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    • 2. 发明公开
    • Silver halide photographic materials
    • 银色摄影材料
    • EP0220746A3
    • 1989-05-24
    • EP86115142.1
    • 1986-10-31
    • FUJI PHOTO FILM CO., LTD.
    • Nakamura, Koki FUJI PHOTO FILM CO. LTD.Nakamura, Shigeru FUJI PHOTO FILM CO. LTD.
    • G03C7/32G03C8/00G03C8/40C07D413/12
    • G03C8/4033G03C7/30511Y10S430/156Y10S430/157Y10S430/158Y10S430/159Y10S430/16
    • The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I)
      wherein EAG represents a group which accepts an electron from a reducing substance; N and 0 each represents nitrogen atom and an oxygen atom, respectively; R' and R 2 each represents a substituent other than a hydrogen atom, and when R' or R 2 is bonded to -(Time)̵― t ― PUG, R' or R 2 is a mere bond or a substituent other than a hydrogen atom, and R' and R 2 may be bonded to each other to form a ring; Time represents a group for releasing PUG via the subsequent reaction as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound of general formula (I); PUG represents a photographically useful group; t is an integer of 0 or 1; the full lines in the formula each mean a bond; and the dotted lines therein mean that at least one of the dotted lines is a bond. In particular, compounds of the following formula (II) and (III) are preferred among those of the formula (I):
      wherein R 3 is bonded to the nitrogen atom or oxygen atom in the formula, and represents an atomic group necessary for the formation of a 3 to 8-membered mono-or fused-hetero ring;
      wherein R 4 and R 5 each represents a mere bond, a hydrogen atm or a substituent group, and they may be . bonded to each other to form a saturated or unsaturated carbon ring or hetero ring; and X represents a divalent binding group.
    • 3. 发明公开
    • Silver halide photographic materials
    • 卤化银照相材料
    • EP0220746A2
    • 1987-05-06
    • EP86115142.1
    • 1986-10-31
    • FUJI PHOTO FILM CO., LTD.
    • Nakamura, Koki FUJI PHOTO FILM CO. LTD.Nakamura, Shigeru FUJI PHOTO FILM CO. LTD.
    • G03C7/32G03C8/00G03C8/40C07D413/12
    • G03C8/4033G03C7/30511Y10S430/156Y10S430/157Y10S430/158Y10S430/159Y10S430/16
    • The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I)
      wherein EAG represents a group which accepts an electron from a reducing substance; N and 0 each represents nitrogen atom and an oxygen atom, respectively; R' and R 2 each represents a substituent other than a hydrogen atom, and when R' or R 2 is bonded to -(Time)̵― t ― PUG, R' or R 2 is a mere bond or a substituent other than a hydrogen atom, and R' and R 2 may be bonded to each other to form a ring; Time represents a group for releasing PUG via the subsequent reaction as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound of general formula (I); PUG represents a photographically useful group; t is an integer of 0 or 1; the full lines in the formula each mean a bond; and the dotted lines therein mean that at least one of the dotted lines is a bond.
      In particular, compounds of the following formula (II) and (III) are preferred among those of the formula (I):
      wherein R 3 is bonded to the nitrogen atom or oxygen atom in the formula, and represents an atomic group necessary for the formation of a 3 to 8-membered mono-or fused-hetero ring;
      wherein R 4 and R 5 each represents a mere bond, a hydrogen atm or a substituent group, and they may be . bonded to each other to form a saturated or unsaturated carbon ring or hetero ring; and X represents a divalent binding group.
    • 本发明提供含有哈夫尔化合物的卤化银照相材料,该哈夫尔化合物在还原时释放由化合物中的氮 - 氧单键裂解引发的照相用途基团,并由下述通式(I)表示: 其中EAG表示接受来自还原物质的电子的基团; N和O分别代表氮原子和氧原子; R'和R2各自表示除氢原子以外的取代基,并且当R'或R2键合于 - (时间)-t-PUG时,R'或R2仅为键或氢原子以外的取代基, 并且R'和R2可以彼此键合形成环; 时间代表通过随后的反应释放PUG的组,由通式(I)化合物中氮 - 氧单键的裂解引发; PUG代表照相有用的组; t是0或1的整数; 公式中的实线均表示债券; 并且其中的虚线意味着至少一条虚线是键。 具体而言,在式(I)的那些中,优选下式(II)和(III)的化合物:其中R 3与式中的氮原子或氧原子键合,并且表示形成所需的原子团 的3至8元单或稠合杂环; 其中R4和R5各自表示纯键,氢原子或取代基,它们可以是。 相互键合形成饱和或不饱和的碳环或杂环; X代表二价结合基团。