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1. 发明授权

US4640748A Polyisothianaphtene, a new conducting polymer 失效
标题翻译： Polyisothianaphtene，一种新的导电聚合物
公开(公告)号：US4640748A
公开(公告)日：1987-02-03
申请号：US736984
申请日：1985-05-22
申请人： Fred Wudl , Masao Kobayashi , Alan Heeger
发明人： Fred Wudl , Masao Kobayashi , Alan Heeger
IPC分类号： C08G61/12 , C09K9/02 , G02F1/15 , H01B1/12 , H01M4/60 , C25C1/00
CPC分类号： C08G61/123 , C09K9/02 , G02F1/15 , H01B1/127 , H01M4/60
摘要： A polymer having an isothianaphthene structure represented by the formula (Ia) and/or Ib): ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a hydrocarbon residue having 1 to 5 carbon atoms such as methyl, methoxy and thiomethyl, with the proviso that R.sup.1 and R.sup.2 may link together to form, along with the benzene ring, a fused ring which is naphthalene; X is sulfur, selenium or tellurium; Y.sup.- represents an anion of an electrolyte; z represents a number from 0.01 to 1 showing a ratio of the anion per mol of a monomer; and n represents a number of from 5 to 500 showing a degree of polymerization.An electrochromic display wherein a high molecular weight conductive membrane formed on a conductive transparent base is used as a display base and an opposing electrode is arranged thereunder via a liquid electrolyte, which is characterized in that said high molecular weight conductive membrane is a polymer having an isothianaphthene structure and capable of being reversibly oxidized or reduced.
摘要翻译：具有由式（Ia）和/或Ib）表示的异硫茚结构的聚合物：其中R 1和R 2各自表示氢原子或具有1至5个碳原子的烃残基如甲基，甲氧基和硫代甲基，条件是R1和R2可以连接在一起，与苯环一起形成为萘的稠环; X是硫，硒或碲; Y-表示电解质的阴离子; z表示0.01〜1的数，表示每摩尔单体的阴离子比; n表示聚合度为5〜500的数。一种电致变色显示器，其中形成在导电透明基底上的高分子量导电膜用作显示基底，并且相对电极经由液体电解质布置在其下方，其特征在于所述高分子量导电膜是具有异硫茚结构并能够被可逆地氧化或还原。

2. 发明授权

US4772940A Polymer having isothianaphthene structure and electrochromic display 失效
标题翻译：具有异硫茚结构和电致变色显示的聚合物
公开(公告)号：US4772940A
公开(公告)日：1988-09-20
申请号：US937115
申请日：1986-12-02
申请人： Fred Wudl , Alan Heeger , Masao Kobayashi
发明人： Fred Wudl , Alan Heeger , Masao Kobayashi
IPC分类号： C08G61/12 , C09K9/02 , G02F1/15 , H01B1/12 , H01M4/60 , H04N9/30
CPC分类号： H01B1/127 , C08G61/123 , C09K9/02 , G02F1/15 , H01M4/60
摘要： An electrochromic display device is provided in which a high molecular weight conductive membrane is formed on a conductive, transparent base, and an opposing electrode is arranged thereunder via a liquid electrolyte. The conductive, electrochromic membrane is a polyisothianaphthene, a chemically and physically stable material which gives the device superior electrochromic switching characteristics, including a fast response time and a high contrast color change upon oxidation and reduction. Other applications which rely on the electrochromic properties of the polyisothianaphthene are disclosed as well.
摘要翻译：提供了一种电致变色显示装置，其中在导电透明基底上形成高分子量导电膜，并且通过液体电解质在其下方布置相对电极。导电的电致变色膜是聚异硫茚，化学和物理稳定的材料，使得器件具有优异的电致变色开关特性，包括在氧化和还原时的快速响应时间和高对比度的颜色变化。还公开了依赖于多异硫茚的电致变色性质的其它应用。

3. 发明授权

US5863981A Electrically conducting water-soluble self-doping polyaniline polymers and the aqueous solutions thereof 失效
标题翻译：导电水溶性自掺杂聚苯胺聚合物及其水溶液
公开(公告)号：US5863981A
公开(公告)日：1999-01-26
申请号：US409509
申请日：1995-03-23
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G73/00
CPC分类号： C08G73/00
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
摘要翻译：一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。还提供导电两性离子聚合物，以及可用于制备聚合物的单体和包含聚合物的电极。

4. 发明授权

US5760169A Self-doped polymers 失效
公开(公告)号：US5760169A
公开(公告)日：1998-06-02
申请号：US473062
申请日：1995-06-07
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G61/12 , G02F1/155 , H01B1/12 , H01M4/60 , C08G75/00 , C08G73/06
CPC分类号： H01M4/60 , C08G61/123 , G02F1/155 , H01B1/127
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.

5. 发明授权

US5367041A Self-doped zwitterionic polymers 失效
标题翻译：自掺杂的两性离子聚合物
公开(公告)号：US5367041A
公开(公告)日：1994-11-22
申请号：US636914
申请日：1991-01-02
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G61/00 , C08G73/00 , C08G83/00 , G02F1/155 , H01B1/12 , H01M4/60
CPC分类号： C08G83/00 , C08G61/00 , C08G73/00 , G02F1/155 , H01B1/127 , H01M4/60
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
摘要翻译：一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。还提供导电两性离子聚合物，以及可用于制备聚合物的单体和包含聚合物的电极。

6. 发明授权

US5310781A Self-doped polymers from polyaniline with bronsted acid groups 失效
标题翻译：具有布朗斯特酸基团的聚苯胺的自掺杂聚合物
公开(公告)号：US5310781A
公开(公告)日：1994-05-10
申请号：US616743
申请日：1990-11-16
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G61/00 , C08G73/00 , G02F1/155 , H01B1/12 , H01M4/60
CPC分类号： C08G61/00 , C08G73/00 , G02F1/155 , H01B1/127 , H01M4/60
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
摘要翻译：一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。还提供导电两性离子聚合物，以及可用于制备聚合物的单体和包含聚合物的电极。

7. 发明授权

US5569708A Self-doped polymers 失效
标题翻译：自掺杂聚合物
公开(公告)号：US5569708A
公开(公告)日：1996-10-29
申请号：US297589
申请日：1994-08-29
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G61/12 , C08G73/00 , C08G83/00 , G02F1/15 , G02F1/155 , H01B1/12 , H01M4/60 , C08K3/00
CPC分类号： C08G61/123 , C08G73/00 , C08G83/00 , G02F1/1525 , G02F1/155 , H01B1/127 , H01M4/60
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
摘要翻译：一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。还提供导电两性离子聚合物，以及可用于制备聚合物的单体和包含聚合物的电极。

8. 发明授权

US5418047A Conductive articles of intractable polymers 失效
标题翻译：难溶性聚合物的导电制品
公开(公告)号：US5418047A
公开(公告)日：1995-05-23
申请号：US108189
申请日：1993-08-17
申请人： Paul Smith , Alan Heeger , Fred Wudl , Jin Chiang
发明人： Paul Smith , Alan Heeger , Fred Wudl , Jin Chiang
IPC分类号： C08J5/00 , C08G73/02 , C08J5/18 , H01B1/12 , B32B5/00 , H01B1/04 , H01B1/06 , H01M4/60
CPC分类号： H01B1/128 , C08G73/0266 , H01B1/125 , Y10T428/24 , Y10T428/24942 , Y10T428/2913 , Y10T428/2929 , Y10T428/31855 , Y10T428/31913
摘要： Conducting articles such as fibers, films, tapes and the like are fabricated from intractable conducting polymers such as polyacetylene. The articles are prepared by (a) forming a gel of a carrier polymer in a compatible solvent, (b) polymerizing, within the gel, a selected monomer, and (c) doping the article so provided. The articles are highly electrically conductive as well as mechanically quite strong.
摘要翻译：诸如纤维，薄膜，胶带等的导电制品由难溶的导电聚合物如聚乙炔制成。制品通过（a）在相容的溶剂中形成载体聚合物的凝胶，（b）在凝胶内聚合所选择的单体，和（c）掺入所提供的制品。这些物品具有很高的导电性和机械性能。

9. 发明授权

US5342912A Self-doped zwitterionic aniline polymers 失效
标题翻译：自掺杂的两性离子苯胺聚合物
公开(公告)号：US5342912A
公开(公告)日：1994-08-30
申请号：US636915
申请日：1991-01-02
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G61/12 , C08G73/00 , C08G83/00 , G02F1/15 , G02F1/155 , H01B1/12 , H01M4/60
CPC分类号： C08G61/123 , C08G73/00 , C08G83/00 , G02F1/1525 , G02F1/155 , H01B1/127 , H01M4/60
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
摘要翻译：一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。还提供导电两性离子聚合物，以及可用于制备聚合物的单体和包含聚合物的电极。

10. 发明授权

US5891968A Method of making self-doped zwitterionic heterocyclic polymers 失效
标题翻译：制造自掺杂的两性离子杂环聚合物的方法
公开(公告)号：US5891968A
公开(公告)日：1999-04-06
申请号：US477186
申请日：1995-06-07
申请人： Fred Wudl , Alan Heeger
发明人： Fred Wudl , Alan Heeger
IPC分类号： C08G73/00 , C08G75/00
CPC分类号： C08G73/00 , C08G75/00
摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided. as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
摘要翻译：一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。还提供了导电两性离子聚合物。以及可用于制备聚合物的单体和包含聚合物的电极。

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