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1. 发明授权

US5093508A Process for producing vanadium-arenes 失效
标题翻译：生产钒酸盐的方法
公开(公告)号：US5093508A
公开(公告)日：1992-03-03
申请号：US641877
申请日：1991-01-04
申请人： Fausto Calderazzo , Guido Pampaloni , Lucia Rocchi , Angelo Moalli , Francesco Masi , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Lucia Rocchi , Angelo Moalli , Francesco Masi , Renzo Invernizzi
IPC分类号： C07F9/00 , C08F4/20
CPC分类号： C07F9/00
摘要： Vanadium-arenes[V(arene).sub.2 ]wherein "arene" means benzene or mono-, di- or poly-(C.sub.1 -C.sub.5)-alkyl-substituted benzene, are prepared by means of a process which comprises:(a) forming a complex:[V(arene).sub.2 ](+).AlCl.sub.4 (-) by reacting vanadium trichloride, aluminum metal and aluminum trichloride with one another, by operating in the presence of the selected arene;(b) treating the so obtained complex with an either cyclic or acyclic, liquid aliphatic ether to obtain the reduction of [V(arene).sub.2 ](+) to [V(arene).sub.2 ]; and(c) recovering the so separated vanadium-arene.The vanadium-arenes are useful in the preparation of catalysts for olefin polymerization.

2. 发明授权

US5210244A Procedure for the production of vanadium bis-arenes from vanadium oxychloride 失效
标题翻译：从氧化亚氮烷中生产钒酸铋的方法
公开(公告)号：US5210244A
公开(公告)日：1993-05-11
申请号：US911286
申请日：1992-07-09
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Maria C. Cassani , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Maria C. Cassani , Renzo Invernizzi
IPC分类号： C07F9/00 , C08F4/06 , C08F4/60 , C08F4/68 , C08F4/76 , C08F10/00
CPC分类号： C07F9/00
摘要： A procedure is described for the preparation of a vanadium bis-arene, [V(arene).sub.2 ], starting from vanadium oxychloride, aluminium metal, aluminium trichloride and an arene, wherein:(a) vanadium oxychloride (VOCl.sub.3), active aluminium metal, and aluminium trichloride are put in contact with each other, in a liquid arene, to transform the vanadium oxychloride into the complex compound [V(arene).sub.2 ].sup.+ [AlCl.sub.4 ].sup.- ;(b) a liquid cyclic or acyclic or acyclic ether is added to the reaction product of step (a) to reduce [V(arene).sub.2 ].sup.+ to [V(arene).sub.2 ]; and(c) the vanadium bis-arene [V(arene).sub.2 ] is recovered from the reacton product of step (b).The vanadium bis-arenes thus obtained are use in the preparation of catalysts for the polymerization of olefins.

3. 发明授权

US4987111A Catalyst component and catalyst for the polymerization of ethylene and the copolymerization of ethylene with alpha-olefins 失效
标题翻译：用于乙烯聚合的催化剂组分和催化剂以及乙烯与α-烯烃的共聚合
公开(公告)号：US4987111A
公开(公告)日：1991-01-22
申请号：US403681
申请日：1989-09-06
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
IPC分类号： C08F4/60 , C08F4/639 , C08F4/646 , C08F4/685 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A solid catalyst component for the polymerization of ethylene and the copolymerization of ethylene with C.sub.3 -C.sub.10 alpha-olefins, contains titanium, vanadium and chlorine, is substantially definable by the formula (in atomic proportions):V (1), Ti (n), Cl (4n)where n varies from 1 to 3, and is prepared by reacting titanium tetrachloride with a vanadium arene [V.degree.(arene).sub.2 ] (arene=benzene or mono-, di- or tri-alkyl substituted benzene) in accordance with the equation:V.degree.(arene).sub.2 +nTiCl.sub.4 .fwdarw.VTi.sub.n Cl.sub.4n +2 arenepossibly followed by treatment with an alkyl aluminum chloride. This catalyst component, when associated with a trialkyl aluminium, is highly active in the production of ethylene polymers and copolymers by low temperature, low pressure methods in suspension, or by high temperature, high pressure methods conducted in a tubular reactor or pressure vessel, or by high temperature methods conducted in solution.

4. 发明授权

US4980491A Process for producing vanadium-arenes 失效
标题翻译：生产钒 - 芳烃的方法
公开(公告)号：US4980491A
公开(公告)日：1990-12-25
申请号：US516267
申请日：1990-04-30
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
IPC分类号： C07F9/00 , C07F17/00 , C08F4/60 , C08F4/68 , C08F10/00 , C08F10/02
CPC分类号： C07F9/00
摘要： Vanadium-arenes [V(arene).sub.2 ] (arene=benzene or mono-, di-, or poly-alkyl-substituted benzene) are obtained, with a high yield, by means of the reduction of a vanadium-arene iodide with zinc, manganese or iron in metal form, or with cobalt di-(cyclopentadienyl).Vanadium-arenes are useful in the preparation of catalyst components active in ethylene polymerization, or in the copolymerization of ethylene in an alpha-olefin.

5. 发明授权

US07081505B2 Activating organometallic composition for the (co) polymerization of alpha-olefins comprising fluorinated cyclopentadienyl compounds 有权
标题翻译：活化用于包含氟化环戊二烯基化合物的α-烯烃的（共）聚合的有机金属组合物
公开(公告)号：US07081505B2
公开(公告)日：2006-07-25
申请号：US10483415
申请日：2002-07-10
申请人： Anna Sommazzi , Francesco Masi , Giampietro Borsotti , Roberto Santi , Fausto Calderazzo , Guido Pampaloni , Vincenzo Passarelli
发明人： Anna Sommazzi , Francesco Masi , Giampietro Borsotti , Roberto Santi , Fausto Calderazzo , Guido Pampaloni , Vincenzo Passarelli
IPC分类号： C08F4/44 , C08F4/6192 , B01J31/14
CPC分类号： C08F10/00 , C08F4/65927 , Y10S526/943 , C08F4/65912
摘要： An organometallic composition which can be used as activating component in a metallocene catalyst for the (co)polymerization of α-olefins, comprises: (A) a fluorinated di-unsaturated cyclic compound, having a relatively acid hydrogen atom, (B) an organometallic compound sufficiently basic to react with the acid hydrogen of the above compound (A), and (C) a polar aprotic organic compound, not containing metallic atoms, having a dielectric constant, in the pure state, equal to or greater than 2, and a weak coordinating capacity. Said composition allows a metallocene catalytic system of the ionic type to be obtained, with a high activity in the (co)polymerization of olefins and a reduced content of metallic residue in the polymeric product thus obtained.
摘要翻译：可用作α-烯烃（共）聚合的茂金属催化剂中的活化组分的有机金属组合物包括：（A）具有相对酸性氢原子的氟化二不饱和环状化合物，（B）有机金属具有足够碱性的化合物与上述化合物（A）的酸性氢反应，和（C）在纯状态下不具有介电常数的金属原子的极性非质子有机化合物等于或大于2，以及协调能力弱。所述组合物允许获得离子型茂金属催化体系，在烯烃的（共）聚合中具有高活性，并且由此获得的聚合物中的金属残余物含量降低。

6. 发明授权

US5821189A Catalyst for the homopolymerization or copolymerization of ethylene and process for its preparation 失效
标题翻译：用于乙烯均聚或共聚的催化剂及其制备方法
公开(公告)号：US5821189A
公开(公告)日：1998-10-13
申请号：US444870
申请日：1995-05-19
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Andrea Vallieri
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Andrea Vallieri
IPC分类号： C08F4/60 , C08F4/619 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02
CPC分类号： C08F10/00 , C08F4/61904 , C08F4/61912 , C08F4/659
摘要： A catalyst for the (co)polymerization of ethylene is obtained by a process comprising the contact of the following components (A), (B), (C) and (D) in the respective molar ratios (1):(0.5-2):(0-25):(0-15): (A): a bivalent arene of titanium having the formula Ti (.eta..sup.6 -arene)(AlR.sub.x X.sub.4-x).sub.2 ; wherein: "arene" indicates benzene, or benzene substituted with from 1 to 6 C.sub.1 -C.sub.10 alkyl groups; each X independently represents a chlorine, bromine or fluorine atom; R is a C.sub.1 C.sub.10 alkyl group, linear or branched; "x" is a number varying from 0.5 to 2.5; (B): a compound or a mixture of compounds selected from the group consisting of the chlorides or bromides of the metals titanium, zirconium, vanadium, hafnium, tin, germanium, cerium or osmium, in the oxidation state (+4), and antimony or vanadium in the oxidation state (+5), and the derivatives of these metals in said oxidation state with oxygenated binders wherein at least one oxygen atom is bound or co-ordinated to the metal; (C): an aluminum alkyl or halide of aluminum alkyl (D): an organic chloroderivative selected from: (a) di- or poly-chloroalkanes; (b) alkyl esters of aliphatic carboxylic acids di- or tri-chlorosubstituted on the carbon in the alpha position with respect to the carboxyl; and (c) derivatives of chlorotriphenylemethane or dichlorodiphenylmethane having a carboxyalkyl group in the para position of at least one of the phenyl rings.
摘要翻译：通过包括以下组分（A），（B），（C）和（D）以相应的摩尔比（1）：（0.5-2）的接触的方法获得乙烯（共）聚合的催化剂）（0-25）：（0-15）：（A）：具有式Ti（eta 6-芳烃）（AlRxX4-x）2的钛的二价芳烃;其中：“芳烃”表示苯，具有1至6个C 1 -C 10烷基; 每个X独立地表示氯，溴或氟原子; R是直链或支链的C1C10烷基; “x”是从0.5到2.5的数字; （B）：处于氧化态（+4）的金属钛，锆，钒，铪，锡，锗，铈或锇的氯化物或溴化物的化合物或化合物的混合物，以及处于氧化态（+5）的锑或钒，以及所述氧化态的这些金属与氧化粘合剂的衍生物，其中至少一个氧原子与金属结合或配位; （C）：烷基铝的烷基铝或卤化物（D）：有机氯化物选自：（a）二 - 或多氯代烷烃; （b）在相对于羧基的α位上的碳上二或三氯取代的脂族羧酸的烷基酯; 和（c）在至少一个苯环的对位具有羧基烷基的氯三苯甲烷或二氯二苯基甲烷的衍生物。

7. 发明授权

US09290586B2 Solid catalyst component, catalyst comprising said solid component, and process for the (CO)polymerization of α-olefins 有权
标题翻译：固体催化剂组分，包含所述固体组分的催化剂，以及α-烯烃的（CO）聚合方法
公开(公告)号：US09290586B2
公开(公告)日：2016-03-22
申请号：US13997967
申请日：2011-12-20
申请人： Anna Sommazzi , Francesco Masi , Guido Pampaloni , Filippo Renili , Fabio Marchetti , Anna Maria Raspolli Galletti
发明人： Anna Sommazzi , Francesco Masi , Guido Pampaloni , Filippo Renili , Fabio Marchetti , Anna Maria Raspolli Galletti
IPC分类号： C08F10/02 , C07F17/00 , C08F4/659 , C08F110/02 , C08F210/16
CPC分类号： C08F10/02 , C07F17/00 , C08F4/52 , C08F4/65912 , C08F4/76 , C08F110/02 , C08F210/16 , C08F4/6557 , C08F4/65904 , C08F4/6552 , C08F2500/12 , C08F210/14
摘要： A solid catalyst component for the (co)polymerization of α-olefins having general formula (I): ZrnMAlxClMgp (I) wherein: M represents titanium (Ti), vanadium (V), or mixtures thereof; n is a number ranging from 0.01 to 2; x is a number ranging from 0.1 to 4; y is a number ranging from 5 to 53; p is a number ranging from 0 to 15; obtained by means of a process comprising putting at least one zirconium arene in contact with at least one metal compound and, optionally, with at least one compound of magnesium. Said solid catalyst component can be advantageously used as a solid component in a catalyst for the (co)polymerization of α-olefins. Said catalyst can be advantageously used in a process for the (co)polymerization of α-olefins.
摘要翻译：用于（a）具有通式（I）的α-烯烃的（共）聚合的固体催化剂组分：ZrnMAlxClMgp（I）其中：M表示钛（Ti），钒（V）或其混合物; n为0.01〜2的数; x是从0.1到4的数字; y是从5到53的数字; p是从0到15的数字; 通过包括将至少一种锆芳烃与至少一种金属化合物和任选地与至少一种镁化合物接触的方法获得。所述固体催化剂组分可有利地用作α-烯烃的（共）聚合催化剂中的固体组分。所述催化剂可以有利地用于α-烯烃的（共）聚合方法中。

8. 发明申请

US20130296592A1 METAL ALKYL-ARENES AND PROCESSES FOR THE PREPARATION THEREOF 有权
标题翻译：金属碱金属及其制备方法
公开(公告)号：US20130296592A1
公开(公告)日：2013-11-07
申请号：US13996842
申请日：2011-12-23
申请人： Guido Pampaloni , Filippo Renili , Anna Sommazzi , Fabio Marchetti , Francesco Masi , Mario Polesello
发明人： Guido Pampaloni , Filippo Renili , Anna Sommazzi , Fabio Marchetti , Francesco Masi , Mario Polesello
IPC分类号： C07F19/00
CPC分类号： C07F19/00 , B01J31/122 , C07F7/003 , C08F4/42 , C08F10/00 , C08F4/659
摘要： Metal alkyl-arene having general formula (I) or (Ia): M (η6-arene)2Al1XrRs (I) M (η6-arene)AlqXrRs (Ia) wherein: —M represents zirconium (Zr), hafnium (Hf), or mixtures thereof, preferably zirconium; —arene represents a benzene, or a benzene 10 substituted with from 1 to 6 linear or branched C1-C6 alkyl groups, or mixtures thereof; —X represents a halogen atom selected from chlorine, bromine, fluorine, iodine, preferably chlorine; —R represents a linear or branched C1-C15 alkyl group; —q is a number ranging from 2 to 6, preferably 3 for a metal alkyl-arene having general formula (I), 2 for a metal alkyl-arene having general formula (Ia); —r is a number ranging from 1 to 20, preferably 9 for a metal alkyl-arene having general formula (I), 6 for a metal alkyl-arene having general formula (Ia); —s is a number ranging from 1 to 6, preferably 2. Said metal alkyl-arene can be advantageously used for the preparation of solid components of catalysts for the (co)polymerization of α-olefins.
摘要翻译：具有通式（I）或（Ia）的金属烷基芳烃：M（eta6-芳烃）2Al1XrRs（I）M（eta6-芳烃）AlqXrRs（Ia）其中：-M代表锆（Zr），铪（Hf）或其混合物，优选锆; 芳烃代表苯，或被1至6个直链或支链C 1 -C 6烷基取代的苯10，或其混合物; -X表示选自氯，溴，氟，碘，优选氯的卤素原子; -R表示直链或支链的C 1 -C 15烷基; 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-q为2至6的数，优选3。对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-r为1至20，优选9。 -s是1至6的数，优选2.所述金属烷基芳烃可有利地用于制备用于α-烯烃的（共）聚合的催化剂的固体组分。

9. 发明授权

US08772521B2 Metal alkyl-arenes and processes for the preparation thereof 有权
标题翻译：金属烷基芳烃及其制备方法
公开(公告)号：US08772521B2
公开(公告)日：2014-07-08
申请号：US13996842
申请日：2011-12-23
申请人： Guido Pampaloni , Filippo Renili , Anna Sommazzi , Fabio Marchetti , Francesco Masi , Mario Polesello
发明人： Guido Pampaloni , Filippo Renili , Anna Sommazzi , Fabio Marchetti , Francesco Masi , Mario Polesello
IPC分类号： C07F19/00 , B01J31/12 , B01J31/00 , C08F4/42
CPC分类号： C07F19/00 , B01J31/122 , C07F7/003 , C08F4/42 , C08F10/00 , C08F4/659
摘要： Metal alkyl-arene having general formula (I) or (Ia): M (η6-arene)2AlqXrRs (I) M (η6-arene)AlqXrRs (Ia) wherein: —M represents zirconium (Zr), hafnium (Hf), or mixtures thereof, preferably zirconium; —arene represents a benzene, or a benzene 10 substituted with from 1 to 6 linear or branched C1-C6 alkyl groups, or mixtures thereof; —X represents a halogen atom selected from chlorine, bromine, fluorine, iodine, preferably chlorine; —R represents a linear or branched C1-C15 alkyl group; —q is a number ranging from 2 to 6, preferably 3 for a metal alkyl-arene having general formula (I), 2 for a metal alkyl-arene having general formula (Ia); —r is a number ranging from 1 to 20, preferably 9 for a metal alkyl-arene having general formula (I), 6 for a metal alkyl-arene having general formula (Ia); —s is a number ranging from 1 to 6, preferably 2. Said metal alkyl-arene can be advantageously used for the preparation of solid components of catalysts for the (co)polymerization of α-olefins.
摘要翻译：具有通式（I）或（Ia）的金属烷基芳烃：M（＆eegr。6-芳烃）2AlqXrRs（I）M（＆eegr; 6-芳烃）AlqXrRs（Ia）其中：-M代表锆（Zr），铪（Hf），或其混合物，优选锆; 芳烃代表苯，或被1至6个直链或支链C 1 -C 6烷基取代的苯10，或其混合物; -X表示选自氯，溴，氟，碘，优选氯的卤素原子; -R表示直链或支链的C 1 -C 15烷基; 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-q为2至6的数，优选3。对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-r为1至20，优选9。 -s是1至6的数，优选2.所述金属烷基芳烃可有利地用于制备用于（共）聚合α-烯烃的催化剂的固体组分。

10. 发明申请

US20130303360A1 SOLID CATALYST COMPONENT, CATALYST COMPRISING SAID SOLID COMPONENT, AND PROCESS FOR THE (CO)POLYMERIZATION OF ALPHA-OLEFINS 有权
标题翻译：固体催化剂组分，包含固体组分的催化剂，以及（CO）聚合烯烃的方法
公开(公告)号：US20130303360A1
公开(公告)日：2013-11-14
申请号：US13997967
申请日：2011-12-20
申请人： Anna Sommazzi , Francesco Masi , Guido Pampaloni , Filippo Renili , Fabio Marchetti , Anna Maria Raspolli Galletti
发明人： Anna Sommazzi , Francesco Masi , Guido Pampaloni , Filippo Renili , Fabio Marchetti , Anna Maria Raspolli Galletti
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C07F17/00 , C08F4/52 , C08F4/65912 , C08F4/76 , C08F110/02 , C08F210/16 , C08F4/6557 , C08F4/65904 , C08F4/6552 , C08F2500/12 , C08F210/14
摘要： A solid catalyst component for the (co)polymerization of α-olefins having general formula (I): ZrnMAlxClMgp (I) wherein: M represents titanium (Ti), vanadium (V), or mixtures thereof; n is a number ranging from 0.01 to 2; x is a number ranging from 0.1 to 4; y is a number ranging from 5 to 53; p is a number ranging from 0 to 15; obtained by means of a process comprising putting at least one zirconium arene in contact with at least one metal compound and, optionally, with at least one compound of magnesium. Said solid catalyst component can be advantageously used as a solid component in a catalyst for the (co)polymerization of α-olefins. Said catalyst can be advantageously used in a process for the (co)polymerization of α-olefins.
摘要翻译：用于通式（I）的α-烯烃的（共）聚合的固体催化剂组分：ZrnMAlxClMgp（I）其中：M表示钛（Ti），钒（V）或其混合物; n为0.01〜2的数; x是从0.1到4的数字; y是从5到53的数字; p是从0到15的数字; 通过包括将至少一种锆芳烃与至少一种金属化合物和任选地与至少一种镁化合物接触的方法获得。所述固体催化剂组分可有利地用作α-烯烃（共）聚合的催化剂中的固体组分。所述催化剂可以有利地用于α-烯烃的（共）聚合方法中。

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