳原子的COR'的脂族或芳族烃基，其中R'是具有1至14个碳原子的脂族或芳族烃基; 每个OR组相同或不同; 每个X独立地是氯，溴或碘; 其中组分（a）被浸渍到无机载体中; 和（b）烃基铝助催化剂。

9. 发明授权

US5030605A Catalyst for regulating the molecular weight distribution of ethylene polymers 失效
标题翻译：用于调节乙烯聚合物分子量分布的催化剂
公开(公告)号：US5030605A
公开(公告)日：1991-07-09
申请号：US459382
申请日：1989-12-29
申请人： Sun-Chueh Kao , Frederick J. Karol
发明人： Sun-Chueh Kao , Frederick J. Karol
IPC分类号： C08F4/68 , C08F4/60 , C08F4/635 , C08F10/00
CPC分类号： C08F10/00
摘要： A vanadium-based catalyst is treated with certain alkylaluminum alkoxide compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.

10. 发明授权

US4999327A Catalyst for regulating the molecular weight distribution of ethylene polymers 失效
公开(公告)号：US4999327A
公开(公告)日：1991-03-12
申请号：US292268
申请日：1988-12-30
申请人： Sun-Chueh Kao , Frederick J. Karol
发明人： Sun-Chueh Kao , Frederick J. Karol
IPC分类号： C08F4/60 , C08F4/68 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00
摘要： A vanadium-based catalyst is treated with certain silicon-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式