会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 4. 发明授权
    • Continuous process for making melt-processable optical grade ring-opened
polycyclic (co)polymers in a single-stage multi-zoned reactor
    • 在单级多区反应堆中制备可熔融加工的光学级开环多环(共)聚合物的连续方法
    • US5439992A
    • 1995-08-08
    • US254381
    • 1994-06-06
    • Kong S. YiLinwood P. TenneyParley C. Lane, Jr.John V. WesselNancy S. Marchant
    • Kong S. YiLinwood P. TenneyParley C. Lane, Jr.John V. WesselNancy S. Marchant
    • C08G61/06C08G61/08G11B7/253C08F232/08
    • C08G61/08G11B7/2538
    • A continuous process for the solution polymerization of appropriate polycycloolefins in a ROMP zone to obtain a processable ROMP homo- or copolymer in solution, and subsequent hydrogenation of the ROMP (co)polymer without removing the residual ROMP catalyst and co-catalyst, provides an optical product having a mol wt M.sub.w in the range from 50,000-300,000 and polydispersity M.sub.w /M.sub.n in the range from 1.3-5.0, more preferably from 1.3-3, the lower the polydispersity the more desirable the physical properties of the (co)polymer. The process comprises, (A) continuously polymerizing a substantially anhydrous solution of said monomer by ring opening metathesis polymerization in at least a first and a last reaction zone of a multi-zoned, single-stage, reaction vessel to form an unsaturated polymer cement essentially free of unreacted monomer; (B) hydrogenating said unsaturated polymer cement in the presence of an effective amount of a nickel-containing hydrogenation catalyst in an amount sufficient to produce a hydrogenareal cement wherein more than 97% of double bonds in said unsaturated polymer are converted to single bonds; (C) removing more than 99% by weight of spent polymerization catalyst, used hydrogenation catalyst and filter aid present in said hydrogenated cement to produce an essentially solids-free hydrogenated cement; (D) devolatilizing said solids-free hydrogenated cement to produce a thickened hydrogeneated polymer cement, and, (E) recovering a solid polymer which meets particle count specifications for optical grade polymer.
    • 在ROMP区域中合适的聚环烯烃的溶液聚合以在溶液中获得可加工的ROMP均聚物或共聚物以及随后的ROMP(共)聚合物的氢化而不除去剩余的ROMP催化剂和助催化剂的连续方法提供光学 摩尔重量Mw在50,000-300,000的范围内,多分散性Mw / Mn在1.3-5.0,更优选1.3-3的范围内,多分散性越低,(共)聚合物的物理性质越好。 该方法包括:(A)在多区,单级反应容器的至少第一和最后反应区中通过开环易位聚合连续聚合所述单体的基本上无水的溶液,以基本上形成不饱和聚合物胶 没有未反应的单体; (B)在有效量的含镍氢化催化剂的存在下,使所述不饱和聚合物水泥的氢化量足以产生所述不饱和聚合物中多于97%的双键被转化为单键; (C)除去99重量%的废聚合催化剂,所用氢化催化剂和所述氢化水泥中的助滤剂以产生基本上不含固体的氢化水泥; (D)使所述不含固体的氢化水泥脱挥发分以产生增稠的氢化聚合物水泥,和(E)回收满足光学级聚合物的粒子数规格的固体聚合物。