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    • 2. 发明申请
    • ELECTRODE MATERIAL FOR A SPARK PLUG
    • 用于火花塞的电极材料
    • WO2011068834A3
    • 2011-10-27
    • PCT/US2010058501
    • 2010-12-01
    • FEDERAL MOGUL IGNITION COMA SHUWEILYKOWSKI JAMES D
    • MA SHUWEILYKOWSKI JAMES D
    • H01T13/20H01T13/32
    • H01T13/39
    • A spark plug electrode material that may be used in spark plugs and other ignition devices including industrial plugs, aviation igniters, glow plugs, or any other device that is used to ignite an air/fuel mixture in an engine. According to an exemplary embodiment, the electrode material includes a refractory metal (for example, tungsten (W), molybdenum (Mo), rhenium (Re), ruthenium (Ru) and/or chromium (Cr)) and a precious metal (for example, rhodium (Rh), platinum (Pt), palladium (Pd) and/or iridium (Ir)), where the refractory metal is present in an amount that is greater than that of the precious metal. This includes, but is certainly not limited to, electrode materials including tungsten-based alloys such as W-Rh and ruthenium-based alloys such as Ru- Rh. Other combinations and embodiments are also possible.
    • 火花塞电极材料,可用于火花塞和其他点火装置,包括工业插头,航空点火器,电热塞或用于点燃发动机中的空气/燃料混合物的任何其他装置。 根据示例性实施例,电极材料包括难熔金属(例如,钨(W),钼(Mo),铼(Re),钌(Ru)和/或铬(Cr))和贵金属 例如铑(Rh),铂(Pt),钯(Pd)和/或铱(Ir)),其中难熔金属的存在量大于贵金属的量。 这包括但不限于包括诸如W-Rh的钨基合金和诸如Ru-Rh的钌基合金的电极材料。 其他组合和实施例也是可能的。
    • 4. 发明申请
    • SPARK PLUG INCLUDING HIGH TEMPERATURE PERFORMANCE ELECTRODE
    • 火花塞包括高温性能电极
    • WO2011008801A2
    • 2011-01-20
    • PCT/US2010041890
    • 2010-07-14
    • FEDERAL MOGUL IGNITION COMA SHUWEILYKOWSKI JAMES D
    • MA SHUWEILYKOWSKI JAMES D
    • H01T13/39H01T13/20
    • H01T13/39H01T21/02
    • A spark plug (20) includes at least one electrode(22, 24) having a sparking end (28, 32). The sparking end (28, 32) is formed of a high temperature performance alloy including chromium in an amount of 10.0 weight percent to 60.0 weight percent, palladium in an amount of 0.5 weight percent to 10.0 weight percent, and a balance substantially of at least one of molybdenum and tungsten. The sparking end (28, 32) presents a spark contact surface (36, 44), and at a temperature of at least 500° C, such as during use of the spark plug (20) in an internal combustion engine, a layer (50) of chromium oxide (Cr2O3) forms at said spark contact surface (36, 44). The layer (50) Of Cr2O3 protects the bulk of the sparking end 32, 38 from the extreme conditions of the combustion chamber and prevents erosion, corrosion, and balling.
    • 火花塞(20)包括具有火花端(28,32)的至少一个电极(22,24)。 火花端(28,32)由高温性能合金形成,所述高温性能合金包含10.0重量百分比至60.0重量百分比的铬,0.5重量百分比至10.0重量百分比的钯,以及余量基本上至少为 钼和钨之一。 火花端(28,32)呈现火花接触表面(36,44),并且在至少500℃的温度下,例如在内燃机中使用火花塞(20)期间,层( 50)的氧化铬(Cr 2 O 3)在所述火花接触表面(36,44)处形成。 Cr2O3的层(50)保护火花端32,38的大部分免受燃烧室的极端条件影响并防止腐蚀,腐蚀和球化。
    • 5. 发明申请
    • ELECTRODE MATERIAL FOR A SPARK PLUG
    • 用于火花塞的电极材料
    • WO2013003325A3
    • 2013-05-10
    • PCT/US2012044160
    • 2012-06-26
    • FEDERAL MOGUL IGNITION COMA SHUWEI
    • MA SHUWEI
    • H01T13/20H01T13/39
    • H01T13/39H01T21/02
    • An electrode material for use with spark plugs (10) and other ignition devices, where the electrode material includes ruthenium (Ru), plus one or more additional constituents like precious metals, refractory metals, active elements, metal oxides, or a combination thereof. In one example, the electrode material is a multi-phase material that has a matrix phase including ruthenium (Ru) and one or more precious metals, refractory metals and/or active elements, and a dispersed phase including a metal oxide. The metal oxide may be provided in particle form or fiber/whisker form, and is dispersed throughout the matrix phase. A powder metallurgy process for forming the electrode material into a spark plug electrode (12, 18, 30, 32) is also provided.
    • 与电火花塞(10)和其他点火装置一起使用的电极材料,其中电极材料包括钌(Ru),加上一种或多种其他成分如贵金属,难熔金属,活性元素,金属氧化物或其组合。 在一个实例中,电极材料是具有包含钌(Ru)和一种或多种贵金属,难熔金属和/或活性元素的基体相以及包含金属氧化物的分散相的多相材料。 金属氧化物可以以颗粒形式或纤维/晶须形式提供,并分散在整个基质相中。 还提供了用于将电极材料形成为火花塞电极(12,18,30,32)的粉末冶金工艺。
    • 6. 发明申请
    • ELECTRODE MATERIAL FOR A SPARK PLUG
    • 用于火花塞的电极材料
    • WO2012102994A3
    • 2012-11-08
    • PCT/US2012022184
    • 2012-01-23
    • FEDERAL MOGUL IGNITION COMA SHUWEI
    • MA SHUWEI
    • H01T13/39
    • H01T13/39B22F1/0003C22C1/0466H01T21/02
    • An electrode material that may be used in spark plugs (10) and other ignition devices including industrial plugs, aviation igniters, glow plugs, or any other device that is used to ignite an air/fuel mixture in an engine. The electrode material is a metal composite (100) and includes a particulate component (104) embedded or dispersed within a matrix component (102) such that the metal composite has a multi-phase microstructure. In one embodiment, the metal composite (100) includes a matrix component (102) that includes a precious metal and makes up about 2-80%wt of the overall composite and a particulate component (104) that includes a ruthenium-based material and makes up about 20-98%wt of the overall composite.
    • 可用于火花塞(10)和其它点火装置的电极材料,包括工业塞子,航空点火器,电热塞或用于点燃发动机中的空气/燃料混合物的任何其它装置。 电极材料是金属复合材料(100),并且包括嵌入或分散在基质组分(102)中的颗粒组分(104),使得金属复合材料具有多相微结构。 在一个实施方案中,金属复合材料(100)包括基体组分(102),其包含贵金属并占组合物总重量的约2-80%wt,以及包含钌基材料的颗粒组分(104) 占整个复合材料的约20-98%wt。
    • 9. 发明申请
    • RUTHENIUM-BASED ELECTRODE MATERIAL FOR A SPARK PLUG
    • 用于火花塞的基于钌的电极材料
    • WO2012094359A3
    • 2012-10-26
    • PCT/US2012020130
    • 2012-01-04
    • FEDERAL MOGUL IGNITION COMA SHUWEI
    • MA SHUWEI
    • H01T13/20H01T13/32
    • H01T13/39C22C1/1078C22C5/04
    • A ruthenium-based electrode material for use with a spark plug. The electrode material comprises ruthenium (Ru) and a precious metal. The ruthenium (Ru) is the single largest constituent of the electrode material on a wt% basis. The electrode material may have a density that is less than or equal to about 15.5 g/cm3 and may include at least one other precious metal. The electrode material may be used in a spark plug that includes a metallic shell having an axial bore, an insulator having an axial bore and at least partially disposed within the axial bore of the metallic shell, a center electrode at least partially disposed within the axial bore of the insulator, and a ground electrode attached to a free end of the metallic shell. The center electrode, the ground electrode or both may be formed at least in part from the electrode alloy.
    • 一种用于火花塞的钌基电极材料。 电极材料包含钌(Ru)和贵金属。 钌(Ru)是基于重量%的电极材料的最大单一成分。 电极材料可以具有小于或等于约15.5g / cm 3的密度,并且可以包括至少一种其它贵金属。 电极材料可以用于包括具有轴向孔的金属壳的火花塞,具有轴向孔的绝缘体,并且至少部分地设置在金属壳的轴向孔内;中心电极,至少部分地设置在轴向孔内 绝缘体的孔,以及附接到金属壳的自由端的接地电极。 中心电极,接地电极或两者可以至少部分地从电极合金形成。
    • 10. 发明申请
    • SPARK PLUG WITH VOLUME-STABLE ELECTRODE MATERIAL
    • SPARK插头与体积稳定的电极材料
    • WO2011066406A2
    • 2011-06-03
    • PCT/US2010058028
    • 2010-11-24
    • FEDERAL MOGUL IGNITION COMA SHUWEI
    • MA SHUWEI
    • H01T13/39
    • H01T13/39H01T21/02
    • A spark plug having one or more electrodes at least partially fabricated from an aluminum-containing Ni-based alloy. The alloy is a volume -stable alloy that includes a Ni3A1 precipitate in a ?' -phase distributed in a Ni matrix ?-phase. The precipitate is formed in the alloy prior to the alloy being used to fabricate electrodes and thus prevents additional Ni3Al precipitate from being formed in the alloy once in service in a high-temperature environment. This, in turn, prevents a volume decrease of the alloy that may lead to an increased spark gap and spark plug malfunction. The volume-stable alloy may be made by solution treatment, quenching, and heat aging of a Ni-Cr-Al-Fe alloy.
    • 具有至少部分地由含铝的Ni基合金制成的一个或多个电极的火花塞。 该合金是体积稳定的合金,其包括在α' 相分布在Ni基体α相中。 在用于制造电极的合金之前,在合金中形成沉淀物,从而防止在合金中在高温环境中使用中另外的Ni 3 Al沉淀物形成。 这又防止合金的体积减小,这可能导致火花间隙增加和火花塞故障。 体积稳定的合金可以通过Ni-Cr-Al-Fe合金的固溶处理,淬火和热老化制成。