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1. 发明申请

US20080221272A1 Polymer Material Comprising Chains Bearing Imidazolidone Functions 审中-公开
标题翻译：包含咪唑啉酮功能的链条的聚合物材料
公开(公告)号：US20080221272A1
公开(公告)日：2008-09-11
申请号：US11631690
申请日：2005-07-06
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： C08F8/30 , C08G63/91
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material. The inventive polymer material can be extruded, co-extruded, injected, blown, moulded, overmoulded, calandered, thermoformed. It can be used to produce articles such as tubes, films, plates, extruded strings, bottles, containers. The inventive polymer material can also be mixed with other materials such as other polymers, thus it is used for example as impact modifier or rheology regulator. The invention further concerns the use of said polymer material as compatibility agent in a composition comprising among others at least two polymers belonging to different classes of polymers.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种或多种能够被氢键和一个或多个能够与聚合物骨架形成共价键的反应性基团结合的更多缔合基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均为1〜 10个咪唑烷酮基团。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。本发明的聚合物材料可以挤出，共挤出，注射，吹塑，模塑，包覆成型，压延，热成型。它可用于生产诸如管，薄膜，板，挤压线，瓶，容器等物品。本发明的聚合物材料也可以与其它材料如其它聚合物混合，因此其用作例如抗冲改性剂或流变调节剂。本发明还涉及所述聚合物材料作为相容剂在包含至少两种属于不同类型聚合物的聚合物的组合物中的用途。

2. 发明授权

US08252872B2 Polymer material containing chains bearing imidazolidone functions 有权
标题翻译：含有咪唑烷酮功能的链的聚合物材料
公开(公告)号：US08252872B2
公开(公告)日：2012-08-28
申请号：US12878383
申请日：2010-09-09
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： C08F8/30 , C08F8/32 , C08G69/48 , C08L77/00
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种，一种或更多的能够被氢键结合的缔合基团和一个或多个能够与聚合物骨架形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均负载，每链1至10个咪唑烷酮基。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。

3. 发明申请

US20110135859A1 POLYMER MATERIAL CONTAINING CHAINS BEARING IMIDAZOLIDONE FUNCTIONS 有权
标题翻译：含有IMIDAZOLIDONE功能的聚合物材料
公开(公告)号：US20110135859A1
公开(公告)日：2011-06-09
申请号：US12878383
申请日：2010-09-09
申请人： Francois-Genes TOURNILHAC , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes TOURNILHAC , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： B32B1/08 , C08G69/48 , C08L77/00 , B32B1/02
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种，一种或更多的能够被氢键结合的缔合基团和一个或多个能够与聚合物骨架形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均负载，每链1至10个咪唑烷酮基。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。

4. 发明授权

US08188293B2 Elastic materials 有权
标题翻译：弹性材料
公开(公告)号：US08188293B2
公开(公告)日：2012-05-29
申请号：US11815982
申请日：2006-02-14
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
IPC分类号： C07D403/12
CPC分类号： C08L101/025 , C08F8/30 , C08F8/34 , C08G83/008
摘要： The present invention relates to materials exhibiting the property of rubbery elasticity, consisting of molecules with a mass of between 9 and 9000 g/mol, all or some of the molecules having at least three groups (also referred to as “associative groups”) capable of associating via non-covalent interactions.Although consisting of small non-polymerized molecules that are not chemically crosslinked, this material exhibits properties of rubbery elasticity. According to an embodiment of the invention, this material exhibits rubbery elasticity at ambient temperature. Above a certain temperature, the material flows like a simple liquid. The material is thermoreversible, i.e. after cooling, the material again exhibits the property of rubbery elasticity. This material is self-repairing and potentially recyclable, which is never the case with a chemically crosslinked elastomer.According to an embodiment of the invention, the molecules constituting the material of the invention bear associative groups of formula (1) below: in which A denotes oxygen, sulphur or NH; the carbon atoms of formula (1) can be substituted. Preferably, A denotes oxygen. Advantageously, the material comprises (i) molecules having at least 3 associative groups, and (ii) molecules having a single associative group. Advantageously, the molecules are obtained from fatty acid derivatives.
摘要翻译：本发明涉及具有弹性弹性的材料，由质量介于9至9000g / mol的分子组成，全部或部分分子具有至少三个基团（也称为“缔合基团”），其能够通过非共价相互作用关联。虽然由不是化学交联的小的非聚合分子组成，但是该材料表现出橡胶弹性的性质。根据本发明的一个实施方案，该材料在环境温度下表现出橡胶弹性。在一定温度以上，材料就像液体一样流动。材料是热可逆的，即在冷却之后，材料再次表现出橡胶弹性的性质。这种材料是自修复和潜在可循环利用的，化学交联的弹性体永远不会这样。根据本发明的一个实施方案，构成本发明材料的分子具有下式（1）的缔合基团：其中A表示氧，硫或NH; 式（1）的碳原子可以被取代。优选地，A表示氧。有利地，该材料包含（i）具有至少3个缔合基团的分子，和（ii）具有单个缔合基团的分子。有利地，分子从脂肪酸衍生物获得。

5. 发明申请

US20090062551A1 ELASTIC MATERIALS 有权
标题翻译：弹性材料
公开(公告)号：US20090062551A1
公开(公告)日：2009-03-05
申请号：US11815982
申请日：2006-02-14
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
IPC分类号： C07D403/12
CPC分类号： C08L101/025 , C08F8/30 , C08F8/34 , C08G83/008
摘要： The present invention relates to materials exhibiting the property of rubbery elasticity, consisting of molecules with a mass of between 9 and 9000 g/mol, all or some of the molecules having at least three groups (also referred to as “associative groups”) capable of associating via non-covalent interactions.Although consisting of small non-polymerized molecules that are not chemically crosslinked, this material exhibits properties of rubbery elasticity. According to an embodiment of the invention, this material exhibits rubbery elasticity at ambient temperature. Above a certain temperature, the material flows like a simple liquid. The material is thermoreversible, i.e. after cooling, the material again exhibits the property of rubbery elasticity. This material is self-repairing and potentially recyclable, which is never the case with a chemically crosslinked elastomer.According to an embodiment of the invention, the molecules constituting the material of the invention bear associative groups of formula (1) below: in which A denotes oxygen, sulphur or NH; the carbon atoms of formula (1) can be substituted. Preferably, A denotes oxygen. Advantageously, the material comprises (i) molecules having at least 3 associative groups, and (ii) molecules having a single associative group.Advantageously, the molecules are obtained from fatty acid derivatives.
摘要翻译：本发明涉及具有弹性弹性的材料，由质量介于9至9000g / mol的分子组成，全部或部分分子具有至少三个基团（也称为“缔合基团”），其能够通过非共价相互作用关联。虽然由不是化学交联的小的非聚合分子组成，但是该材料表现出橡胶弹性的性质。根据本发明的一个实施方案，该材料在环境温度下表现出橡胶弹性。在一定温度以上，材料就像液体一样流动。材料是热可逆的，即在冷却之后，材料再次表现出橡胶弹性的性质。这种材料是自修复和潜在可循环利用的，化学交联的弹性体永远不会这样。根据本发明的一个实施方案，构成本发明材料的分子具有下式（1）的缔合基团：其中A表示氧，硫或NH; 式（1）的碳原子可以被取代。优选地，A表示氧。有利地，该材料包含（i）具有至少3个缔合基团的分子，和（ii）具有单个缔合基团的分子。有利地，分子从脂肪酸衍生物获得。

6. 发明申请

US20100135940A1 SEMI-CRYSTALLINE SUPRAMOLECULAR POLYMERS 有权
标题翻译：半结晶分子聚合物
公开(公告)号：US20100135940A1
公开(公告)日：2010-06-03
申请号：US12440308
申请日：2007-09-07
申请人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
发明人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
IPC分类号： C08G69/14 , C08L77/00 , A61K8/84 , A61Q19/02 , C09J179/04 , C08L95/00 , C09D11/10
CPC分类号： A61K8/84 , A61K2800/54 , A61Q19/00 , C08G69/00 , C09D177/00
摘要： The invention relates to a supramolecular polymer derived from the reaction between (i) an amine bearing a nitrogen-containing heterocyclic group: imidazolidone, trimethyleneurea or triazine, capable of joining together via hydrogen bonds with (ii) at least one fatty acid monomer comprising at least one reactive functional group, a dimer of identical or different fatty acids and/or a trimer of identical or different fatty acids, or a derivative of said fatty acid(s) chosen from a fatty acid ester, and a fatty acid chloride.
摘要翻译：本发明涉及一种超分子聚合物，其衍生自（i）带有含氮杂环基的胺：咪唑烷酮，三亚甲基脲或三嗪，其能够通过氢键与（ii）至少一种含有至少一个反应性官能团，相同或不同脂肪酸的二聚物和/或相同或不同脂肪酸的三聚体，或所述脂肪酸的衍生物，选自脂肪酸酯和脂肪酰氯。

7. 发明授权

US08916142B2 Semi-crystalline supramolecular polymers 有权
标题翻译：半结晶超分子聚合物
公开(公告)号：US08916142B2
公开(公告)日：2014-12-23
申请号：US12440308
申请日：2007-09-07
申请人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
发明人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
IPC分类号： A61K31/785 , A61K8/84 , A61Q19/00 , C09D177/00 , C08G69/00
CPC分类号： A61K8/84 , A61K2800/54 , A61Q19/00 , C08G69/00 , C09D177/00
摘要： The invention relates to a supramolecular polymer obtained from the reaction of (i) an amine bearing a nitrogen-containing heterocyclic group: imidazolidone, trimethyleneurea or triazine, which is capable of associating by means of hydrogen bonds and (ii) at least one fatty acid monomer comprising at least one reactive function, a dimer of identical or different fatty acids and/or a trimer of identical or different fatty acids, or a derivative of said fatty acid(s) which is selected from a fatty acid ester, and a fatty acid chloride.
摘要翻译：本发明涉及从（i）带有含氮杂环基的胺：咪唑烷酮，三亚甲基脲或三嗪的反应得到的超分子聚合物，其能够通过氢键缔合，和（ii）至少一种脂肪酸包含至少一种反应性官能团的单体，相同或不同脂肪酸的二聚体和/或相同或不同脂肪酸的三聚体或所述脂肪酸的衍生物，其选自脂肪酸酯和脂肪酸酰氯。

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