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    • 2. 依法登记的发明
    • Insecticidal photostable acid salt derivatives of N-benzyl-4-benzhydrolpiperidines
    • N-苄基-4-二苯甲基哌啶的杀虫光稳定酸盐衍生物
    • USH1996H
    • 2001-10-02
    • US19688098
    • 1998-11-20
    • FMC CORP
    • PEAKE CLINTON JCULLEN THOMAS GHENRIE II ROBERT NDYBAS JANE A
    • A01N43/40A01N43/713A01N47/20C07D211/22C07D211/94C07D401/10C07D421/00C07D211/08C07D211/68C07D401/00
    • C07D401/10A01N43/40A01N43/713A01N47/20C07D211/22C07D211/94
    • It has now been found that certain novel photostable agriculturally acceptable organic or inorganic salts of formula I are useful as insecticides:whereR is alkoxycarbonyl, alkoxycarbonylamino, cycloalkylalkoxy, 2-alkyl-2H-tetrazol-5-yl, or 2-haloalkyl-2H-tetrazol-5-yl; R1 is trihaloalkyl, or trihaloalkoxy; n is 0, or 1; and, wherein said salts are derived from hydrochloric acid; hydrobromic acid; boric acid; phosphoric acid; maleic acid; fumaric acid; phthalic acid; salicylic acid optionally substituted with alkyl or halogen; D-glucuronic acid; the sulfonic acid R2SO3H where R2 is alkyl, haloalkyl, hydroxyalkyl, D-10-camphoryl, or phenyl optionally substituted with alkyl or halogen; the carboxylic acid R3CO2H where R3 is hydrogen, alkyl, trihaloalkyl, carboxyl, phenyl optionally substituted with alkyl or halogen, or pyridyl; the boronic acid R4B(OH)2 where R4 is alkyl or phenyl optionally substituted with alkyl or halogen; the phosphonic acid R5PO3H2 where R5 is alkyl, haloalkenyl, or phenyl optionally substituted with alkyl or halogen; the sulfuric acid R6OSO3H where R6 is hydrogen or alkyl; or the alkanoic acid X-(CH2)qCO2H where q is 0 to 11, X is halogen, trihaloalkyl, haloalkenyl, cyano, aminocarbonyl, or CO2R7 where R7 is hydrogen or alkyl. Preferred compounds include those where R is 2-ethyl-2H-tetrazol-5-yl; R1 is trifluoromethyl; n is 1; and said salts are derived from hydrochloric acid, or the sulfonic acid R2SO3H where R2 is alkyl, or hydroxyalkyl.
    • 现在已经发现,某些新颖的光稳定性农业上可接受的式I的有机或无机盐可用作杀虫剂:其中R是烷氧基羰基,烷氧基羰基氨基,环烷基烷氧基,2-烷基-2H-四唑-5-基或2-卤代烷基-2H- 四唑-5-基; R1是三卤代烷基或三卤代烷氧基; n为0或1; 并且其中所述盐衍生自盐酸; 氢溴酸; 硼酸 磷酸; 马来酸; 富马酸; 邻苯二甲酸 任选被烷基或卤素取代的水杨酸; D-葡萄糖醛酸 其中R2是烷基,卤代烷基,羟烷基,D-10-樟脑基或任选被烷基或卤素取代的苯基的磺酸R2SO3H; 羧酸R3CO2H,其中R3是氢,烷基,三卤代烷基,羧基,任选被烷基或卤素取代的苯基或吡啶基; 硼酸R4B(OH)2,其中R4是烷基或任选被烷基或卤素取代的苯基; 膦酸R5PO3H2,其中R5是烷基,卤代烯基或任选被烷基或卤素取代的苯基; 硫酸R6OSO3H,其中R6是氢或烷基; 或链烷酸X-(CH 2)q CO 2 H,其中q为0至11,X为卤素,三卤代烷基,卤代烯基,氰基,氨基羰基或CO 2 R 7,其中R 7为氢或烷基。 优选的化合物包括其中R是2-乙基-2H-四唑-5-基的化合物; R1是三氟甲基; n为1; 并且所述盐衍生自盐酸或其中R2是烷基的磺酸R2SO3H或羟烷基。
    • 6. 发明专利
    • 5-[(ARIL SUBSTITUIDO) ALQUENILEN Y ALQUINILEN)]-2,4- DIAMINOPIRIMIDINAS COMO PESTICIDAS .
    • CO4750757A1
    • 1999-03-31
    • CO96060699
    • 1996-11-19
    • FMC CORP
    • HENRIE II ROBERT NCULLEN THOMAS GYEAGER WALTER HBROWN MARY EBUSER JOHN W
    • A01N33/06A01N43/54
    • Un compuesto 2,4-diaminopirimidina 5-sustituido de fórmula: donde R, R1, R2 y R3 son independientemente seleccionados entre hidrógeno, alquilo, cicloalquilo, alcoxialquilo, alcoxialcoxialqui]o, arilalquilo, alquilcarbonilo, cicloalquilcarbonilo, alcoxicarbonilo, alcoxialquilcarbonilo, alcoxialcoxialquilcarbonilo, arilcarbonilo, piridinilcarbonilo, ariloxialquilo, haloalquilcarbonilo y cianoalquilcarbonilo, o R1 y R2 y R3 y R, cada uno independientemente, cuando son tomados junto con pentileno o 3-oxapentileno, forman sistemas de anillo de piperidina y morfolina, respectivamente; R4 es hidrógeno o alquilo inferior: U es un alquenileno C3 a aproximadamente C12, haloalquenileno, alcoxialquenileno, 2-(1-cicloalquil 1-substituido) alquenileno, 2-(oxacicloalquil substituido) alquenileno, 2-(2(1,3-dioxacicloalquil) 2-substituido) alquenileno, dialquilsililalquenileno, oxoalquenileno o hidroxialquenileno, o un alquinileno C3 a aproximadamente C12, heterocicloalquilalquinileno, 2-(1-cicloalquil 1-substituido) alquinileno, 2-(oxacicloalquil substituido) alquinileno, 2-(2-(1,3-dioxacicloalquil) 2-substituido) alquinileno, dialquilsililalquinileno, oxoalquinileno o hidroxialquinileno; donde V, W, X, Y y Z son independientemente seleccionados entre hidrógeno, halógeno, alquilo inferior, haloalquilo inferior, alcoxi inferior, haloalcoxi inferior, alcoxialquilo inferior, alquilsulfonilo inferior, arilo substituido, e hidroxi, y n es O ó 1 y sus sales aceptables desde el punto de vista agrícola.