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    • 5. 发明申请
    • ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, MANUFACTURING METHOD THEREOF, AND ELECTROPHOTOGRAPHIC DEVICE
    • 电子照相光电子器件及其制造方法和电子照相器件
    • US20110244381A1
    • 2011-10-06
    • US12999308
    • 2009-12-14
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiSeizo KitagawaKazuki Nebashi
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiSeizo KitagawaKazuki Nebashi
    • G03G5/04
    • G03G5/142G03G5/144
    • Provided is an electrophotographic photoconductor that has good coating solution stability and metal oxide dispersibility, is free of image defects including ground fogging and black spots, and affords good image characteristics in various environments, as well as a manufacturing method therefore and a device including the same. The electrophotographic photoconductor includes a conductive substrate; an undercoat layer; and a photosensitive layer. The undercoat layer contains, as a main component, a resin obtained by polymerizing, as starting materials, an aromatic dicarboxylic acid, at least one aliphatic dicarboxylic acid having 8 or more carbon atoms, and at least one diamine having a cycloalkane structure, and further contains a metal oxide. The aromatic dicarboxylic acid in the resin is present in an amount that ranges from 0.1 to 10 mol %, and the resin has an acid value and a base value that are each no greater than 10 KOH mg/g.
    • 提供了具有良好的涂布溶液稳定性和金属氧化物分散性的电子照相感光体,没有包括地雾和黑点的图像缺陷,并且在各种环境中提供良好的图像特性,因此其制造方法和包括其的装置 。 电子照相感光体包括导电性基板; 底漆层; 和感光层。 作为主要成分,底涂层含有通过使作为原料的芳香族二羧酸,至少一种碳原子数8以上的脂肪族二羧酸和至少一种具有环烷烃结构的二胺的原料聚合而得到的树脂,进一步 含有金属氧化物。 树脂中的芳族二羧酸的存在量为0.1〜10摩尔%,树脂的酸值和碱值不大于10KOHmg / g。
    • 6. 发明授权
    • Electrophotographic photoconductor, manufacturing method thereof, and electrophotographic device
    • 电子照相感光体,其制造方法和电子照相装置
    • US09081319B2
    • 2015-07-14
    • US12999308
    • 2009-12-14
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiSeizo KitagawaKazuki Nebashi
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiSeizo KitagawaKazuki Nebashi
    • G03G5/04G03G5/14
    • G03G5/142G03G5/144
    • Provided is an electrophotographic photoconductor that has good coating solution stability and metal oxide dispersibility, is free of image defects including ground fogging and black spots, and affords good image characteristics in various environments, as well as a manufacturing method therefore and a device including the same. The electrophotographic photoconductor includes a conductive substrate; an undercoat layer; and a photosensitive layer. The undercoat layer contains, as a main component, a resin obtained by polymerizing, as starting materials, an aromatic dicarboxylic acid, at least one aliphatic dicarboxylic acid having 8 or more carbon atoms, and at least one diamine having a cycloalkane structure, and further contains a metal oxide. The aromatic dicarboxylic acid in the resin is present in an amount that ranges from 0.1 to 10 mol %, and the resin has an acid value and a base value that are each no greater than 10 KOH mg/g.
    • 提供了具有良好的涂布溶液稳定性和金属氧化物分散性的电子照相感光体,没有包括地雾和黑点的图像缺陷,并且在各种环境中提供良好的图像特性,因此其制造方法和包括其的装置 。 电子照相感光体包括导电性基板; 底漆层; 和感光层。 作为主要成分,底涂层含有通过使作为原料的芳香族二羧酸,至少一种碳原子数8以上的脂肪族二羧酸和至少一种具有环烷烃结构的二胺的原料聚合而得到的树脂,进一步 含有金属氧化物。 树脂中的芳族二羧酸的存在量为0.1〜10摩尔%,树脂的酸值和碱值不大于10KOHmg / g。
    • 7. 发明授权
    • Electrophotographic photoreceptor, process for producing the electrophotographic photoreceptor, and electrophotographic device
    • 电子照相感光体,电子照相感光体的制造方法和电子照相装置
    • US08735031B2
    • 2014-05-27
    • US13132031
    • 2009-11-27
    • Kazuki NebashiYoichi NakamuraIkuo TakakiSeizo KitagawaShinjiro Suzuki
    • Kazuki NebashiYoichi NakamuraIkuo TakakiSeizo KitagawaShinjiro Suzuki
    • G03G5/14
    • G03G5/142G03G5/144
    • An electrophotographic photoreceptor includes an electroconductive substrate; an undercoat layer provided on the electroconductive substrate and composed of: metal oxide fine particles including particles of at least one metal oxide and at least one organic compound provided on the particles of the at least one metal oxide as a surface treatment; and a copolymer resin synthesized by copolymerization of essential constituent monomers composed of a dicarboxylic acid, a diol, a triol and a diamine; and a photosensitive layer laminated on the undercoat layer. The undercoat layer permits (a) attaining stable electric potential characteristics in all environments ranging from low temperature and low humidity environments to high temperature and high humidity environments, (b) suppressing the occurrence of printing defects and density differences, and (c) simultaneously attaining transfer restorability and restorability from intense light-induced fatigue even in a wide variety of usages and operation environments.
    • 电子照相感光体包括导电基片; 设置在导电性基体上的由下述构成的底涂层构成:包含至少一种金属氧化物的颗粒的金属氧化物微粒和至少一种金属氧化物颗粒上提供的至少一种有机化合物作为表面处理; 以及由二羧酸,二醇,三醇和二胺组成的必需构成单体共聚而合成的共聚物树脂; 和层压在底涂层上的感光层。 底涂层允许(a)在从低温和低湿环境到高温和高湿度环境的所有环境中获得稳定的电势特性,(b)抑制印刷缺陷和密度差异的发生,和(c)同时获得 即使在各种各样的使用和操作环境中,也可以将恢复性和恢复性从强烈的光诱导疲劳中转移出来。
    • 8. 发明授权
    • Electrophotographic photoconductor
    • 电子照相感光体
    • US07723000B2
    • 2010-05-25
    • US11641949
    • 2006-12-20
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiKazuki Nebashi
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiKazuki Nebashi
    • G03G5/14
    • G03G5/144G03G5/142
    • An electrophotographic photoconductor includes an undercoat layer and a photosensitive layer sequentially provided on a conductive substrate. The undercoat layer is mainly composed of a resin and contains a metal oxide. The resin is provided by mixing and polymerizing raw materials of aromatic dicarboxylic acid in a range of 0.1 to 10 mol %, two or more types of dicarboxylic acid other than the aromatic dicarboxylic acid, two or more types of diamine, and at least one type of cyclic amide compound. The resin exhibits an acid value and a base value each of at most 6.0 KOH mg/g. Advantageously, generation of secondary aggregates in the undercoat layer, which result in image defects such as black spots and fogging on a white field, is suppressed.
    • 电子照相感光体包括依次设置在导电性基板上的底涂层和感光层。 底涂层主要由树脂构成,含有金属氧化物。 通过将芳族二羧酸的原料在0.1〜10摩尔%的范围内混合并聚合而得到的树脂,2芳香族二羧酸以外的2种以上的二羧酸,2种以上的二胺和至少1种 的环酰胺化合物。 该树脂的酸值和基本值均为6.0KOHmg / g以下。 有利地,抑制了在底涂层中产生二次聚集体,这导致图像缺陷如黑点和白色场上的起雾。
    • 9. 发明申请
    • ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS FOR PRODUCING THE ELECTROPHOTOGRAPHIC PHOTORECEPTOR, AND ELECTROPHOTOGRAPHIC DEVICE
    • 电子照相光电子产品,电摄影光刻胶的制造方法以及电子照相装置
    • US20120034556A1
    • 2012-02-09
    • US13132031
    • 2009-11-27
    • Kazuki NebashiYoichi NakamuraSeizo KitagawaIkuo TakakiShinjiro Suzuki
    • Kazuki NebashiYoichi NakamuraSeizo KitagawaIkuo TakakiShinjiro Suzuki
    • G03G5/04
    • G03G5/142G03G5/144
    • An electrophotographic photoreceptor includes an electroconductive substrate; an undercoat layer provided on the electroconductive substrate and composed of: metal oxide fine particles including particles of at least one metal oxide and at least one organic compound provided on the particles of the at least one metal oxide as a surface treatment; and a copolymer resin synthesized by copolymerization of essential constituent monomers composed of a dicarboxylic acid, a diol, a triol and a diamine; and a photosensitive layer laminated on the undercoat layer. The undercoat layer permits (a) attaining stable electric potential characteristics in all environments ranging from low temperature and low humidity environments to high temperature and high humidity environments, (b) suppressing the occurrence of printing defects and density differences, and (c) simultaneously attaining transfer restorability and restorability from intense light-induced fatigue even in a wide variety of usages and operation environments.
    • 电子照相感光体包括导电基片; 设置在导电性基体上的由下述构成的底涂层构成:包含至少一种金属氧化物的颗粒的金属氧化物微粒和至少一种金属氧化物颗粒上提供的至少一种有机化合物作为表面处理; 以及由二羧酸,二醇,三醇和二胺组成的必需构成单体共聚而合成的共聚物树脂; 和层压在底涂层上的感光层。 底涂层允许(a)在从低温和低湿环境到高温和高湿度环境的所有环境中获得稳定的电势特性,(b)抑制印刷缺陷和密度差异的发生,和(c)同时获得 即使在各种各样的使用和操作环境中,也可以将恢复性和恢复性从强烈的光诱导疲劳中转移出来。
    • 10. 发明申请
    • Electrophotographic photoconductor
    • 电子照相感光体
    • US20070154827A1
    • 2007-07-05
    • US11641949
    • 2006-12-20
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiKazuki Nebashi
    • Shinjirou SuzukiYoichi NakamuraIkuo TakakiKazuki Nebashi
    • G03G5/14
    • G03G5/144G03G5/142
    • An electrophotographic photoconductor includes an undercoat layer and a photosensitive layer sequentially provided on a conductive substrate. The undercoat layer is mainly composed of a resin and contains a metal oxide. The resin is provided by mixing and polymerizing raw materials of aromatic dicarboxylic acid in a range of 0.1 to 10 mol %, two or more types of dicarboxylic acid other than the aromatic dicarboxylic acid, two or more types of diamine, and at least one type of cyclic amide compound. The resin exhibits an acid value and a base value each of at most 6.0 KOH mg/g. Advantageously, generation of secondary aggregates in the undercoat layer, which result in image defects such as black spots and fogging on a white field, is suppressed.
    • 电子照相感光体包括依次设置在导电性基板上的底涂层和感光层。 底涂层主要由树脂构成,含有金属氧化物。 通过将芳族二羧酸的原料在0.1〜10摩尔%的范围内混合并聚合而得到的树脂,2芳香族二羧酸以外的2种以上的二羧酸,2种以上的二胺和至少1种 的环酰胺化合物。 该树脂的酸值和基本值均为6.0KOHmg / g以下。 有利地,抑制了在底涂层中产生二次聚集体,这导致图像缺陷如黑点和白色场上的起雾。