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1. 发明申请

US20060107876A1 Glycol-functional siloxane mixture 审中-公开
标题翻译：乙二醇官能的硅氧烷混合物
公开(公告)号：US20060107876A1
公开(公告)日：2006-05-25
申请号：US11282143
申请日：2005-11-18
申请人： Frank Sandmeyer , Georg Loessel , Dieter Gerhardinger
发明人： Frank Sandmeyer , Georg Loessel , Dieter Gerhardinger
IPC分类号： C04B28/14 , C04B11/00
CPC分类号： C04B24/42 , C04B28/14 , C04B2111/27 , C04B22/062
摘要： Water-repellent gypsum compositions of components (A) 100 parts by weight of gypsum (B) 0.05-50 parts by weight of oxide and/or hydroxide or alkali and/or alkaline earth metals (C) 0.05-20 parts by weight of glycol-functional siloxane mixture, preparable by the reaction of 1 mole of alkyltrihalosilane or alkyltrialkoxysilane with at least 2.5 moles of a glycol or mixture of glycols, exhibit water repellancy similar to gypsum which has been hydrophobed with H-siloxane.
摘要翻译：组分（A）的拒水石膏组合物100重量份石膏（B）0.05-50重量份的氧化物和/或氢氧化物或碱金属和/或碱土金属（C）0.05-20重量份的二醇功能性硅氧烷混合物可通过1摩尔烷基三卤硅烷或烷基三烷氧基硅烷与至少2.5摩尔二醇或二醇的混合物的反应制备，具有类似于用H-硅氧烷疏水化的石膏的防水性。

2. 发明授权

US06486338B1 Preparation of organosilicon compounds containing &agr;, &bgr;-unsaturated carboxylic acids 失效
标题翻译：制备含有α，β-不饱和羧酸的有机硅化合物
公开(公告)号：US06486338B1
公开(公告)日：2002-11-26
申请号：US09491034
申请日：2000-01-25
申请人： Eckhard Hanelt , Frank Sandmeyer , Norman Häberle , Wolfram Schindler
发明人： Eckhard Hanelt , Frank Sandmeyer , Norman Häberle , Wolfram Schindler
IPC分类号： C02F708
CPC分类号： C09K19/408 , C07F7/0879 , C07F7/0889 , C07F7/14 , C08G77/045
摘要： Organosilicon compounds (P) containing &agr;,&bgr;-unsaturated carboxylic acid radicals, of the general formula (1) —A—O—C(O)—CR═CH2 (1), are prepared by a process in which, in a first step, organosilicon compounds (H) containing hydrogen atoms bonded directly to silicon are reacted with olefinically unsaturated compounds (U) containing a terminal double or triple bond, of the general formula (2) &OHgr;—O—C(O)—CRH—CH2—Z (2), in the presence of metals or compounds from the platinum group as catalyst, to give organosilicon compounds (E) containing radicals of the general formula (3) —A—O—C(O)—CRH—CH2—Z (3), and, in a second step, H—Z compounds are eliminated from organosilicon compounds (E), where A is a divalent organic radical, &OHgr; is a monovalent organic radical containing a terminal double or triple bond, R is an H atom or a methyl radical, and Z is Cl, I, Br or 4-methyltoluenesulfonyl.
摘要翻译：通过以下方法制备含有通式（1）的α，β-不饱和羧酸基团的有机硅化合物（P），其中在第一步中，将含有与硅直接键合的氢原子的有机硅化合物（H）与在由铂族作为催化剂的金属或化合物存在下，通式（2）所示的含有末端双键或三键的烯属不饱和化合物（U），得到含有通式（3）的基团的有机硅化合物（E）），并且在第二步中，从有机硅化合物（E）中除去HZ化合物，其中A是二价有机基团，OMEGA是含有末端双键或三键的单价有机基团，R是H原子或甲基基团，且Z为Cl，I，Br或4-甲基甲苯磺酰基。

3. 发明授权

US08409710B2 Particles with structured surface 失效
标题翻译：具有结构化表面的颗粒
公开(公告)号：US08409710B2
公开(公告)日：2013-04-02
申请号：US13105265
申请日：2011-05-11
申请人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
发明人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
IPC分类号： B32B5/16
CPC分类号： C08K9/08 , C08J3/03 , C08J2383/04 , C08K9/02 , C08L83/04 , C09D7/65 , Y10S524/923 , Y10T428/24372 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： Particles with a structural surface which are useful to produce abrasion resistant self-cleaning surfaces contain particulate solid particles having a superstructured overlayer of fine particles. The particles may be prepared by polymerizing a polymerizable siloxane, silane, or mixture thereof in a Pickering emulsion.
摘要翻译：具有可用于制造耐磨自清洁表面的结构表面的颗粒包含具有细颗粒的超结构覆盖层的颗粒状固体颗粒。可以通过在Pickering乳液中聚合可聚合硅氧烷，硅烷或其混合物来制备颗粒。

4. 发明授权

US07972696B2 Particles with structured surface 失效
标题翻译：具有结构化表面的颗粒
公开(公告)号：US07972696B2
公开(公告)日：2011-07-05
申请号：US12295456
申请日：2007-03-16
申请人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
发明人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
IPC分类号： B32B5/16 , B32B9/00 , B60C1/00 , C08K3/34 , C08K9/04 , C08K9/02 , A61K6/083 , C08G77/06 , C08G77/00 , B01F3/12
CPC分类号： C08K9/08 , C08J3/03 , C08J2383/04 , C08K9/02 , C08L83/04 , C09D7/65 , Y10S524/923 , Y10T428/24372 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： Particles with a structural surface which are useful to produce abrasion resistant self-cleaning surfaces contain particulate solid particles having a superstructured overlayer of fine particles. The particles may be prepared by polymerizing a polymerizable siloxane, silane, or mixture thereof in a Pickering emulsion.
摘要翻译：具有可用于制造耐磨自清洁表面的结构表面的颗粒包含具有细颗粒的超结构覆盖层的颗粒状固体颗粒。可以通过在Pickering乳液中聚合可聚合硅氧烷，硅烷或其混合物来制备颗粒。

5. 发明申请

US20100160590A1 SILICONE RESINS HAVING A DEFINED REACTIVITY 审中-公开
标题翻译：具有定义反应性的硅树脂
公开(公告)号：US20100160590A1
公开(公告)日：2010-06-24
申请号：US11993231
申请日：2006-06-22
申请人： Frank Sandmeyer , Hans Mayer
发明人： Frank Sandmeyer , Hans Mayer
IPC分类号： C08G77/00
CPC分类号： C08G77/38 , C08G77/08
摘要： Reactivity of silicone resins containing silanol functionality is enhanced by including HCl in the resin.
摘要翻译：含有硅烷醇官能度的有机硅树脂的反应性通过在树脂中包含HCl来增强。

6. 发明授权

US07674868B2 Copolymers containing nanoparticles 失效
标题翻译：含纳米颗粒的共聚物
公开(公告)号：US07674868B2
公开(公告)日：2010-03-09
申请号：US11722567
申请日：2005-12-22
申请人： Oliver Minge , Richard Weidner , Frank Sandmeyer , Hans-Peter Weitzel
发明人： Oliver Minge , Richard Weidner , Frank Sandmeyer , Hans-Peter Weitzel
IPC分类号： C08F230/08
CPC分类号： C09C1/3081 , C01P2004/64 , C08F2/22 , C08F4/40 , C08F218/08 , C08F220/14 , C08F220/18 , C08F230/08 , C08F283/12 , C08F292/00 , C08L51/085 , C09D133/06 , Y10T428/2995 , Y10T428/2998 , C08L2666/02
摘要： The invention provides copolymers of ethylenically unsaturated monomers and of ethylenically functionalized nanoparticles in the form of their aqueous polymer dispersions or water-redispersible polymer powders, obtainable by means of free-radically initiated polymerization in an aqueous medium and, if desired, subsequent drying of the resultant polymer dispersion, ofA) one or more monomers from the group consisting of vinyl esters, (meth)acrylic esters, vinylaromatics, olef ins, 1,3-dienes, vinyl ethers and vinyl halides and, if desired, further monomers copolymerizable therewith, in the presence ofB) at least one particle P having an average diameter of ≦1000 nm, which is functionalized with ethylenically unsaturated, free-radically polymerizable groups, characterized in thatB2) particles P used are one or more from the group of metal oxides and semimetal oxides, and/orB2) particles P used are silicone resins composed of repeating units of the general formula [R4(p+Z)SiO(4−p−Z)/2] (II), where for at least 20 mol % of the respective silicone resin p+z=0, 1 or 3,and where B1) and B2) are each functionalized with one or more α-organosilanes of the general formula (R1O)3−(R2)nSi—(CR32)—X (I), where X is a radical having 2 to 20 hydrocarbon atoms and containing an ethylenically unsaturated group.
摘要翻译：本发明提供烯键式不饱和单体和烯属官能化纳米颗粒的共聚物，其形式为它们的水性聚合物分散体或水分可再分散聚合物粉末，其通过在水性介质中自由引发聚合获得，并且如果需要，随后干燥得到的聚合物分散体A）一种或多种由乙烯基酯，（甲基）丙烯酸酯，乙烯基芳烃，烯烃，1,3-二烯，乙烯基醚和乙烯基卤化物组成的组中的单体，如果需要，可与其共聚的其它单体在B存在的情况下，至少一个具有平均直径为＆nlE; 1000nm的颗粒P，其被烯键式不饱和的可自由基聚合的基团官能化，其特征在于所用的B2）颗粒P是一个或多个基团的金属氧化物和半金属氧化物，和/或B2）颗粒P是由通式[R4（p + Z）SiO（4-p）的重复单元构成的硅氧烷树脂 -Z）/ 2]（II），其中对于至少20mol％的各有机硅树脂p + z = 0,1或3，并且其中B1）和B2）各自被一个或多个α-有机硅烷官能化通式（R1O）3-（R2）nSi-（CR32）-X（I），其中X是具有2至20个烃原子且含有烯属不饱和基团的基团。

7. 发明申请

US20110268919A1 Particles With Structured Surface 失效
标题翻译：结构表面颗粒
公开(公告)号：US20110268919A1
公开(公告)日：2011-11-03
申请号：US13105265
申请日：2011-05-11
申请人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
发明人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
IPC分类号： B32B3/00 , C09D183/06 , C08G77/38
CPC分类号： C08K9/08 , C08J3/03 , C08J2383/04 , C08K9/02 , C08L83/04 , C09D7/65 , Y10S524/923 , Y10T428/24372 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： Particles with a structural surface which are useful to produce abrasion resistant self-cleaning surfaces contain particulate solid particles having a superstructured overlayer of fine particles. The particles may be prepared by polymerizing a polymerizable siloxane, silane, or mixture thereof in a Pickering emulsion.
摘要翻译：具有可用于制造耐磨自清洁表面的结构表面的颗粒包含具有细颗粒的超结构覆盖层的颗粒状固体颗粒。可以通过在Pickering乳液中聚合可聚合硅氧烷，硅烷或其混合物来制备颗粒。

8. 发明申请

US20090176920A1 PARTICLES WITH STRUCTURED SURFACE 失效
标题翻译：具有结构表面的颗粒
公开(公告)号：US20090176920A1
公开(公告)日：2009-07-09
申请号：US12295456
申请日：2007-03-16
申请人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
发明人： Frank Sandmeyer , Herbert Barthel , Torsten Gottschalk-Gaudig
IPC分类号： C08L83/00 , C08L83/04 , C08K3/22 , C08K3/36 , C09D183/00
CPC分类号： C08K9/08 , C08J3/03 , C08J2383/04 , C08K9/02 , C08L83/04 , C09D7/65 , Y10S524/923 , Y10T428/24372 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： Particles with a structural surface which are useful to produce abrasion resistant self-cleaning surfaces contain particulate solid particles having a superstructured overlayer of fine particles. The particles may be prepared by polymerizing a polymerizable siloxane, silane, or mixture thereof in a Pickering emulsion.
摘要翻译：具有可用于制造耐磨自清洁表面的结构表面的颗粒包含具有细颗粒的超结构覆盖层的颗粒状固体颗粒。可以通过在Pickering乳液中聚合可聚合硅氧烷，硅烷或其混合物来制备颗粒。

9. 发明申请

US20120142844A1 Aqueous hybrid binder for jointing mortars 审中-公开
标题翻译：用于连接砂浆的水性混合粘合剂
公开(公告)号：US20120142844A1
公开(公告)日：2012-06-07
申请号：US13302681
申请日：2011-11-22
申请人： Frank Sandmeyer , Dominik Auer
发明人： Frank Sandmeyer , Dominik Auer
IPC分类号： C04B26/06 , B82Y30/00
CPC分类号： C04B26/06 , B82Y30/00 , C04B2111/00008 , C04B2111/00672 , C04B2111/2076 , C08F2/22 , C08F2/44 , C08F220/14 , C08F220/18 , C08G77/70 , C04B14/06 , C04B14/066 , C04B20/0076 , C04B20/008 , C04B24/42
摘要： A process for preparing jointing mortar includes using copolymers of ethylenically unsaturated monomers and of ethylenically functionalized nanoparticles in the form of their aqueous polymer dispersions or water-redispersible polymer powders. The copolymers are obtained by means of free-radically initiated polymerization in aqueous medium, and optionally subsequent drying of the resultant polymer dispersion, of A) one or more unsaturated monomers in the presence of B) at least one particle P having an average diameter of ≦1000 nm and functionalized with ethylenically unsaturated, free-radically polymerizable groups.
摘要翻译：制备接合砂浆的方法包括使用烯键式不饱和单体和烯属官能化纳米颗粒的共聚物以其聚合物水分散体或水分散性聚合物粉末的形式。共聚物通过在水性介质中的自由基引发聚合获得，并且任选地随后干燥所得聚合物分散体，A）一种或多种不饱和单体在B存在下将至少一种平均粒径为＆nlE; 1000nm，并用烯键式不饱和，可自由基聚合的基团官能化。

10. 发明申请

US20080146743A1 Copolymers Containing Nanoparticles 失效
标题翻译：含有纳米粒子的共聚物
公开(公告)号：US20080146743A1
公开(公告)日：2008-06-19
申请号：US11722567
申请日：2005-12-22
申请人： Oliver Minge , Richard Weidner , Frank Sandmeyer , Hans-Peter Weitzel
发明人： Oliver Minge , Richard Weidner , Frank Sandmeyer , Hans-Peter Weitzel
IPC分类号： C08F261/00
CPC分类号： C09C1/3081 , C01P2004/64 , C08F2/22 , C08F4/40 , C08F218/08 , C08F220/14 , C08F220/18 , C08F230/08 , C08F283/12 , C08F292/00 , C08L51/085 , C09D133/06 , Y10T428/2995 , Y10T428/2998 , C08L2666/02
摘要： Copolymers of ethylenically unsaturated monomers and ethylenically functionalized nanoparticles in the form of aqueous polymer dispersions or water-redispersible polymer powders, are obtained by aqueous free-radically polymerizing and optionally drying a copolymerizate of,A) one or more ethylenically unsaturated monomers in the presence of B) particles having an average diameter of ≦1000 nm, functionalized with ethylenically unsaturated, free-radically polymerizable groups, wherein B1) particles are metal oxides or semimetal oxides, and/or B2) particles are silicone resins and where B1) and B2) are functionalized with one or more α-organosilanes of the formula (R1O)3−n(R2)nSi—(CR32)—X (I), where X is a radical having 2 to 20 hydrocarbon atoms containing an ethylenically unsaturated group.
摘要翻译：通过水溶液自由基聚合和任选地干燥A）一种或多种烯键式不饱和单体的共聚物，在存在下共聚物的情况下获得烯键式不饱和单体和烯键式官能化纳米颗粒的聚合物分散体或水可再分散聚合物粉末形式的共聚物 B）具有平均直径<= 1000nm的颗粒，用烯属不饱和的可自由基聚合的基团官能化，其中B1）颗粒是金属氧化物或半金属氧化物，和/或B2）颗粒是有机硅树脂，其中B1）和B2 ）用一种或多种下式的α-有机硅烷（R 1 O 3）3-n（R 2）n n进行官能化 X（I），其中X是含有烯属不饱和基团的具有2-20个烃基的基团。

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