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1. 发明申请

WO2011079116A1 CATALYTIC DEWAXING PROCESS 审中-公开
标题翻译：催化脱蜡工艺
公开(公告)号：WO2011079116A1
公开(公告)日：2011-06-30
申请号：PCT/US2010/061542
申请日：2010-12-21
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , ELIA, Christine N. , HILBERT, Timothy Lee , BURNS, Louis Francis , JOSECK, Eric D. , KIM, Jeenok T. , HANTZER, Sylvain S.
发明人： ELIA, Christine N. , HILBERT, Timothy Lee , BURNS, Louis Francis , JOSECK, Eric D. , KIM, Jeenok T. , HANTZER, Sylvain S.
IPC分类号： C10G47/12
CPC分类号： C10G45/64 , C10G45/62 , C10G65/043 , C10G2300/20 , C10G2300/202 , C10G2300/4018
摘要： In a catalytic dewaxing process, a catalyst comprising from 40 to 80 wt% of ZSM-48 having a silica to alumina molar ratio of less than 200:1 and from 0.3 to 1.5 wt% of a metal or metal compound from Groups 8 to 10 of the Periodic Table of the Elements is provided in a reaction zone. The catalyst is periodically contacted in the reaction zone under dewaxing conditions with a first hydrocarbon feedstock having a wax content of less than 50 wt% and with a second hydrocarbon feedstock having a wax content of 50 wt% or more.
摘要翻译：在催化脱蜡方法中，催化剂包含40至80重量％的二氧化硅与氧化铝摩尔比小于200:1的ZSM-48和0.3至1.5重量％的第8-10族金属或金属化合物的元素周期表提供在反应区中。催化剂在脱蜡条件下在反应区域中与蜡含量小于50重量％的第一烃原料和蜡含量为50重量％以上的第二烃原料在反应区域中周期性接触。

2. 发明申请

WO2018026462A1 RAFFINATE HYDROCONVERSION FOR PRODUCTION OF HIGH PERFORMANCE BASE STOCKS 审中-公开
标题翻译：用于生产高性能基础原料的RAFFINATE HYDROCONVERSION
公开(公告)号：WO2018026462A1
公开(公告)日：2018-02-08
申请号：PCT/US2017/041079
申请日：2017-07-07
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： CALLA, Jason T. , FISHER Jr., Will G. , JOSECK, Eric D. , FORTNEY, Seth D.
IPC分类号： C10G67/04
摘要： Systems and methods are provided for production of base stocks with a viscosity index of at least 120 and/or a sulfur content of 300 wppm or less and/or a kinematic viscosity at 100°C of 3.0 cSt to 8.0 cSt by hydroconversion of a raffinate from aromatic extraction of a feed. The base stocks can further have a reduced content of 3+ ring naphthenes, such as 4.0 wt% or less, or 1.0 wt% or less. The base stocks can be produced by performing an elevated amount of feed conversion relative to 370°C during hydroconversion of the raffinate, and optionally additional conversion during catalytic dewaxing of the hydroconverted raffinate. The base stocks can optionally be blended with additional base stocks and/or lubricant additives for production of lubricant compositions.
摘要翻译：提供了用于生产粘度指数为至少120和/或硫含量为300wppm或更低和/或在100℃下的运动粘度为3.0cSt的基础油料的系统和方法通过加氢转化来自芳香族提取物的提余液至8.0cSt。基础油可以进一步具有降低的3+环环烷烃的含量，例如4.0重量％或更少，或1.0重量％或更少。可以通过在提余液加氢转化过程中相对于370℃进行升高的进料转化量以及任选地在加氢转化的提余液的催化脱蜡过程中进行额外的转化来生产基础油料。基础油料可以任选与另外的基础油料和/或润滑剂添加剂混合用于生产润滑剂组合物。

3. 发明公开

EP2516597A1 CATALYTIC DEWAXING PROCESS 审中-公开
标题翻译：催化脱蜡
公开(公告)号：EP2516597A1
公开(公告)日：2012-10-31
申请号：EP10840062.3
申请日：2010-12-21
申请人： ExxonMobil Research and Engineering Company
发明人： ELIA, Christine N. , HILBERT, Timothy Lee , BURNS, Louis Francis , JOSECK, Eric D. , KIM, Jeenok T. , HANTZER, Sylvain S.
IPC分类号： C10G47/12
CPC分类号： C10G45/64 , C10G45/62 , C10G65/043 , C10G2300/20 , C10G2300/202 , C10G2300/4018
摘要： In a catalytic dewaxing process, a catalyst comprising from 40 to 80 wt% of ZSM-48 having a silica to alumina molar ratio of less than 200:1 and from 0.3 to 1.5 wt% of a metal or metal compound from Groups 8 to 10 of the Periodic Table of the Elements is provided in a reaction zone. The catalyst is periodically contacted in the reaction zone under dewaxing conditions with a first hydrocarbon feedstock having a wax content of less than 50 wt% and with a second hydrocarbon feedstock having a wax content of 50 wt% or more.

4. 发明授权

EP3221428B1 PRODUCTION OF LUBRICANT BASE STOCKS WITH CONTROLLED AROMATIC CONTENTS 有权
公开(公告)号：EP3221428B1
公开(公告)日：2019-07-03
申请号：EP15802271.5
申请日：2015-11-13
申请人： ExxonMobil Research and Engineering Company
发明人： LYON, Kristen S. , JOSECK, Eric D. , SCHLEICHER, Gary P. , DOUGHERTY, Richard C. , HORTON, Angela
IPC分类号： C10G45/02 , C10G45/58 , C10G47/00 , C10G65/04 , C10G65/12 , C10G67/04 , C10G69/02 , C10M101/02

5. 发明公开

EP3122843A1 BASESTOCK PRODUCTION FROM FEEDS CONTAINING SOLVENT EXTRACTS 无效
标题翻译：葛兰素多TEL UNG UNG TEN BUSCHICKUNGEN MITLÖSEMITTELEXTRAKTEN
公开(公告)号：EP3122843A1
公开(公告)日：2017-02-01
申请号：EP15711345.7
申请日：2015-02-27
申请人： Exxonmobil Research And Engineering Company
发明人： VAUGHN, Nicole D. , HOO, Teck-Mui , CARROLL, Michael B. , SHIH, Stuart S , JOSECK, Eric D. , NOVAK, William J.
IPC分类号： C10G65/04 , C10G65/12
CPC分类号： C10G67/02 , C10G65/043 , C10G65/12 , C10G2300/1096 , C10G2300/301 , C10G2400/10 , C10M101/02
摘要： Methods are provided for producing Group II/III lubricant base oil products where at least a portion of the feedstock for forming the lubricant base oil product is a solvent extract fraction from a Group I lubricant production facility. This can increase the overall volume of feedstock available for production of Group II/III lubricant base oils by using a lower value stream (Group I solvent extract) as a portion of the feedstock. The solvent extract fraction can be added to a full range lubricant feedstock or to a portion of a lubricant feedstock, such as adding an extract fraction to a higher viscosity portion (such as a heavy neutral portion) of a feedstock for lubricant production, while a lower viscosity portion (such as a light neutral portion) is processed without addition of an extract fraction.
摘要翻译：提供了用于生产组II / III润滑剂基础油产品的方法，其中用于形成润滑剂基础油产品的原料的至少一部分是来自第I组润滑剂生产设备的溶剂萃取部分。这可以通过使用较低价值的流（I类溶剂提取物）作为原料的一部分来增加可用于生产II / III族润滑油基础油的原料的总体积。可以将溶剂萃取馏分加入到全润滑剂原料或一部分润滑剂原料中，例如将提取物馏分加入用于润滑剂生产的原料的较高粘度部分（例如重中性部分），而低粘度部分（如轻中性部分）被加工而不添加提取部分。

6. 发明公开

EP3494195A1 RAFFINATE HYDROCONVERSION FOR PRODUCTION OF HIGH PERFORMANCE BASE STOCKS 审中-公开
公开(公告)号：EP3494195A1
公开(公告)日：2019-06-12
申请号：EP17746224.9
申请日：2017-07-07
申请人： ExxonMobil Research and Engineering Company
发明人： CALLA, Jason T. , FISHER Jr., Will G. , JOSECK, Eric D. , FORTNEY, Seth D.
IPC分类号： C10G67/04

7. 发明公开

EP3221428A1 PRODUCTION OF LUBRICANT BASE STOCKS WITH CONTROLLED AROMATIC CONTENTS 有权
标题翻译：有控制芳烃含量的润滑油基础油的生产
公开(公告)号：EP3221428A1
公开(公告)日：2017-09-27
申请号：EP15802271.5
申请日：2015-11-13
申请人： ExxonMobil Research and Engineering Company
发明人： LYON, Kristen S. , JOSECK, Eric D. , SCHLEICHER, Gary P. , DOUGHERTY, Richard C. , HORTON, Angela
IPC分类号： C10G45/02 , C10G45/58 , C10G47/00 , C10G65/04 , C10G65/12 , C10G67/04
CPC分类号： C10G69/02 , C10G45/02 , C10G45/58 , C10G47/00 , C10G65/04 , C10G65/12 , C10G67/04 , C10G2400/10 , C10M101/00 , C10M101/02 , C10M2203/1006 , C10M2203/1045 , C10M2205/223 , C10N2220/022 , C10N2230/43
摘要： Methods are provided for producing Group II and Group III base stocks with a controlled or consistent aromatics content. An aromatics-rich base stock, such as a Group I base stock or an alkylated aromatic base stock, can be added to the catalytically treated base stock in a minimal amount after the final catalytic treatment step but prior to fractionation. At the beginning of a processing run for forming lubricant base stock products, about 0.25 wt % to about 1.25 wt % of the Group I base stock can be added to a catalytically processed feed after the final catalytic processing stage but prior to fractionation to form the Group II and/or Group III base stock. During the course of the processing run, the amount of Group I base stock added can be reduced roughly in correspondence with the increase in aromatics caused by catalyst deactivation. This can allow a catalytically processed lubricant base stock product to be generated that contains at least about a threshold (minimum) aromatics content during the course of a processing run. Alternatively, this can allow a catalytically processed lubricant base stock product to be generated that has consistent aromatics content during the course of the processing run.
摘要翻译：提供了用于生产具有受控或一致芳烃含量的II类和III类基础油料的方法。在最终催化处理步骤之后但在分馏之前，可以以最小量将富含芳族化合物的基础油料（例如第I组基础油料或烷基化芳族基础油料）加入催化处理的基础油料中。在形成润滑剂基础油产品的加工过程开始时，可以在最终催化加工阶段之后但在分馏之前将约0.25wt％ - 约1.25wt％的I类基础油料加入催化加工的加料中以形成第II组和/或第III组基础原料。在加工过程中，添加的I类基础原料的量可以大致减少，与由催化剂失活导致的芳烃增加相对应。这可以允许催化加工的润滑剂基础油产品在加工过程中产生至少包含大约阈值（最小）的芳烃含量。或者，这可以允许催化加工的润滑剂基础油产品在加工过程中产生具有一致的芳族化合物含量。

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