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1. 发明申请

WO2007147061A2 TRIDENTATE METAL CATALYST FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的三元金属催化剂
公开(公告)号：WO2007147061A2
公开(公告)日：2007-12-21
申请号：PCT/US2007/071229
申请日：2007-06-14
申请人： FINA TECHNOLOGY, INC. , RAZAVI, Abbas , MARIN, Vladimir , LOPEZ, Margarito
发明人： RAZAVI, Abbas , MARIN, Vladimir , LOPEZ, Margarito
IPC分类号： C08F4/06
CPC分类号： C08F10/00 , B01J31/122 , B01J31/143 , B01J31/1815 , B01J31/2243 , B01J2531/0244 , B01J2531/40 , B01J2531/48 , B01J2531/49 , B01J2531/50 , C07F7/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/04 , C08F2500/20 , C08F2500/18 , C08F2500/12 , C08F210/14 , C08F210/08 , C08F2500/15 , C08F4/64113 , C08F4/64151 , C08F4/64093 , C08F2500/24
摘要： A process for the preparation of a tridentate transition metal catalyst components incorporating pyridinyl bis-amino or monoamino ligand structures which do not require π bonding of the transition metal through the use of cyclopentadienyl rings. The ligand structure incorporates a heteroatom group that involves nitrogen in one organogroup and either oxygen or nitrogen in another organogroup. The process of preparing the catalyst component involves the reaction of a bis-amino or oxyamino pyridenyl ligand compound with an organo transition metal compound involving a tetrabenzyl ligand or other functional group ligands linked to a transition metal such as titanium zirconium or hafnium.
摘要翻译：制备结合吡啶基双氨基或单氨基配体结构的三齿过渡金属催化剂组分的方法，其不需要通过使用环戊二烯基环P过渡金属的p键合。配体结构包含在一个有机组中涉及氮的杂原子基团和另一有机基团中的氧或氮。制备催化剂组分的方法包括双 - 氨基或氧氨基吡啶基配体化合物与涉及四苄基配体或与过渡金属例如钛锆或铪连接的其它官能团配体的有机过渡金属化合物的反应。

2. 发明申请

WO2004047972A3 NEW CATALYST STRUCTURE FOR OLEFIN POLYMERIZATION 审中-公开
公开(公告)号：WO2004047972A3
公开(公告)日：2004-06-10
申请号：PCT/US2003/036049
申请日：2003-11-12
申请人： FINA TECHNOLOGY, INC.
发明人： RAZAVI, Abbas , LOPEZ, Margarito , BAEKELMANS, Didier , MARIN, Vladimir
IPC分类号： B01J31/00
摘要： A catalyst comprising e.g. a pyridine bisimine ligand bonded to a transition metal by at least two heteroatoms of the ligand, the ligand having at least two aromatic groups or cyclopentadienyl groups on different heteroatoms of the ligand. The transition metal compound, its preparation, preparation and use of the catalyst in an olefin polymerization catalyst are also disclosed.

3. 发明申请

WO2007078387A1 CATALYST COMPOSITIONS AND METHODS OF FORMING ISOTACTIC POLYPROPYLENE 审中-公开
标题翻译：催化剂组合物和形成异构聚丙烯的方法
公开(公告)号：WO2007078387A1
公开(公告)日：2007-07-12
申请号：PCT/US2006/041686
申请日：2006-10-27
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir , RAZAVI, Abbas
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： B01J31/12
CPC分类号： C08F110/06 , B01J31/2295 , B01J2531/48 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F4/65927 , C08F2500/03 , C08F2500/15 , C08F2500/20
摘要： Olefin polymerization processes are described herein. In one embodiment, the process generally includes introducing propylene monomer to a reaction zone, disposing an isospecific metallocene catalyst within the reaction zone, wherein the isospecific metallocene catalyst has the formula: (SiR A 2 )(CpR B 4 )(FluR C 8 )MA n ; wherein Si is silicon and is a structural bridge between Cp and Flu, Cp is a cyclopentadienyl group, Flu is a fluorenyl group, M is a transition metal, A is a leaving group, n is an integer equal to the valence of M minus 2, R A is independently selected from hydrogen, alkyls, aromatics and combinations thereof, R B is independently selected from hydrogen, alkyls and combinations thereof and R C is independently selected from hydrogen, alkyls, aromatics and combinations thereof, contacting the propylene monomer with the isospecific metallocene catalyst to form isotactic polypropylene and recovering the isotactic polypropylene from the reaction zone.
摘要翻译：烯烃聚合方法在本文中描述。在一个实施方案中，该方法通常包括将丙烯单体引入反应区，在反应区内设置等体金属茂催化剂，其中该特异性金属茂催化剂具有下式：（SiR 2 O 2 / SUB>）

4. 发明申请

WO2007022244A2 PREPARATION AND USE OF TETRASUBSTITUTED FLUORENYL CATALYSTS FOR POLMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的四取代芴酮催化剂的制备和应用
公开(公告)号：WO2007022244A2
公开(公告)日：2007-02-22
申请号：PCT/US2006/031950
申请日：2006-08-16
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir , RAZAVI, Abbas
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： C08F4/44 , B01J31/00 , C08F110/06
CPC分类号： C07F7/00 , B01J31/2282 , B01J2231/122 , B01J2531/0263 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/20 , C08F2500/12 , C08F2500/04 , C08F2500/03
摘要： Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Such monomers include ethylene, C 3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The polymerization catalyst characterized by the formula B(FIuL)MQ n in which Flu is a fluorenyl group substituted at at least the 2,7- and 3,6-positions by hydrocarbyl groups, preferably relatively bulky hydrocarbyl groups. L is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 of the Periodic Table of Elements, such as nitrogen, R is an alkyl group, a cycloalkyl group or an aryl group and B is a structural bridge extending between the groups L and Flu, which imparts stereorigidity to the ligand structure, M is a Group 4 or Group 5 transition metal, such as titanium, zirconium or hafnium and Q is selected from the group consisting of chlorine, bromine, iodine, an alkyl group, an amino group, an aromatic group and mixtures thereof, with n being 1or 2.
摘要翻译：用于烯属不饱和单体聚合以制备聚合物（包括共聚物或均聚物）的催化剂组合物和方法。这样的单体包括乙烯，C 3 +α烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。由式B（FIuL）MQ n表示的聚合催化剂，其中Flu是在至少2,7-和3,6位被烃基取代的芴基，优选相对大体积的烃基组。 L是取代或未取代的环戊二烯基，茚基或芴基或杂环基XR，其中X是元素周期表第15或16族的杂原子，如氮，R是烷基，环烷基或芳基，B是在L和Flu之间延伸的结构桥，其赋予配体结构立体刚性，M是第4族或第5族过渡金属，如钛，锆或铪，Q选自由氯，溴，碘，烷基，氨基，芳族基及其混合物组成的基团，其中n为1或2。

5. 发明申请

WO2007022243A2 BIDENTATE CATALYST FOR OLEFIN POLYMERIZATION, METHODS OF FORMING SUCH AND PRODUCTS THEREFROM 审中-公开
标题翻译：用于烯烃聚合的双向催化剂，其形成方法和产品
公开(公告)号：WO2007022243A2
公开(公告)日：2007-02-22
申请号：PCT/US2006/031949
申请日：2006-08-16
申请人： FINA TECHNOLOGY, INC. , RAZAVI, Abbas , MARIN, Vladimir , LOPEZ, Margarito
发明人： RAZAVI, Abbas , MARIN, Vladimir , LOPEZ, Margarito
IPC分类号： C08F4/44 , B01J31/00 , C08F110/06
CPC分类号： C08F10/00 , B01J31/1825 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F110/06 , C08F4/64048 , C08F4/659 , C08F2500/04 , C08F2500/15
摘要： Bidentate catalyst systems and the methods or forming such are described herein. The catalyst systems generally are compounds having the general formula: where R, R 1 , R 2 and R 3 are optional and independently selected from hydrogen, C 1 to C 20 alkyl groups or C6 to C20 aryl groups, A' and A" are independently selected from coordination groups, M is a Group 4 or 5 transition metal, X is selected from halogens, alkyl groups, aromatic groups or combinations thereof and n is less than 4.
摘要翻译：双齿催化剂体系和方法或形成方法在本文中描述。催化剂体系通常是具有以下通式的化合物：其中R 1，R 2，R 2和R 3是任选的，并且独立地选自氢 C 1至C 20烷基或C 6至C 20芳基，A'和A“独立地选自配位基团，M为第4或5族过渡金属 X选自卤素，烷基，芳基或其组合，n小于4。

6. 发明申请

WO2006137818A1 CATALYST COMPONENTS AND THEIR USE IN THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：催化组分及其在烯烃聚合中的用途
公开(公告)号：WO2006137818A1
公开(公告)日：2006-12-28
申请号：PCT/US2005/000109
申请日：2005-01-04
申请人： FINA TECHNOLOGY, INC. , MARIN, Vlaimir , RAZAVI, Abbas
发明人： MARIN, Vlaimir , RAZAVI, Abbas
IPC分类号： C08F4/64 , C08F210/06 , C08F110/06
CPC分类号： C07F17/00 , C08F4/65912 , C08F110/06 , C08F2500/15 , C08F4/65927
摘要： Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers specific to the polymerization of propylene to produce isotactic polypropylene and copolymer, specifically an ethylene-propylene copolymer. An olefin polymerization catalyst is characterized by the formula: B(FluA)MQ n wherein Flu is a fluorenyl group substituted at the 4(5) position by a bulky hydrocarbyl group having at least 3 carbon atoms, A is a substituted or unsubstituted cyclopentadienyl or indenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 such as nitrogen. R is an alkyl group or cycloalkyl group or a mononuclear aromatic group which may be substituted or unsubstituted. B is a structural bridge which imparts stereorigidity to the ligand structure. The bridge B is characterized by the formula ER'R", in which E is a carbon, silicon or germanium atom, and R' and R" are each independently an alkyl group, an aromatic group or a cycloalkyl group. M is a Group 4 or Group 5 transition metal such as titanium, zirconium or hafnium. Q is chlorine, bromine, iodine, an alkyl group, an amino group or an aromatic group. n is 1 or 2. The fluorenyl group may be substituted at both of the 4 or 5 positions with a bulky hydrocarbyl group containing at least 3 carbon atoms. A may take the form of an indenyl group which is substituted or unsubstituted, or a cyclopentadienyl group which is substituted at the 3 or the 3 and 5 positions. The fluorenyl group may be mono-substituted at the 4 (or 5) position and is otherwise unsubstituted or is di-substituted at the 2,7 positions with alkyl or phenyl or substituted phenyl groups.
摘要翻译：催化剂组合物和烯属不饱和单体的聚合方法，用于制备丙烯聚合物特异性聚合物以产生全同立构聚丙烯和共聚物，特别是乙烯 - 丙烯共聚物。烯烃聚合催化剂的特征在于下列通式：其中Flu是在4（5）位被具有至少3个碳原子的庞大烃基取代的芴基，其中Flu 是取代或未取代的环戊二烯基或茚基或杂有机基团XR，其中X是第15族或第16族的杂原子如氮。 R是可以被取代或未取代的烷基或环烷基或单核芳香基。 B是赋予配体结构立体刚性的结构桥。桥B的特征在于式ER'R“，其中E是碳，硅或锗原子，R'和R”各自独立地为烷基，芳族基团或环烷基。 M是第4族或第5族过渡金属，例如钛，锆或铪。 Q是氯，溴，碘，烷基，氨基或芳基。 n是1或2.芴基可以在具有至少3个碳原子的庞大烃基的4或5位上被取代。 A可以是取代或未取代的茚基，或在3或3和5位被取代的环戊二烯基的形式。芴基可以在4（或5）位上被单取代，并且是未取代的或在2,7位被二烷基或苯基或取代的苯基二取代。

7. 发明申请

WO2008051956A1 SYNDIOTACTIC POLYPROPYLENE AND METHODS OF PREPARING SAME 审中-公开
标题翻译： SYNDIOTACTIC POLYPROPYLENE AND METHODS OF PREPARTING SAME
公开(公告)号：WO2008051956A1
公开(公告)日：2008-05-02
申请号：PCT/US2007/082199
申请日：2007-10-23
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir , RAZAVI, Abbas
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： C08F4/44
CPC分类号： C08F110/06 , C08F4/65912 , C08F10/00 , Y10S526/943 , C08F4/65927 , C08F2500/16 , C08F2500/03 , C08F2500/12 , C08F2500/20
摘要： A syndiotactic polypropylene comprising a melting temperature of greater than 160 °C, a percentage of syndiotactic pentads greater than 95%, a toluene soluble fraction of equal to or less than 0.4, and a molecular weight of from 10,000 Daltons to 1,000,000 Daltons. A syndiotactic polypropylene comprising a melting temperature of greater than 170 °C, a molecular weight of from 100,000 Daltons to 300,000 Daltons, a molecular weight distribution of less than 3, and a toluene soluble fraction of less than 0.4. A syndiotactic polypropylene comprising a tensile modulus of equal to or greater than 60,000 psi, a tensile strength at yield of equal to or greater than 3,600 psi, a tensile strength at break of equal to or greater than 3,900 psi, an elongation at yield of equal to or greater than 13%, and an elongation at break of equal to or greater than 400%.
摘要翻译：包含熔融温度大于160℃，间同立构五单元组百分比大于95％，甲苯可溶组分等于或小于0.4，分子量为10,000道尔顿至1,000,000道尔顿的间同立构聚丙烯。包含熔融温度大于170℃，分子量为100,000道尔顿至300,000道尔顿，分子量分布小于3，甲苯可溶成分小于0.4的间同立构聚丙烯。间同立构聚丙烯，其包含等于或大于60,000psi的拉伸模量，收率等于或大于3,600psi的拉伸强度，断裂时的拉伸强度等于或大于3900psi，产率下的伸长率相等至大于13％，断裂伸长率等于或大于400％。

8. 发明申请

WO2008014217A3 FLUORENYL CATALYST COMPOSITIONS AND OLEFIN POLYMERIZATION PROCESS 审中-公开
公开(公告)号：WO2008014217A3
公开(公告)日：2008-01-31
申请号：PCT/US2007/074150
申请日：2007-07-24
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir , RAZAVI, Abbas
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： C08F4/74 , C08F4/52 , C08F210/06 , C07F17/00
摘要： An olefin polymerization process comprising contacting one or more olefins and a catalyst component in a reaction zone under suitable reaction conditions to form a polyolefin, wherein the catalyst component is characterized by the formula: B(Cp)(Fl)MQ 2 wherein M comprises a metal, Q comprises a halogen, an alkyl group or an aryl group or combinations thereof, Cp comprises a cyclopentadienyl group, Fl comprises a fluorenyl group, B is a bridging group that may be characterized by the general formula -YRH wherein Y comprises C or Si and R comprises an alkyl group, an aryl group, a poly-aryl group or combinations thereof.

9. 发明申请

WO2008014217A2 FLUORENYL CATALYST COMPOSITIONS AND OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译：芴基催化剂组合物与烯烃聚合工艺
公开(公告)号：WO2008014217A2
公开(公告)日：2008-01-31
申请号：PCT/US2007/074150
申请日：2007-07-24
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir , RAZAVI, Abbas
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： C08F4/06
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/15 , C08F2500/20 , C08F210/16 , C08F2500/03 , C08F2500/12
摘要： An olefin polymerization process comprising contacting one or more olefins and a catalyst component in a reaction zone under suitable reaction conditions to form a polyolefin, wherein the catalyst component is characterized by the formula: B(Cp)(Fl)MQ 2 wherein M comprises a metal, Q comprises a halogen, an alkyl group or an aryl group or combinations thereof, Cp comprises a cyclopentadienyl group, Fl comprises a fluorenyl group, B is a bridging group that may be characterized by the general formula -YRH wherein Y comprises C or Si and R comprises an alkyl group, an aryl group, a poly-aryl group or combinations thereof.
摘要翻译：一种烯烃聚合方法，该方法包括使一种或多种烯烃和催化剂组分在合适的反应条件下在反应区中接触以形成聚烯烃，其中该催化剂组分由下式表征：B（Cp）（F1）MQ <2> 其中M包含金属，Q包含卤素，烷基或芳基或其组合，C p包含环戊二烯基，F 1包含芴基，B为桥接基团，其可由通式 -YRH其中Y包含C或Si且R包含烷基，芳基，多芳基或其组合。

10. 发明授权

EP2044131B1 FLUORENYL CATALYST COMPOSITIONS AND OLEFIN POLYMERIZATION PROCESS 有权
公开(公告)号：EP2044131B1
公开(公告)日：2019-07-17
申请号：EP07813246.1
申请日：2007-07-24
申请人： Fina Technology, Inc.
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： C08F4/74 , C08F4/52 , C08F210/06 , C07F17/00 , C08F10/00 , C08F4/6592

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