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1. 发明授权

US4492654A Water-soluble azo compounds, a process for their preparation and their use as dyes 失效
标题翻译：水溶性偶氮化合物，其制备方法及其作为染料的用途
公开(公告)号：US4492654A
公开(公告)日：1985-01-08
申请号：US515442
申请日：1983-07-20
申请人： Ernst Hoyer , Folker Kohlhaas , Fritz Meininger
发明人： Ernst Hoyer , Folker Kohlhaas , Fritz Meininger
IPC分类号： C09B33/10 , C09B62/513 , D06P1/384 , D06P3/32 , C09B33/02 , C09B31/02
CPC分类号： C09B62/513
摘要： Disazo compounds corresponding to the general formula (1) ##STR1## as well as their metal salts, in which D.sub.1 denotes the benzene or naphthalene nucleus, which can be further substituted by one or two substituents from the group of fluorine, chlorine, bromine, carboxy, lower alkyl, lower alkoxy and nitro and/or one, two or three sulfo groups, D.sub.2 is the benzene or naphthalene nucleus, which is substituted by the substituent X defined below and, in addition to the group --SO.sub.2 --Y, can be further substituted by one or two substituents from the group of carboxy, lower alkyl and lower alkoxy and/or by one substituent from the group of fluorine, chlorine, bromine and nitro and/or one, two or three sulfo groups, X denotes a fluorine, chlorine or bromine atom, which is necessarily bonded to D.sub.2 in ortho-position to the azo group, Y denotes the vinyl, .beta.-sulfatoethyl, .beta.-chloroethyl, .beta.-thiosulfatoethyl or a .beta.-acyloxyethyl group with the acyl radical of a lower alkanecarboxylic acid or of a benzoic acid or of a benzenesulfonic acid, and a and b each represent the number zero or 1, the sum of (a+b) being equal to 1 or 2. These compounds (1) are very suitable as fiber-reactive dyes for dyeing, for example natural or regenerated cellulose fiber, wool or synthetic polyamide fibers. They give on these materials intense dyeings and prints of good fastness properties, and are distinguished, in particular, by a good stability to copper ions, when used in printing processes.
摘要翻译：对应于通式（1）的双偶氮化合物（1）及其金属盐，其中D1表示苯或萘核，其可以进一步被氟，氯的一个或两个取代基取代，溴，羧基，低级烷基，低级烷氧基和硝基和/或一个，两个或三个磺基，D2是苯或萘核，其被下面定义的取代基X取代，并且除了-SO 2 - Y可以进一步被一个或两个来自羧基，低级烷基和低级烷氧基的取代基和/或由氟，氯，溴和硝基和/或一个，两个或三个磺基组中的一个取代基取代， X表示氟原子，氯原子或溴原子，其与偶氮基的邻位必须与D2结合，Y表示乙烯基，β-磺基乙基，β-氯乙基，β-硫代乙酰基乙基或β-酰氧基乙基，与酰基低级链烷羧酸的自由基或苯甲酸或苯磺酸，a和b各自表示数字0或1，（a + b）之和等于1或2.这些化合物（1）非常适合作为纤维反应性用于染色的染料，例如天然或再生纤维素纤维，羊毛或合成聚酰胺纤维。它们赋予这些材料强烈的染色和良好的牢度性质的印刷品，特别是当用于印刷工艺时，特别是对铜离子具有良好的稳定性。

2. 发明授权

US4485041A Water-soluble metal free or copper triazino-bis-[hydroxy-naphthylamino]-disazo dyestuffs containing fiber reactive groups, and a process for dyeing or printing cellulose fibers 失效
标题翻译：含有纤维反应性基团的水溶性无金属或铜三嗪基 - 双 - [羟基 - 萘基氨基] - 二偶氮染料，以及染色或印刷纤维素纤维的方法
公开(公告)号：US4485041A
公开(公告)日：1984-11-27
申请号：US234966
申请日：1981-02-17
申请人： Ernst Hoyer , Fritz Meininger , Rudolf Fass
发明人： Ernst Hoyer , Fritz Meininger , Rudolf Fass
IPC分类号： C09B62/513 , C09B62/44 , C09B62/515 , D06P3/10 , D06P3/66 , C09B62/09 , C09B62/095 , C09B62/533 , C09B62/535
CPC分类号： C09B62/4411
摘要： The novel water-soluble disazo dyestuffs consist of two monoazo dyestuff moieties each containing as diazo component an amine of the benzene or naphthalene series and as coupling component an amino-naphthol-mono- or disulfonic acid. The two moieties are bonded to each other via a triazine radical which carries a halogen atom, and is bound to the amino groups of the coupling components and the diazo components contain a fiber-reactive radical of the vinyl sulfone series. To produce the dyestuffs 2 mols of the diazo compound carrying the fiber-reactive radical of the vinyl sulfone series is coupled with 1 mol of a bivalent coupling component consisting of 2 radicals of the aminonaphthol bound to the triazine ring via the amino groups, or two monoazo dyestuffs each synthesized from the aforesaid diazo component and an aminonaphthol-disulfonic acid coupling component are reacted with a 1,3,5-trihalogeno-triazine. The metal-free dyestuffs can be transformed into the corresponding heavy metal complex dyestuffs, preferably copper, cobalt and chromium complex dyestuffs, by treatment with an agent donating a heavy metal cation. The novel dyestuffs are excellently suitable for dyeing and printing fiber material of natural and regenerated cellulose and natural, regenerated and synthetic polyamides. They are distinguished by clear shades, high tinctorial strength, a very good uptake from a long liquor and a good color-build up. The dyeings obtained therewith have a high fastness to processing and in use.
摘要翻译：新型水溶性双偶氮染料由两种单偶氮染料组成，每个单偶氮染料部分均含有作为重氮组分的苯或萘系的胺，作为偶联组分为氨基萘酚单或二磺酸。两个部分通过携带卤素原子的三嗪基彼此键合，并且与偶合组分的氨基结合，重氮组分含有乙烯基砜系列的纤维反应性基团。为了生产染料，携带乙烯基砜系列的纤维反应性基团的重氮化合物的2摩尔与1摩尔由通过氨基结合到三嗪环的氨基萘酚的2个基团组成的二价偶联组分偶联，或两个将由上述重氮组分和氨基萘酚 - 二磺酸偶合组分合成的单偶氮染料与1,3,5-三卤代三嗪反应。通过用赋予重金属阳离子的试剂处理，无金属染料可以转化成相应的重金属络合物染料，优选铜，钴和铬复合染料。新型染料非常适用于天然和再生纤维素以及天然，再生和合成聚酰胺的染色和印花纤维材料。它们的特征是清晰的色调，高着色强度，从长酒中很好的摄取和良好的颜色搭配。由此获得的染色具有高的加工牢度和使用性。

3. 发明授权

US4378312A Water-soluble azo dyestuffs 失效
公开(公告)号：US4378312A
公开(公告)日：1983-03-29
申请号：US219499
申请日：1980-12-23
申请人： Ernst Hoyer , Fritz Meininger , Rudolf Fass
发明人： Ernst Hoyer , Fritz Meininger , Rudolf Fass
IPC分类号： C09B62/44 , C09B62/513 , C09B62/515 , D06P3/66 , C09B33/02 , C09B33/06
CPC分类号： C09B62/4411 , C09B62/513 , Y10S534/01
摘要： Water-soluble compounds and their salts suitable as dyestuffs of the formula ##STR1## in which D is a benzene or naphthalene nucleus, R.sub.1 and R.sub.2 are, inter alia, hydrogen, halogen, lower alkyl, lower alkoxy and sulfo, R.sub.1 being in ortho-position to the azo group, X is a fiber-reactive radical of the vinyl sulfone series, K.sub.1 and K.sub.2 are radicals of coupling components of the acetoacetarylide and pyrozolone series and K.sub.2 additionally denotes a radical of the sulfonaphthol series, the coupling components being bound to the triazine ring via amino groups, Y is a halogen atom, a sulfo group, a thio ether or oxygen ether radical, or a primary, secondary or tertiary amino group, A is an aliphatic, aliphatic-heterocyclic, aliphatic-aromatic or aromatic bridge member and n is zero or one. The novel compounds are prepared, for example, by reacting 2 mols of the diazo component with the fiber-reactive radical of the vinyl sulfone series with 1 mol of a bivalent coupling component containing the two radicals K.sub.1 and K.sub.2 linked to each other by the triazine ring, or 2 triazine radicals linked with each other by bridge member A; or by reacting one mol each of a monoazo compound consisting of the said diazo component with the fiber reactive radical and a coupling component K.sub.1 or K.sub.2 with a corresponding triazine radical additionally carrying a halogen atom capable of reacting with the amino group. The metal-free compounds can be transformed into the corresponding heavy metal complex, preferably copper, cobalt and chromium complex compounds, by treatment with an agent donating a heavy metal cation. The novel compounds are excellently suitable for dyeing and printing fiber material of natural and regenerated cellulose and natural, regenerated and synthetic polyamides. They are distinguished by high tinctorial strength, a very good uptake from a long liquor, a good color-build up. The dyeings and prints obtained therewith have a high fastness to processing and in use.

4. 发明授权

US4242258A Water-soluble dyestuffs, processes for their manufacture, their use as fiber-reactive dyestuffs for dyeing and printing fiber materials and the fiber materials dyed with these dyestuffs 失效
标题翻译：水溶性染料，其制造方法，用作染色和印花纤维材料的纤维活性染料和用这些染料染色的纤维材料
公开(公告)号：US4242258A
公开(公告)日：1980-12-30
申请号：US13308
申请日：1979-02-21
申请人： Walter Noll , Fritz Meininger , Ernst Hoyer
发明人： Walter Noll , Fritz Meininger , Ernst Hoyer
IPC分类号： C09B62/513 , D06P3/66 , C09B31/30 , C09B33/00 , C09B35/00
CPC分类号： C09B62/513
摘要： Water-soluble dyestuffs are described which in the acid form possess the formula ##STR1## wherein D is a benzene or naphthalene nucleus, R.sub.1 is linked to D in ortho-position to the azo group and means hydrogen, halogen, lower alkoxy, lower alkyl, carboxy or sulfo, R.sub.2 is hydrogen, halogen, lower alkyl, lower alkoxy or sulfo and X is the vinyl group or a sulfato-, chloro- or thiosulfatoethyl group, A is a bridging member preferably selected from the diphenylene, diphenylsulfone and diphenylamine series, Z and Z.sup.1 each represent a hydroxy or amino group with the proviso that each Z and each Z.sup.1 have the same meaning. These novel dyestuffs are prepared by diazotization and coupling of the corresponding diazo and coupling components in usual manner known in the art. The novel dyestuffs possess a very valuable fiber-reactivity and are suitable for dyeing natural and regenerated cellulose or natural, regenerated or synthetic polyamide fiber materials. They can easily be applied and fixed by application methods usual and known in the art, and yield on these fiber materials dyeings and prints which possess good fastnesses, especially fastnesses to light, to washing, to perspiration and to cross-dyeing. Their fixation degree on the fiber material and correspondingly their tinctorial strength are outstanding.
摘要翻译：描述了水溶性染料，其酸形式具有下式：其中D是苯或萘核，R1在与偶氮基的邻位连接到D，并且是指氢，卤素，低级烷氧基，低级烷基，羧基或磺基，R 2为氢，卤素，低级烷基，低级烷氧基或磺基，X为乙烯基或硫酸酯基，氯代或硫代硫代乙基，A为优选选自二亚苯基，二苯基砜和二苯胺系列，Z和Z1各自表示羟基或氨基，条件是每个Z和每个Z1具有相同的含义。这些新颖的染料通过本领域已知的通常方式的重氮化和相应的重氮和偶合组分的偶联来制备。新型染料具有非常有价值的纤维反应性，适用于染色天然和再生纤维素或天然，再生或合成聚酰胺纤维材料。它们可以通过本领域通常和已知的应用方法容易地施加和固定，并且对这些具有良好牢度，特别是耐光性，耐洗涤，出汗和交叉染色的纤维材料染色和印花产率。它们对纤维材料的固着度和相应的着色力都非常出色。

5. 发明授权

US4939243A Water-soluble copper complex disazo compounds containg a chloro triazinylamino group and a group of the vinylsulfone series as fiber-reactive groups and their dyestuffs 失效
标题翻译：包含氯三嗪基氨基和一组乙烯基砜系列的水溶性铜络合物双偶氮化合物作为纤维反应性基团及其染料
公开(公告)号：US4939243A
公开(公告)日：1990-07-03
申请号：US702687
申请日：1985-02-20
申请人： Fritz Meininger , Ernst Hoyer
发明人： Fritz Meininger , Ernst Hoyer
IPC分类号： C09B62/095 , C09B62/44 , C09B62/515 , D06P1/384 , D06P3/24 , D06P3/66
CPC分类号： C09B62/4416
摘要： Water-soluble copper complex disazo compounds with fiber-reactive dyestuff properties of the general formula ##STR1## in which m and n are the number zero or 1;the group --SO.sub.2 Y is bonded in the 5-position to the benzene nucleus if n is zero, or in the 4-position if n is zero or 1;the free azo can be bonded to the 6'-or 7'-position of the central naphthalene nucleus;if m is 1, this sulfo is bonded in the 5'-position if the azo is in the 6'-position, and is bonded in the 6'-position if the azo is in the 7'-position;X is chlorine, bromine, ##STR2## in which R.sup.1 represents optionally substituted alkyl with 1 to 4 carbon atoms, optionally substituted aryl or hydrogen,R.sup.2 is optionally substituted alkyl with 1 to 4 carbon atoms or optionally substituted aryl,R.sup.3 is hydrogen or optionally substituted alkyl with 1 to 4 carbon atoms andR.sup.4 is hydrogen, cycloalkyl which is optionally subsituted by 1 to 3 methyl, optionally substituted alkyl with 1 to 4 carbon atoms or optionally substituted aryl, orR.sup.3 and R.sup.4, as alkylene radicals with 1 to 4 carbon atoms together with the nitrogen atom and optionally an oxygen, sulfur or nitrogen atom as a further hetero-atom, form a heterocyclic six-membered radical;Y is vinyl or of the formula--CH.sub.2 --CH.sub.2 --R in whichR is a radical which can be eliminated under alkaline conditions; andM is hydrogen or the equivalent of a metal.
摘要翻译：水溶性铜络合物双偶氮化合物，其具有通式 + TR 的纤维反应性染料性质，其中m和n为数字0或1; 如果n为0，则基团-SO 2 Y在5位上键合到苯核，如果n为0或1，则在4位上键合; 游离偶氮可以结合到中心萘核的6'或7'位; 如果m为1，如果偶氮在6'位，则该磺基键合在5'位，如果偶氮位于7'-位，则其键合在6'位; X是氯，溴，其中R 1表示任选取代的具有1至4个碳原子的烷基，任选取代的芳基或氢，R 2是任选取代的具有1至4个碳原子的烷基或任选取代的芳基，R 3是氢或任选地具有1至4个碳原子的取代烷基，R 4为氢，任选被1至3个甲基，任选取代的具有1至4个碳原子的烷基或任选取代的芳基或R 3和R 4取代的环烷基，其具有1至4个亚烷基碳原子和氮原子以及任选的氧，硫或氮原子作为另外的杂原子形成杂环六元基; Y是乙烯基或式-CH 2 -CH 2 -R，其中R是在碱性条件下可被除去的基团; M为氢或相当于金属。

6. 发明授权

US4334076A Process for the preparation of sulfuric acid semiester ethylsulfonyl compounds of aminophenols, aminobenzanilides or phenylpyrazolones by esterification with sulfuric acid and/or sulfur trioxide in a kneader 失效
标题翻译：在捏合机中用硫酸和/或三氧化硫酯化制备氨基苯酚，氨基苯甲酰苯胺或苯基吡唑啉的硫酸半酯乙基磺酰基化合物的方法
公开(公告)号：US4334076A
公开(公告)日：1982-06-08
申请号：US820884
申请日：1977-08-01
申请人： Hans H. Steuernagel , Ernst Hoyer , Fritz Meininger
发明人： Hans H. Steuernagel , Ernst Hoyer , Fritz Meininger
IPC分类号： C07D231/24 , C07D231/26 , C07D231/46 , C09B62/507 , C07C139/00 , C07C139/10 , C07D231/02 , C07D231/34
CPC分类号： C09B62/507 , C07D231/24 , C07D231/26 , C07D231/46
摘要： An improved and novel process had been found for the esterification of aminophenol, amino-benzanilide and pyrazolone compounds containing a .beta.-hydroxyethylsulfonyl group, by means of sulfuric acid or sulfur trioxide which improvement is characterized by that the esterification is performed in a machine which is operating with a kneading action and effect, using per mol .beta.-hydroxyethylsulfonyl compound 1 to 2.5 times the equivalent molar amount of concentrated sulfuric acid, oleum or sulfur trioxide. This novel process has the great advantage that great amounts of sulfuric acid are saved which could charge the waste water, also in form of sodium sulfate formed after the required neutralization. Furthermore, the .beta.-sulfatoethylsulfonyl compounds formed as end-products in the esterification process are prepared by this novel process in higher yields, in a higher degree of esterification rate and in a higher purity. They are obtained in form of a powder or plastic mass from the kneading machine, which is well transportable and storable, and can advantageously used in the form of this consistency, without intermediate isolation of the pure .beta.-sulfato compound itself, directly for the preparation of azo dyestuffs which are poor of inert salts, possess a high tinctorial strength and purity.
摘要翻译：已经发现通过硫酸或三氧化硫酯化氨基苯酚，氨基 - 苯甲酰苯胺和含有β-羟基乙基磺酰基的吡唑啉酮化合物的改进和新方法，其改进的特征在于酯化是在机器中进行的，以混合作用和效果操作，使用每摩尔β-羟乙基磺酰化合物1倍至2.5倍于当量摩尔浓度的浓硫酸，发烟硫酸或三氧化硫。这种新方法具有很大的优点，可以节省大量的硫酸，这可以在所需中和后形成的硫酸钠形式对废水进行充电。此外，在酯化过程中形成作为终产物的β-磺基乙基磺酰基化合物通过该新方法以更高的收率，更高的酯化速率和更高的纯度制备。它们是由捏合机形式的粉末或塑料块形成的，该混合机具有良好的可运输和储存性能，并且可有利地以这种稠度的形式使用，而不用直接用于制备的纯β-硫酸酯化合物本身的中间分离的惰性盐不良的偶氮染料具有高的着色强度和纯度。

7. 发明授权

US4730038A Water-soluble disazo compounds of 1-amino-8-naphthal-3,6- or 4,6-disulfonic acid as bivalent coupling component, containing fiber-reactive groups suitable as dyestuffs 失效
公开(公告)号：US4730038A
公开(公告)日：1988-03-08
申请号：US811303
申请日：1985-12-16
申请人： Fritz Meininger , Ernst Hoyer , Rudolf Fass
发明人： Fritz Meininger , Ernst Hoyer , Rudolf Fass
IPC分类号： C09B62/513 , C07C245/10 , C07C303/22 , C09B62/09 , C09B62/44 , D06P1/382 , D06P1/384
CPC分类号： C09B62/09 , C09B62/4415
摘要： Water-soluble disazo compounds having fiber-reactive dyestuff properties of the general formula (1) ##STR1## in which D.sub.1 and D.sub.2 are identical or different and each represents a phenyl radical or a naphthyl radical, both of which are substituted by a group of the formula moiety Y or formula moiety Z defined below and can additionally be substituted by one or two substituents from the group comprising sulfo, chlorine, bromine, lower alkyl and lower alkoxy, Z is a group of the formula (2a), (2b), (2c), (2d), (2e) or (2f) ##STR2## in which R denotes an alkyl group having 1 to 4 C atoms and X denotes a chlorine atom, the acetoxy group, the thiosulfate group, the phosphate group or the sulfato group; Y is a radical of the formula (3) ##STR3## in which R.sup.1 and R.sup.2 are identical to or different from one another and each denotes hydrogen or alkyl having 1 to 4 C atoms, and A is hydrogen or an optionally substituted alkyl group having 1 to 6 C atoms or a radical of the formula (4)--B--Z (4)in which B is the phenylene radical or a naphthylene radical, both of which can be substituted by one or two substituents chosen from the set comprising a sulfo group, a chlorine atom, one or two methyl or ethyl groups and one or two methoxy or ethoxy groups, and Z has the abovementioned meaning; n is the number 1 or 2 and m is the number zero or 1, and the sum (m+n) is equal to 2, and M denotes hydrogen or the equivalent of a metal, preferably sodium or potassium; the compounds of the general formula (1) must contain at least three radicals selected from those of formulae (2a) to (2f) defined above and from the group of formula ##STR4## The compounds of the general formula (1) produce, for example on cellulose fiber materials, wool and synthetic polyamide fiber materials, fast and intensely colored, navy to black dyeings and prints.

8. 发明授权

US4622390A Water-soluble disazo compounds containing an amino naphthol-disulfonic acid moiety as a coupling component and fibre-reactive groups 失效
标题翻译：含有氨基萘酚 - 二磺酸部分作为偶联成分的水溶性双偶氮化合物和纤维反应性基团
公开(公告)号：US4622390A
公开(公告)日：1986-11-11
申请号：US774171
申请日：1985-09-09
申请人： Fritz Meininger , Ernst Hoyer , Joachim W. Otten, deceased , by Ursula Otten, heir , by Anna G. Rudolph nee Otten, heir , Rudolf Fass
发明人： Fritz Meininger , Ernst Hoyer , Joachim W. Otten, deceased , by Ursula Otten, heir , by Anna G. Rudolph nee Otten, heir , Rudolf Fass
IPC分类号： C09B62/513 , C09B62/09 , C09B62/44 , D06P1/38 , C09B62/453 , C09B62/533 , D06P1/382
CPC分类号： C09B62/09 , C09B62/4415
摘要： Water-soluble disazo dyestuffs of the formula ##STR1## which contain a 1-amino-8-naphthol-3,6- or -4,6-disulfonic acid moiety as a bivalent coupling component and which contain diazo components with fibre-reactive groups characterized by the inclusion of one or two chloro-triazinyl groups and one or two of the six groups defined by the substituent Z, namely, ##STR2## each of which are connected to the benzene moiety of the diazo component; the chloro-triazinyl group is further substituted by a substituted or unsubstituted phenylamino or substituted or unsubstituted naphthylamino group, a substitutent of which may be one of the six groups defined by the Z substituent; if there is only one chloro-triazinyl group in the compound, then the diazo component is also substituted by one of the Z substituents; these compounds are dyestuffs which exhibit a good fixation degree of the dyestuffs in fabrics.
摘要翻译：含有作为二价偶联组分的1-氨基-8-萘酚-3,6-或-4,6-二磺酸部分并含有具有纤维反应性基团的重氮组分的式“IMAGE”的水溶性双偶氮染料其特征在于包含一个或两个氯 - 三嗪基和由取代基Z限定的六个基团中的一个或两个，即，＆lt; IMAGE＆gt; CH2SO2CH2CH2OSO3H; SO2CHCH2; + TR＆lt; IMAGE＆gt;各自与重氮组分的苯部分相连; 氯代三嗪基进一步被取代或未取代的苯基氨基或取代或未取代的萘基氨基取代，其取代基可以是由Z取代基限定的六个基团之一; 如果化合物中只有一个氯三嗪基，则重氮组分也被Z取代基之一取代; 这些化合物是在织物中表现出良好的染料固着度的染料。

9. 发明授权

US4323497A Water-soluble disazo dyestuffs 失效
标题翻译：水溶性双偶氮染料
公开(公告)号：US4323497A
公开(公告)日：1982-04-06
申请号：US956322
申请日：1978-10-31
申请人： Ernst Hoyer , Fritz Meininger , Rudolf Fass
发明人： Ernst Hoyer , Fritz Meininger , Rudolf Fass
IPC分类号： C09B62/44 , C09B62/513 , D06P3/66 , C09B45/00 , C09B29/22
CPC分类号： C09B62/513 , C09B62/4411
摘要： The novel water-soluble disazo dyestuffs consist of two monoazo dyestuff moieties each containing as diazo component an amine of the benzene or naphthalene series and as coupling component an amino-naphthol-mono- or disulfonic acid. The two moieties are bonded to each other via a bridge member bound to the amino groups of the coupling components and comprising two triazine radicals each containing a halogen atom, a sulfonic acid group or a thio ether or oxygen ether group or an amino group and the diazo components contain a fiber-reactive radical of the vinyl sulfone series. The metal-free dyestuffs can be transformed into the corresponding heavy metal complex dyestuffs, preferably copper, cobalt and chromium complex dyestuffs, by treatment with an agent donating a heavy metal cation. The novel dyestuffs are excellently suitable for dyeing and printing fiber material of natural and regenerated cellulose and natural, regenerated and synthetic polyamides. They are distinguished by a high tinctorial strength, a very good uptake from a long liquor, a good color- build up and good printing properties. The dyeings obtained therewith have a high fastness to processing and in use.
摘要翻译：新型水溶性双偶氮染料由两种单偶氮染料组成，每个单偶氮染料部分含有作为重氮组分的苯或萘系的胺，作为偶联组分为氨基萘酚单 - 或二磺酸。两个部分通过结合到偶联组分的氨基的桥连构件彼此键合，并且包含两个各自含有卤素原子，磺酸基或硫醚或氧醚基或氨基的三嗪基，重氮组分含有乙烯基砜系列的纤维反应性基团。通过用赋予重金属阳离子的试剂处理，无金属染料可以转化成相应的重金属络合物染料，优选铜，钴和铬复合染料。新型染料非常适用于天然和再生纤维素以及天然，再生和合成聚酰胺的染色和印花纤维材料。它们的特征在于高着色力，从长酒中吸收很好，色泽良好，印刷性能好。由此获得的染色具有高的加工牢度和使用性。

10. 发明授权

US4370145A Copper formazan compounds, processes for their preparation and their use as dyestuffs 失效
公开(公告)号：US4370145A
公开(公告)日：1983-01-25
申请号：US324871
申请日：1981-11-25
申请人： Gunther Schwaiger , Ernst Hoyer
发明人： Gunther Schwaiger , Ernst Hoyer
IPC分类号： C09B62/503 , C09B62/50 , C09B50/00
CPC分类号： C09B62/5036
摘要： New copper-complex formazan compounds of the general formula: ##STR1## in which A is a phenylene or naphthylene radical which can be substituted by halogen, nitro, lower alkyl, lower alkoxy, lower alkylsulfonyl, phenylsulfonyl and optionally alkylated sulfonamide groups and can also be substituted by the radical Z, defined below, B is a straight-chain or branched-chain alkyl group or alkenyl group, which can be substituted by an optionally substituted phenyl radical, or is a phenyl or naphthyl radical, which can be substituted by halogen, lower alkyl, lower alkoxy and lower carbalkoxy, or is the radical or a furan, thiophene, pyrrole, imidazole, indole, pyrazole, pyridine, pyrimidine, quinoline or benzimidazole, it being possible for B likewise to be substituted by the group Z, defined below, Z denotes a group which confers solubility in water, such as the carboxyl group or sulfo group, one to three of which are bonded to A and/or B, Cu is a copper atom, X denotes an oxygen atom or a carbonyloxy group and is bonded to A in the ortho-position relative to the nitrogen atom, Y represents the vinyl or .beta.-thiosulfatoethyl group and M denotes a hydrogen atom or the equivalent of a metal. The new copper-complex formazan compounds can be prepared in a manner which is in itself customary, for example by reacting an aromatic hydrazone compound of the general formula: ##STR2## in which A, B, X and Z have the abovementioned meaning, with the diazonium compound of an aromatic amine of the general formula: ##STR3## in which M and Y have the abovementioned meaning, and with an agent which donates copper. The new copper-complex formazan compounds have valuable dyestuff properties and are particularly suitable as fiber-reactive dye-stuffs for dyeing, for example, cellulose fiber materials, wool and synthetic polyamide fibers, on which they give strong reddish-tinged to greenish-tinged blue or clear blue dyeings with good fastness to light and wet processing.

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