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1. 发明授权

US5360350A Sealant compositions and sealed electrical connectors 失效
标题翻译：密封剂组合物和密封电连接器
公开(公告)号：US5360350A
公开(公告)日：1994-11-01
申请号：US878807
申请日：1992-05-05
申请人： Francis F. Koblitz , Thomas J. Lynch , Ricky C. Mellinger
发明人： Francis F. Koblitz , Thomas J. Lynch , Ricky C. Mellinger
IPC分类号： H01R13/52 , C08L53/00 , C08L53/02 , C09K3/10 , H01B7/282 , H01B7/285 , H01B7/29 , H01R4/24 , H01R4/70 , H01R13/533 , H01B3/44
CPC分类号： H01R13/5216 , C08L53/005 , C08L53/02 , C08L53/025 , C09K3/10 , H01B7/282 , H01B7/285 , H01B7/292 , H01R4/2495 , H01R4/70 , C09K2200/0247 , C09K2200/0405 , C09K2200/06 , C09K2200/0617 , C09K2200/062 , C09K2200/0632 , C09K2200/0642 , Y10S439/936 , Y10S525/903
摘要： Disclosed are sealant compositions having excellent slump and spew resistance, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.
摘要翻译：公开了具有优异的坍落度和耐冲击性的密封剂组合物，即使在电连接器的相对高的操作温度下也是如此。可在这样升高的温度下流动的密封剂包括两个必需组分：弹性体热塑性聚合物，优选包含二嵌段和三嵌段共聚物的有机聚合物复合物，以及聚合物的增量剂。增量剂可分别包含初级和次级增量剂，例如聚丁烯油和矿物油。

2. 发明授权

US5580265A Sealant compositions and sealed electrical connectors 失效
标题翻译：密封剂组合物和密封电连接器
公开(公告)号：US5580265A
公开(公告)日：1996-12-03
申请号：US297574
申请日：1994-08-29
申请人： Francis F. Koblitz , Thomas J. Lynch , Ricky C. Mellinger
发明人： Francis F. Koblitz , Thomas J. Lynch , Ricky C. Mellinger
IPC分类号： C08L53/00 , C08L53/02 , C09K3/10 , H01B7/282 , H01B7/285 , H01B7/29 , H01R4/24 , H01R4/70 , H01R13/52 , H01B3/44
CPC分类号： H01R13/5216 , C08L53/00 , C08L53/005 , C08L53/02 , C08L53/025 , C09K3/10 , H01B7/282 , H01B7/285 , H01B7/292 , H01R4/2495 , H01R4/70 , C09K2200/0247 , C09K2200/0405 , C09K2200/06 , C09K2200/0617 , C09K2200/062 , C09K2200/0632 , C09K2200/0642 , Y10S439/936
摘要： Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.
摘要翻译：公开的是具有优异的坍落度和防溅性的密封剂组合物，即使在相对高的操作温度下用于电连接器。可在这样升高的温度下流动的密封剂包括两个必需组分：弹性体热塑性聚合物，优选包含二嵌段和三嵌段共聚物的有机聚合物复合物，以及聚合物的增量剂。增量剂可分别包含初级和次级增量剂，例如聚丁烯油和矿物油。

3. 发明授权

US5354210A Sealant compositions and sealed electrical connectors 失效
标题翻译：密封剂组合物和密封电连接器
公开(公告)号：US5354210A
公开(公告)日：1994-10-11
申请号：US749373
申请日：1991-08-23
申请人： Francis F. Koblitz , Ricky C. Mellinger
发明人： Francis F. Koblitz , Ricky C. Mellinger
IPC分类号： H01R13/52 , C08L53/00 , C08L53/02 , C09K3/10 , H01B7/282 , H01B7/285 , H01B7/29 , H01R4/24 , H01R4/70 , H01R13/533 , C08L83/00 , C08L83/04
CPC分类号： H01R13/5216 , C08L53/005 , C08L53/02 , C08L53/025 , C09K3/10 , H01B7/282 , H01B7/285 , H01B7/292 , H01R4/2495 , H01R4/70 , C09K2200/0247 , C09K2200/0405 , C09K2200/06 , C09K2200/0617 , C09K2200/062 , C09K2200/0632 , C09K2200/0642 , Y10S439/936 , Y10S525/903
摘要： Disclosed are moisture and temperature resistant electrical connectors for sealingly connecting transmission means and sealant compositions adapted for use in such connectors, the sealants comprising (i) elastomeric thermoplastic polymer; (ii) extender for said elastomeric thermoplastic polymer; and (iii) cross-linked polymer. The cross-linked polymer is preferably cross-linked in the presence of said elastomeric thermoplastic polymer and is preferably a silicon-based cross-linked polymer.
摘要翻译：公开了用于密封地连接传动装置和适于在这种连接器中使用的密封剂组合物的防潮和耐温的电连接器，所述密封剂包括（i）弹性体热塑性聚合物; （ii）所述弹性体热塑性聚合物的增量剂; 和（iii）交联聚合物。交联聚合物优选在所述弹性体热塑性聚合物的存在下进行交联，优选为硅基交联聚合物。

4. 发明授权

US4714801A Sealant composition 失效
标题翻译：密封胶组成
公开(公告)号：US4714801A
公开(公告)日：1987-12-22
申请号：US767566
申请日：1985-08-20
申请人： Francis F. Koblitz , Lynn K. Snyder
发明人： Francis F. Koblitz , Lynn K. Snyder
IPC分类号： H01R4/24 , H01R13/52 , H01R4/00 , H02G15/08
CPC分类号： H01R13/5216 , H01R4/2495 , H01R4/2433
摘要： A sealant material that is relatively chemically inert toward plastics and adhesives is comprised of a homogeneous mixture of polymeric adipate polyester and fumed silica, the polyester comprising about 80 to 85 percent by weight of the mixture and the fumed silica comprising about 15 percent to 20 percent by weight of the mixture. In the preferred embodiment, the sealant material further contains about 0.02 to 0.04 percent of an organofunctional silane and about 0.03 percent to 0.07 percent of a fluorosurfactant.
摘要翻译：对塑料和粘合剂相对化学惰性的密封剂材料由聚合己二酸酯聚酯和热解法二氧化硅的均匀混合物组成，聚酯包含约80至85重量％的混合物，热解二氧化硅包含约15％至20％的混合物。在优选实施方案中，密封剂材料还含有约0.02至0.04％的有机官能硅烷和约0.03％至0.07％的含氟表面活性剂。

5. 发明授权

US4553940A Visible light curable dental compositions 失效
标题翻译：可见光固化牙科用组合物
公开(公告)号：US4553940A
公开(公告)日：1985-11-19
申请号：US652172
申请日：1984-09-18
申请人： Francis F. Koblitz , Roy L. Smith
发明人： Francis F. Koblitz , Roy L. Smith
IPC分类号： A61K6/08 , A61K6/09
CPC分类号： A61K6/083 , A61K6/08 , A61K6/09
摘要： Visible light curable dental restorations are provided having improved color stability. According to a preferred embodiment, visible light hardenable restorative materials are formulated from a major proportion of inorganic filler and a minor proportion of a resin component comprising a binder resin selected from the group of acrylated polyesters, acrylated polyesters reacted with an isocyanate, and hydroxyalkyl acrylic esters reacted with an isocyanate, polymerizable acrylic diluent monomer in an amount sufficient to control the viscosity of the resin component, and a photosensitizing system comprising of from about 0.05% to about 0.50% by weight of the restorative material of an alpha diketone together with an amine reducing agent. American Dental Association color stability standards are met by these compositions.
摘要翻译：提供具有改善的颜色稳定性的可见光固化牙科修复体。根据优选实施方案，可见光可硬化的修复材料由主要比例的无机填料和少量的树脂组分配制，所述树脂组分包含选自丙烯酸酯化的聚酯，与异氰酸酯反应的丙烯酸酯化聚酯和丙烯酸羟烷基酯的粘合剂树脂酯与异氰酸酯，可聚合的丙烯酸类稀释剂单体反应，其量足以控制树脂组分的粘度，以及光敏剂体系，其包含按重量计约0.05％至约0.50％的α-二酮的修复材料和胺还原剂。美国牙科协会颜色稳定性标准由这些组合物来满足。

6. 发明授权

US4504231A Process for filling teeth 失效
标题翻译：灌牙的过程
公开(公告)号：US4504231A
公开(公告)日：1985-03-12
申请号：US470177
申请日：1983-04-11
申请人： Francis F. Koblitz , Jane L. Reichart
发明人： Francis F. Koblitz , Jane L. Reichart
IPC分类号： A61K6/08 , C09J4/00
CPC分类号： C09J4/00 , A61K6/08 , Y10S522/908
摘要： Process for filling dental cavities with radiation curable silaneous adhesives comprising a polymerizable resin comprising at least 20% by weight of a polymerizable silane and optionally up to about 80% by weight of a polymerizable, ethylenically unsaturated material. According to a preferred embodiment, the polymerizable silane is either an acrylosilane or a vinyl silane.
摘要翻译：用可辐射固化的皮肤粘合剂填充牙腔的方法，包括可聚合树脂，其包含至少20重量％的可聚合硅烷和任选地至多约80重量％的可聚合的烯属不饱和材料。根据优选实施方案，可聚合硅烷是丙烯硅烷或乙烯基硅烷。

7. 发明授权

US4935454A Broad spectrum light and heat curable sealant composition and method of using same 失效
标题翻译：广谱光热可固化密封胶组合物及其使用方法
公开(公告)号：US4935454A
公开(公告)日：1990-06-19
申请号：US353218
申请日：1989-05-16
申请人： Francis F. Koblitz , Thomas M. O'Shea , Lynn K. Snyder
发明人： Francis F. Koblitz , Thomas M. O'Shea , Lynn K. Snyder
IPC分类号： C08F2/50 , C09J4/06 , H01L23/29
CPC分类号： H01L23/293 , C09J4/06 , H01L2924/0002 , Y10S439/936
摘要： A dielectric composition capable of being polymerized for use in sealing electrical and electro-optical connectors and devices is disclosed. Said composition is comprised of a major proportion of vinyl ester resins, a minor proportion of polymerizable acrylic diluent monomers, and a polymerization activation system comprised of from about 0.25 percent to about 17 percent by weight of the resin. A process of the present invention includes applying a layer of said composition to desired areas or to desired locations such as apertures surrounding electrical terminals extending from a connector housing, and exposing said composition to actinic radiation which activates the polymerization activation system which causes the composition to polymerize to form a sealant material that exclused solder and solvents from the connector and its apertures.
摘要翻译：公开了能够聚合用于密封电气和电光连接器和装置的电介质组合物。所述组合物由主要比例的乙烯基酯树脂，少量可聚合的丙烯酸稀释剂单体和由约0.25％至约17％重量的树脂组成的聚合活化体系组成。本发明的方法包括将所述组合物的层施加到期望的区域或期望的位置，例如围绕从连接器壳体延伸的电端子的孔，并将所述组合物暴露于光化辐射，所述光化辐射激活聚合活化系统，聚合形成密封剂材料，其从连接器及其孔中分离出焊料和溶剂。

8. 发明授权

US5395269A Method of sealing electrical connectors using a broad spectrum light and heat curable composition 失效
标题翻译：使用广谱光和热固化组合物密封电连接器的方法
公开(公告)号：US5395269A
公开(公告)日：1995-03-07
申请号：US753024
申请日：1991-08-26
申请人： Francis F. Koblitz , Thomas M. O'Shea , Lynn K. Snyder
发明人： Francis F. Koblitz , Thomas M. O'Shea , Lynn K. Snyder
IPC分类号： C09J4/06 , H01L23/29 , H01R9/09 , H05K1/00 , H05K5/06
CPC分类号： H01L23/293 , C09J4/06 , H01L2924/0002
摘要： An electrical connector of the type having a housing with terminals extending from apertures thereof, is sealed at the aperture entrances around the extending terminal portions. The sealant material is polymerized of a major proportion of at least one vinyl ester resin, a minor proportion of at least one polymerizable acrylic diluent monomer and a polymerization activation system comprising from about 0.025% to about 17% by weight of the resin, by being exposed to actinic radiation selected to activate the system. The polymerized material excludes solder and solvents from the aperture entrances.
摘要翻译：具有从其孔径延伸的端子的壳体的类型的电连接器被密封在延伸端子部分周围的孔口处。密封剂材料由主要比例的至少一种乙烯基酯树脂，少量的至少一种可聚合丙烯酸类稀释剂单体和包含约0.025％至约17％重量的树脂的聚合活化体系聚合，通过暴露于选择激活系统的光化辐射。聚合材料不包括孔径入口处的焊料和溶剂。

9. 发明授权

US5004869A Electrical connector containing adipic acid polyester sealant composition 失效
标题翻译：含有己二酸聚酯密封剂组合物的电连接器
公开(公告)号：US5004869A
公开(公告)日：1991-04-02
申请号：US136143
申请日：1987-12-21
申请人： Francis F. Koblitz , Thomas M. O'Shea , Beverly A. Stoner , Joseph J. Yula
发明人： Francis F. Koblitz , Thomas M. O'Shea , Beverly A. Stoner , Joseph J. Yula
IPC分类号： H01R4/24 , H01R13/52
CPC分类号： H01R13/5216 , H01R4/2495 , H01R4/2433
摘要： A sealant material that is relatively chemically inert toward plastics and adhesives is comprised of a homogeneous mixture of polymeric polyester, said polyester being derived from adipic acid, and silica, the polyester comprising more than about 50 percent by weight of the mixture and the fumed silica comprising less than about 20 percent by weight of the mixture. In a preferred embodiment, the sealant material further contains an organofunctional silane coupling agent, a polyfunctional bridging agent, a dispersing agent and a fluorosurfactant.
摘要翻译：对塑料和粘合剂相对化学惰性的密封剂材料由聚合聚酯的均匀混合物组成，所述聚酯衍生自己二酸和二氧化硅，所述聚酯包含超过约50重量％的混合物和热解法二氧化硅占混合物重量的约20％。在优选的实施方案中，密封材料还含有有机官能硅烷偶联剂，多官能桥连剂，分散剂和含氟表面活性剂。

10. 发明授权

US4595724A Flame retardant sealant 失效
标题翻译：阻燃密封剂
公开(公告)号：US4595724A
公开(公告)日：1986-06-17
申请号：US763076
申请日：1985-08-05
申请人： Francis F. Koblitz
发明人： Francis F. Koblitz
IPC分类号： C08K3/22 , C08L27/16 , C08L33/06 , C08L51/04 , H01R4/70
CPC分类号： H01R4/70 , C08K3/22 , C08L27/16 , C08L33/06 , C08L51/04
摘要： A fusible flame retardant sealant composition comprised of a homogeneous mixture of polyvinylidene fluoride, methacrylate polymer, and antimony oxide is disclosed. In the preferred embodiment, the sealant composition also contains zinc oxide. The sealant composition as disclosed herein is used to make fusible sealant inserts for preinsulated electrical connectors having a heat recoverable sleeve. The connectors are essentially comprising a conductor connecting means positioned within the heat recoverable sleeve, the conductor connecting means being designed to receive and electrically connect two or more electrical conducting members, the members being inserted from the ends of the sleeve, and one fusible sealant insert member made of said composition positioned near each one of the open ends of the sleeve. Upon application of sufficient heat to the sleeve, the sleeve recovers around the conductor connecting means and the electrical conducting members, and the fusible sealant insert members soften, conform and adapt to the conducting member, adhere to the conducting member and the sleeve, and seal the interstices between the conducting member and the recovered sleeve. The resulting seal is flame retardant and resistant to corrosive chemicals such as jet fuel and lubricant.
摘要翻译：公开了一种由聚偏二氟乙烯，甲基丙烯酸酯聚合物和氧化锑的均匀混合物组成的可熔阻燃密封剂组合物。在优选的实施方案中，密封剂组合物还含有氧化锌。本文公开的密封剂组合物用于制造用于具有可热回收套筒的预绝缘电连接器的可熔密封剂插入物。连接器基本上包括位于可加热回收套筒内的导体连接装置，该导体连接装置被设计成接收和电连接两个或多个导电构件，这些构件从套筒的端部插入，以及一个可熔密封剂插入件由所述组合物制成的构件定位在套筒的每个开口端附近。当向套管施加足够的热量时，套管围绕导体连接装置和导电构件回收，并且可熔密封剂插入件软化，适应并适应于导电构件，粘附到导电构件和套筒上，并且密封导电构件和回收套管之间的间隙。所得的密封件是阻燃的，并且耐腐蚀性化学品，例如喷气燃料和润滑剂。

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