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1. 发明授权

US08497330B2 Methods for polymerization using spray dried and slurried catalyst 有权
标题翻译：使用喷雾干燥和浆化催化剂进行聚合的方法
公开(公告)号：US08497330B2
公开(公告)日：2013-07-30
申请号：US12976059
申请日：2010-12-22
申请人： F. David Hussein , Kevin J. Cann , Ann M. Schoeb-Wolters , Phuong A. Cao , Bruce J. Savatsky , Eric J. Markel , Daniel P. Zilker, Jr. , Garth R. Giesbrecht
发明人： F. David Hussein , Kevin J. Cann , Ann M. Schoeb-Wolters , Phuong A. Cao , Bruce J. Savatsky , Eric J. Markel , Daniel P. Zilker, Jr. , Garth R. Giesbrecht
IPC分类号： C08F4/64 , C08F4/76 , C08F4/52 , C08F2/34
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F210/16 , C08F4/65916 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/03
摘要： Methods for gas phase olefin polymerization are provided. The method can include combining a spray dried catalyst system with a diluent to produce a catalyst slurry. The catalyst system can include a metallocene compound. Ethylene, a continuity additive, and the catalyst slurry can be introduced to a gas phase fluidized bed reactor. The reactor can be operated at conditions sufficient to produce a polyethylene. The spray dried catalyst system can have a catalyst productivity of at least 12,000 grams polyethylene per gram of the catalyst system.
摘要翻译：提供了气相烯烃聚合方法。该方法可以包括将喷雾干燥的催化剂体系与稀释剂组合以产生催化剂浆料。催化剂体系可以包括金属茂化合物。可将乙烯，连续性添加剂和催化剂浆料引入气相流化床反应器。反应器可以在足以产生聚乙烯的条件下操作。喷雾干燥的催化剂体系可以具有每克催化剂体系至少12,000克聚乙烯的催化剂生产率。

2. 发明授权

US08835582B2 Catalyst systems and methods for using same to produce polyolefin products 有权
标题翻译：用于制备聚烯烃产品的催化剂体系和方法
公开(公告)号：US08835582B2
公开(公告)日：2014-09-16
申请号：US13576908
申请日：2011-02-18
申请人： Kevin J. Cann , C. Jeff Harlan , Wesley R. Mariott , Lixin Sun , Daniel P. Zilker, Jr. , F. David Hussein , Phuong A. Cao , John H. Moorhouse , Mark G. Goode
发明人： Kevin J. Cann , C. Jeff Harlan , Wesley R. Mariott , Lixin Sun , Daniel P. Zilker, Jr. , F. David Hussein , Phuong A. Cao , John H. Moorhouse , Mark G. Goode
IPC分类号： C08F4/54 , C08F10/02 , C08F4/58
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F210/16 , C08F4/65916 , C08F4/02 , C08F4/64148 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Catalyst systems and methods for making and using the same. The catalyst system can include a single site catalyst compound, a support comprising fluorinated alumina, and an aluminoxane. The aluminoxane can be present in an amount of about 10 mmol or less per gram of the support.
摘要翻译：催化剂体系及其制造和使用方法。催化剂体系可以包括单中心催化剂化合物，包含氟化氧化铝的载体和铝氧烷。铝氧烷可以以每克载体约10mmol或更少的量存在。

3. 发明授权

US07847036B2 Method for reducing and/or preventing production of excessively low density polymer product during polymerization transitions 有权
标题翻译：用于在聚合过渡期间减少和/或防止生产过低密度聚合物产物的方法
公开(公告)号：US07847036B2
公开(公告)日：2010-12-07
申请号：US12519484
申请日：2007-12-12
申请人： Bruce J. Savatsky , Daniel P. Zilker, Jr.
发明人： Bruce J. Savatsky , Daniel P. Zilker, Jr.
IPC分类号： C08F2/34 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F2400/02 , Y10S526/901 , Y10S526/905 , C08F2/34 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： A method for controlling a transition from an initial polymerization reaction to a target polymerization reaction in a manner that reduces significantly the amount of off-grade product having excessively low density produced during the transition, including steps of: during the transition, maintaining a first one of a concentration ratio and a feed ratio at an at least substantially constant value while implementing process changes in an effort to bring produced polymer into compliance with a target specification set and monitoring (without controlling) the other one of the concentration ratio and the feed ratio to generate first data; and during the transition, determining from the first data whether polymer having excessively low density is likely to be produced during the transition, and upon determining that polymer having excessively low density is likely to be produced during the transition, maintaining during the remaining portion of the transition the other ratio at a value that is at least substantially constant while allowing the first ratio to vary is provided.
摘要翻译：用于控制从初始聚合反应转变为目标聚合反应的方法，其显着降低在转变期间产生的具有过低密度的低级产物的量，包括以下步骤：在转变期间，保持第一个浓度比和进料比在至少基本恒定的值的同时，同时实施过程变化，努力使生成的聚合物符合目标规范集和监测（不控制）另一个浓度比和进料比生成第一个数据; 并且在转变期间，从第一数据确定是否可能在转变期间产生具有过低密度的聚合物，并且在确定在转变期间可能产生密度过低的聚合物时，保持在剩余部分提供了在允许第一比率变化的同时至少基本上恒定的值的另一比例的转变。

4. 发明授权

US08318872B2 Method for controlling bimodal catalyst activity during polymerization 有权
标题翻译：在聚合过程中控制双峰催化剂活性的方法
公开(公告)号：US08318872B2
公开(公告)日：2012-11-27
申请号：US12808946
申请日：2008-12-17
申请人： Bruce J. Savatsky , John H. Oskam , Mark W. Blood , Mark B. Davis , Douglas H. Jackson , Timothy R. Lynn , Daniel P. Zilker, Jr.
发明人： Bruce J. Savatsky , John H. Oskam , Mark W. Blood , Mark B. Davis , Douglas H. Jackson , Timothy R. Lynn , Daniel P. Zilker, Jr.
IPC分类号： C08F4/06 , C08F4/44 , C08F4/68 , C08F4/00 , C08F4/80 , C08F210/00 , C08F110/02
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65925 , C08F110/02 , C08F4/65904 , C08F2/34 , C08F2/38 , C08F2500/05
摘要： A method of performing a polymerization reaction in a gas phase polymerization reactor to produce a bimodal polymer while controlling activity of a bimodal polymerization catalyst composition in the reactor by controlling concentration of at least one induced condensing agent (‘ICA’) in the reactor is provided. In some embodiments, the ICA is isopentane (or another hydrocarbon compound) and the bimodal catalyst composition includes a Group 15 and metal containing catalyst compound (or other HMW catalyst for catalyzing polymerization of a high molecular weight fraction of the product), and a metallocene catalyst compound (or other LMW catalyst for catalyzing polymerization of a low molecular weight fraction of the product).
摘要翻译：提供了一种在气相聚合反应器中进行聚合反应以制备双峰聚合物的方法，同时通过控制反应器中至少一种诱导的缩合剂（ICA）的浓度来控制反应器中双峰聚合催化剂组合物的活性。在一些实施方案中，ICA是异戊烷（或另一种烃化合物），双峰催化剂组合物包括第15族和含金属的催化剂化合物（或用于催化产物的高分子量级分聚合的其它HMW催化剂）和茂金属催化剂化合物（或用于催化产物的低分子量级分的聚合的其它LMW催化剂）。

5. 发明授权

US09637567B2 Spray-dried catalyst compositions and polymerization processes employing the same 有权
公开(公告)号：US09637567B2
公开(公告)日：2017-05-02
申请号：US14117272
申请日：2012-03-28
申请人： Wesley R. Mariott , Phuong A. Cao , Daniel P. Zilker, Jr. , John H. Oskam , Cliff R. Mure
发明人： Wesley R. Mariott , Phuong A. Cao , Daniel P. Zilker, Jr. , John H. Oskam , Cliff R. Mure
IPC分类号： B01J31/28 , C08F4/52 , C08F4/80 , C08F4/70 , C08F10/00 , B01J31/40 , B01J37/00
CPC分类号： C08F4/7042 , B01J31/403 , B01J37/0045 , C08F10/00 , C08F4/61904
摘要： Spray-dried catalyst compositions comprising a transition metal complex and polymerization processes employing the same are disclosed herein. An embodiment provides a spray-dried catalyst composition comprising a transition metal catalyst component represented by the following formula: (I) and polymerization process employing the same.

6. 发明授权

US5342907A Ethylene/propylene copolymer rubbers 失效
标题翻译：乙烯/丙烯共聚物橡胶
公开(公告)号：US5342907A
公开(公告)日：1994-08-30
申请号：US83616
申请日：1993-06-28
申请人： Kevin J. Cann , Fathi D. Hussein , Kiu H. Lee , Daniel P. Zilker, Jr. , James W. Nicoletti , Xinlai Bai
发明人： Kevin J. Cann , Fathi D. Hussein , Kiu H. Lee , Daniel P. Zilker, Jr. , James W. Nicoletti , Xinlai Bai
IPC分类号： C08F2/34 , C08F4/60 , C08F4/68 , C08F210/00 , C08F210/02 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/901
摘要： A process comprising contacting a mixture comprising ethylene, propylene, and, optionally, a diene, in the gas phase, under polymerization conditions, with a catalyst system comprising:(a) a catalyst precursor, in independent or prepolymer form, consisting of vanadium (acetylacetonate).sub.3 ;(b) optionally, a support for said precursor;(c) a cocatalyst consisting essentially of (i) an alkylaluminum halide having the formula AlR.sub.(3-a) X.sub.a wherein each R is independently alkyl having 1 to 14 carbon atoms; each X is independently chlorine, bromine, or iodine; and a is 1 or 2, and (ii) optionally, a trialkylaluminum provided that the molar ratio of alkylaluminum halide to trialkylaluminum is at least about 1.5:1; and(d) optionally, a promoter, which is a chlorinated ester having at least 2 chlorine atoms; a saturated or unsaturated aliphatic halocarbon having at least 3 carbon atoms and at least 6 halogen atoms; or a haloalkyl substituted aromatic hydrocarbon wherein the haloalkyl substituent has at least 3 halogen atoms.
摘要翻译：一种方法，包括在气相中在聚合条件下将包含乙烯，丙烯和任选的二烯的混合物与催化剂体系接触，所述催化剂体系包含：（a）催化剂前体，其独立或预聚物形式由钒乙酰丙酮）3; （b）任选地，所述前体的载体; （c）助催化剂，其基本上由（i）具有式AlR（3-a）Xa的烷基铝卤化物组成，其中每个R独立地为具有1至14个碳原子的烷基; 每个X独立地是氯，溴或碘; 并且a为1或2，和（ii）任选的三烷基铝，条件是卤化烷基铝与三烷基铝的摩尔比为至少约1.5:1; 和（d）任选地，具有至少2个氯原子的氯化酯的促进剂; 具有至少3个碳原子和至少6个卤素原子的饱和或不饱和脂族卤代烃; 或卤代烷基取代的芳族烃，其中卤代烷基取代基具有至少3个卤素原子。

7. 发明授权

US5548040A Process for passivation of a reactor after shutdown of alpha olefin polymerization processes 失效
标题翻译：在关闭α-烯烃聚合方法后钝化反应器的方法
公开(公告)号：US5548040A
公开(公告)日：1996-08-20
申请号：US359513
申请日：1994-12-20
申请人： Kevin J. Cann , Fathi D. Hussein , Daniel P. Zilker, Jr. , Kiu H. Lee
发明人： Kevin J. Cann , Fathi D. Hussein , Daniel P. Zilker, Jr. , Kiu H. Lee
IPC分类号： C08F2/00 , C08F2/34 , C08F4/60 , C08F4/68 , C08F10/00 , C08F210/16
CPC分类号： C08F210/16
摘要： A method for passivating internal surfaces of a reactor system during start-up and shutdown of an alpha olefin polymerization or copolymerization reaction by adding a passivation agent such as a dialkyl zinc compound, an alcohol, or an epoxide, to the reactor prior to exposing the internal reactor surfaces to air or moisture before reaction initiation and/or after reaction ceases.
摘要翻译：一种在将α-烯烃聚合或共聚反应的启动和停止期间钝化反应器系统的内表面的方法，在暴露所述反应器之前，向所述反应器中加入钝化剂，例如二烷基锌化合物，醇或环氧化物在反应开始和/或反应停止之后内部反应器表面与空气或水分。

8. 发明授权

US5034361A Catalyst precursor production 失效
标题翻译：催化剂前体生产
公开(公告)号：US5034361A
公开(公告)日：1991-07-23
申请号：US527804
申请日：1990-05-24
申请人： Robert C. Job , Daniel P. Zilker, Jr. , John C. Chadwick
发明人： Robert C. Job , Daniel P. Zilker, Jr. , John C. Chadwick
IPC分类号： C08F4/02 , C07C31/30 , C08F4/00 , C08F4/60 , C08F4/654 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00
摘要： Normally sparingly soluble magnesium alkoxide is solubilized in alkanol by the additional presence of certain acidic materials. The resulting solution is used to produce a mixture of substantially spherical particles, substantially free of fines, containing an adduct magnesium alkoxide. The particles are converted by conventional methods to a procatalyst precursor of an olefin polymerization catalyst of good activity and good selectivity to stereoregular polymer whenever appropriate, which catalyst produces polymer product of good morphology.

9. 发明授权

US5567665A Shape-shifted magnesium alkoxide component for polymerizing olefins 失效
标题翻译：用于聚合烯烃的形状转化的醇镁组分
公开(公告)号：US5567665A
公开(公告)日：1996-10-22
申请号：US447921
申请日：1995-05-23
申请人： Burkhard E. Wagner , Daniel P. Zilker, Jr. , Robert J. Jorgensen
发明人： Burkhard E. Wagner , Daniel P. Zilker, Jr. , Robert J. Jorgensen
IPC分类号： B01J21/10 , B01J37/08 , C07C29/68 , C07C31/30 , C08F4/656 , C08F10/00 , C08F210/06 , C08F210/16
CPC分类号： C07C31/30 , B01J21/10 , B01J37/088 , C07C29/68 , C08F10/00 , C08F210/06 , C08F210/16 , Y10S526/908
摘要： A process is provided for preparing a shape-shifted catalyst component comprising (1) contacting a dihydrocarbyloxide magnesium compound with carbon dioxide in the presence of a slurrying agent to form a slurry of a carboxylated dihydrocarbyloxide magnesium compound; (2) adding a filler to the slurry either before or after the carboxylation of step (1); (3) spray drying the slurry of step (2) to evaporate the slurrying agent and to produce solid particles of the carboxylated dihydrocarbyloxide magnesium compound incorporating the filler; and, optionally, (4) heating the solid particles to remove carbon dioxide to produce a shape-shifted dihydrocarbyloxide magnesium compound component. A catalyst system using the component and a polymerization process employing the catalyst system are also provided.
摘要翻译：提供了一种制备形状转移催化剂组分的方法，其包括（1）在淤浆剂存在下使二氢氧化镁镁化合物与二氧化碳接触以形成羧基化二氢氧化镁镁化合物的浆料; （2）在步骤（1）的羧化之前或之后向浆料中加入填料; （3）喷雾干燥步骤（2）的浆料以蒸发制浆剂并产生掺入填料的羧化二氢氧化镁镁化合物的固体颗粒; 和（4）加热固体颗粒以除去二氧化碳以产生形状转移的二氢氧化镁化合物组分。还提供了使用该组分的催化剂体系和采用催化剂体系的聚合方法。

10. 发明授权

US08329835B2 Polyethylene compositions having improved properties 有权
标题翻译：具有改进性能的聚乙烯组合物
公开(公告)号：US08329835B2
公开(公告)日：2012-12-11
申请号：US12739313
申请日：2008-10-09
申请人： Mark G. Goode , Rainer Kolb , Chi-I Kuo , Tae Hoon Kwalk , Dongming Li , Ching-Tai Lue , Francis C. Rix , Daniel P. Zilker, Jr.
发明人： Mark G. Goode , Rainer Kolb , Chi-I Kuo , Tae Hoon Kwalk , Dongming Li , Ching-Tai Lue , Francis C. Rix , Daniel P. Zilker, Jr.
IPC分类号： C08F4/76 , C08F4/64 , C08F4/52 , C08F210/02 , C08F210/08
CPC分类号： B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/03 , C08F2500/11 , C08F2500/26
摘要： Polyethylene compositions having improved properties are provided. In one aspect, a polyethylene composition having a long chain branching index (g′avg) of 0.5 to 0.9; a Melt Flow Rate (MFR) of greater than (49.011×MI(−0.4304)), where MI is Melt Index; and a weight average molecular weight to number average molecular weight (Mw/Mn) of less than or equal to 4.6 is provided.
摘要翻译：提供具有改进性能的聚乙烯组合物。一方面，长链支化指数（g'avg）为0.5〜0.9的聚乙烯组合物; 熔体流动速率（MFR）大于（49.011×MI（-0.4304）），其中MI是熔体指数; 并且提供了小于或等于4.6的数均分子量（Mw / Mn）的重均分子量。

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