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    • 8. 发明申请
    • Swelling Inhibitors for Clays and Shales
    • 膨胀抑制剂用于粘土和页岩
    • US20090239771A1
    • 2009-09-24
    • US12441269
    • 2007-09-11
    • Franco FedericiLuigi MerliLaura ViganoLorena BottarelloThierry BossiGiuseppe Li Bassi
    • Franco FedericiLuigi MerliLaura ViganoLorena BottarelloThierry BossiGiuseppe Li Bassi
    • C09K8/22
    • C09K8/22C09K8/12C09K2208/12
    • Method for inhibiting the hydration of clays and shales during drilling operations comprising the use of a water base drilling fluid, which contains from 0.2 to 5% by weight of the condensation product of a dicarboxylic acid having 4 to 10 carbon atoms with alkanolamines, diamines or polyalkyleneamines of formula R′″R″N—R′—XH, where X is O or NR0; R0 is hydrogen or a linear or branched alkyl group having from 1 to 6 carbon atoms, R′ is a linear or branched, aliphatic or cicloaliphatic alkylene group having from 2 to 10 carbon atoms or R′ is R″″(NH—R″″)n where R″″ is ethylene or CH(CH3)CH2, n is a number from 1 to 6 and X is NR0; R″ and R′″ can be equal or different from one another and are hydrogen or a linear or branched alkyl group having from 1 to 6 carbon atoms, optionally substituted with a hydroxyl group, the condensation product being in neutral form or in the form of salt.
    • 用于在钻井操作期间抑制粘土和页岩水化的方法,包括使用水基钻井液,其含有0.2至5重量%的具有4至10个碳原子的二羧酸与链烷醇胺,二胺或二胺的缩合产物 式R“R''N-R'-XH的聚亚烷基二胺,其中X是O或NRO; R 0是氢或具有1至6个碳原子的直链或支链烷基,R'是具有2至10个碳原子的直链或支链,脂族或环脂族亚烷基或者R'是R“'(NH- R“')n,其中R”'是亚乙基或CH(CH 3)CH 2,n是1至6的数,X是NR 0; R“和R”可以彼此相同或不同,并且是氢或具有1-6个碳原子的直链或支链烷基,任选被羟基取代,缩合产物为中性形式或在 盐的形式。
    • 10. 发明授权
    • Glyoxal free purified cationic polygalactomannan
    • 无乙二醛纯化阳离子聚半乳甘露聚糖
    • US08580952B2
    • 2013-11-12
    • US12986785
    • 2011-01-07
    • Ugo PfeifferMauro TenconiEva BaldaroValentina LangellaGiovanni FloridiGiuseppe Li Bassi
    • Ugo PfeifferMauro TenconiEva BaldaroValentina LangellaGiovanni FloridiGiuseppe Li Bassi
    • C08B37/00C07H1/00C07H3/00
    • C08B37/0087C08B37/0096
    • A glyoxal and boron free purified cationic polygalactomannan may be prepared by reacting a polygalactomannan flour, a nonionically derivatized polygalactomannan flour, or a mixture thereof, with a cationising reagent, adjusting the pH to be from about 4 to about 6; cross-linking the cationic with glyoxal, and filtering and water washing the cationic polygalactomannan to produce a glyoxalated purified cationic polygalactomannan containing not more than 70% by weight of water. In some cases it may be desirable to introduce a buffering agent to the glyoxalated purified cationic polygalactomannan to regulate the pH to from 8.0 to about 9.5, when measured at 1% (dry matter) in water. In other cases, it may be desirable to remove water to produce glyoxal free purified cationic polygalactomannan in powder form. Such compounds are particularly useful in personal care products.
    • 乙二醛和无硼纯化的阳离子聚半乳甘露聚糖可以通过使聚半乳甘露聚糖粉末,非离子衍生化的聚半乳甘露聚糖粉末或其混合物与阳离子化试剂反应来制备,将pH调节至约4至约6; 将阳离子与乙二醛交联,并过滤并水洗阳离子聚半乳甘露聚糖以产生含有不超过70重量%水的乙二醛纯化阳离子聚半乳甘露聚糖。 在一些情况下,当在水中以1%(干物质)测量时,可能需要向乙醛酸化的纯化阳离子聚半乳甘露聚糖引入缓冲剂以将pH调节至8.0至约9.5。 在其他情况下,可能需要除去水以产生无乙醛酸的纯化的粉末形式的阳离子聚半乳甘露聚糖。 这些化合物特别适用于个人护理产品。