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1. 发明申请

WO2007022243A3 BIDENTATE CATALYST FOR OLEFIN POLYMERIZATION, METHODS OF FORMING SUCH AND PRODUCTS THEREFROM 审中-公开
标题翻译：用于烯烃聚合的二元催化剂，其形成方法及其产物
公开(公告)号：WO2007022243A3
公开(公告)日：2007-12-13
申请号：PCT/US2006031949
申请日：2006-08-16
申请人： FINA TECHNOLOGY , RAZAVI ABBAS , MARIN VLADIMIR , LOPEZ MARGARITO
发明人： RAZAVI ABBAS , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： C07F7/00 , C07F7/28 , C07F9/00 , C08F4/602 , C08F4/64
CPC分类号： C08F10/00 , B01J31/1825 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F110/06 , C08F4/64048 , C08F4/659 , C08F2500/04 , C08F2500/15
摘要： Bidentate catalyst systems and the methods or forming such are described herein. The catalyst systems generally are compounds having the general formula: where R, R 1 , R 2 and R 3 are optional and independently selected from hydrogen, C 1 to C 20 alkyl groups or C6 to C20 aryl groups, A' and A" are independently selected from coordination groups, M is a Group 4 or 5 transition metal, X is selected from halogens, alkyl groups, aromatic groups or combinations thereof and n is less than 4.
摘要翻译：本文描述了双齿催化剂体系及其形成方法。催化剂体系通常是具有以下通式的化合物：其中R 1，R 2，R 2和R 3是任选的并且独立地选自氢，C 1至C 20烷基或C 6至C 20芳基，A'和A“独立地选自配位基，M为第4族或第5族过渡金属 X选自卤素，烷基，芳族基团或其组合，并且n小于4。

2. 发明申请

WO2007147061A3 TRIDENTATE METAL CATALYST FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的三元金属催化剂
公开(公告)号：WO2007147061A3
公开(公告)日：2008-04-03
申请号：PCT/US2007071229
申请日：2007-06-14
申请人： FINA TECHNOLOGY , RAZAVI ABBAS , MARIN VLADIMIR , LOPEZ MARGARITO
发明人： RAZAVI ABBAS , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： B01J27/24
CPC分类号： C08F10/00 , B01J31/122 , B01J31/143 , B01J31/1815 , B01J31/2243 , B01J2531/0244 , B01J2531/40 , B01J2531/48 , B01J2531/49 , B01J2531/50 , C07F7/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/04 , C08F2500/20 , C08F2500/18 , C08F2500/12 , C08F210/14 , C08F210/08 , C08F2500/15 , C08F4/64113 , C08F4/64151 , C08F4/64093 , C08F2500/24
摘要： A process for the preparation of a tridentate transition metal catalyst components incorporating pyridinyl bis-amino or monoamino ligand structures which do not require p bonding of the transition metal through the use of cyclopentadienyl rings. The ligand structure incorporates a heteroatom group that involves nitrogen in one organogroup and either oxygen or nitrogen in another organogroup. The process of preparing the catalyst component involves the reaction of a bis-amino or oxyamino pyridenyl ligand compound with an organo transition metal compound involving a tetrabenzyl ligand or other functional group ligands linked to a transition metal such as titanium zirconium or hafnium.
摘要翻译：制备结合吡啶基双氨基或单氨基配体结构的三齿过渡金属催化剂组分的方法，其不需要通过使用环戊二烯基环p过渡金属的p键合。配体结构包含在一个有机组中涉及氮的杂原子基团和另一有机基团中的氧或氮。制备催化剂组分的方法包括双 - 氨基或氧氨基吡啶基配体化合物与涉及四苄基配体或与过渡金属例如钛锆或铪连接的其它官能团配体的有机过渡金属化合物的反应。

3. 发明申请

WO2007022244A3 PREPARATION AND USE OF TETRASUBSTITUTED FLUORENYL CATALYSTS FOR POLMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的四氟乙烯催化剂的制备和使用
公开(公告)号：WO2007022244A3
公开(公告)日：2007-11-01
申请号：PCT/US2006031950
申请日：2006-08-16
申请人： FINA TECHNOLOGY , MARIN VLADIMIR , RAZAVI ABBAS
发明人： MARIN VLADIMIR , RAZAVI ABBAS
IPC分类号： C07F17/00 , C08F4/6392 , C08F4/64
CPC分类号： C07F7/00 , B01J31/2282 , B01J2231/122 , B01J2531/0263 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/20 , C08F2500/12 , C08F2500/04 , C08F2500/03
摘要： Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Such monomers include ethylene, C 3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The polymerization catalyst characterized by the formula B(FIuL)MQ n in which Flu is a fluorenyl group substituted at at least the 2,7- and 3,6-positions by hydrocarbyl groups, preferably relatively bulky hydrocarbyl groups. L is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 of the Periodic Table of Elements, such as nitrogen, R is an alkyl group, a cycloalkyl group or an aryl group and B is a structural bridge extending between the groups L and Flu, which imparts stereorigidity to the ligand structure, M is a Group 4 or Group 5 transition metal, such as titanium, zirconium or hafnium and Q is selected from the group consisting of chlorine, bromine, iodine, an alkyl group, an amino group, an aromatic group and mixtures thereof, with n being 1or 2.
摘要翻译：催化剂组合物和用于聚合烯属不饱和单体以生产聚合物的方法，包括共聚物或均聚物。这些单体包括乙烯，C 3+α-烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。其特征在于式B（FIuL）MQ N n的聚合催化剂，其中Flu是在至少2,7-和3,6位被烃基取代的芴基，优选相当大的烃基组。 L是取代或未取代的环戊二烯基，茚基或芴基或杂有机基团XR，其中X是元素周期表第15或16族的杂原子，例如氮，R是烷基，环烷基或芳基，B是在基团L和Flu之间延伸的结构桥，其赋予配体结构立体刚性，M是第4族或第5族过渡金属，例如钛，锆或铪，Q选自由氯，溴，碘，烷基，氨基，芳基及其混合物组成的组，n为1或2。

4. 发明申请

WO2007139439A8 ACTIVATORS FOR THE HOMO-OR CO-POLYMERISATION OF ALPHA-OLEFINS WITH HOMOGENEOUS METALLOCENE CATALYST SYSTEMS 审中-公开
标题翻译：用均相金属催化剂体系共聚合ALPHA-烯烃的活化剂
公开(公告)号：WO2007139439A8
公开(公告)日：2009-01-29
申请号：PCT/RU2007000255
申请日：2007-05-23
申请人： INST OF PROBLEMS OF CHEMICAL P , TOTAL PETROCHEMICALS RES FELUY , ALDOSHIN SERGEI MIKHAILOVICH , BRAVAYA NATALIA MIKHAILOVNA , PANIN ANDREI NIKOLAEVICH , CHUKANOVA OLGA MIKHAILOVNA , RAZAVI ABBAS
发明人： ALDOSHIN SERGEI MIKHAILOVICH , BRAVAYA NATALIA MIKHAILOVNA , PANIN ANDREI NIKOLAEVICH , CHUKANOVA OLGA MIKHAILOVNA , RAZAVI ABBAS
IPC分类号： C07F17/00 , C08F4/659 , C08F10/02 , C08F10/06 , C08F10/14 , C08F210/02 , C08F210/06 , C08F210/14
CPC分类号： C08F10/00 , C08F110/06 , C08F210/06 , C08F4/6592 , C08F4/65912 , C08F4/65927 , C08F210/16
摘要： The present invention discloses a class of metallocene catalyst systems suitable for the homogeneous polymerisation of ethylene or alpha olefins that does not require the addition of aluminoxane or perfluorophenylborates as activating agent.
摘要翻译：本发明公开了一类适用于不需要加入铝氧烷或全氟苯基硼酸盐作为活化剂的乙烯或α-烯烃的均相聚合的茂金属催化剂体系。

5. 发明申请

WO2007139439A3 ACTIVATORS FOR THE HOMO-OR CO-POLYMERISATION OF ALPHA-OLEFINS WITH HOMOGENEOUS METALLOCENE CATALYST SYSTEMS 审中-公开
标题翻译：用均相金属催化剂体系共聚合ALPHA-烯烃的活化剂
公开(公告)号：WO2007139439A3
公开(公告)日：2008-06-26
申请号：PCT/RU2007000255
申请日：2007-05-23
申请人： INST OF PROBLEMS OF CHEMICAL P , TOTAL PETROCHEMICALS RES FELUY , ALDOSHIN SERGEI MIKHAILOVICH , BRAVAYA NATALIA MIKHAILOVNA , PANIN ANDREI NIKOLAEVICH , CHUKANOVA OLGA MIKHAILOVNA , RAZAVI ABBAS
发明人： ALDOSHIN SERGEI MIKHAILOVICH , BRAVAYA NATALIA MIKHAILOVNA , PANIN ANDREI NIKOLAEVICH , CHUKANOVA OLGA MIKHAILOVNA , RAZAVI ABBAS
IPC分类号： C07F17/00 , C08F4/659 , C08F10/02 , C08F10/06 , C08F10/14 , C08F210/02 , C08F210/06 , C08F210/14
CPC分类号： C08F10/00 , C08F110/06 , C08F210/06 , C08F4/6592 , C08F4/65912 , C08F4/65927 , C08F210/16
摘要： The present invention discloses a class of metallocene catalyst systems suitable for the homogeneous polymerisation of ethylene or alpha olefins that does not require the addition of aluminoxane or perfluorophenylborates as activating agent.
摘要翻译：本发明公开了一类适用于不需要加入铝氧烷或全氟苯基硼酸盐作为活化剂的乙烯或α-烯烃的均相聚合的茂金属催化剂体系。

6. 发明申请

WO2007107189A3 IMPACT COPOLYMER OF PROPYLENE PREPARED IN SINGLE REACTOR 审中-公开
标题翻译：丙烯在单反应器中制备的影响共聚物
公开(公告)号：WO2007107189A3
公开(公告)日：2007-12-06
申请号：PCT/EP2006065675
申请日：2006-08-25
申请人： TOTAL PETROCHEMICALS RES FELUY , RAZAVI ABBAS
发明人： RAZAVI ABBAS
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65904 , C08F4/65916 , C08F2500/15 , C08F210/16 , C08F2500/21
摘要： This invention relates to the field of impact copolymers and their preparation in a single reactor.
摘要翻译：本发明涉及抗冲共聚物领域及其在单一反应器中的制备。

7. 发明申请

WO2005005494A3 HETEROGENISATION OF CATALYST COMPONENTS 审中-公开
标题翻译：催化剂组分的异构化
公开(公告)号：WO2005005494A3
公开(公告)日：2005-06-16
申请号：PCT/EP2004051370
申请日：2004-07-06
申请人： ATOFINA RES , RAZAVI ABBAS
发明人： RAZAVI ABBAS
IPC分类号： C08F4/659 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F4/7042
摘要： Provided is a method for the production of an olefin polymer, which method comprises polymerising an olefin monomer in the presence of a metallocene catalyst, which catalyst comprises one or more alkyl moieties having a terminal olefin group, and is selected from a catalyst of formula (I): R" (CpRq)XMQpwherein Cp is a substituted or unsubstituted cyclopentadienyl or fluorenyl ring; R" is a structural bridge between Cp and X imparting stereorigidity to the component; each R is the same or different and is selected from a hydrocarbyl group having from 1-20 carbon atoms, a halogen, an alkoxy group, an alkoxyalkyl group, an alkylamino group or an alkylsilylo group; q is an integer from 0-8; X is a heteroatom from group VA or group VIA; M is a metal atom from group 11113, IVB, VB or VIB in any of its theoretical oxidation states; and each Q is a hydrocarbon having from 1-20 carbon atoms or is a halogen; p is an integer which is the oxidation state of M minus 2; wherein the alkyl moiety having a terminal olefin group is a substituent on R", Cp and/or X; and from a catalysts of formula (II): (L)nM(Q)p wherein L is an heteroatom -containing ligand; n is an integer of 1, 2, or 3; M is selected from Ti, Zr, Sc, V, Cr, Fe, Co, Ni, Pd, or a lanthanide metal; each Q is independently a hydrocarbon having 1-20 carbon atoms or a halogen; and p is the valence of M minus the sum of the coordination numbers of all L; wherein the alkyl moiety having a terminal olefin group is a substituent on L, and/or Q.
摘要翻译：提供了一种生产烯烃聚合物的方法，该方法包括在茂金属催化剂存在下聚合烯烃单体，该催化剂包含一个或多个具有末端烯烃基团的烷基部分，并且选自式（ I）：R“（CpRq）XMQp其中Cp是取代或未取代的环戊二烯基或芴基环; R”是赋予组分立体刚性的Cp和X之间的结构桥; 每个R相同或不同，并且选自具有1-20个碳原子的烃基，卤素，烷氧基，烷氧基烷基，烷基氨基或烷基甲硅烷基; q是0-8的整数; X是VA或VIA族的杂原子; M是来自其任何理论氧化态的第11113，IVB，VB或VIB族的金属原子; 并且每个Q是具有1-20个碳原子的烃或是卤素; p是M的氧化态减去2的整数; 其中具有末端烯基的烷基部分是R“，Cp和/或X上的取代基;以及式（II）的催化剂：（L）nM（Q）p其中L是含杂原子的配体; n 是1,2或3的整数; M选自Ti，Zr，Sc，V，Cr，Fe，Co，Ni，Pd或镧系金属;每个Q独立地为具有1-20个碳原子的烃或卤素; p是M的化合价减去所有L的配位数之和;其中具有末端烯基的烷基部分是L和/或Q上的取代基。

8. 发明申请

WO2005047350A2 HETEROGENISATION OF POLYMERISATION CATALYSTS BY IONIC LIQUIDS 审中-公开
标题翻译：离子液体催化聚合催化剂的异氰酸酯化反应
公开(公告)号：WO2005047350A2
公开(公告)日：2005-05-26
申请号：PCT/EP2004052820
申请日：2004-11-05
申请人： TOTAL PETROCHEMICALS RES FELUY , CENTRE NAT RECH SCIENT , LAVASTRE OLIVIER , BONNETTE FABIEN , RAZAVI ABBAS
发明人： LAVASTRE OLIVIER , BONNETTE FABIEN , RAZAVI ABBAS
IPC分类号： B01J31/02 , B01J31/12 , B01J31/14 , B01J31/18 , C08F110/02 , C08F4/70
CPC分类号： B01J31/143 , B01J31/0284 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2531/0241 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F2500/24 , C08F4/7042 , C08F4/7006
摘要： The present invention discloses a method for preparing a dissolved catalyst component comprising the steps of: a) providing a halogenated precursor component of formula (I) X¯[CH2-]- b) reacting the halogenated bisimine precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; c) mixing in a solvent one equivalent of the ionic liquid prepared in step b) with a metallic complex of formula (II) L2MY2 wherein L is a coordinating ligand for the metallic site, said coordination being achieved by phosphorus, nitrogen or oxygen; d) evaporating the solvent; and e) retrieving a hybrid single site catalyst component/ionic liquid system. It also discloses an active catalyst system heterogenised by an ionic liquid and its use in the polymerisation of olefins.
摘要翻译：本发明公开了制备溶解的催化剂组分的方法，其包括以下步骤：a）提供式（I）的卤化前体组分X [CH 2 - ] - b）使卤化的双亚胺前体与离子液体前体在溶剂以制备离子液体; c）在溶剂中混合1当量的步骤b）中制备的离子液体与式（II）的金属络合物L2MY2，其中L为金属位点的配位配体，所述配位通过磷，氮或氧实现; d）蒸发溶剂; 和e）回收混合单中心催化剂组分/离子液体体系。它还公开了一种由离子液体异质化的活性催化剂体系及其在烯烃聚合中的用途。

9. 发明申请

WO2004060942A3 GROUP III BRIDGED METALLOCENE BASED ON CYCLOPENTADIENYL-FLUORENYL LIGANDS 审中-公开
标题翻译：基于环戊二烯基 - 芴基配体的III族桥联金属茂
公开(公告)号：WO2004060942A3
公开(公告)日：2004-11-11
申请号：PCT/EP2004000142
申请日：2004-01-06
申请人： ATOFINA RES SA , CENTRE NAT RECH SCIENT , CARPENTIER JEAN-FRANCOIS , KIRILLOV EVGUENI , RAZAVI ABBAS
发明人： CARPENTIER JEAN-FRANCOIS , KIRILLOV EVGUENI , RAZAVI ABBAS
IPC分类号： C07F17/00 , C08F2/38 , C08F4/52 , C08F10/00 , C08F112/08 , C08F120/06
CPC分类号： C08F4/52 , C07F17/00 , C08F10/00 , Y10S526/943
摘要： The present invention discloses a metallocene catalyst component of formula (Flu-R"-Cp)M(eta -C3R'5)(ether)n (I) wherein Cp is a cyclopentadienyl, substituted or unsubstituted, Flu is a fluorenyl, substituted or unsubstitutted, R" is a structural bridge between Cp and Flu imparting stereorigidity to the component, M is a metal Group III of the Periodic Table, each R' is the same or different and is hydrogen or a hydrocarbyl having from 1 to 20 carbon atoms and n is 0, 1 or 2. It further discloses a process for preparing said catalyst component and its used in the controlled polymerisation of polar or non polar monomers.
摘要翻译：本发明公开了式（Flu-R“-Cp）M（η3 -C 3 R'5）（醚）n（I）的茂金属催化剂组分，其中Cp是取代或未取代的环戊二烯基，Flu是芴基，取代的或未取代的，R“是Cp和Flu之间的结构桥，赋予组分立体刚性，M是元素周期表第III族金属，每个R'相同或不同，并且是氢或具有1至 20个碳原子和n是0,1或2.它进一步公开了制备所述催化剂组分和其用于极性或非极性单体的受控聚合的方法。

10. 发明申请

WO2010066906A3 PREPARATION OF LONG-CHAIN BRANCHED ISOTACTIC POLYPROPYLENE 审中-公开
标题翻译：长链分支异构聚丙烯的制备
公开(公告)号：WO2010066906A3
公开(公告)日：2010-09-23
申请号：PCT/EP2009067062
申请日：2009-12-14
申请人： TOTAL PETROCHEMICALS RES FELUY , CENTRE NAT RECH SCIENT , CARPENTIER JEAN-FRANCOIS , KIRILLOV EVGUENI , MARQUET NICOLAS , RAZAVI ABBAS
发明人： CARPENTIER JEAN-FRANCOIS , KIRILLOV EVGUENI , MARQUET NICOLAS , RAZAVI ABBAS
IPC分类号： C08F210/06 , C08F4/6592
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F210/14 , C08F2500/09 , C08F2500/15 , C08F2500/03
摘要： The present invention discloses a method for preparing long-chain-branched isotactic polypropylene by first oligomerising propylene with a suitable oligomerisation catalyst system and then copolymerising propylene and the oligomer obtained in situ with a mono-aryl-substituted methylene bridged catalyst system.
摘要翻译：本发明公开了一种制备长支链全同立构聚丙烯的方法，首先用合适的低聚催化剂体系将丙烯低聚，然后使丙烯与通过单芳基取代的亚甲基桥接催化剂体系原位获得的低聚物共聚。

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