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1. 发明申请

US20090176913A1 POLYESTER RESIN COMPOSITION 有权
标题翻译：聚酯树脂组合物
公开(公告)号：US20090176913A1
公开(公告)日：2009-07-09
申请号：US12299915
申请日：2007-04-13
申请人： Takahiro Horikoshi , Kazukiyo Nomura , Naoshi Kawamoto , Etsuo Tobita
发明人： Takahiro Horikoshi , Kazukiyo Nomura , Naoshi Kawamoto , Etsuo Tobita
IPC分类号： C08K5/435 , C08K5/47
CPC分类号： C08K5/0091 , C08K5/435 , C08L67/02
摘要： The present invention provides a polyester resin composition having an excellent crystallization rate.The polyester resin composition includes (a) a polyester resin containing (b) a sulfonamide compound metal salt which has a structure represented by the following general formula (1): (in the formula (1), R and R′ each independently represent a hydrogen atom, a halogen atom, an alkali metal atom, an amino group, an alkyl group which has 1 to 10 carbon atoms and which may be branched or substituted, an alkoxy group which has 1 to 10 carbon atoms and which may be branched or substituted, or a cyclic group which has 3 to 30 carbon atoms and which may be substituted; R and R′ may be bonded together to form a cyclic group; n represents a number of 1 or 2).
摘要翻译：本发明提供了具有优异结晶速率的聚酯树脂组合物。聚酯树脂组合物包含（a）含有（b）具有由以下通式（1）表示的结构的磺酰胺化合物金属盐的聚酯树脂：（在式（1）中，R和R'各自独立地表示氢原子，卤素原子，碱金属原子，氨基，具有1-10个碳原子并且可以是支链或取代的烷基，具有1-10个碳原子的烷氧基，并且可以是支链或或具有3至30个碳原子并且可以被取代的环状基团; R和R'可以键合在一起形成环状基团; n表示1或2的数）。

2. 发明授权

US08017678B2 Polyester resin composition 有权
标题翻译：聚酯树脂组合物
公开(公告)号：US08017678B2
公开(公告)日：2011-09-13
申请号：US12299915
申请日：2007-04-13
申请人： Takahiro Horikoshi , Kazukiyo Nomura , Naoshi Kawamoto , Etsuo Tobita
发明人： Takahiro Horikoshi , Kazukiyo Nomura , Naoshi Kawamoto , Etsuo Tobita
IPC分类号： C08J7/04
CPC分类号： C08K5/0091 , C08K5/435 , C08L67/02
摘要： The present invention provides a polyester resin composition having an excellent crystallization rate.The polyester resin composition includes (a) a polyester resin containing (b) a sulfonamide compound metal salt which has a structure represented by the following general formula (1): (in the formula (1), R and R′ each independently represent a hydrogen atom, a halogen atom, an alkali metal atom, an amino group, an alkyl group which has 1 to 10 carbon atoms and which may be branched or substituted, an alkoxy group which has 1 to 10 carbon atoms and which may be branched or substituted, or a cyclic group which has 3 to 30 carbon atoms and which may be substituted; R and R′ may be bonded together to form a cyclic group; n represents a number of 1 or 2).
摘要翻译：本发明提供了具有优异结晶速率的聚酯树脂组合物。聚酯树脂组合物包含（a）含有（b）具有由以下通式（1）表示的结构的磺酰胺化合物金属盐的聚酯树脂：（在式（1）中，R和R'各自独立地表示氢原子，卤素原子，碱金属原子，氨基，具有1-10个碳原子并且可以是支链或取代的烷基，具有1-10个碳原子的烷氧基，并且可以是支链或或具有3至30个碳原子并且可以被取代的环状基团; R和R'可以键合在一起形成环状基团; n表示1或2的数）。

3. 发明授权

US07442735B2 Nucleating agent composition and crystalline polymer compositions containing the same 有权
标题翻译：成核剂组合物和含有它们的结晶聚合物组合物
公开(公告)号：US07442735B2
公开(公告)日：2008-10-28
申请号：US10566684
申请日：2004-07-30
申请人： Etsuo Tobita , Kazukiyo Nomura , Naoshi Kawamoto
发明人： Etsuo Tobita , Kazukiyo Nomura , Naoshi Kawamoto
IPC分类号： C08K5/00
CPC分类号： C08K5/0083 , C08K5/0091 , C08K5/527 , C08L23/02
摘要： A crystal nucleating agent composition comprising 100 mass parts of a crystal nucleating agent compound represented by the following general formula (I), -50 mass parts of a lithium salt of an organic fatty acid represented by the following general formula (II), and 5-50 mass parts of a metal salt of an organic fatty acid represented by the following general formula (III): (in the formula R1 and R2 are alkyl groups having 1-4 carbon atoms, R3 is a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4, R5 are groups derived from an organic fatty acid having 10-30 carbon atoms, and M is a divalent metal atom).
摘要翻译：一种晶体成核剂组合物，其包含100质量份由以下通式（I）表示的结晶成核剂化合物，-50质量份由以下通式（II）表示的有机脂肪酸锂盐和5质量份 -50质量份由以下通式（III）表示的有机脂肪酸金属盐：（式R 1和R 2中的烷基是具有 1-4个碳原子，R 3是氢原子或具有1-4个碳原子的烷基，R 4，R 5是衍生自具有10-30个碳原子的有机脂肪酸的基团，M是二价金属原子）。

4. 发明申请

US20070054996A1 Nucleating agent composition and crystalline polymer compositions containing the same 有权
标题翻译：成核剂组合物和含有它们的结晶聚合物组合物
公开(公告)号：US20070054996A1
公开(公告)日：2007-03-08
申请号：US10566684
申请日：2004-07-30
申请人： Etsuo Tobita , Kazukiyo Nomura , Naoshi Kawamoto
发明人： Etsuo Tobita , Kazukiyo Nomura , Naoshi Kawamoto
IPC分类号： C08K5/15 , C07F9/6574
CPC分类号： C08K5/0083 , C08K5/0091 , C08K5/527 , C08L23/02
摘要： A crystal nucleating agent composition comprising 100 mass parts of a crystal nucleating agent compound represented by the following general formula (I), 5-50 mass parts of a lithium salt of an organic fatty acid represented by the following general formula (II), and 5-50 mass parts of a metal salt of an organic fatty acid represented by the following general formula (III): (in the formula R1 and R2 are alkyl groups having 1-4 carbon atoms, R3 is a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4, R5 are groups derived from an organic fatty acid having 10-30 carbon atoms, and M is a divalent metal atom).
摘要翻译：包含100质量份以下通式（I）表示的结晶成核剂化合物，5-50质量份由以下通式（II）表示的有机脂肪酸锂盐的结晶成核剂组合物，和 5-50质量份由以下通式（III）表示的有机脂肪酸金属盐：（式R 1和R 2中的一个是烷基具有1-4个碳原子，R 3是氢原子或具有1-4个碳原子的烷基，R 4，R 5，是衍生自具有10-30个碳原子的有机脂肪酸的基团，M是二价金属原子）。

5. 发明授权

US07910643B2 Polylactic acid resin composition, moldings, and process for production thereof 有权
标题翻译：聚乳酸树脂组合物，成型品及其制造方法
公开(公告)号：US07910643B2
公开(公告)日：2011-03-22
申请号：US11661671
申请日：2005-09-02
申请人： Etsuo Tobita , Naoshi Kawamoto , Tsuyoshi Urushihara , Hitoshi Saito , Hisashi Okuyama , Naomi Okuyama, legal representative , Takeshi Kanamori , Mitsuru Nakano , Hirotaka Okamoto
发明人： Etsuo Tobita , Naoshi Kawamoto , Tsuyoshi Urushihara , Hitoshi Saito , Hisashi Okuyama , Takeshi Kanamori , Mitsuru Nakano , Hirotaka Okamoto
IPC分类号： C08K5/24 , C08G63/08
CPC分类号： C08K5/25 , C08K3/34 , C08L67/04
摘要： A polylactic acid resin composition in which polylactic acid is blended with dibasic acid bis(benzoylhydrazide) represented by general formula (I) below; and a process for producing heat-resistant polylactic acid resin moldings, wherein after the polylactic acid resin composition is melted, the polylactic acid resin composition melted is filled in a die of a molding machine and molded accompanied with crystallization, in which the temperature of the die has been set in a range not higher than the initiation temperature of crystallization and not lower than the glass transition temperature determined with a differential scanning calorimeter (DSC). (In the formula, R represents a alkylene, alkenylene, cycloalkylene, alkylene having an ether bond, or alkylene interrupted with a cycloalkylene, the groups each having 1 to 12 carbon atoms; and R1, R2, R3, and R4 each represent a hydrogen atom, halogen atom, alkyl, cycloalkyl, aryl, aralkyl, or alkylaryl, the groups each having 1 to 12 carbon atoms, or R1 and R2 and/or R3 and R4 bond to each other to form a five- to eight-membered ring.)
摘要翻译：将聚乳酸与下述通式（I）表示的二元酸二（苯甲酰基酰肼）配合的聚乳酸树脂组合物; 以及制造耐热性聚乳酸树脂成形体的方法，其中在聚乳酸树脂组合物熔融之后，熔融的聚乳酸树脂组合物被填充在模塑机的模具中，并且随着结晶而成型，其中，晶粒已经设定在不高于结晶的起始温度的范围内，并且不低于用差示扫描量热计（DSC）测定的玻璃化转变温度。（式中，R表示亚烷基，亚烯基，亚环烷基，具有醚键的亚烷基，或亚环烷基间隔的亚烷基，各自具有1〜12个碳原子的基团，R1，R2，R3，R4分别表示氢原子原子，卤素原子，烷基，环烷基，芳基，芳烷基或烷基芳基，各自具有1至12个碳原子，或R 1和R 2和/或R 3和R 4彼此键合以形成五至八元环。）

6. 发明授权

US07714046B2 Process for producing crystal nucleator composition and crystalline polymer composition 有权
标题翻译：制备晶体成核剂组合物和结晶聚合物组合物的方法
公开(公告)号：US07714046B2
公开(公告)日：2010-05-11
申请号：US12088726
申请日：2006-08-24
申请人： Manabu Ishii , Naoshi Kawamoto , Etsuo Tobita
发明人： Manabu Ishii , Naoshi Kawamoto , Etsuo Tobita
IPC分类号： C08K5/00
CPC分类号： C08K5/527 , C08K5/0083 , C08K5/098
摘要： The present invention provides a process for producing a crystal nucleator composition comprising; a first step pulverizing 95% by mass or more of a crystal nucleator ingredient containing one or two or more kinds of specific compounds to a primary particle diameter of 0.8 μm or smaller with a dry medium-stirring type pulverizer; and a second step mixing and pulverizing the pulverized crystal nucleator ingredient obtained in the previous step and a metal aliphatic carboxylate ingredient containing one or two or more kinds of specific metal aliphatic carboxylates. Also provided is a crystalline polymer composition comprising a crystal nucleator composition obtained by the production process
摘要翻译：本发明提供一种制备晶体成核剂组合物的方法，其包括：用干介质搅拌式粉碎机将含有一种或两种以上特定化合物的晶体成核剂成分粉碎成初级粒径为0.8μm以下的第一步骤; 以及将上一步骤中获得的粉碎晶体成核剂成分和含有一种或两种以上特定金属脂肪族羧酸盐的金属脂族羧酸盐成分混合粉碎的第二步骤。还提供了包含通过制备方法获得的晶体成核剂组合物的结晶聚合物组合物

7. 发明申请

US20090156744A1 PROCESS FOR PRODUCING CRYSTAL NUCLEATOR COMPOSITION AND CRYSTALLINE POLYMER COMPOSITION 有权
标题翻译：生产晶体核素组合物和晶体聚合物组合物的方法
公开(公告)号：US20090156744A1
公开(公告)日：2009-06-18
申请号：US12088726
申请日：2006-08-24
申请人： Manabu Ishii , Naoshi Kawamoto , Etsuo Tobita
发明人： Manabu Ishii , Naoshi Kawamoto , Etsuo Tobita
IPC分类号： C08L85/02 , C09K3/00
CPC分类号： C08K5/527 , C08K5/0083 , C08K5/098
摘要： The present invention provides a process for producing a crystal nucleator composition comprising; a first step pulverizing 95% by mass or more of a crystal nucleator ingredient containing one or two or more kinds of specific compounds to a primary particle diameter of 0.8 μm or smaller with a dry medium-stirring type pulverizer; and a second step mixing and pulverizing the pulverized crystal nucleator ingredient obtained in the previous step and a metal aliphatic carboxylate ingredient containing one or two or more kinds of specific metal aliphatic carboxylates. Also provided is a crystalline polymer composition comprising a crystal nucleator composition obtained by the production process
摘要翻译：本发明提供一种制备晶体成核剂组合物的方法，其包括：用干介质搅拌式粉碎机将含有一种或两种以上特定化合物的结晶成核剂成分粉碎成一次粒径为0.8μm以下的第一步骤; 以及将上一步骤中获得的粉碎晶体成核剂成分和含有一种或两种以上特定金属脂肪族羧酸盐的金属脂族羧酸盐成分混合粉碎的第二步骤。还提供了包含通过制备方法获得的晶体成核剂组合物的结晶聚合物组合物

8. 发明申请

US20100174017A1 Polylactic Acid Resin Composition, Moldings, and Process for Production Thereof 有权
标题翻译：聚乳酸树脂组合物，成型品及其制造方法
公开(公告)号：US20100174017A1
公开(公告)日：2010-07-08
申请号：US11661671
申请日：2005-09-02
申请人： Etsuo Tobita , Naoshi Kawamoto , Tsuyoshi Urushihara , Hitoshi Saito , Hisashi Okuyama , Naomi Okuyama , Takeshi Kanamori , Mitsuru Nakano , Hirotaka Okamoto
发明人： Etsuo Tobita , Naoshi Kawamoto , Tsuyoshi Urushihara , Hitoshi Saito , Hisashi Okuyama , Naomi Okuyama , Takeshi Kanamori , Mitsuru Nakano , Hirotaka Okamoto
IPC分类号： C08K5/24
CPC分类号： C08K5/25 , C08K3/34 , C08L67/04
摘要： A polylactic acid resin composition in which polylactic acid is blended with dibasic acid bis(benzoylhydrazide) represented by general formula (I) below; and a process for producing heat-resistant polylactic acid resin moldings, wherein after the polylactic acid resin composition is melted, the polylactic acid resin composition melted is filled in a die of a molding machine and molded accompanied with crystallization, in which the temperature of the die has been set in a range not higher than the initiation temperature of crystallization and not lower than the glass transition temperature determined with a differential scanning calorimeter (DSC). (In the formula, R represents a alkylene, alkenylene, cycloalkylene, alkylene having an ether bond, or alkylene interrupted with a cycloalkylene, the groups each having 1 to 12 carbon atoms; and R1, R2, R3, and R4 each represent a hydrogen atom, halogen atom, alkyl, cycloalkyl, aryl, aralkyl, or alkylaryl, the groups each having 1 to 12 carbon atoms, or R1 and R2 and/or R3 and R4 bond to each other to form a five- to eight-membered ring.)
摘要翻译：将聚乳酸与下述通式（I）表示的二元酸二（苯甲酰基酰肼）配合的聚乳酸树脂组合物; 以及制造耐热性聚乳酸树脂成形体的方法，其中在聚乳酸树脂组合物熔融之后，熔融的聚乳酸树脂组合物被填充在模塑机的模具中，并且随着结晶而成型，其中，晶粒已经设定在不高于结晶的起始温度的范围内，并且不低于用差示扫描量热计（DSC）测定的玻璃化转变温度。（式中，R表示亚烷基，亚烯基，亚环烷基，具有醚键的亚烷基，或亚环烷基间隔的亚烷基，各自具有1〜12个碳原子的基团，R1，R2，R3，R4分别表示氢原子原子，卤素原子，烷基，环烷基，芳基，芳烷基或烷基芳基，各自具有1至12个碳原子，或R 1和R 2和/或R 3和R 4彼此键合以形成五至八元环。）

9. 发明授权

US07662893B2 Method for producing stabilized polymer 有权
标题翻译：稳定化聚合物的制备方法
公开(公告)号：US07662893B2
公开(公告)日：2010-02-16
申请号：US11795646
申请日：2006-03-06
申请人： Etsuo Tobita , Naoshi Kawamoto , Takahiro Horikoshi
发明人： Etsuo Tobita , Naoshi Kawamoto , Takahiro Horikoshi
IPC分类号： C08F4/00
CPC分类号： C08F10/06 , C08F10/00 , C08F110/06 , C08F2/34 , C08F4/6545 , C08F4/6494 , C08F4/6495 , C08F4/651 , C08F4/6497
摘要： A method for producing a stabilized polymer comprising adding at least one kind of a phenolic antioxidant masked with an organic aluminum and represented by general formula (I) in a catalyst system or a polymerization system, before or during polymerization, on gas-phase polymerization of a monomer having an ethylenic unsaturated bonding, wherein R1 and R2, each is independently a hydrogen atom, an alkyl group having 1 to 9 carbon atoms, a cycloalkyl group or an arylalkyl group; X is an alkylene group having 1 to 8 carbon atoms; R3 is a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; and R4 is an alkyl group having 1 to 30 carbon atoms.
摘要翻译：一种稳定化聚合物的制造方法，其特征在于，在聚合前或聚合过程中，在催化剂体系或聚合体系中，将由有机铝掩蔽的酚类抗氧化剂和通式（I）所示的酚类抗氧化剂在气相聚合反应具有烯键式不饱和键的单体，其中R 1和R 2各自独立地为氢原子，具有1至9个碳原子的烷基，环烷基或芳基烷基; X为碳原子数1〜8的亚烷基。 R3是氢原子或碳原子数1〜8的烷基。 R4为碳原子数1〜30的烷基。

10. 发明申请

US20080214752A1 Method for Producing Stabilized Polymer 有权
标题翻译：生产稳定聚合物的方法
公开(公告)号：US20080214752A1
公开(公告)日：2008-09-04
申请号：US11795646
申请日：2006-03-06
申请人： Etsuo Tobita , Naoshi Kawamoto , Takahiro Horikoshi
发明人： Etsuo Tobita , Naoshi Kawamoto , Takahiro Horikoshi
IPC分类号： C08F2/44
CPC分类号： C08F10/06 , C08F10/00 , C08F110/06 , C08F2/34 , C08F4/6545 , C08F4/6494 , C08F4/6495 , C08F4/651 , C08F4/6497
摘要： A method for producing a stabilized polymer comprising adding at least one kind of a phenolic antioxidant masked with an organic aluminum and represented by general formula (I) in a catalyst system or a polymerization system, before or during polymerization, on gas-phase polymerization of a monomer having an ethylenic unsaturated bonding, wherein R1 and R2, each is independently a hydrogen atom, an alkyl group having 1 to 9 carbon atoms, a cycloalkyl group or an arylalkyl group; X is an alkylene group having 1 to 8 carbon atoms; R3 is a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; and R4 is an alkyl group having 1 to 30 carbon atoms.
摘要翻译：一种稳定化聚合物的制造方法，其特征在于，在聚合前或聚合过程中，在催化剂体系或聚合体系中，将由有机铝掩蔽的酚类抗氧化剂和通式（I）所示的酚类抗氧化剂在气相聚合反应具有烯键式不饱和键的单体，其中R 1和R 2各自独立地为氢原子，具有1至9个碳原子的烷基，环烷基或芳基烷基; X为碳原子数1〜8的亚烷基。 R 3是氢原子或具有1至8个碳原子的烷基; R 4是具有1〜30个碳原子的烷基。

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