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    • 1. 发明授权
    • Process for the preparation of stable mixtures of bitumen and polymer
    • 制备沥青和聚合物稳定混合物的方法
    • US5756563A
    • 1998-05-26
    • US565810
    • 1995-11-30
    • Ernesto BrandoleseLuigi D'EliaPaolo ItaliaNicola Onorati
    • Ernesto BrandoleseLuigi D'EliaPaolo ItaliaNicola Onorati
    • C08J3/00C08L53/00C08L95/00C10C3/00E01C7/26C08J3/22
    • E01C7/265C08J3/005C08L95/00
    • Mixtures of bitumen and thermoplastic polymer stable to storage are prepared by a process comprising: (i) mixing a bituminous product having a content of total asphaltenes, resins, saturated and aromatic products which satisfies the condition that the I.sub.c value is between 0.200 and 0.270 in the expression: I.sub.c =(C7+C5+S)/(A+R) with a thermoplastic polymer, the reaction being carried out at a temperature of between 160.degree. C. and 200.degree. C. and for a time of between 15 and 120 minutes and (ii) diluting the bituminous composition obtained in (i) with a bitumen or bituminous component having an I.sub.c defined as specified above in (i) of between 0.270 and 0.700 in such a quantity that the final concentration of the polymer is between 2.5 and 15% by weight, and heating to a temperature of between 160.degree. C. and 200.degree. C. for a time of between 30 and 90 minutes.
    • 稳定储存的沥青和热塑性聚合物的混合物通过以下方法制备,该方法包括:(i)混合具有总沥青质含量,沥青,饱和和芳香族产物的沥青产品,其满足Ic值在0.200至0.270之间的条件 表达式:Ic =(C7 + C5 + S)/(A + R)与热塑性聚合物,反应在160℃和200℃之间的温度下进行,时间介于15和 120分钟,和(ii)将(i)中得到的沥青组合物用在(i)中定义的具有如上述(i)中所定义的Ic的沥青或沥青组分以0.270至0.700之间的量稀释,使得聚合物的最终浓度介于 2.5至15重量%,并加热至160℃至200℃的温度,时间为30至90分钟。
    • 2. 发明申请
    • BITUMINOUS MIXTURES WITH A HIGH POLYMER CONTENT
    • 具有高聚合物含量的BITUMINOUS混合物
    • US20110257308A1
    • 2011-10-20
    • US13128353
    • 2009-11-05
    • Paolo ItaliaLuigi D'Elia
    • Paolo ItaliaLuigi D'Elia
    • C08L95/00
    • C08J3/226C08J2391/06C08J2495/00C08L95/00C08L2555/72C08L2555/84C08L2666/02C08L91/06C08L53/02
    • The invention relates to a process for the preparation of mixtures containing bitumen and thermoplastic polymer at a high concentration, stable during storage, with particular characteristics of easy processability and movability which, once diluted, allow modified bitumens to be obtained with high performance characteristics. In particular, the process allows mixtures containing bitumen, thermoplastic polymer and wax, to be prepared, wherein the polymer is in a quantity varying from 5 to 30% by weight with respect to the weight of the mixture consisting of bitumen and polymer, and the wax is in a quantity varying from 4.7 to 16.7% by weight with respect to the weight of the total mixture, and comprises reacting a concentrated mixture (A), stable during storage, containing bitumen and from 5 to 30% by weight of thermoplastic polymer, with a hydrocarbon wax containing at least 40 carbon atoms and having a melting point of at least 700 C, in a weight ratio between the mixture (A) and wax ranging from 100:5 to 100:20, at a temperature ranging from 160 to 2000 C and for a time ranging from 15 minutes to 7 hours, preferably from 15 to 120 minutes. An object of the invention also relates to new mixtures containing bitumen and thermoplastic polymer at a high concentration and mixtures obtainable from these by dilution.
    • 本发明涉及一种制备含有高浓度沥青和热塑性聚合物的混合物的方法,其在储存期间是稳定的,具有容易加工性和可移动性的特定特性,其一旦稀释,就可以获得具有高性能特征的改性沥青。 特别地,该方法允许制备含有沥青,热塑性聚合物和蜡的混合物,其中相对于由沥青和聚合物组成的混合物的重量,聚合物的量为5至30重量%,并且 相对于总混合物的重量,蜡的量为4.7至16.7重量%,并且包括在储存期间稳定的含有沥青的浓缩混合物(A)和5至30重量%的热塑性聚合物 ,含有至少40个碳原子并且熔点至少为700℃的烃蜡,混合物(A)和蜡的重量比为100:5至100:20,温度范围为160 至2000℃,时间为15分钟至7小时,优选15至120分钟。 本发明的目的还涉及含有高浓度的沥青和热塑性聚合物的新混合物以及通过稀释从这些混合物获得的混合物。
    • 3. 发明授权
    • Bituminous mixtures with a high polymer content
    • 具有高聚合物含量的沥青混合物
    • US08697781B2
    • 2014-04-15
    • US13128353
    • 2009-11-05
    • Paolo ItaliaLuigi D'Elia
    • Paolo ItaliaLuigi D'Elia
    • C08L95/00
    • C08J3/226C08J2391/06C08J2495/00C08L95/00C08L2555/72C08L2555/84C08L2666/02C08L91/06C08L53/02
    • The invention relates to a process for the preparation of mixtures containing bitumen and thermoplastic polymer at a high concentration, stable during storage, with particular characteristics of easy processability and movability which, once diluted, allow modified bitumens to be obtained with high performance characteristics. In particular, the process allows mixtures containing bitumen, thermoplastic polymer and wax, to be prepared, wherein the polymer is in a quantity varying from 5 to 30% by weight with respect to the weight of the mixture consisting of bitumen and polymer, and the wax is in a quantity varying from 4.7 to 16.7% by weight with respect to the weight of the total mixture, and comprises reacting a concentrated mixture (A), stable during storage, containing bitumen and from 5 to 30% by weight of thermoplastic polymer, with a hydrocarbon wax containing at least 40 carbon atoms and having a melting point of at least 700 C., in a weight ratio between the mixture (A) and wax ranging from 100:5 to 100:20, at a temperature ranging from 160 to 2000 C. and for a time ranging from 15 minutes to 7 hours, preferably from 15 to 120 minutes. An object of the invention also relates to new mixtures containing bitumen and thermoplastic polymer at a high concentration and mixtures obtainable from these by dilution.
    • 本发明涉及一种制备含有高浓度沥青和热塑性聚合物的混合物的方法,其在储存期间是稳定的,具有容易加工性和可移动性的特定特性,其一旦稀释,就可以获得具有高性能特征的改性沥青。 特别地,该方法允许制备含有沥青,热塑性聚合物和蜡的混合物,其中相对于由沥青和聚合物组成的混合物的重量,聚合物的量为5至30重量%,并且 相对于总混合物的重量,蜡的量为4.7至16.7重量%,并且包括在储存期间稳定的含有沥青的浓缩混合物(A)和5至30重量%的热塑性聚合物 具有至少40个碳原子并且熔点至少为700℃的烃蜡,混合物(A)和蜡的重量比为100:5至100:20,温度范围为 160至2000℃,时间为15分钟至7小时,优选15至120分钟。 本发明的目的还涉及含有高浓度的沥青和热塑性聚合物的新混合物以及通过稀释从这些混合物获得的混合物。